(12) INTERNATIONAL APPLICATION PUBL (19) World Intellectual Property Orgai International Bureau (43) International Publication Date 13 April 2017 (13.04.2017) p PATE! SHED UNDER TH ‘T COOPERATION TREATY (PCT) (10) International Publication Number WO 2017/060918 Al Zz ANOKA A = WIPO|PCT G1) International Patent Classification tion Lid., HP Green R&D Centre, KIADB Industrial Area, 10M 15710 2006.01) C1O¥ 171/06 (2006.01) Tarabanshalli, Devanagund, Hoskote, Bengluru 360 067 2 (IN). NETTEM, Venkateswarla. Choudary; Hindustan 21) International Application Number: | veosozos __‘Petoleum Corporation Lud, HP Green R&D Centte, KI- STN cea) ADB Industrial Area, Tarabanahali, Devanagundi (2) Imternational Filing Date: Hoskote, Benghuns 560.067 (IN). GANDHAM, Sri 30 June 2016(8006,2016) Ganesh: Hindustan Petroleum Corporation Lid., Visakin i Refinery PB. No, 15, Malkapuram, Visakhapatnam 25) Filing Language: English $3001 (IN). (26) Publication Language: FPrglish (74) Agents: PHILLIPS, Prashant ct al; Lakshmikumaran & (00) Priority Data: Sridharan, Be 6/10, Safdarjung Enclave, New Delhi 3793/MUM/2015 6 October 2015 (06.10.2015) ww 110029). (71) Applicant: HINDUSTAN PETROLEUM CORPORA- (81) Designated States (urless otherwise indicated for every TION LIMITED [INN Petroleum House, 17 Junshedji ‘itd of national protection available): AE, AG, AL, AM, Tata Rood, Churchgate, Maharishi, Mumbai 400020 AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, on 7 : BZ, CA CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, FE, EG. ES. Fl, GB, GD, GE, Gli, GM. GT, (72) Inventors: TOMPALA, Annaji Rajlv Kumar; Hindustan HIN HR” HU ID, IL, IN, IR, IS, 1B, KE, KG, KN, KP, KR Petroleum Corporation Ld,, HP Green R&D Cent Devanagundi ADB Industrial Ares, Tarabanahall, Hoskote, Bengluru $60 067 (IN). VADAPALL GITAM University, Department Of Mechanical Engineer Rushikonda, Visakhapatnam $30 045 (IN). Amitabh Kumar; Hindustan Petroleum Corporation Lim= ited, R&D Centre, Plot D-S00, TTC Industrial Area, Turbhe, Thane, Navi Mumbai 400 705 (IN), Venkata Chalipathi Rao; Hindustan Petroleum Corpor KI KZ, LA, LCL MK, MN, MQ IER, LS, LU, LY, MA, MD, ME, MG, IX, MY, MZ, NA, NG, NI, NO, NZ, OM, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV. SY, TH, TH, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW Designated States (unless otherwise indicated, for every lind of regional protection available); ARIPO (BW, C GM, KE, LR, LS, MW, MZ, NA, RW, SD, S Srinivas; JAIN, (84) PEDDY, ST, SZ, {Continued om next page) WO 2017/060918 At Ill (&4 Title: NANOS 'SPENSION LUBRICANTS rc ° fenras mer ui Fig. 1 (87) Abstract: A method for preparing @ nano suspension lubricant eon prises providing substantially spherical nano particles of size maging fom bout less than $0 nanometers 19 about 100 nanometers, The method further ‘comprises mixing the nano particles and a surfactant in about 1:1 ratio in a solvent to form a mixture, The solvent is evaporated from the mixture to ob in surface modified nano particles, The surface modified nano particles in- clude the nano particles coated with the surfactant, The method comprises mixing the surface modified nano particles with 2 lubricating flu to form the nano suspension lubricant, where the lubricating uid comprises about 90% t0 99% base cil and about 1% to 10% additives,WO 2017/060918 A1 MINNIE HINT ANN V), Furasian (AM, AZ, BY, KG, KZ, RU, Declarations under Rule 4.17 (AL, AT, BE, BG, CH, CY, CZ, DE, R, GB, GR, HR, HU, Ie, IS, TT, LT, . MT, NL, NO, PL, S ), OAPL (BF, BI, CF 1, ML, MR, NE, SN, = oftinventorship Rule 4.176) Published with international search report (Art. 21(3))WO 2017/060918 PCT/IN2016/050208 NANO SUSPENSION LUBRICANTS TECHNICAL FIELD [0001] The present subject matter relates, in general, to lubricants and, in articular, to nano suspension lubricants. BACKGROUND [0002] Lubricants play an important role in improving machine life and performance characteristics of a machine. Lubricants are generally used in mechanical components of machines and automobiles to reduce friction and wear. Friction and wear between moving mechanical components of machines and automobiles often result in energy and material losses. Thus, lubricants are used to improve energy efficiency and mechanical durability of the moving mechanical components. [0003] In general, the functions of a lubricant are to: (a) keep surfaces of moving components separated under all loads, temperatures and speeds, thus minimizing friction and wear; (b) act as a cooling fluid removing the heat produced by friction or from external sources; (c) remain adequately stable in order to ensure uniform behavior over the forecasted useful life; and (d) protect surfaces of the moving mechanical components from the attack of corrosive products formed during operation. [0004] In order to meet the various requirements, one or more types of additives or property modifiers are added into a base oil in a lubricant composition. These additives can be, for example, antioxidants, detergents, anti-wear substances, metal deactivators, corrosion inhibitors, rust inhibitors, etc. BRIEF DESCRIPTION OF DRAWINGS [0005] The detailed description is described with reference to the accompanying figures. In the figures, the left-most digit(s) of a reference number identifies the figure in which the reference number first appears. The same numbers are used throughout the drawings