JI plas 9 &usSgoull duleVJl 2013 : Sy gd Ly silSall Salgad Gilad oly i All (GB pal Arai) Len ol gS: bald Adal eens] sijne (53) €.2523) Gay) patie jg Eas 0,25 05 0,25 1 | 0,25x4 0,75 | 0,25x3 (1 05) S81 oe pet rua (1-1 M(CyHans) = 12n + 2n-6 = 78 14n-6=78 n=—=6 14 CoHy tod Acciles 81 tas 9 poagll anil Alepell dapaall ade 9 CO toh Leda) Gnas dauuall y ere Alia ead dual (2 ° I ec Cy": 7 8 ome: ei Hyo—CH,—{ \ > NH Cg yall gle Spuaall diet! HY ales (3 +480, (CH2-CH3 CH>-CH HS0,, CHp-CHy, + HNO, + HO Ho-CHg, ,CH-CHy, NO; HN 2 i Fe/HCl olSe (8 LIAIHWH2O Chari (Sa; 4s 11 81 dake(G31 pb eats) bas gl 93S: SaLall Le Yl aati (38) gaged) TGY patie ee 0,75 0,25 05 0,75 os 0,75 0,25 0,25 05 0,25x2 0,25 05 0,25 0,25 0,25 05 jac GY ge ce — (1 WI 5 m 9,84 ee eee M8) = py = 4420.06 mol 3 BN Jeli 253 ye 0,08 Rena = neste) =" x 100 = 60% n(acide) 0, ga UpaS ga F Syed Gia = HAO“GH-OH GF yas hada Gnas Stal (2 ods 1 fu) Jeli Males (3 q i bon E-0-CH.CHy + Hyc-GH-oH dy + H,0 Os iv Hy F cyl gal) Ge SSI Maid Cine dull — (Ll 4 F : HyC—CHy~CH)-OH H: HgC—CH=CH, foto SP jaded ded dee - CHs " eli dates (2 2 CH;-CH,-CH,-OH ae CHaCH,-CH,-O-CH,-CHo-CH, + HO (SUR 05): iN 9 pill N@QOH 2 peel Sole (II) jot Cit pS Solas seg yp RUS Se“ (1 Lala) Cates tA Anil - BN aul) - cles} nae oh ude gsi Y has) tel Uae cle gsi Ser — Val - Asp sisi) dene -i (2 i I HyN—GH—C—NH—GH-G HH GH-COOH Has cH Cre I eN, [ OH -HyC™ SCHy COOH 11 O82 dakea gis Ae (551 jal) Asin) bp gl 96h = Bala yall yh at ad (039) goad) Lia) patie a 2,25 0,25 0,25 0,25x4 0,25x2 0,25 05 05 05 aud Lib) Gus Val suet Gnaall L 5) gual Uke tASP it (socal pH) Gus -@ pka;+ pKar 188+ 368 _ 577 ASP sited) crac 45 5) Qual) 2 pKaR® pka,=0,6 pH=12 HyN*cH—CooH SH Hynt-ch—coo QL Hyn-cr—coo 2 y.n—c—c00" ie a b Gh boon boon boo! boo GR Ales patel 5 gba LE Lah 2 Slag (SN By 5 Cut 5 shld Bia -i (3 AR DBs shay Sb Lead May yb G5 Gy aati GUS 4p ge coped GSE List Ae) Galea) aS ge olebt Tyr « Ala « Lys +o B aia G Sal) MW yale -@ slot ales AES -a HaN—CH-COCH + HNO, ——m HO—CH-COOH + No + HzO Hye HC HyN—GH-COCH + 2HNO; ——e HyN-CH—GOOH + 24:0 Hy HC 11 O03 dakeay oi ae (GaN Aosta) bea I 8S + Blab Sail Uy! ali Aadbell 1 : 1 gas [ened] tae (JS) ga 5a) LEY poli poe nh (BYE 05): 22) oy pal AHS{Hy,)) ¢tsas (2 Hess gyilé Gulbis AH, = SAH! (Produlis) -° AH? (Re actifs) 0.25 AH, = 28H} (NHy.,)-[AH} (Na,))+34H! (Ha) -92= 20H? (NHy,))—(0+3%0) ie AH} (NHy,,)=—92 =~ 46 kJ/mol 0,25 AH? (NH, == 46 kJ / mot AH, hus (2 0.25 AH, = [svi }>9H8(H.09)]-[20H(H, + 5811°(0,,)] AH, =043(-286)-2(-46)-3(0) AH, 0,25 AH, 0,5 0,25 AH =AU +AnRT 3 2 AOjy Aud Dad 8 9 3 2NH ag) # 509) > Nojy) # 3H 0,25 An =1-(2+3)=-25mor T =25+273= 208K AH -AU RT =—2,5x8,314 x 298 0,25 6193,93J =— 6,194k) ER a z 