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entropy changes as the ions move away from each other to interact with the liquid. These stabilized
species are more commonly found in the environment at low temperatures. A common example is
the ions present in seawater, which are derived from dissolved salts.
As charged objects, ions are attracted to opposite electric charges (positive to negative, and vice
versa) and repelled by like charges. When they move, their trajectories can be deflected by
a magnetic field.
Electrons, due to their smaller mass and thus larger space-filling properties as matter waves,
determine the size of atoms and molecules that possess any electrons at all. Thus, anions
(negatively charged ions) are larger than the parent molecule or atom, as the excess electron(s)
repel each other and add to the physical size of the ion, because its size is determined by
its electron cloud. Cations are smaller than the corresponding parent atom or molecule due to the
smaller size of the electron cloud. One particular cation (that of hydrogen) contains no electrons, and
thus consists of a single proton - much smaller than the parent hydrogen atom.

Anions and cations[edit]


"Anion" redirects here. It is not to be confused with the quasiparticle Anyon.

Hydrogen atom (center) contains a single proton and a single electron. Removal of the electron gives a cation
(left), whereas addition of an electron gives an anion (right). The hydrogen anion, with its loosely held two-
electron cloud, has a larger radius than the neutral atom, which in turn is much larger than the bare proton of
the cation. Hydrogen forms the only charge-+1 cation that has no electrons, but even cations that (unlike
hydrogen) retain one or more electrons are still smaller than the neutral atoms or molecules from which they
are derived.

Since the electric charge on a proton is equal in magnitude to the charge on an electron, the net
electric charge on an ion is equal to the number of protons in the ion minus the number of electrons.
An anion (−) (/ˈænˌaɪ.ən/ ANN-eye-ən, from the Greek word ἄνω (ánō), meaning "up"[10]) is an ion
with more electrons than protons, giving it a net negative charge (since electrons are negatively
charged and protons are positively charged).[11]
A cation (+) (/ˈkætˌaɪ.ən/ KAT-eye-ən, from the Greek word κάτω (káto), meaning "down"[12]) is an ion
with fewer electrons than protons, giving it a positive charge.[13]
There are additional names used for ions with multiple charges. For example, an ion with a −2
charge is known as a dianion and an ion with a +2 charge is known as a dication. A zwitterion is a
neutral molecule with positive and negative charges at different locations within that molecule.[14]
Cations and anions are measured by their ionic radius and they differ in relative size: "Cations are
small, most of them less than 10−10 m (10−8 cm) in radius. But most anions are large, as is the most
common Earth anion, oxygen. From this fact it is apparent that most of the space of a crystal is
occupied by the anion and that the cations fit into the spaces between them."[15]
The terms anion and cation (for ions that respectively travel to the anode and cathode during
electrolysis) were introduced by Michael Faraday in 1834.

Natural occurrences[edit]
Further information: List of oxidation states of the elements
Ions are ubiquitous in nature[citation needed] and are responsible for diverse phenomena from the
luminescence of the Sun to the existence of the Earth's ionosphere. Atoms in their ionic state may
have a different color from neutral atoms, and thus light absorption by metal ions gives the color
of gemstones. In both inorganic and organic chemistry (including biochemistry), the interaction of
water and ions is extremely important[citation needed]; an example is energy that drives the breakdown of
adenosine triphosphate (ATP)[clarification needed]. The following sections describe contexts in which ions
feature prominently; these are arranged in decreasing physical length-scale, from the astronomical
to the microscopic.

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