to reference like features and components. For simplicity and clarity of illustration, elements in the figures are not necessarily to scale. [0006] Fig. 1 illustrates a method for preparing a nano suspension lubricant, according to an example implementation [0007] Fig. 2 graphically illustrates X-ray Diffraction analysis test results for a copper based nano suspension lubricant, according to an example implementation.WO 2017/060918 PCT/IN2016/050208 [0008] Fig. 3(a) illustrates wear test results for a Molybdenum Disulphide (MoS) based nano suspension lubricant with diesel engine oil as the lubricating fluid at a load of 40 kgf, according to an example implementation. [0009] Fig. 3(b) illustrates wear test results for a Molybdenum Disulphide (MoS,) based nano suspension lubricant with diesel engine oil as the lubricating fluid at a load of 60 kgf, according to an example implementation. [0010] Fig. 3(c) illustrates wear test results for a Molybdenum Disulphide (MoS) based nano suspension lubricant with petrol engine oil as the lubricating fluid at a load of 40 kgf, according to an example implementation. [0011] Fig. 3(d) illustrates wear test results for a Molybdenum Disulphide (MoS) based nano suspension lubricant with petrol engine oil as the lubricating fluid at a load of 60 kf, according to an example implementation. [0012] Fig. 3(e) illustrates wear test results for a Molybdenum Disulphide (Mo$,) based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid at a load of 40 kgf, according to an example implementation. [0013] Fig. 3(f illustrates wear test results for a Molybdenum Disulphide (MoS.) based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid at a load of 80 kaf, according to an example implementation. [0014] Fig. 3(g) illustrates wear test results for a Molybdenum Disulphide (MoS) based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid at a load of 40 kgf, according to an example implementation. [0015] Fig. 3(h) illustrates wear test results for a Molybdenum Disulphide (MoS) based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid at a load of 80 kgf, according to an example implementation, [0016] Fig. 4(a) graphically illustrates friction test results indicating the variation in coefficient of friction for the MoS, based nano suspension lubricant with diesel engine oil as the lubricating fluid, according to an example implementation. [0017] Fig. 4(b) graphically illustrates friction test results indicating the variation in seizure load for the MoS, based nano suspension lubricant with diesel engine oil as the lubricating fluid, according to an example implementation.WO 2017/060918 PCT/IN2016/050208 [0018] Fig. 4(c) graphically illustrates friction test results indicating the variation in coefficient of friction for the MoS. based nano suspension lubricant with petrol engine oil as the lubricating fluid, according to an example implementation. [0019] Fig. 4(d) graphically illustrates friction test results indicating the variation in seizure load for the MoS, based nano suspension lubricant with petrol engine oil as the lubricating fluid, according to an example implementation. [0020] Fig. 4(e) graphically illustrates friction test results indicating the variation in coefficient of friction for the MoS, based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation. [0021] Fig. 4(1) graphically illustrates friction test results indicating the variation in seizure load for the MoS, based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation. [0022] Fig. 4(g) graphically illustrates friction test results indicating the variation in coefficient of friction for the MoS, based nano suspension lubricant with gear cil of grade EP 140 as the lubricating fluid, according to an example implementation. [0023] Fig. 4(h) graphically illustrates friction test results indicating the variation in seizure load for the MoS, based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid, according to an example implementation. [0024] Fig. 5(a) graphically illustrates extreme pressure (EP) test results indicating the variation in Load wear index (LW!) of the MoS. based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation [0025] Fig. 5(b) graphically illustrates the extreme pressure (EP) test results indicating the variation in weld load of the MoS, based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation, [0026] Fig. 5(c) graphically illustrates the extreme pressure (EP) test results indicating the variation in Load wear index (LWI) of the MoS, based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid, according to an example implementation,WO 2017/060918 PCT/IN2016/050208 [0027] Fig. 5(d) graphically illustrates the extreme pressure (EP) test results indicating the variation in weld load of the MoS, based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid, according to an example implementation. [0028] Fig. 6 graphically illustrates characterization of worn out balls on a scanning electron microscope with X-ray diffraction attachment for the MoS, based nano suspension lubricant, according to an example implementation. [0029] Fig. 7 graphically illustrates variations in brake thermal efficiency of the MoS, based nano suspension lubricant in a petrol engine test rig, according to an example implementation [0030] Fig. 8 graphically illustrates variations in brake thermal efficiency of the