1H, 33380 Wad 8g ; 3 ; 0,25 AN Fly) +5 Ory) > Nay) 3HO,) 0,25 an=(148)-(2+ 0,5mol 0,25 AH ~AU =AnRT =0,5x8,314X298 AH —AU =1238,786J =1,239kF 1184 daieay oi ae (GaN Aosta) bea I 8S + Blab Sse ay! gas wal 7 ge aT (93) & ye BOY) palis * [eoanad] ie (AS g da gall) La) pa Eocayad 2(N-H) ag 3 42s hae (4 1 3 ast (it FN +3 Hay) 05 | Sam (fen) dane, (rz) Not 025 AH9(NHy,,)= RAH" (v= N)+3aH, (H-H)+3E : 40=1(015)+3(490)+3F,., 025 Eyag 22S 300 83k) mor 550°C se (2)Uetii AH, dg ne (6 : Se asd S Gb ye 0,25 | AH, =AH,, +f AC,aT AC, = DC, (Produits)- YC, (Reactifs) 0,25 (WH.)-[C, (M2) #36, (H)] (29, 72+ 2,5x10°7')—(27,84+4,2x10°P )—3(27,25+3,2x10°7 )| 0,25 AC, =-50,15-8,8x10°T T =550+273=823K 15 T, =25+273= 208K 025 | AH, =AH;, +], (-50,15-88x10°7 Jar 0,25 | AH, =AH;, -50,15(T -1,) aaa S-2) 2 2 AH gy =-92X10° ~50, 15 (823 - 298) -8, onan (E-C9"| 0,25 | AMfy, =-120918, 26 =-120,924F 11 O85 dake(GN Assia) Lea SG : Sala gg gall 3 (855) gaged) Tip patie Eas 05 0,25 0,75 0,25 O5 0,75 0,75 0,25 0,25 0,25 0,25 0,75 0,25 05 0,25 05 0,25 0,25 0,25 0,25 (B16 05)egah a cn al Cf fe pend deat (1-1 Aue de gam : HyN-(CH2)gp—NHp OS yall - Addu 9: 0 Apeall de yan): HOOC—(CH;)~—COOH CS yall ~ GISIY yb 5 jal) G8 (2 6 paldh Jeli Alstes (3 1 H000-(-CO0H + MHL OAH = Beeb arronme} emie Gehl 99 CCl cab (1 =I 3 yall) Joli sles (2 remoenrcossaeenici—e LE ob graeme + ma Appl de gap go 6-6 Co slall Uta diguall 4 Abad de gana -i (3 ° Cay Glo gH 6-6 ashi ow ahaa Uta Gs fe} ° i i t i += C= (CH) —C—NH-{CH)g NH C— (CH) 7 C—NH—(CH}g—NH— aN yal le Soualls eau (gi) Jeli tes dus (4 HOOC—(CHz),—COOH + 2PCls —» CIOC-(CH,),-COC] + 2POCls + 2HCI é HOOC—(CHz)¢—COOH + 2800, —m CIOC-(CH,)y-COC] + 280, + 2HCI 26-6 shy lau gic Ayal ASH (5 M(Polymere) ————_ ==> m(Polymare) = 1 M(Monomere) M(Monomere) M(Monomére) = (12 x 12) + (22 x1) + (2x 16) + (2 x 14)= 226 g/mol M(Poly) = 200 x 226 = 45200 g/mol las Gane 6-6 Gleb OS fd Ay 16-6 ola Les 235 (6 CS CI 29 ae gle og sin Logie JS A Gad (pil GalfinluSell 11 0 6 daia0,25 0,75 3x05 5x05 0,5 0,5 0,5 0,25 A: HOLS yall Aad) Gai -1(2 ou iri Mgcl D: Hj,C—CH—CH,, E: HyC—CH—CHy Fr HyC—CH—CHy 9 9 I G: Hyo—gH-C—oMger Hi Hyo—gh-E—on Ot Ces detail Sls} a OH Hempel + (er a Horoittory + of CH, (CHs CHs + PVC el lh le J puaily anad i) CDbetall (1 HjC=CH-Cl CH + HCI 8 HyC=9H | foro a bo petals 5 pals 13 yall g 95 (2 PVC 1 Abas giall Al gall AUS Glen (3 Moonomire® 2x12 + 3x1 + 35,5 = 62,5 g/mol = XM ponomire Mj aymire = 1936X62,5 = 121000g/ mol (i ts oh Aa (Ga ph Asata)lea BSS: Salad Aap dgaill UY! ot ae ; a3 lemeat Wes (22 gpagad) a9 patio ean 2x 0,25 2 11 08 7 dake2s gi Agel (Ga ph Asata)lea BSS: Salad Aap dgaill UY! ot ae ; a3 lemeat Wes (22 gpagad) a9 patio ean 0,75 0,5 0,25 0,25 