KChemical kinehes is the sluctey of chemical cen celas 4 (Xn mechanisms, N The studey of chemical pen Bagi ave cone (exe) com, aes the Study of chemicer| kine lies ith Uke reactors 1a which the rendions otCur. How is a Chemica) Engineer dilferercl from oblec en reers? tChomical Kinetics 4 ceachr casinn are at fhe henry of Prrducrns almost all cadusteval che micedS Such as th mannfactuce of phthalic adhydesde TU ig pomacily A knowledge of chemical kinetics 4 eactee design dhat aidVnquishes th Chemical Enagineee from othr engineers €The seleckion of a ceacton System Yant operas wn the safest and most ebhicrent manner can be key fo the economic snccass ow Palace of a chemical plant - ¥ Fer exarnplo ) if a cen sistem prodwes a large anmourt of uncls/rovble product gu b Sand ut parhcedven & se pacaticn of the fo sik cl p' selwet cod make th onkre pe Os! economical] n untae acible. #lhemical Reaction Eng neerine (cae) pena ples acne hore can aloe be applied un areas Bufh aS waste treat? ny microadectoon es, pane acd les & \nin syskms in addon © more XladiHonad aceas of He maanute oh ke wee——eE af themmrcels ¢ pharnincou beats. The Rate of Reactor) —G fT cate of teachion tolls us how fast @ numbe, of moles of one chemical specks ait being conswmed tO form another chomueal spends ¥Tle berm cher cnl_Speret refers to aay, Chemical componend oF ee med worth a ave tdewh4 a Ia The ich of a chemical Species 16 “determined Yb te kid) number anal conbausestts of Ahab opener otoms: Whea has a Cheminl Rencton taker P a \Ne 5a Ahad a Chen cal mn haf taken place When « Artectrble number ot wolecwles af tne or more Speces have lo their iebrinty and assumed A how form bay a change ta tho kind of number of atoms tn the wompenrd andkr bw a change in structure of conhawithon of Hase atoms Hn tars clageical apprrach bh Q he micel thiinge ) it is assumed Abed] hy total mags if neither created nee destroyed when a chemical Mn occu is The moss referred to 1s the total collective mene of oll the Atferend Spenes in He syste law ? © |~ of disa ppes cance of Species y Sir) Spores & amber of AH molecales Ahad lowe thee chemical STH Pee unit hime pec und volarve theove ta breaking aad Subleque ce-Porraina of Chemicet beads ducing Ue concse de erchon. HThore are three basie waus 4 Spee t man la4e “AS clomieal tde mht f 4) Decemposi Hon 2) Combinatiin , and 3) [Somer 2A on Hln clecrmpositinn 5 bre mae caber lose’ its ide hy by bein orakon down inde Smaller melecwleyy > Praarne wis For example) fF was or ob we are formtd Prin a eer eaeacy) propyl v® Cumene moloorte CH(CP3)9. O — O + C3hy comend be azene prepa Cument metlocale has lod AS, idenddn Be ee eared) bry peeakies us binds form } here milecule Sah secink we thah a ma lecrle many love species idenhty Us trough conbinadAdnr wy fanothic molecule oF oto: ‘Un the pre ads a4 axnrwple the pO py (one molten, wold lege US spenet de nd) iP the (o< chi ~ wore carried owt in the (everse direckon $o iaak Ve tarebotced ad heaters ¥ borin “Curmane- ete Lic d war a 3 ’ Kdewkiey is theongh semen’ ) | Ue renctron mn spenes ny lore a Such af ci chs CUCM Ly ‘qece, alongs the ravlcule neither adds other molemtes bw ikso ner bronks inte Smaller milecwles) A sti) Log eg tts take wh Theva h la Chanoye m conkaucovk 29 : Dehiniien of G 4 ts the cate of Pomme uni4 volume ad j a) Hey Vel cf is te number of moles of speaer gf tecnted per Unit