MoS, based nano suspension lubricant in a diesel engine test rig, according to an example implementation, [0031] Fig. 9 graphically illustrates variation in total fuel consumption for the MoS, based nano suspension lubricant, according to an example implementation. [0032] Fig. 10(a) illustrates wear test results for a Tungsten Disulphide (WS.) based nano suspension lubricant with diesel engine oil as the lubricating fluid at a load of 40 kgf, according to an example implementation: [0033] Fig. 10(b) illustrates wear test results for the Tungsten Disulphide (WS,) based nano suspension lubricant with diesel engine oil as the lubricating fluid at a load of 60 kgf, according to an example implementation [0034] Fig. 10(c) illustrates wear test results for the Tungsten Disulphide (WS.) based nano suspension lubricant with petrol engine oil as the lubricating fluid at a load of 40 kgf, according to an example implementation [0035] Fig. 10(d) illustrates wear test results for the Tungsten Disulphide (WS,) based nano suspension lubricant with petrol engine oil as the lubricating fluid at a load of 60 kgf, according to an example implementation. [0036] Fig. 10(e) illustrates wear test results for the Tungsten Disulphide (WS;) based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid at a load of 40 kgf, according to an example implementation.WO 2017/060918 PCT/IN2016/050208 [0037] Fig. 10(f) illustrates wear test results for the Tungsten Disulphide (WS,) based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid at a load of 80 kgf, according to an example implementation. [0038] Fig. 10(g) illustrates wear test results for the Tungsten Disulphide (WS;) based nano suspension lubricant with gear oil of grade EP 140 as the lubricating fluid at a load of 40 kgf, according to an example implementation. [0039] Fig. 10(h) illustrates wear test results for the Tungsten Disulphide (WS-) based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid at a load of 80 kgf, according to an example implementation. [0040] Fig. 11(a) graphically illustrates friction test results indicating the variation in coefficient of friction for the WS, based nano suspension lubricant with diesel engine oil as the lubricating fluid, according to an example implementation. [0041] Fig. 11(b) graphically illustrates friction test results indicating the variation in seizure load for the WS, based nano suspension lubricant with diesel engine oil as the lubricating fluid, according to an example implementation. [0042] Fig. 11(c) graphically illustrates friction test results indicating the variation in coefficient of friction for the WS, based nano suspension lubricant with petrol engine oil as the lubricating fluid, according to an example implementation. [0043] Fig. 11(d) graphically illustrates friction test results indicating the variation in seizure load for the WS, based nano suspension lubricant with petrol engine oil as the lubricating fluid, according to an example implementation. [0044] Fig. 11(e) graphically illustrates friction test results indicating the variation in coefficient of friction for the WS, based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation. [0045] Fig. 11(f) graphically illustrates friction test results indicating the variation in seizure load for the WS; based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation. [0046] Fig. 11(g) graphically illustrates friction test results indicating the variation in coefficient of friction for the WS. based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid, according to an example implementation.WO 2017/060918 PCT/IN2016/050208 [0047] Fig. 11(h) graphically illustrates friction test results indicating the variation in seizure load for the WS. based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid, according to an example implementation. [0048] Fig. 12 graphically illustrates characterization of worn out balls on a scanning electron microscope with X-ray diffraction attachment for the WS, based nano suspension lubricant, according to an example implementation. [0049] Fig. 13 graphically illustrates variations in brake thermal efficiency of the WS, based nano suspension lubricant in the petrol engine rig, according to an example implementation. [0050] Fig. 14 graphically illustrates variations in brake thermal efficiency of the WS, based nano suspension lubricant in the diesel engine rig, according to an example implementation. [0051] Fig. 15 graphically illustrates the variation in total fuel consumption for the WS, based nano suspension lubricant, according to an example implementation. [0052] Fig. 16(a) graphically illustrates extreme pressure (EP) test results indicating the variation in Load wear index (LWI) of the WS; based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation. [0053] Fig. 16(b) graphically illustrates the extreme pressure (EP) test results indicating the variation in weld load of the WS, based nano suspension lubricant with gear oil of viscosity grade SAE 80 W 90 as the lubricating fluid, according to an example implementation. [0054] Fig. 16(c) graphically illustrates the extreme pressure (EP) test results indicating the variation in Load wear index (LWI) of the WS, based nano suspension lubricant with gear oil of viscosity grade EP 140 as the lubricating fluid, according to an example implementation, [0055] Fig. 16(d) graphically illustrates the