xil PART-B :: CHEMISTRY SECTION ~1 (Total Marks : 20) (Single Correct Answer Type) This section contains $ multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct. Each question carries +4 marks for correct response and -1 mark 21. 22, In the formation of sulphur trioxide by contact process, 2SO, +0, == 2S0,, the rate of reaction was measured as = 2.510 molL-'sec”. the rate of reaction expressed in terms of SO, will be (a) -1.25x10* molL*see* (b) 50%104 molE-'see (©) -3.75x10" molLsec (@ 5.00x10" molL"sec™ If the concentration of the reactants in the reaction 2A +B > C + D is increased by three folds, the rate of the reaction will be increased by (a) 27 times (b) 9 times (c) 64 times (d) 01 times A first order reaction takes 40 minute for 30% decom-position th2 for the reaction is (a) 66.67 min (b) 80 min (©) 77.70 min (@) infinite time Units of rate constant of first and zero order reactions in terms of molarity unit are respectively (a) sec“, M sec (b) sec, M (c) M sec, sect (@M, sec 99% ofa first order reaction was completed in 32 min. When will 50% of the reaction complete? (@) 24 min (b) 8 min (4 min (4.8 min SECTION - Il (Total Marks : 16) (Multiple Correct Answer Type) This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONE or MORE is/are correct. Each question carries +4 marks each for correct answer(s). There are no negative marks in this section 26. 28. ‘Analyse the rate expression for the following reactions: (@ 3NO(g)—N, 0(2); Rate = k{NOF Gi) HO, (aq) +31 (aq) + 2H” —2H,0()+1, Rate =k[H,0, IT] Gii) CH,CHO(g) + CH, (2) + CO(a) Rate = k[CH,CHO}’* (iv) C,H,CI(g) —> C,H, (@)+ HCI(@) Rate = k{C,H,CI] Based on the above expressions, which of the following is/are correct? (a) Order of (i) reaction is two and unit of k is (concentration) 'see* (b) Order of (ii) reaction is one and unit of & is sec’ (©) Order of (iii) reaction is three/two and unit of k is (concentration) "* sec’ (d) Order of (iv) reaction is one and unit of k is sec Rate constant k varies with temperature as given by equation: Jogk(min") =3-22°K We can conclude (a) pre-exponential factor 4 is 5 (b) &, is 2000kcal () pre-exponential factor 4 is 10° (@ £, is 9.152keal Which of the following statements are correct about half-life period? (a) It is proportional to initial concentration for zeroth order. (b) Average life = 1.44 x half-life; for first order reaction. (©) Time of 75% reaction is thrice of half-life period in first order reaction.xil (a) 99.9% reaction takes place in 100 minntes for the case when rate constant is 0.0693 min”! 29. In Asthenius equation, K = Ae™*®T. A may be termed as the rate constant at (a) very low temperature (b) very high temperature (©) zero activation energy (@ the boiling temperature of the reaction mixture SECTION - Ill (Total Marks : 20) (Comprehension Type) Section III contains 2 groups of questions. Each group has 3 questions based on a paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which only one ts correct. you will be awarded 4 marks if you darken the bubble(s) corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (1) mark will be awarded. Paragraph for Question No’s. 30 to 32 Half life period 1, «1 where a, is the initial concentration of the reactant and 1 is the order of the 7 a’ 2303 log—“— ,.where x is the amount of reactant reaction. The first order rate equation is given as ¢=—> a-x consumed. 30. Half-life period for the first order is 60 minute, the fraction of time, fy) i8 a) 2 times of 60 min b) 3 times of 60min c)4 times of 60min d) 5 times to 60min 31. The relation between Ty, and Tay, in a first order reaction is 8) Tages =1-STiges D) Tose, = 17ST ©) Tsy = 2Toor 9) Treg = 37s 32. Number of average life for a first order reaction to complete 99.9% level of the reaction is 8) 2.303 b) 6.909 ©) 9.212 4) 11.515 Paragraph for Question No’s. 33 to 34 2611 ‘The rate constant for a first order reaction is given as logk =16—""~ where K refers to rate constant and T refers to temperature in Kelvin scale 33. The value of pre-exponential factor is (A) e* (B) e* (©) 10" (D) 10° 34. The energy of activation of the reaction is (A) 22kJ mol" ) 60kcalmol (©) 65kJmol* (D) 50kImol* SECTION — IV (Total Marks : 8) Matching Type) This section contains 2 matching type questions. Each question has 4 choices (4), (B), (C) and (D) for its answer, out of which ONLY ONE is correct. Each question carries +4 marks for correct response and -1 mark 35. Match the following Column, Column = 11 1) Boiling point p) HoTe < HSe < His < Hx 2) Thermal stability q) H20 > H2S > HaSe > HaTe 3) Reducing character 1) HO < HS < HiSe < HoTexil 4) Bond angle s) E20 > HaTe > HbSe > oS A) li; 2 ii; iv, di B) liv; 29; 3ili; 45 ©) Lois 2 ii; 3 iv; Ai D) li; iv; 3 itis di 36. Match Column I with Column II for the reaction A —> Products, with initial concentration of 'A' equal to 'a'M. » = 1p) Half-life of zero-order reaction 2 a q) Half-life of first-order reaction, 3) i 1) Average life of zero-order reaction. 4) 4 8) Average life of first-order reaction. a t) Half-life of second-order reaction. A) Loi: 2 itis 3iv; 451 B) liv; 2%; 3; 491 ©) Sil; 2, 3103 41 D) Lis 25iv3 358 41 SECTION — V (Total Marks : 16) (Integer Answer Type) This section contains 4 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The appropriate bubbles corresponding to the respective question numbers in the ORS have to be darkened. Each question carries +4 marks for correct answer. There are no negative marks in this section. 37. How many of the following oxides are basic oxides? CO», SnO2, PbO, PbO», Pb304, AbOs 38. The relation between t75*; and ts0% for first order reaction is 39. Rate of the reaction A —> B is 0.001 mol min“ order of reaction is ... 40 Amorganic compound undergoes first order decomposition. The time taken for it’s decomposition to ; and t49 respectively. What is the value of “4% 10 1 and [5 of it’s initial concentration are r