volvme per unit Kaa keReneral Mote Ralane € Perform a mole balance ia anv Syslt my the Syslem ey eyes wnclaries must [rst be speoiad The Nolume enclose a buy Use boundaries is eeferred jbo as Uw System volume, Ne shall poche a mol batana on eae on (A System Nolune, where species | represents ty partrentac chemical Species of inbrest) Such as water or Nadh. Suslem hie f Fie Figquee 4 » Balan on syle Value xA mole baland 9% 6 pecies A ad any iastaved un tame yt ) welds the fallooing enna _ Dab of qineiobon tof | ate of Pes | Yor tony chum ical econ hin Pa yuk ‘adda vidkin}=| 4 Se \ i “y Whe Snot he 6 He Syston \us}bimg , wi) pracy} JOS] (rms) Fel) be In Cub + Genertion =Accumplaton aie - . = dh 6 8 F 8 “aeBN ye ete eee a ie | = 0 x hy ae t (4-1 YoY mmpn pyuss uy peo L “IW9I0) Yo “Oy, myer wv soy apay vayrn) MCs | wUY uM 51 AVS WME weapon Ty Cunmpn tours vw Oq parune snes) ea J voyva yo Wy TmHpn wv Sey H Si YUL “mmr wasGs ™) uw vay tod ™m v2) 4m Sa\ san viwpwes 0) * svals {2 YXP™Y fo Tos MH PY cou asaddnc, ¢ TWH WY Duy i a4 manne syn = “Shou metan ~ pen We aoe raweg Ne ve ‘y SOP Sag ads / vonrM soy PP Mos ny pus Now mp vaweay ap fo Peed mH yenl 51 ‘he , Vsazeds yo uryrvovad {2 WS ay rumor wa s\5 ™ pray Gira Mp yay coy Vypoyds av, \ snmdy poses ™) 0 cag ev) Gussoy o4b)upr> mba) FY vn MMs ny) Ww tlé ‘+ ownyy yo ways ™) w 5 Pade, JO SOM Jo rap way MH spuavardan \N OH alin i amy adenpy a eae YS “wr of oer se rabron A on ‘ ) C. in teres of Fi, ant ova Me AN, ‘ a it @) ! AG = AN timo ex pPressyins Can be voritten For AGe and te ther Siystare sibvilume AN; « U The both cate of ge neccdion wilhin the 4ygten Volant ic Ho sum af ath He Coes oF apaecohir tn eadh af! the Bwlavolanes: a|f te ttar Susteren vol Gib vdlunnss y a ee cate of Oe { M Gy? Sage ok Ve ropriots Writs Cu, lal pyc ant AN>0) i the deb cuttin of an inenyvh) we bisa un the Poor! ame 1S olevioled unto M nerohion 1S * “HBy whine Us sand making wse ‘can ceoctbe Ue foregnng enaw Nv Ge ad ca From ts cant in we see Yl ry will be an adit HPunckion of post Hine singe he popeces of th ceackine ratarials and reackon Londrtiors le Heat rebion ttt) can have aod Values ot Taleo lacatronS ws the reactet * vie nos ceplade Gy in Equation (9 (-E+G.= x ee)FR ws wtraral form bv yulel a tom of the a reali Ar ann Chemical Species Y Mole balan eqnatienr cen Chany Godlot acu ha Nhat Vs errle. 479) low vent) we Kin anny sys tim Volume Ne (\-4) ahs is basic eapatin for Chenaicel reackon ang: noeting’ 1 WFrom Hrs aeveral nule loerlen te Royton wie can gdnvelo tho design oawatra ns’ for the wanws dupes of Cnghusl io cercho(S 1) Rodeh 3) Sorat bow ch andy ni) Con Mnnons-F PO | #Upin avalnaten of tyyse Panatrons we CON | Actecm ine the ame (barch) or (eactec Nola me | (egatsravs —f 1069 nece savy t Conver a spetitied ampunt of reactants inte pridacksICH REACTOR DESISN a sa —————— Madliten cen dar wt nded Pe }- 6) 1) Sone ll seote ope erm tin 2) bed hn ner protesyes thal hove rct heen Pall se\>peil f Q D)manatedare ef expensive prode chy and, IaJlec prowes ses that are ch°fbiesth Yo converk bo fentinnew oper ations, , Th ety, (iy aAvertags of high Conve (Lit ny lbhet car be chhavacd by lenny fhe coqck ant in Lhe cecdbor Poe bn pediedy cf Rie Ib Piel e hay the ae of Kink leler corts pee hatch y Fhe va iabilF 5 proida dy trom bareh be hatch and the AXE i rt larger Seake production. lr the generat mole belane