extreme pressure (EP) test results indicating the variation in weld load of the WS. based nano suspension lubricant with gear cil of viscosity grade EP 140 as the lubricating fluid, according to an example implementation.WO 2017/060918 PCT/IN2016/050208 DETAILED DESCRIPTION [0056] Typically, lubricants are prepared by adding additives to a base oil Generally, on fractional distillation of crude oil, different base oils separate out as distillates. Examples of base oils are petroleum distillates, mineral oils, vegetable oils, esters, polyolefin, etc. Recently, nano particles have been tested for use as additives in the base oils for lubricants in automobile and other industrial applications. The nano particles may be metals, non-metals, or salts of metals and non-metals having an average particle diameter upto 100 nanometers. Nano particle based lubricants exhibit better tribological properties as compared to ordinary lubricants without nanoparticles. Nanoparticles are considered well suited for tribological applications since lubrication takes place at nano scale level. For instance, certain nano particle molecules can form a thin coating with the thickness of just one or two molecules to separate surface asperities of the moving components of a machine. This may result in better friction resistance between the moving components. [0057] Nano particles have a high surface affinity and chemical reactivity and their small sizes enable them to penetrate into wear crevices. Thus, nano particles are emerging as suitable additives for industrial lubricants, such as, lubricating engine oils, greases, dry film lubricants, and forging lubricants. Several types of nanoparticles have been studied as potential additives for lubricants, including metal oxides of silicon, titanium, nickel, tin, aluminium, and zinc; fluorides of metals such as cerium, lanthanum, and calcium; and zinc, tin, and lead sulfides, and metals, such as nickel, zine, tin, and silver, and non-metals like carbon nanotubes. [0058] Itis generally postulated that rigid spherical and cylindrical nanoparticles dispersed in the base oils protect contacting metal surfaces that are in relative motion from wear by rolling actions, i.e., the nano particles act as miniature ball bearings. However, at higher loads and speeds, the nano particles fall short in the intended lubricating functions. In particular, high wear rates and friction failures remain to be challenging issues for nano particle based lubricants. Thus, nano particles dispersed in base oils are not able to sufficiently provide the intended functions of the nano particle based lubricant. [0059] Better lubricating properties may be obtained when the nano particles are dispersed in lubricating fluids, such as fully formulated lubricants, for example, petrol engine oil of SM grade, diesel engine oil of Cl 4 grade, and gear oil GL 4 grade. The lubricating fluids include base oils and other additives, such as, detergents, anti-WO 2017/060918 PCT/IN2016/050208 foaming agents, antioxidants, etc., that have different property modifying effects which make them suitable for use as lubricants. However, there lies a crucial challenge with dispersing the nano particles in the lubricating fluid. On mixing the nano particles in the lubricating fluid, the nano particles have a tendency to agglomerate and settle down after a certain period of time. This results in an unstable solution of the nano particles in the lubricating fluid. Additionally, it is a challenge to obtain a uniform dispersion of the nano particles in the lubricating fluid. [0060] The subject matter described herein relates to a method for preparing a nano suspension lubricant. The nano suspension lubricant described herein includes nano particles dispersed in the lubricating fluid. The lubricating fluid includes a base oil, such as, mineral oils, vegetable oils, esters, etc., and other additives, such as, boron, calcium, ete., that act as antioxidants, anti-wear agents, and the like. In an example implementation, the lubricating fluid may be a fully formulated lubricant, such as, petrol engine oil of SM grade, diesel engine oil Cl 4 grade, and gear oil GL 4 grade. The nano suspension lubricant is prepared by mixing surface modified nano particles in the lubricating fluid. As explained later based on test results, the nano suspension lubricant has a greater stability in the lubricating fluid. In an example implementation, surface modification of the nano particles results in the nano particles being coated with an appropriate surfactant selected based on the electrostatic charge of the nano particle and the surfactant that coats on the nano particle. The surface modified nano particles are mixed in the lubricating fluid to form the nano suspension lubricant. The surfactant coated on the surface of the nano particles prevents agglomeration of the nano particles in the lubricating fluid and ensures formation of a stable suspension of the surface modified nano particles in the lubricating fluid. In addition, the nano suspension lubricant obtained on mixing the surface modified nano particles in the lubricating fluid also has better tribological properties, such as, better friction resistance, wear resistance, and an improved brake thermal efficiency, as compared to a conventional nano particle lubricant in which the nano particles are dissolved in a base