VII.

Data Pengamatan

 Pengaruh Suhu terhadap Kelarutan

No Zat Suhu ( ̊C) V NaOH (mL)

1 60 3,85
2 50 5,7
Asam Benzoat
3 40 6,1
4 30 6,4

 Hasil Kali Kelarutan

No AgNO3 KCl T ( ̊C) Awal Akhir

(mL)
1 1 65 Larutan Larutan
keruh+endapan bening+endapan
abu putih serbuk halus coklat
2 1,2 75 Larutan Larutan
keruh+endapan bening+endapan
abu putih serbuk halus coklat
3 1,4 80 Larutan Larutan
5 mL keruh+endapan bening+endapan
abu putih serbuk halus coklat
4 1,6 90 Larutan Larutan
keruh+endapan bening+endapan
abu putih serbuk halus coklat
5 1,8 100 Larutan Larutan
keruh+endapan bening+endapan
abu putih serbuk halus coklat

Note:
1. Awal: semakin banyak volume KCl, semakin banyak endapan
berwarna putih keabu-abuan.
2. Akhir: semakin banyak volume KCl, semakin banyak endapan
serbuk halus coklat.

VIII. Perhitungan
1. Pembuatan NaOH
gram 1000
 N = x
BE v
0,01 x 40 x 60
gram = = 0,024 gram
1000
gram 1000
 N = x
BE v
40 x 60 x 0,1
gram = = 0,24 gram
1000
2. AgNO3
N x BE x V
gram =
1000
0,075 x 170 x 40
= = 0,51 gram
1000
3. KCl
N x BE x V
gram =
1000
0,1 x 74 x 20
= = 0,148 gram
1000
4. Asam Benzoat
gram 1000
N = x
BE v
gram
1000
0,1 = 122 x = 1,22 gram
100
1

Uji Kelarutan

 Titrasi I
VAB x NAB = VNaOH x NNaOH
10 x NAB = 3,85 x 0,1
NAB= 0,0385 N
 Titrasi II
VAB x NAB = VNaOH x NNaOH
10 x NAB = 5,7 x 0,1
 NAB = 0,057 N
 Titrasi III
VAB x NAB = VNaOH x NNaOH
10 x NAB = 6,1 x 0,1
NAB = 0,061 N
 Titrasi IV
VAB x NAB = VNaOH x NNaOH
10 x NAB = 6,4 x 0,1
NAB = 0,064 N
 log N1 = - 1,4145
1
 = 3 x 10-3
T
 log N2 = - 1,2441
1
 = 3,09 x 10-3
T
 log N3= - 1,2146
1
 = 3,19 x 10-3
T
 log N4= - 1,1938
1
 = 3,3 x 10-3
T

1
Grafik Hubungan log N dan
T
 Grafik Hubungan log N dengan 1/T
-1.05
0 0 0 0 0 0 0 0 0
-1.1
-1.15
-1.2
log N
log N

-1.25 Linear (log N)

-1.3
-1.35
-1.4
-1.45
1/T

Ksp

AgCl ↔ Ag+ + Cl-

Ksp AgCl = [Ag+] [Cl-]

[Ag+] = 0,075 x 5 = 0,375

[Cl-]1 = 0,1 x 1 = 0,1

[Cl-]2 = 0,1 x 1,2 = 0,12

[Cl-]3 = 0,1 x 1,4 = 0,14

[Cl-]4 = 0,1 x 1,6 = 0,16

[Cl-]5 = 0,1 x 1,8 = 0,18

 Ksp 1 = 0,375 x 0,1 = 0,0375

 log Ksp = - 1,4259
 Ksp 2 = 0,375 x 0,12 = 0,045
 log Ksp = - 1,3467
 Ksp 3 = 0,375 x 0,14 = 0,0525
 log Ksp = - 1,2790
  Ksp 4 = 0,375 x 0,16 = 0,06
 log Ksp = - 1,2218
 Ksp 5 = 0,375 x 0,18 = 0,0675
 log Ksp = - 1,1706
 log Ksp rata-rata = - 1,2888192
1 1
 → = 2,96 x 10-3
T 338 K
1 1
 → = 2,87 x 10-3
T 348 K
1 1
 → = 2,83 x 10-3
T 353 K
1 1
 → = 2,75 x 10-3
T 363 K
1 1
 → = 2,68 x 10-3
T 373 K

1
Grafik Hubungan log Ksp dan
T

Grafik Hubungan log Ksp dengan 1/T

0
0 0 0 0 0 0 0 0
-0.2
-0.4
-0.6
log ksp
log Ksp

-0.8 Linear (log ksp)

-1
-1.2
-1.4
-1.6
1/T

Panas Pelarutan
1. ∆Ho = - 1,4259 x 2,303 x 8,314 x 338 = - 9328,04 J/mol
2. ∆Ho = - 1,3467 x 2,303 x 8,314 x 348 = - 8973,39 J/mol
3. ∆Ho = - 1,2790 x 2,303 x 8,314 x 353 = - 8644,68 J/mol
4. ∆Ho = - 1,2218 x 2,303 x 8,314 x 363 = - 8492,01 J/mol
5. ∆Ho = - 1,1706 x 2,303 x 8,314 x 373 = - 8360,28 J/mol
 Rata-rata suhu = 355 K
 Rata-rata log Ksp = - 1,2888192
 ∆Ho= - 1,2888192 x 2,303 x 8,314 x 355 = - 8760,41 J/mol
= - 8,76041 kJ/mol
 Panasnya adalah = - 8,76041 kJ/mol