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Shailesh Patel
The Maharaja Sayajirao University of Baroda
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Abstract— Greenhouse gases are the main cause behind the different methods of hydrogen production, water electrolysis
current climate change and global warming issue. The seems to be suitable approach which can be used for internal
transportation sector generate the largest share of the combustion engine. However there are still work need to
greenhouse gas emission. To address this issue fuel economy of increase the efficiency of hydrogen generation rate [2].
the automobile engine is one of the profound way through Hydrogen can be used as a primary fuel in internal
which one can attain the solution about fuel scarcity and combustion engine, since hydrogen is in gaseous fuel, it
carbon emission of the engine. The unique combustion required larger space for storage. When hydrogen stored as a
characteristics of hydrogen helps to reduce the carbon cryogenic liquid, additional cost of convert the gaseous
emission of the engine. In this context, on board hydrogen-
hydrogen in to liquid is not economical solution. On board
hydrogen-oxygen (HHO) gas generator has been proposed to
hydrogen generation through electrolysis process can resolve
increase the fuel economy without major modification in the
existing automobile engine. In this work HHO gas was
this issue. Gas produce through electrolysis is in form of a
produced by electrolysis process in a leak proof multi tubular hydrogen-oxygen-hydrogen (HHO) mixture. Production of
type HHO generator, with different two electrolyte NaOH, & HHO gas is considered experimental method but still it can
NaCl. The production rate of HHO gas has been investigated used as a supplemental fuel additive which promotes the
with different parameters, i.e. applied voltage, quality of water, combustion of primary fuels, which result in reduced the
temperature of water. An efficient HHO generator is supposed emission. Energy contain by HHO gas can release during
to produce a large amount of HHO gas by using a less amount combustion, which leads to increase total engine power
of power. This HHO gas can directly use as a supplementary output. It has been recommended from the various
fuel on demand, in four stroke petrol and diesel engine without investigation and research that the hydrogen has potential to
any need of storage. Characteristics of HHO gas helps to be a promising nature friendly fuel. However there is a
enhanced the combustion which ultimately reduces the engine misconception about vehicle mileage will increase due to in
emission. board HHO generator. But in reality HHO gas act as a
supplement fuel to the conventional engine fuel system,
Key word: HHO generator, Hydroxy gas, Hydrogen, which helps to improve the combustion of the internal
electrolysis, automobile engine combustion engine leads to improve the efficiency.
HHO gas is also referred as Brown gas or hydroxyl gas
I. INTRODUCTION or oxy-hydrogen gas. Electrolysis process break water in to
Everyday increase in energy demands create scarcity of two part contain two moles of hydrogen a one mole of
fossil fuel, which leads to continuous exploration of new oxygen. The device called hydrogen generator or HHO
energy resources [1]. In the process of exploration, it is generator used the electrolysis process to split water particle
found that hydrogen has great potential to replace fossil fuel and extract hydrogen and oxygen. Earlier development for
used in internal combustion engine [5, 6]. Hydrogen has a hydrogen generator were designed to extract hydrogen-
good combustion characteristics with wide flammability hydrogen-oxygen gas or Browns gas, they were originally
range (5-74%) with high burning velocity and flame speed. designed for welding and cutting purpose. But it can be used
These characteristics allows the engine to work on a very as a supplemental fuel for internal combustion for both petrol
lean fuel mixture [7]. Hydrogen can identified as a clean and diesel engine. Objective of present study is to suggest
burning fuel which has almost zero carbon footprint. Above optimize parameters which increases the production rate of
all hydrogen is also renewable fuel. However there are HHO gas. Proposed HHO generator can be installed on
several ways to generate hydrogen gas, among the all petrol engine to improve the combustion characteristics.
A. Fundamental of water Electrolysis Components of HHO generator:
The simplest water electrolysis unit, consisting of an anode (a) Electrode housing: Here, the housing used is similar to
and a cathode connected through an external power supply vessel used in the water purify system, to provide covering to
and immersed in a conductive electrolyte media. A direct the electrode and leak proof arrangement for the electrolysis
current (DC) is supplied to the electrode which create process shown in figure 3(b)
positive charge on anode and negative charge on cathode. (b) Bubbler: the bubbler is a cylindrical vessel, which is
During water electrolysis process hydrogen (H+) ions moves connected with the HHO generator through plastic hose pipe.
towards cathode (-ve charge) and hydroxide (OH-) ions It allows the hydrogen to bubble up through the water in the
moves towards anode (+ve charge). Hydrogen and oxygen bubbler cylinder. The water prevent backfire from returning
gases are then collected in to measuring cylinder through of hydrogen in to generator and the cap will closed in case of
gas receiving plastic pipe. The electrons flow through an a backfire.
external circuit. (c) Air cleaner: A filter that prevents dust and other particles
Anode Reaction: 2H2O → O2(g) + 4H+(aq)+ 4e- from entering the air-intake of an internal-combustion
engine.
Cathode Reaction: 4H+(aq) + 4e- → 2H2(g)
(d) Electrodes (Anode & Cathode): Two struts are used to
connect anode and cathode respectively to the positive and
negative terminal of the battery. Anode is connected to the
inner cylinder and cathode is connected to the outer cylinder.
Struts are 15 cm long and 8mm in diameter of stainless teel.
Specification of two co-centric cylinder are placed in
electrode housing. Diameter of outer cylinder is 64mm and
inner cylinder is of 50mm. Hollow cylinder thickness is
2.5mm which makes clearance of 3.5mm between two
cylinders.
