FINAL JEE–MAIN EXAMINATION – AUGUST, 2021

(Held On Thursday 26th August, 2021) TIME : 3 : 00 PM to 6 : 00 PM

CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A Sol. Photochemical smog causes cracking of rubber, the
1. Which one of the following phenols does not give common component of photochemical smog are
colour when condensed with phthalic anhydride in ozone, nitric oxide, acrolein, formaldehyde and
presence of conc. H2SO4 ? peroxyacetyle nitrate (PAN).
OH 3. The interaction energy of London forces between
(1)
two particles is proportional to rx, where r is the
OH distance between the particles. The value of x is :
(1) 3 (2) –3
(2)
(3) –6 (4) 6
CH3 Official Ans. by NTA (3)
OH
Sol. For london dispersion forces.
(3)

OH
OH
EN E
1
r6
Hence x = –6
OH
4. The number of non-ionisable hydrogen atoms
(4)
present in the final product obtained from the
LL
Official Ans. by NTA (2) hydrolysis of PCl5 is :
Sol. Only p-methyl, phenol does not give any colour (1) 0 (2) 2 (3) 1 (4) 3
with phthalic anhydroxide with cons. H2SO4. Official Ans. by NTA (1)
2. Given below are two statements : one is labelled as Sol. PCl5 + H2O  POCl3 + 2HCl
A

Assertion (A) and the other is labelled as Reason (R). + 3H2O

Assertion (A) : Photochemical smog causes
cracking of rubber. H3PO4 + 3HCl
O
Reason (R) : Presence of ozone, nitric oxide,
acrolein, formaldehyde and peroxyacetyl nitrate in In P + HCl
O O
photochemical smog makes it oxidizing. H O
H H
Choose the most appropriate answer from the
all hydrogens are ionisable
options given below :
 Ans is zero.
(1) Both (A) and (R) are true but (R) is not the
5. The bond order and magnetic behaviour of O 2 ion
true explanation of (A)
are, respectively :
(2) (A) is false but (R) is true. (1) 1.5 and paramagnetic
(3) (A) is true but (R) is false (2) 1.5 and diamagnetic
(4) Both (A) and (R) are true and (R) is the true (3) 2 and diamagnetic
explanation of (A) (4) 1 and paramagnetic
Official Ans. by NTA (4) Official Ans. by NTA (1)
1
Sol. O2  (1s )2 (1s* )2 (2s ) 2 (*2s ) 2 (2pz ) 2 H3O+
Sol. CH3–C–O–CH2CH3 CH3CO2H+CH3CH2OH

 2
2px  2
2py  
*2
2px 
*1
2py  O

10  7 CH3–C–O–CH3 DIBALH/H2O CH3CHO

Bond order = = 1.5 –78ºC
2 O
and paramagnetic SnCl2+HCl CH CH=O
CH3–CN 3
6. Given below are two statements : one is labelled as /H2O
Assertion (A) and other is labelled as Reason (R). O
Assertion (A) : Sucrose is a disaccharide and a CH3MgBr (1eq)
CH3–CN
non-reducing sugar. /H3O+
8. Given below are two statements : one is labelled as
Reason (R) : Sucrose involves glycosidic linkage
between C1 of -glucose and C2 of -fructose. Assertion (A) and the other is labelled as Reason
Choose the most appropriate answer from the (R).
options given below : Assertion (A) : Barium carbonate is insoluble in
(1) Both (A) and (R) are true but (R) is not the true water and is highly stable.
explanation of (A) Reason (R) : The thermal stability of the
(2) (A) is false but (R) is true.
EN carbonates increases with increasing cationic size.
(3) (A) is true but (R) is false
(1) Both (A) and (R) are true but (R) is the true
(4) Both (A) and (R) are true and (R) is the true
explanation of (A)
explanation of (A)
(2) (A) is true but (R) is false
Official Ans. by NTA (3)
(3) Both (A) and (R) are true and (R) is not the
Sol. Surcrose is example of disaccharide & non
true explanation of (A)
LL
reducing sugar
Assertion : correct (4) (A) is false but (R) is true.
Sucrose involves glycosidic linkage between C1 of Official Ans. by NTA (1)
-D-glucose C2 of -D-fructose
Sol. In IIA group on moving down the group size of
Reason : Incorrect
cation increases and show thermal stability of
A

7. Match List-I with List-II : carbonate increases.

List-I List-II NH2
(Chemical Reaction) (Reagent used)