equation ¢ thebt Conk below -7 1’ fe &§ +h 7 SM apn (1-3 ) we } pe |g — Out t+ Sratctine, ARetmmnnlekie IE its han e Feykh (-4) jaiegral Fo oY hal a iaflos nor ont sa hb aU A batch 7 eta dun ck! vokile tha reaction in 20 chant £ r « dA ont thet am et ta cache \ oie = 0, 7 mond ae | . ar He evnkht “\ geet mae Be Hlang@ on Spee: fa) ut Beal dir as Vet dasiand¢ o> dN _ pY ae ga BIE Phe conden matatnrt 14 perPedlly ree ds He Hen te no yatiaon in th re oe ee Face nahtowt > the reactor Volume WE Can take ont of the inkeg cal intig & and write Hy ele ee ans= 6 JY Ay (Toking Gent of Fe integral) ae Ni ES y = GV Eat (| Ss) = YR. fheby conider The Nomeritation of Spearer ft in bate Gernteg J ps he acdien rece elt) Khe nn mbey al proler the t P ) B daceenle! aang Pht nantes of nner of B per as Sher Zs Figure tL é. og Lattin Figue 46 Meer Vine trajectriedmistiadale CTULED TANY CE ACTH might ov k wh at mS cx WG 4 LCSTILY DESLEN - bint yy ir netewrary ty @° Tednw the initiel number of woly Prem Nao to Finat desired ramaeer Np» 4 UMppty'= 9 Expiration (45) be Ha ivemerirtion ! dM 2g V Bate (i-S) ae =S'dNa & V dt Barr angi ng: dk = sas tN A integrating vith Rely Thet at t= 0) Then (> Naoy then Nae Naa) we olobain { dk - [de Naw fav Exfall- US eametion if the integmal rs cea cn nw bate renchl. be oredace He ~| er Oo ak ee ee ee) Bay te reser Prine Niger Sha And alt bo m Noo mely of B.CONTI Now - Low REACTORS g Gontinney bles reactor are + neo enctors Umrah atevnay *perabedeap sheady stale. pwe o" warile three taper 'o athe unlinnery pleted tank rea cher (ste) t) Fhe ploy Mor reach (PER) and ; s) rhe parked hed concter (PB O Taale Reactor (este) Contingent = SHered woe wed ceoame slay in jadarte's! “So ah dave of re W ig the shee A bank per abd certinne [5 precer7' 74 What iv @ C570 nad for? vik relerred boos bho Tinbinnens whi cred fanle ceactur, reste) or Vat or back nix tence anh iy usd rea cdioar. pimerily for Rapid phase rie iv merrell operated at Gleada vtete aot ard ob , rdf . er te H ly Londen we atlyy Thore Sono time di pence of pretties depen drra of le mee atudy The [en ents FO por the react pty inside The CSTR ‘ The US, every valieble iv fhe Sane at every point nside The reactor. Sl nae Recanse the mpertoe and Concentration art AerriceA evel ed within the Ceaction vee | . ) aan are bbe Some ak tee ex pint as + in le Uechere 6 fhe tank. P ys Thay the ftmper start and conuntretion in tie ext+ ‘ & odelet ag bes Lepom art quot os being Me Lene of Phe rule reactl.FWe wy : © la ao Doar noal fe gi ye negearasy te 6 ¢ Chae the initial number of mole Prem Nao + 04 inet desired Dumloer Npg AO es ye EO - Mook What bins, by WNpplyis) Eaynation (HS) bh be Vomerimtien | dN, 5 Gj Vv Pate (i-s) at = dNa 2 fh V dt Pearl anging dt = 4Na_ tN fe Thet at $20) thee eA integrating tien Ngz Naa) we olobain ia abe Mer Ny ‘0 Naw fav =) = ~ Nar fav In 7 Nao) Expo(\-6/ This taypneten vc the integal , ch the role danw orn 4 batch rea def. wen fe oredaw the ft give the Hit) by eer 'y wou of pasley beim Nao te Nee cee "4 lim New mely of &. peCONTI NUans- STIRRED TANK RENCTVE (CSTIL) DESIGN @ hee ————————————E—TE Whee the general mele halane eeyaation ! ee ee is applied to « CSTR operated at Ghendy shade lice. onditieny do not thange with time) Thea) aN. 0 ! dk lin calaich hp art no spahal vavtatloar in the rate of reactttn (ie per Feet naling ); iq av =NG Wy pebes the