(e) Measuring Cylinder: Measuring cylinder is used to
measure the amount of hydrogen produced during the
process.
(f) Catalyst: Distilled water has been used as electrolyte in
present study. However to accelerate the electrolysis process
catalyst must be add with the distilled water, to increase the
Fig. 1 Basic scheme of a water electrolysis system[4] efficiency of HHO generation. Catalyst act as an ionizer and
increase the conductivity of electrolyte. Commonly used
B. HHO generator catalyst in HHO generator are Sodium Chloride (NaCl),
There are two different approaches for electrolysis Sodium Hydroxide (NaOH) and Potassium Hydroxide
process, based on ambience around the electrodes, wet cell (KOH). In present study NaCl and NaOH has been used for
type and dry cell type. In wet cell all the electrodes are the HHO generation.
submerged in the electrolyte solution filled inside closed
vessel. However in the dry cell type, instead of submerging
electrode in to the electrolyte, it is fills in the gap generated
between electrodes placed in series. It is found that HHO gas
produce by HHO generator through this approach is
completely different in chemical composition than the
Brown gas, even though both gases having common features.
Molarity (moles/liter)
II. RESULTS AND DISCUSSION Fig. 5-a Effect of Electrolyte molarity on the HHO gas production
at 12 V, 20⁰ C of Normal tap water
A. Effect of Electrolyte Quality
Acids and bases are known to change the nonconductive
12
nature of pure water. These compounds have a great
reducing effect on the overvoltage value of an electrolyze 11
NaCl
NaOH
because of its improve the ionic conductivity of electrolyte Exponential growth
solution. However there are limitation of the concentration Cubic Polynomial growth
Production Rate (cm3/s)
10
level of alkali and acidic solution due to its highly corrosive
behavior with electrode material. In present study electrodes 9
were made of stainless steel. The generator was powered up
for 25 sec with a different content of NaCl and NaOH, mixed 8
0
20 Water Temperature 12 Volt
0
80 Water Temperature 16 Volt
10 10
8 8
6
6
4
4
2
2
20 30 40 50 60 70 80 90
20 40 60 80
NaCl (gram)
NaCl (gram)
12
12
12 Volt
16 Volt
200 Water Temperature
0 10
80 Water Temperature
10
8
8
6
6
4
4
2
2 10 20 30 40 50 60 70 80
20 40 60 80
NaOH (gram)
NaOH (gram)
Fig. 7 Effect of Battery voltage on HHO gas Production rate
Fig. 6 Effect of Water temperature on HHO gas Production rate
D. Quality of Water
If any impurities exist in to electrolyte causes unwanted 10
side reaction in the HHO cell. Calcium, magnesium an
chloride are the few common impurity found in water. Normal Water
Distilled Water
Contaminated water can block the electrode plate, in result 9
Production rate (cm3/s)
[2] Schulte, I.; Hart, D.; Vorst, V.: Issues affecting the acceptance of
9 hydrogen fuel. Int. J. Hydrogen Energy 29(7), 677–685 (2004)
[3] Ahmed Rashad, Ali Elmaihy, “Theoretical and Experimental
8 Performance of Oxy-hydrogen Generators”, Arab J Sci Eng 43:1279–
1289, (2018)
7
[4] Diogo M. F. Santos,Cesar A. C. SequeiraI, Jose L. Figueiredo,
“Hydrogen production by alkaline water electrolysis” Quim Nova
vol.36 no.8 (2013)
6
[5] A.A. Al-Rousan, Reduction of fuel consumption in gasoline engines
by introducing HHO gas into intake manifold, Int. J. Hydrogen
5 Energy 35 (2010) 12930–12935.
10 20 30 40 50 60 70 80 [6] A.C. Yilmaz, E. Uludamar, K. Aydin, Effect of hydroxy (HHO) gas
NaOH (gram) addition on performance and exhaust emissions in compression
ignition engines, Int. J. Hydrogen Energy 35 (2010) 11366–11372.
Fig. 8 Effect of water quality on production rate of HHO gas with [7] C. Ji, S. Wang, B. Zhang, Effect of spark timing on the performance
NaOH of a hybrid hydrogen–gasoline engine at lean conditions, Int. J.
Hydrogen Energy 35 (2010) 2203–2212.
CONCLUSIONS [8] Mohamed M. EL-Kassaby, Yehia A. Eldrainy, Mohamed E. Khidr,
Kareem I. Khidr, “Effect of hydroxy (HHO) gas addition on gasoline
In this work various experiment have been performed to engine performance and emissions” Alexandria Engineering Journal
optimize the HHO production rate. Major focus is to Volume 55, Issue 1, March 2016, Pages 243-251
identify suitable catalyst for electrolysis, and it is firmly
observed that NaOH have advantages over NaCl to increase
the HHO production rate. Other concludind remarks
observed as follow:
Production rate of HHO has been increase rapidly
when molarity of electrolyte solution is greater
than unity.
At lower molarity, the effect of rise of solution
temperature is notable, but at higher molarity,
production rate remain unchanged with
temperature rise.
The effect of voltage rise on production rate is also
negligible.
Tap water have more potential of HHO gas
production than the distilled water.
Present study proposed parametric conditions of HHO
generator in which it can be used 70 gm of NaOH
mixed in to normal tap water at room temperature with
12 volt of battery, generate more than 10 cm3/s of HHO
gas. This device can generate onboard HHO gas which
will feed in to intake manifold of the petrol engine to
improve the petrol combustion, which is proposed as a
future work shown in Fig.9.