cil, [0061] Further, tests reveal that there is no deterioration of the physico- chemical properties, such as viscosity index, total acid number, total base number, etc. of the nano suspension lubricant and hence the nano suspension lubricant is suitable for use in the automobile environment. [0062] These and other advantages of the present subject matter would be described in greater detail in conjunction with the following figures. It should be notedWO 2017/060918 PCT/IN2016/050208 that the description and figures merely illustrate the principles of the present subject matter and in no way limit the present subject matter to the description and figures illustrated herein [0063] Fig. 1 illustrates a method 100 for preparing the nano suspension lubricant, according to an example implementation of the present subject matter. The method 100 for preparing the nano suspension lubricant includes providing substantially spherical nano particles, at block 102. The nano particles may have different structures. For instance, metallic nano particles, such as zinc, tin, copper, tungsten, etc., generally have a substantially spherical structure, while non-metallic nano particles like, tungsten disulphide nano rods and carbon nano tubes have a cylindrical structure with diameters in the nanometric range. The present method includes providing substantially spherical nano particles having an average particle diameter ranging from about less than 50 nanometers to about 100 nanometers. It has been tested that the substantially spherical nano particles over the mentioned range exhibit optimal lubricating properties. Nano particles having a greater particle diameter may tend to wear out the surfaces of the moving mechanical components that are lubricated using the nano suspension lubricant. In an example implementation, the nano particles used for the method 100 may be selected from one of copper, molybdenum disulphide, and tungsten disulphide. [0064] At block 104, the method 100 includes mixing the nano particles and a surfactant in about 1:1 ratio in a solvent to form a mixture. In an example implementation, the solvent may be one of n-hexane, iso octane and toluene. In an example implementation, the solution is stirred in a probe sonicator for about 1 hour for thorough mixing. For stability in a fluid medium, the surface of the nano particles needs to be suitably modified with the surfactant. The surfactants include compounds that lower the surface tension between two liquids or a liquid and a solid and may be used as detergents, anti-foaming agents, and dispersants. Common examples of surfactants include oleic acid, palmitic acid, lauryl alcohol, etc. When the surfactants are mixed with the Nano particles, one end of the surfactant molecule attach to the surface of the nano particle through chemical bonds. The other end of the surfactant molecule is free and extends into the lubricating fluid. Thus, the surfactants generate an effective repulsive force between the nano particles due to steric repulsion between the surfactant molecules attached to the surface of the nano particles. The effective repulsive force between the nano particles coated with the surfactant results in a stable mixture of theWO 2017/060918 PCT/IN2016/050208 nano particles in the lubricating fluid. According to an example implementation, the surfactant may be selected from one of lauric acid, , and cetrimonium bromide based on the electronegativity of the surfactant and the type of nano particle on which it is to be coated. In an example implementation, the nano particles and the surfactant are mixed in the solvent by stirring the nano particles and the surfactant in the solvent in an ultra-sound sonicator for about 7 to 8 hours. [0065] At block 106, the method 100 includes evaporating the solvent from the mixture to obtain surface modified nano particles. In an example implementation, the solvent may evaporated at room temperature. On evaporation of the solvent, one end of the surfactant molecule properly bonds to the surface of the nano particles. The surface modified nano particles include the nano particles coated with the surfactant. The surfactant ensures that the surface modified nano particles do not agglomerate when mixed in the lubricating fluid. Thus, a stable dispersion of the surface modified nano particles in the lubricating fluid may be obtained. [0066] At block 108, the method 100 includes mixing the surface modified nano particles with the lubricating fluid. The lubricating fluid includes base oil and additives. In an example implementation, the lubricating fluid includes about 90% to 99% base oil and about 1% to 10% additives. The additives present in the lubricating fluid may include corrosion inhibitors often used in engine coolant like Boron, alkaline or detergent additives, such as magnesium and calcium used to neutralize acids which form during a combustion process in an engine, a friction-reducer and anti-oxidant, such as molybdenum, an anti-foaming agent, such as silicon, and an anti-oxidant and anti-wear agent, such as Zinc dialkyl dithio phosphate (ZDDP). The lubricating fluid contains the above mentioned elements as additives for functioning under severe conditions. In an example implementation, mixing the surface modified nano particles with the lubricating fluid may include sonicating the surface modified nano particles in the lubricating