fdamibar Pores kyr av the Bele = eopastis bea GS Ces Eye O-9 EThe CSTR diviqn eayrets er grey The reat’ Volant) V) neces/ >“ to ‘reduce the entering Mow rate of spec:e/ to bennn “Fen He dhe oat flan cate Fe, When soectes Sitediva (att ak a cate -4, AN, nob. thal ThE CSTR,,igrmedblid saa Thad the tond tions in Fhe ect Arend eg fon ead afin, Crnporator) act (dintieal Wo thou in the bank. The molar flow rats fj iS jra the prided of the fonuntraton of pecs a7 j ard He Valamotrre fy pote vs Eas l-9 Flonuarerdtty ) We Cotd Work e Ee ad) aad(-S be onthe a bane on specie aw 8 =f. -f foplreing \ with Ain Ve Beh cyt () hh Eve cl ove oft “4 Vefao= fe. Pint) ant fe B = Cj v Eat (-8) fn =Cy NU Eatult 9) huf Fo =CpoN Trew Fate (1-9) become Vs lao vy - fav Cro = CAN ~hqlee Maaco Play Flos Reactor (pre) g ee HT louie Reactor Pipe Yerough wheb & Flad Howe and ee H Proc mmaney A DEhearlk FO Combed Wemperabart Vane hea s Ain advanrane (6 Yre seplheot~ of Ceashenehen at any “y ) nde, ‘ Play Flaca Peloular Render ¢ - A Pogue PER Derign Enyehen —— A Desian Fane en | ‘ yz Ane fae be SY Qt? GE te x Re ee er Inv) ads \eed) ha end Ya came cadres %% Ya enbre pipe Fa (ut A fies of B oS) an of oo Clamtnt he Flows of A veto Elem v? Buy¥lt the aumeyd VS tno 7 fa 4 (ta dN= 0 Diblecenhats ware Nl O- Ay = -%q aN 6 dfs | The narod face, is. : NE \ Ad Ca LE Ths ic Uw Volum mwas ser ww cedua te entation folae les coke (eadlls) Crome tas the ods maar Glove cote of & Fy. aq lecusd Ged Coote WN, From Fa 4 \ew" a Sturdy State | dNa = 2 a?Raclud Gad Cerctoe Kyo Fa QoQ dvd =0 | \ Nifecendoe week WW a0 Fearrone,. | The akageah foe to Bad the cotelgch woeighh iS 4 (is df Fro GQ Rake has by \nteaye oh MevhoA Ubyeck ves aod secre each 4) Dekermine the cendion orcler oltaioe A Horm cate Peom Prom expersmentor| darn either belch 0° flows compbor$ WNoyescerbe hs Ye anc\wX2e- tage omen dee oe omvae Une coke Varo Ddacrninevtion of cote von st ont \ ui acy Lutoacod MeVhoA TLL Conditions foe lato Methed TL € Plot Se aqersagk tine) 4)f Ve dada de not oth va a Sd Coney vane ber oe Od oe D Swh as oz 2}Fone te us fee Weay ah Maw 11d lave - “> See o- v4 L\ y 5 12 _——> A Then we should SP Ants nn. com Ao orders eal georted Yo euthe the Ai iter-aviel oie oe naolusys tc Ye Cen lessroe (ntaayal Mahod TIL) Ener Consider Ure ceria ‘ MIR) eettenncl (SY > Meher vesved owl w 4 be ane ond P eicline : = 0.0SN\ ,C Qe OS). Ah e cdant em cnstont v The \n vevble t - Tout The cendktn 16 Ce coin oh 25°C (ab b- 04 CA One of We pcodnds CL roots & preci pilates: Deborrin Ue cok ress Pre Wee ceachan act Shor Tovble Fime(mad 0 \50 | 20 {iso \2m [ase | 300 Conte ralken “Al co Z 40.6 5.6 9. Gadldetycv@ | 2 (AE b=} (qz0.0S¥\)ee 13 Fable 1" Processed Deven Emin) To [sp \ivo fiso | 290} 25° 300 Ca(ontlden®) — |g.os}00%6)0-0300/0.025 o.wmmlnoas|o.014 E (acslen\) |20 fas.sfs2-9]3r-1 |S [513] 52. € Rake lus -dln = < ak FAscume 1% occer cx0 oo ow retention Lathe, -e| A 0 H Reaccaneyney A 2b RE Ca Cao 1 eyo 1210-2 Ca \e = ON2 densFrodran | 7 7. |= Slope of Ue bene A 2 09k 20.0% 1% j Shape = Inctense Sry = Boy \nceease me Agr ak Foun ayenph E by a §G~ LOAD a On %~00-0 yes OED Ame mo)" mo = 0N\Q dm? mle mn : j 2. L EW OND ded }ena\s me = sab} | 2k 2 Ode ee Cgo 0.5 mo den? o\ ' Deke Lavo e | 1. f “1 }™k) | (ie Cg 4 mv Qeoce Desire Recipe ~— 4» 4 oa " Develop om ala torn Aha® combs ays cenchoe a des yn Cranmtrarns rib fencthye