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CHEMISTRY FOR (I.I.T. J.E.E.) --By-Pa nka jAg a rw a l (B.Tech.I.I.T./K .)

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Assignment ON Chemical kinetics—4

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ES W
01M. The correct nature of plot for first order reaction is /are :

SE RW
AR SS AR
100%

AS GA
AG CLA AG
— log c 

KA 

S
CL J A
J

— c
50%
KA

AL
(a) (b)
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25%
N

SE RW
N
W
PA

t x 3x

PA
t

AS GA
S
S

CL J A
SE
J
PA 

KA
KA

AS

—dc
— 1/c

log
N dt
N
CL

PA
(c) (d)
o
where  = 45

t — log c
AL

AL
(2 - 2 ) 1/2
02. For a certain of order n, the time for half change, t1/2 is given by t1/2 = x C0 where
k
SE RW

W
k is constant and C0 is the initial concentration. What is n ?
AR
AL
A

(a) 1 (b) 2 (c) 0 (d) 0.5 .

AG

AG
W
S

S _2
03. for a reaction A  B + C the value of rate constant k = 2 x 10 mol / l—min. Which
SE
AR
J

J
KA

KA
AS

of the following is correct for the graph (conc. of B vs time) and t1/2 for the reaction, given
AS
AG

initial conc. of A is 0.04 M :

N
CL

SE

N
CL
J
PA

PA
KA

AS
N
CL

(a) , 60 sec (b) , 30 sec .

PA

(c) , 60 sec (d) , 30 sec .

04. A plot of ln rate Vs ln C for the nth order reaction gives :

(a) a straight line with slope n and intercept ln Kn

(b) a straight line with slope (n — 1) .

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(c) a straight line with slope ln kn and intercept ‘n’

ES W

SE RW
(d) a straight line with slope — n and intercept kn .

AR SS AR
05. The time for half-life period of a certain reaction , A  Product is 1 hour. When the initial

AS GA
AG CLA AG _1
concentration of the reactant ‘A’ is 2 mol L , how much time does it take for its concentration

S
CL J A
_1
J

to come from 0.50 to 0.25 mol L if it is a zero order reaction ?

KA

AL
KA
(a) 0.25 h
AL (b) 1 h
N

SE RW
N
W
(c) 4 h (d) 0.5 h .
PA

PA
06. Following data is obtained in a chemical reaction occuring with a single reactant. The order of

AS GA
the reaction will be (if t1/2=40 min, t3/4=360 min) :

S
S

CL J A
SE

(a) 9 (b) 8 (c) 4 (d) 3 .

J

KA
KA

AS

07. At 300 K , half-life of a gaseous reactant initially at 58 K Pa is 320 min. When the pressure
N
N
CL

is 29 K Pa, the half-life is 160 min. The order of the reaction is .....................
PA
PA

08. In a reaction aA  Products, the rate is doubled when the concentration of A is in-

creased 4 times. If 50% of the reaction occurs in 1414 s, how long would it take for the
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AL
completion of 75% reaction ?
SE RW

W
(a) 4242 s AR (b) 2828 s
AL

(c) 2414 s (d) 2121 s .

A
AG

AG
W

d [A ]
S

09. A 
S
Product, [A]O = 2 M. After 10 minutes reaction is 10% completed. If - =k
SE
AR

dt
J

J
KA

KA
AS

AS

t1/2 is approximately :
AG

S
N
CL

SE

N
CL

(a) 0.693 minutes (b) 69.3 minutes

J
PA

PA
KA

AS

(c) 50 minutes (d) 0.0693 minutes .

N

10. Which does not change with time for a first-order reaction ?
CL
PA

(a) The amount of reactant that disappears in each half-life .

(b) The concentration of the reactant .

(c) The length of each half-life .

(d) The rate of the reaction .

11. For a first order reaction nA  B whose concentration vs time curve is as shown below.

Concentration

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ES W

SE RW
AR SS AR

AS GA
AG CLA AG

S
CL J A
J
KA

AL
KA
AL 48 Time (min.)
N

SE RW
N
W
PA

PA
If half life for the reaction is 24 minutes the value of n is :

AS GA
S
(a)1 (b) 2
S

CL J A
SE
J

(c) 3 (d) 4 .

KA
KA

AS

_3
12. For a reaction : 2 A(g)  B(g) + 3C(g), rate constant of disappearance of A is 10
N M
N
CL

_1
PA
PA

sec . If initially 2 M of A is taken then what will be concentration of C after 5 minutes ?

(a) 0.3 M (b) 0.9 M

_2
(c) 0.45 M (d) 1.5 x 10 M.
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13. The decomposition of HI to yield H 2 and I 2 at 508 OC has a half-life of 135 minutes when
SE RW

W
P HI = 0.1 atm (initial) whcih comes down to one-tenth of that value when the initial
AR
AL
A

pressure is 1 atm. Calculate the rate constant .

AG

AG
W
S

S
SE
AR

14. The following data are obtained from the decomposition of a gaseous compound
J

J
KA

KA
AS

AS

Initial pressure , (atm) 1.6 0.8 0.4

AG

S
N
CL

SE

N
CL

Time for 50% reaction, (min.) 80 113 160

J
PA

PA
KA

AS

The order of the reaction is :

N
CL

(a) 1.0 (b) 1.5 (c) 2.0 (d) 0.5 .

PA

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