0,25 2x 0,25 0,5 0,5 (is 06) £5 cs a AM AYU Cb GSN) See aad (1-1 cas os) USE le BY OS (ee bes) pHed Be - HL) bat 535 Gales arr arc CH; Lal eS alee Og) USE le Ga) os pH=pHi aie - Y . te HaN—cH—coo" CH calle ost USE cle Gs Y) Gs (gael Lug) pH=11 aie - age) hil jas pale Hg—¢Hi—coo, CH3, rpdhd Bia) Cue oS L yD Giype dite (2 COOH COOH H + NH HN —- H CHy CH D b tb glad ¢L8 Gass (ll Gell (1- I 1 Aut gest) uae # CH—COO + H,0 H3N“—CH—COOH + HO. ————> HN CH Hy ApUM Aza gaall Jase * Hy —et—c0o" + Ho ———> H,N—cH—o00' + H,0 CH Hs 11 Os 8 dakeBH aD) Assia) lag gl BSS ¢ Salad! yal UY! Ayay is . (328 gpasall) Law pol Epayd PH=f ( Vyaow ) sina au 5 (2 shily pKar 9 pHi Gs US Aad Guset (3 1 | byes 2,3 5 pHi=6 taa3 cla Ge ies ro8YOU pkay ded Glan (4 —PKas + PKA, oka op o pH, = PRG: SPS2 = pKa, = 2H, ~pKa, 05 pKa, =2x6-2,3=9,7 0,25 AVON Sag) Qual (5 290 lag je Lal pH= pKay asc — 2x 0,25 tenor 600 3 HyN“—CH—COCH CHs CH; tps | HgN*—CH—cO0" rly) pH=pHj sie — Hs oye lay je Lind pH= play aie ~ 2x0,25 HgN—CH—COO' 3 Haters ees cHy CH pitt 44 qa 4 6 8 40 a2 u ae as 20 22 28 26 28 30VWeOr) 11.089 dakecoal gill aa (Ga ph Asata)lea BSS: Salad ApSjall LEY at Taal (ABD gps) a patie qe [| Egepall | Sijne Enegall (208 07) 22 ys pt Jill J sitiaall gist alas} Gls (1-1 0,25 AH=AU+AnRT 0,25 An 0,5mol 2 1 7 =25+273 = 208K ~724,76x1 0° -0,5x8,314x298 ~724760 ~1238, 786 = ~725998,786Jmol " 05 AH =~726kJmol"* 1AH?(CH;OH,)) Glas (2 :Hess oi Gubis AH =D. AH/ (produits) - AH! (reactifs) 05 | SH=[AHR(CO,,.)+ 24H H,0,)]-[ AHRICHOH,)+ 2403.) 3 —j =~ 2 —AH* as 0,75 726 = -393 +-2{-286) - AHi(CH,OH,)~5(0) AH} (CH,OH,,) = 726 -393 -572 0,25 ‘AH? (CH,OH,,) = -239kJmol-* too Ala) J) Ail Glo (3 AH, °(CH,OH, Oy + Big + 120, SCH) ou, 0,75 | AH (Co)|2AH°gH-H) |1%AH",,(0-0) ~ AH’,,,(CH,OH) \ ab. Be gtk ©(9)+ 4 Hig) +01 ——* S98", HOH AH#(CH,OH)= AHS (C,q)+24H3,(H—H)+2.aH,(O=0) 15 0,5 2 4+3E, 4) +E go +Eoy ~AH’,,(CH,OH) -239=717 + 2(436) + 1/2(498) + 3(-413) +E, -463-35,4 E, 5 = 239-717 -872-249 +1239 + 463+ 35,4 0,25 E,., =-339,6kJmol CH,OH,, S23 Labs lariat Sl dale! Jai Abs @ 11.04 10 4aia(G4 pa Ansa)ien S85 5 SaLd Apigall Gayl gb (ABD gps) a patie jg Eas 0,75 05 0,5 0,25 05 0,25 0,25 0,25 0,25 0,5 0,25 tJ OY ye oe Giles -f (1 - I rg PV, =nRT=n= PM a ERT, P, =tatm =1,013x10°Pa V, =24,5L =24,5x10°%m? 1 =25 +273 = 298K 4,013x10°x24,5%10° “8314x298 =1mol rable a jl aaa -G w=fo- aT SY = RTI oat We RT Inde “ART In W=-1 x8,314x298 In245 - 704,82 J 245 W =5,705 kJ (AU Ajlasall AMUN (gi yg) Aad g tisk - AU=0 G38: 485 8 i ps Aa ys te rolacaiy) ptti laid) sy) yal) Aus —a AU=Q+W Gal =Q+W=>Q=-W=-5,705 kJ tdgalla W Gaal Glas (2 W = -Pext AV = -Pext(V2 Vi) 583 Cut akae ac - 30x1,013x10°(10° - 0,9x10°) W =- 303,9J 11d 114aia