fluid. The sonication may be performed in an ultra-sound sonicator at an amplitude of about 50% and a power of about 200 watts for a duration of about 60 minutes. To obtain optimal results, in an example implementation, the sonication of the surface modified nano particles in the lubricating fluid may be performed in two different modes of sonication. in the example implementation, for 30 minutes the sonication may be performed in pulse mode with 0.5 second pulse. This prevents the agglomeration of the surface modified nano particles. For remaining 30 minutes the sonication is 10WO 2017/060918 PCT/IN2016/050208 performed in continuous mode which uniformly disperses the surface modified nano particles into the lubricating fluid. [0067] The following discussion is directed to various examples of the present subject matter. Although certain methods and compositions have been described herein as examples, the scope of coverage of this patent application is not limited thereto. On the contrary, the present subject matter covers all methods and compositions fairly falling within the scope of the claims either literally or under the doctrine of equivalents [0068] Certain terms are used throughout the description to refer to certain components and are to be construed as being mentioned by way of example and for purposes of explanation and not as limiting. [0069] The term “viscosity index’ as used in the examples refers to change in viscosity of a lubricant with change in temperature. The lower the viscosity index, the greater is the change of viscosity of a lubricant with temperature. Thus, the higher the viscosity index, the better is the quality of the lubricant. A viscosity index value greater than 90 is preferred for the lubricant. [0070] The term “American Society for Testing and Materials (ASTM) D 445" as used in the examples refers to a test method that specifies a procedure for determination of kinematic viscosity of the lubricant by measuring the time for a volume of liquid to flow under gravity through a calibrated glass capillary viscometer. [0071] The term ‘total acid number" (TAN) ASTM D 664 as used in the examples refer to a measure of weak organic and strong inorganic acids present in a lubricant. The TAN is the amount of potassium hydroxide in milligrams required to neutralize the acids in one gram of the lubricant. The TAN value indicates potential corrosiveness of the lubricant. A TAN value lesser than 3 indicates that the lubricant is stable. [0072] The term “total base number” (TBN) as used in the examples refers to effectiveness of the lubricant in controlling acid formation during combustion process. The higher the TBN, the more effective the lubricant is in suspending wear-causing contaminants and reducing the corrosive effects of acids over an extended period of time. A TBN value higher than 9 indicates that the lubricant has good control over acid formation during the combustion process. uWO 2017/060918 PCT/IN2016/050208 [0073] The term “ASTM D 2896" as used in the examples refers to a test method for determination of the TBN of the lubricant by potentiometric titration with perchloric acid in glacial acetic acid. [0074] The term “ASTM copper strip corrosion standard as per ASTM D 130" as used in the examples refers to a standard used for representing corrosion protection of the lubricant. The standard has classification numbers from 1 to 4 for various color and tarnish levels of a copper strip immersed in the lubricant. A classification number of 1a indicates excellent corrosion protection, 1b indicates good corrosion protection, and 1c indicates sufficient corrosion protection of the lubricant. [0075] The term “copper strip corrosion test” as used in the examples refers to a test used for determining the classification number of the lubricant. The test involves immersion of a polished copper strip in the lubricant at elevated temperature for a period of time and testing the color and tarnish levels of the copper strip. [0076] The term “four-ball wear test machine’ as used in the examples refers to a machine used for testing various performance characteristics of the lubricant. The machine comprises of a ball pot in which three balls are clamped together and thereby kept stationary or fixed in one position. These balls are then covered with the lubricant. A fourth ball is pressed against a cavity formed by the three stationary balls and the fourth ball is rotated. [0077] The term “wear scar diameter’ as used in the examples refers to diameter of wear scars on the three stationary balls tested on the four-ball wear test machine. The larger the wear scar, the poorer is the lubricating abilty of the lubricant. [0078] | The term “ASTM D 4172" as used in the examples refers to a test method for evaluation of the anti-wear properties of the lubricants in sliding contact by means of the Four-Ball Wear Test Machine. [0079] The term “seizure load” as used in the examples refers to a load at which a sudden increase in coefficient of friction value occurs. The higher the seizure load, the better the anti-friction property of the lubricant. [0080] The term “ASTM D 5183" as used in the examples refers to a test method for determining coefficient of friction of the lubricant by means of the Four-Ball Wear Test Machine. Initially, a load is applied which gradually increased at regular time intervals until the