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Common Equations Used in Chemistry: N X Molar Mass of Element
Common Equations Used in Chemistry: N X Molar Mass of Element
m
Equation for density: d= v
5
Converting ˚F to ˚C: ˚C = (˚F - 32) x 9
9
Converting ˚C to ˚F: ˚F = ˚C x 5 + 32
actual yield
% yield = theoretical yield x 100%
moles of solute
molarity (M) = liters of solution
Dilution of Solution: M i V i = M f V f
V
Charles’ law - Constant P and n : T = k
V1 V2
Charles’ law - For calculating temperature or volume changes: T = T
1 2
3RT
Root-mean-square speed of gas molecules: u rms = ( M )0.5
Van der waals equation; for calculating the pressure of a nonideal gas:
an 2
(P + 2 ) (V - n b) = n RT
V
q1q2
Electrical force: Fel = k 2
r
q1q2
Potential energy: V = k r
Definition of enthalpy: H = E + PV
Energy of a photon: E = hν
1
Energy of an electron in the n th state in a hydrogen atom: En = -R H( 2 ),
n
where R H = Rydberg constant = 2.18 x 10 -18 J
Dipole moment in terms of charge (Q) and distance of separation (r) between
charges: µ = Q x r
Bond order =
Error!
moles of solute
Calculating the molality of a solution: molality (m) = 1000 g solvent
Raoult’s law relating the vapor pressure of a liquid to its vapor pressure in a
solution:
P1 = X1P ˚ 1
Rate law expression. The sum (x+ y) gives the overall order of the reaction:
rate = k[A]x[B]y
ln 2 0.693
Half-life for a first-order reaction: t1/2 = k = k
1
Relationship between concentration and time for a second-order reaction: [A]
1
= [A] + kt
o
The Arrhenius equation expressing the dependence of the rate constant on
activation energy and temperature: k = Ae-E a /RT
Ea
Equation for the graphical determination of activation energy: ln k = (- R )
1
(T ) + ln A
k1
Relationships of rate constants at two different temperatures: ln k =
2
Ea T 1 - T 2
R ( T 1T 2 )
[C]c[D]d
Law of Mass Action - General expression of equilibrium constant: K =
[A]a [B]b
The equilibrium constant for the overall reaction is given by the product of
the equilibrium constants for the individual reactions: Kc = K’cK”c
Ion-product constant of water: Kw = [H+ ][OH-]
[conjugate base]
Henderson-Hasselbach equation: pH = pKa + log [acid]
Standard free energy change: ∆G˚ = -nFE˚ cell , where F is the Faraday
constant
The Nernst equation - For calculating the emf of a cell under non-standard
conditions:
RT
E = E˚ - nF ln Q