(a) CH3COOCH2CH3 CH3CH2OH 

(CH3CO)2 O
(i) CH3MgBr / H3O+ 9. NH2
P
(Major product)
(1.equivalent)
(b) CH3COOCH3  CH3CHO O
(ii) H2SO4 / H2O
The major product in the above reaction is :
(c) CH3C N  CH3CHO NHCOCH3 NH2
(iii) DIBAL-H/H2O
O

(d) CH3C  N  CH3 CH3 (1) (2)

(iv) SnCl2, HCl/H2O NHCOCH3 NHCOCH3

Choose the most appropriate match : O O


(1) a-ii, b-iv, c-iii, d-i NH3CH3COO–
NHCOCH3

(2) a-iv, b-ii, c-iii, d-i

(3) a-ii, b-iii, c-iv, d-i (3) NHCOCH3 (4)
NH2
(4) a-iii, b-ii, c-i, d-iv O
O
Official Ans. by NTA (3) Official Ans. by NTA (4)
2
 NH2 NH–C–CH3 Sol. Sphalerite-ZnS, copper glance - Cu2S two sulphide
O ores can be separated by adjusting proportions of
Ac2O
Sol. NH2 (CH CO) O NH2 oil to water or by using ' Depressants '
3 2

O O 13. Given below are two statements : one is labelled as

10. Indicate the complex/complex ion which did not Assertion (A) and the other is labelled as Reason
show any geometrical isomerism : (R).
(1) [CoCl2(en)2] (2) [Co(CN)5(NC)]3– Assertion (A) : Heavy water is used for the study
(3) [Co(NH3)3(NO2)3] (4) [Co(NH3)4Cl2]+ of reaction mechanism.
Official Ans. by NTA (2) Reason (R) : The rate of reaction for the cleavage
Sol. (1) [CoCl2(en)2] show of O - H bond is slower than that of O-D bond.
Cis-trans isomerism Choose the most appropriate answer from the
(2) [Co(CN)5(NC)]–3 can't options given below :
Show G.I.
(1) Both (A) and (R) are true but (R) is not the true
(3) [Co(NH3)3(NO2)3]
explanation of (A).
Show fac & mer isomerism
(4) [Co(NH3)4Cl2] show cis & trans isomerism (2) Both (A) and (R) are true and (R) is the true
11. The sol given below with negatively charged
colloidal particles is :
EN explanation of (A).
(3) (A) is false but (R) is true.
(1) FeCl3 added to hot water (4) (A) is true but (R) is false.
(2) KI added to AgNO3 solution Official Ans. by NTA (4)
(3) AgNO3 added to KI solution Sol. D2O in used for the study of reaction mechanism.
LL

(4) Al2O3.xH2O in water Rate of reaction for the cleavage of O–H bond >

Official Ans. by NTA (3) O-D bond.

14. Arrange the following Cobalt complexes in the
Sol.
12. Given below are two statements : order of increasing Crystal Field Stabilization
A

Statement I : Sphalerite is a sulphide ore of zinc Energy (CFSE) value.

and copper glance is a sulphide ore of copper. Complexes : [CoF6 ]3 ,[Co(H 2 O)6 ]2  ,[Co(NH 3 )6 ]3
A B C

Statement II : It is possible to separate two

and[Co(en)3 ]3
sulphide ores by adjusting proportion of oil to
Choose the correct option :
water or by using 'depressants' in a froth flotation
(1) A < B < C < D (2) B < A < C < D
method.
(3) B < C < D < A (4) C < D < B < A
Choose the most appropriate answer from the
Official Ans. by NTA (2)
options given below :
Sol. (i) CFSE  charge or oxidation no. of central metal
(1) Statement I is true but Statement II is false.
ion.
(2) Both Statement I and Statement II are true.
(ii) CFSE  strength of ligand
(3) Statement I is false but Statement II is true.
en > NH3 > H2O > F–
(4) Both Statement I and Statement II are false.  order of CFSE
Official Ans. by NTA (2) III III III II
[Co(en)3 ]3  Co(NH 3 )6 ]3  [CoF6 ]3  [Co(H 2 O) 6 ]2

3
15. H 18. The number of stereoisomers possible for 1,2-
N dimethyl cyclopropane is :
N=C CH3
H (1) One (2) Four
C
+ (3) Two (4) Three
Cl C=N H
Official Ans. by NTA (4)
O–