lubricant undergoes seizure.WO 2017/060918 PCT/IN2016/050208 [0081] The term “friction test’ as used in the examples refers to a test performed for determining the seizure load and the coefficient of friction of the lubricant. The seizure load refers to the load at which there is a sharp rise in fractional torque characterized on a graph while the machine is running. The coefficient of friction is determined by considering the loads between initial load and the seizure load, [0082] The term “ASTM D 2783" as used in the examples refers to a test method for determination of the load-carrying properties of lubricating fluids. The following two determinations are made using ASTM D 2783: 1. Load-wear index, and 2. Weld load by means of the four-ball extreme-pressure tester. [0083] The term “load-wear index’ as used in the examples refers to an extreme pressure (EP) property of the lubricant calculated using the four-ball wear test machine Here the speed of rotation is maintained at 1760 RPM and the whole test procedure is done under room temperature. A series of tests of 10-s duration are carried out with increasing loads during each tests until 4 balls weld under extreme pressure. The load at which weld occurs is called the weld load. The first run is made at an initial load of 40 kgf and the additional runs are carried out at consecutively higher loads until and the 4 balls weld under extreme pressure. A total of 10 readings are considered in the test and the corrected load is calculated for all ten readings. The load wear index is calculated from the corrected load. The corrected load is calculated as follows: Corrected load=LDh/xX; where L is the applied load in kgf, Dh is hertz scar diameter in mm, and X is average scar diameter in mm. Hertz scar diameter is the average diameter, in mm, of an indentation caused by deformation of the balls under static load before application of the load. It may be calculated from the equation Dh = 8.73X10-3 (P)"®. [0084] The term “endurance test” as used in the examples refers to a test conducted on an engine by subjecting it to varying loads and varying speeds for a continuous period of 80 hours without stoppage. This is used to determine the engine wear & tear and fuel consumption over a period of time. [0085] The term ‘bench test” as used in the examples refers to a test performed on the engine at a particular load and a particular speed to determine the efficiency of the engine at that particular load and speed.WO 2017/060918 PCT/IN2016/050208 [0086] The term "petrol engine rig’ as used in the examples refers to a test rig consisting of petrol engine connected to a dynamometer for applying speed and loads to an engine. [0087] The term “diese! engine rig" as used in the examples refers to test rig consisting of diesel engine connected to dynamometer for applying speed and loads to an engine. EXAMPLES [0088] |The following general compositions of nano suspension lubricants, are used in the Examples. Example 1 Copper based nano suspension lubricant [0089] In an example implementation, the nano suspension lubricant includes surface modified copper nano particles. The copper nano particles have a particle diameter of less than about 50 nanometers. At this range the copper nano particles used in the nano suspension lubricant gives optimal results. A surface of the copper nano particles is modified using a surfactant to prevent agglomeration of the copper nano particles and to get a uniform dispersion of the copper nano particles in the lubricating fluid. Generally, carboxylate groups attach themselves to metal and metal oxide nano particles making them stable in fluids. The carboxylate groups are soluble in both water as well as oils as they contain both lipophilic and hydrophilic ends. Some of the carboxylate groups mostly used for oil dispersion are lauric acid, stearic acid, and maleic acid. In an example implementation, lauric acid is selected as a surfactant for surface modification of the copper nano particles. The copper nano particles are coated with the laurie acid surfactant to form the surface modified copper nano particles. As a result of the surface modification, the polar head of the lauric acid surfactant attaches to the copper nano particles and the hydrophobic end of the laurie acid surfactant attaches to the oil molecule enabling a stable dispersion of the surface modified copper nano particles in the lubricating fluid. In the example implementation, the surface modified copper nano particles from about 0.05 weight % to 0.1 weight % is dispersed in the lubricating fluid. Mixing the surface modified copper nano particles at the mentioned range gives optimal results for the nano suspension lubricant. Beyond the above mentioned range of weight % of the surface modified nano particles there may be an increase in wear effects on mechanical moving components of an engine 14WO 2017/060918 PCT/IN2016/050208 where the nano suspension lubricant is being used. This may be due to overcrowding of the surface modified copper nano particles at an interface between the mechanical moving components of the engine in relative motion. In the example implementation, the lauric acid surfactant is mixed in approximately 25.0 ml of n-hexane or toluene solvent by proper stirring to form a mixture. In an example implementation, lauryl alcohol and triton-X may also be used as surfactants. The copper