totes dye dhe de 5.40 of dhttecenA rendrs,| a The hose ol \sothee mn Quarter Brsign aS, ey A Gol ue mole Sewlanw Pre Speci Cente 7 | \a- Ow N Benerebion = Recumulaten IS | Fao - Fy +f man = dN, Oe 1. Verve BSA Lanetro va ke KX on oan ~ n rms of f he Bod ah CSTQ PER XK, b= Nao) dhe Ve Fast \efro" AX 0 -G\\ Cn a a & Pw Cy tea terms of Xp aod ey wo Sy C= Cag enor E-| “| i.) © eke We WT At n tak Capt ylao re | P\ PTs \) Be | Lreka \® WY LZ b> Pluw FQ vad Aas yo ervalron aod Solve hr i\ kavcne Nant th) ve Nour (L\aes renvrod te a SPEAR L ea, “Yq = VyNR -yekly i, ordas (0am code 1A Cal alae the Rene ferred luc a Conversion Xp Inn a lnctond \) bedch Codd’: t SV Mole belanw Nao 24a. . “tN | at, | V ote haw - tq =k VStedhionetiy Cy = Can (4-% (Ped Cas va Keceng of x) a no ( >) V Cardone Nao 4% Ho k(Cao! ) (-%)" N Bath Niolwe i$ con srevyt VEN => Nap 4208 a = (Cao \(\-e)” \ JS ENolnate # Ode buy Nao’- ax a 1Nle = =\lag (\-%) Keo es we Kars thd Cao Nao a Now eee No Nad Cro > te Cag (\- ce PV 4 ap) as de 2k tod AF 2 Ad uh ta.las De 2\Cno (W-%y) (+ TReaccane Yo op Whe we calles \oaedher 0 AXn AN d Xa OME a eh = (\-% JP Meat ales Xn)" =a K fe coastandt for an Isothacna) centr vn | AL Kn aes , + Time coayece dh fo odiede yA — | Xa) = » Yayo kCao “TX Ya for PO order tor CSTR Ogerckion 4-——_ 29 29 0 RDB -HeK Cy Lingid-phese I PP ovlar cao cote ¥ Colewlote he CSTR vouune canysced to ek & onversion of Xp 2 VY Msle ballin Nz Fro Xa -p SY Rote las -hekla | Nordic eye = Yen tn rte app) La? “0 (Ae) a AV Comotnt le FroX wi Ib kGo (1-Xa) ab Fro tn termg of Cao We knw Ahead Fro > Cao No where. No 2 Nolumede), fli cody, “ \|= Erexoka KtnolL Xn) Nola ne conn rce)\ bo achieve Xa tyr aor or dee ra Domkbhler Number, Da Da = eaeN _ coke of coogisn ob evrtronie rant ove cl Tipo Te ae ee a Flas cake of A conversoor, fo enter 4 Ww oe P Estimates ho dear ee of waversionw Aho con be cbYamed ia a flow reaches: Wesh ocd Weenes ble cenyarn % Da 2 oo cra => Das KN Sabet Sno Geo e Nlo tz iy =>Pa-kt ast oder Ne ia Uren sibly creer,th eel damier Nonber Do CONT O _ waht Dad > 10! he is PY pcder secade cai filed can so lost coaene, thea = Xie Des ae SA On | CONNERS Lon 4 Wous bo delrac cooniers tic EEA tp _detine Cones ba | ales choose vac of the conto os he basis of calewatana. a) Tara colake. the sthac Specs tasolve din he ceackiv ke W's hash als b& — eC + dd the epercase Lett 8 1A &. C apd 0) cope sen ——_theeicoh ss a Si a : Jeknidmomed ce caeltviend s b,c ao «i seu \ Ime VTalene specie sf as the boc of calculation. Wal? alDevide the ee eee wa_2drpressive Thfonal Itn. ee i sh spaies Bo | = ag pe S$ ——s5, Crd H ; _ re = — To fpac ntl ol AT nasi ¢ ha Bin content. — QuecHo re — | At+b Bose C td © a Svea G we avant! \. due x : ya owed ~ OY ch Cate foo ed boc ) COUe Y Ze pe miples Lae Los mpl of A consuere 2 Anéwee a~—_@_ + i mee aoe eco a ome _ = aN ee ___\tonuelsyun ishe OO { De Senaktihler Pavanioe Oe ONT S wu ole conhs on: ‘ * V rds or der Vee % Ns oo | Fao ae Ne - Guard ve uF Le 5 Qa zklaot 2 order “rey erga CHO © biest aes é a Vows 1s ha celeded & On wa \eceversible ceotwon we & flows cencsve | Xq 2h => X, > Da jy vk L4De Reade Yq Yo DA oe a as occur ‘ereners bla fin in & Flo ce achoc 7 X aces ) 2 i: yok en order =e 2 Bo NAQa r \ overs oe an DalLoA f ' . \ be Anis ys* wcder vereue roy Oe xo tr a Flos Cenpor ven’ ne XY 2 Da , = ) oie Xgz Br = DOM TtBATLB TOR BAL! gen Cree