Sol. + +
Chlordiazepoxide
The class of drug to which chlordiazepoxide with A B C
above structure belongs is :
(1) Antacid (2) Analgesic
(3) Tranquilizer (4) Antibiotic O OH
"X" CN
Official Ans. by NTA (3) H HCN,H O H
2
19.
Sol. The drug named chlordiate poxide is example of 
tranquilizer. "Y" LiAlH4
+
(Major Product) H3O
16. Chalcogen group elements are :
(1) Se, Tb and Pu.
(3) S, Te and Pm.
(2) Se, Te and Po.
(4) O, Ti and Po.
EN Consider the given reaction, Identify 'X' and 'Y' :
OH
NH
Official Ans. by NTA (2) (1) X – NaOH Y – H
Sol. Group 16/oxygen family is known as Chalcogens OH
the members are O, S, Se, Te, Po
(2) X – HNO3 Y –
LL
H NH2
17. Which one of the following compounds is not
OH
aromatic ?
(3) X – NaOH Y –
(1) (2) H NH2
OH
A
:

 
NH2
(4) X – HNO3 Y –
H
: :

O
H
(3) (4) Official Ans. by NTA (3)
Sol.
Official Ans. by NTA (3) O OH
NaOH(x)
Sol. : Non aromatic H HCN/H2O CN
H
X NaOH
OH All are LiAlH4


; ; aromatic OH OH
Y NH2 NH2
(+)
H H
(major product)

4
 O OR
Br2
AlBr3(C2H5)2O
'A' O.C.  BaSO4
WOC 0.471g 1.44g
(Major product)
20.
1.44
Consider the given reaction, the product A is :  ns = n BaSO 4 
233
O
O Br 1.44
 ws   32g
233
(1) (2)
Br
Ws 1.44  32
therefore %S   100   100
WO.C. 233  0.471
O O 46.08
  100  41.98 42
109.743
(3) (4)
Br 2. The equilibrium constant Kc at 298 K for the
Br
reaction A + B C+D
Official Ans. by NTA (3) is 100. Starting with an equimolar solution with
O concentrations of A, B, C and D all equal to 1M,
CH2–CH2–CH2–CH3 the equilibrium concentration of D is_____ × 10–2
Sol.
(m–directing)
EN M. (Nearest integer)

Official Ans. by NTA (182)

Br2+AlBr3(El2O)
Sol. A + B C + D : Keq = 100
O 1M 1M 1M 1M
First check direction of reversible reaction.
LL

[C][D]
Since QC =  1 < Keq.  reaction will
Br [A][B]
move in forward direction to attain equilibrium
SECTION-B
state.
A

1. In the sulphur estimation, 0.471 g of an organic  A + B C + D : Keq = 100

compound gave 1.44 g of barium sulphate. The to 1 1 1 1
teq. 1–x 1–x 1+x 1+x
percentage of sulphur in the compound is _____%.
  
(Nearest integer) Now : Keq = 100 = 1  x 1  x
1  x 1  x 
(Atomic Mass of Ba = 137 u) 1 x 
2
 100   
Official Ans. by NTA (42) 1 x 
1 x 
Sol. Molecular mass of BaSO4 = 233 g (i) 10 =  
1 x 
 233 BaSO4 contain  32 g sulphur  10 – 10x = 1+x
 11 x = 9
32
1.44 g BaSO4 contain  × 1.44 g sulphur 9
233  x
11
 given : 0.471 g of organic compound
1 x
32  1.44 (ii) –10 =
% of S = × 100 = 41.98%  42% 1 x
233  0.471
 –10 + 10x = 1 + x

5
  –9x = –11 hc 1
  h0  mv 2
 2
11
 x 6.63  10 34  3  108 1
9   6.63  10 34  4.3  1014  mv 2
500  10 9 2
 'x' cannot be more than one, therefore not valid.
.63  30  10 20 1
therefore equation concretion of (D) = 1 + x   6.63  4.3  10 20  mv 2
5 2
9 20
1  1
11 11  11.271 × 10–20 J = × 9 × 10–31 × 2
2
= 1.8181 = 181.81 × 10–2
182 × 10–2    5 105 m / sec.
3. For water vap H = 41 kJ mol–1 at 373 K and 1 bar 5. For the galvanic cell,
pressure. Assuming that water vapour is an ideal
Zn(s) + Cu2+ (0.02 M)  Zn2+ (0.04 M) + Cu(s),
gas that occupies a much larger volume than liquid
water, the internal energy change during Ecell =_______ × 10–2 V. (Nearest integer)
evaporation of water is_____kJ mol–1 0 0
[Use : E Cu /Cu 2 = –0.34 V, E Zn / Zn 2 =+0.76 V,
[Use : R = 8.3 J mol–1 K–1]
2.303 RT
Official Ans. by NTA (38) = 0.059 V]
F
Sol. Given equation is
kJ
EN Official Ans. by NTA (109)
H2O()  H2O(g) : H = 41 Sol. Galvanic cell:
mol
2
Zn (s)  Cu (aq.)  Zn 2  Cu(s)
 From the relation : H = U + ngRT 0.02M
0.04 M

kJ 8.3 0.059 [2n 2 ]

