21, Thefndanetal equation parte yp of w-cononent sem Wi)
37 N, ae
> s= was vain N,RInn?
= riod ay |
Foal ” N N
vit Me Uv Oem CD {
where A is an unspecified constant. A closed rigid cylinder of total volume 10
liters is divided into two chambers of equal volume by a diathermal rigid
‘membrane, permeable to the first component but impermeable to the second, In
‘one chamber is placed a sample ofthe system with original parameters N{? = 0.5,
Nf? = 0.75, V = 5 liters, and T" = 300 K. In the second chamber is placed &
sample with original parameters Mj = 1, N{2= 05, V® = § liters, and 72 =
250 K. After equilibrium is established, what are the values of M{®, Ni, T, PO,
and PO?
Nee
wo a)
Wong
TO. ume
Ns epuclcbe 45.0
dU=0 =
dy=0S= NA + Ta
A at wd 2 4
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N Nets co
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T
ne
(u") =
cee A)