 U  (1)   373
LL
 41 Nernst equation = Fcell = Eocell  log
mol 1000 2 [Cu 2 ]
 DU = 41 – 3.0959
0.059 0.04
 E cell  E ocell  E oZn 2 / Zn   log
= 38 kJ/mol 2 0.02
4. A metal surface is exposed to 500 nm radiation. 0.059 2
 E cell  0.34   0.76   log
A

The threshold frequency of the metal for 2

photoelectric current is 4.3 × 1014 Hz. The velocity 0.059

 E cell 1  1   0.3010
2
of ejected electron is ________× 105 ms–1 (Nearest
= 1.0911 = 109.11 × 10–2
integer)
= 109
[Use : h = 6.63 × 10–34 Js, me = 9.0 × 10–31 kg] 6. 100 mL of Na3PO4 solution contains 3.45 g of
Official Ans. by NTA (5) sodium. The molarity of the solution is _____×10–2

e– mol L–1 . (Nearest integer)

=500nm
[Atomic Masses - Na : 23.0 u, O : 16.0 u, P : 31.0 u]

Official Ans. by NTA (50)

Sol.
Na3PO4 Na3PO4 3Na
Sol. 3.45g
 : speed of electron having max. K.E.
100ml Sol.
 from Einstein equation : E =  + K.E.max

6
 therefore molarity of Na3PO4 Solution =
n Na3 PO4
volume of solution in L
1 3.45
 mol 9. The reaction rate for the reaction
 3 23
0.1L
[PtCl4]2– + H2O [Pt(H2O)Cl3]– + Cl–
–2
= 0.5 = 50 × 10
was measured as a function of concentrations of
7. The overall stability constant of the complex ion
different species. It was observed that
[Cu(NH3)4]2+ is 2.1 × 1013. The overall
d  PtCl 4  
2
dissociations constant is y × 10–14. Then y is
  = 4.8 × 10–5  PtCl 2   –2.4 ×
____.(Nearest integer) dt  4


Official Ans. by NTA (5)

10–3  Pt(H2 O)Cl3   Cl –  .


 
Sol. Given kf = 2.1 × 1013
1 where square brackets are used to denote molar
Kd =  4.7  10 14
kf concentrations. The equilibrium constant

 y = 4.7  5
EN Kc=_____. (Nearest integer)

8. 83 g of ethylene glycol dissolved in 625 g of water. Official Ans. by NTA (50)

The freezing point of the solution is _______K. Sol. [PtCl4]–2 + H2O [Pt(H2O)Cl3]– + Cl–
(Nearest integer) d[Pt Cl 4 ]2
 4.8 × 10–5 [PtCl4–2] – 2.4 × 103
dt
[Use : Molal Freezing point depression constant of
LL
o
water = 1.86 K kg mol–1] [Pt(H2O)Cl3][ u ]
Freezing Point of water = 273 K k f 4.8  10 5
 K eq    0.02
k b 2.4  10 3
Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u]
10. A chloro compound "A".
A

Official Ans. by NTA (269)

(i) forms aldehydes on ozonolysis followed by the
Sol. kf = 1.86 k. kg/mol
hydrolysis.
Tfo = 273 k
solvent : H2O(625 g) (ii) when vaporized completely 1.53 g of A, gives
 CH2  CH 2  448 mL of vapour at STP.
Solute : 83 g  | |   Non dissociative
  The number of carbon atoms in a molecule of
 OH OH 
compound A is _______.
solute
 Tf = kf × m Official Ans. by NTA (3)
83 / 62 Sol. 448 ml of A  1.53 gm A
  Tfo  Tf1   1.86 
624 / 1000 1.53
22400 ml of A  × 22400 gm A = 7650
1.86  83  1000 154380 445
 273 – Tf1 = 
62  625 38750 O3
H3CHC–CH–Cl CH3–CH=O
 273 – T  4 It has 3 carbon atoms Zn /H2O
1
f Aldehyde

 Tf1  259 K & mm is 36 + 5 + 35.5 = 76.5