nano particles are added to the mixture and stirred again for 7-8 hours. The n-hexane or toluene solvent is evaporated at room temperature by keeping the mixture undisturbed overnight thus leaving behind the surface modified copper nano particles. The surface modified copper nano particles are coated with the lauric acid surfactant. The surface modified copper nano particles are mixed in the lubricating fluid using an ultra-sound sonicator for 1 hour to achieve a stable suspension of the surface modified copper nano particles in the lubricating fluid [0090] In an example implementation, the amount of the copper nano particles and surfactant to be mixed in the lubricating fluid to form the stable suspension of the surface modified copper nano particles in the lubricating fluid is given in the following table. Table 1.1: Amount of the copper nano particles and surfactants used to obtain a stable nano suspension lubricant according to an example implementation Surfactant Mass fraction Mass of nano particles to | Amount of surfactant 10 of nano particles be dispersed in of be mixed with nano lubricant particles and solvent for surface modification Laurie acid 0105 % 045 gm 04 gm 01% 09gm 08 em Lauryl alcohol 0105 % 045 gm 12m 01% ‘09gm 20m Triton X -100 0105 % 045 gm 12 mi 01% ‘09gm 24 ml [0091] To test the stability of the copper nano suspension lubricant, an accelerated stability test on a high speed centrifuge has been conducted. In a centrifuge due to the centrifugal action the lighter object move to the top and heavier objects move to the 15WO 2017/060918 PCT/IN2016/050208 bottom. Different suspensions of nano lubricants made of bare and surface modified nano particles are tested on a centtifuge for accelerated agglomeration of the nano patticles under centrifugal action. The centrifugal force applied in the centrifuge tends to bring the nano particles together and agglomerates them. Thus, an uniformly dispersed solvent would remain stable for a longer period of time in the centrifuge. [0092] The following conditions are employed in the test + Duration of the test 20 mins + Speed of the centrifuge 10, 000 RPM The test results indicate that when uncoated nano particles are dispersed in the lubricating fluid, the nano particles get agglomerated and settle within the first minute of the test. In an example implementation, the nano suspension lubricant containing 2 ™mMol of lauryl alcohol as surfactant remains stable for about 10 minutes and the nano suspension lubricant containing 2.5 mMol of lauryl alcohol remains stable for about 20 minutes under the centrifugal action. [0093] Further, tests are also being performed for evaluating changes in Physico- chemical properties, such as, density, viscosity index, total acid number, total base number, sulfonated ash, flash Point, fire point, pour point, etc., of the nano suspension lubricant dispersed with surface modified copper nano particles according to an example implementation of the present subject matter. Any deterioration of the Physico-chemical properties of the nano suspension lubricant below predetermined standards may render the nano suspension lubricant unsuitable for use in automotive environment. The Table 1.2 depicts test results of the physico-chemical properties of the copper based nano suspension lubricant. 16WO 2017/060918 PCTYIN2016/050208 Table 1.2: Test results of the physico chemical properties of the copper based nano suspension lubricant SR PROFERTIES Bee Se baa xo METHOD Ibriewit a renine DEM @ 1S DEG Ca aaa a9 | Ranenatie Vicon ar 40 deg Co iT est ise 3 | Rises Vases at 100 dea ©, | ASRED BE we ee 188 Sa eo ASD ESS | Tat ot Tes TAN weKOW Sa aes | Tae 1 se 2 | Sara ASD EN | 1a aT TF | Fi Point dea ASTM DS? Tse 195 3 | Faw Poms deg ASREDST co a S| Bapoaed Tones Cs saw 255 | AED SSO] 3S =F cs) aes} Ti | cold Conk Sema PH FDISE | SOS a bege Wisi Feapesme Rigi Sher ® [ASTD Wa] 75 7E or Ta | Tow eam pupina vacony ap PASTAE SSS Ec) Soe FER 2 | Capper wap wontons 0100 deg [ASD BIS TR TA TA TE | Conrsoon Caton Raise AaB as TE The test results tabulated in table 1.2 indicate that there is no significant change in the physico-chemical properties of the nano suspension lubricant that may render the nano suspension lubricant unsuitable for use in the automotive environment. [0094] |The tribological properties, such as friction resistance, wear resistance, etc., of the copper based nano suspension lubricant is also tested to evaluate improvements in lubricating properties of the nano suspension lubricant. Table 1.3 illustrates the same. [0095] A detailed Tribological analysis and testing is being done as per ASTM G99 standard on a pin on disc tribometer. Prior to conducting the test, the discs are ground in a grinding machine and ensured to be smooth uniformly. The surface roughness is checked for all discs under testing and ensured that they are in the same range (0.2 - 0.4 jum Ra). This is done to ensure that all the tests are conducted under the same conditions to achieve uniformity. 7WO 2017/060918 PCT/IN2016/050208 The test conditions are listed below: * Load: 5, 10, 15 & 20 kot * Speed of rotation: 300, 600, 1200 RPM * Pin & Disc materials: Cast Iron Table 1.3: Variation in coefficient of friction of the copper based nano suspension lubricant at a range of increasing speeds at constant loads Pin on disc resale ge Coelliceat of Bienon % Chauge fom base Mibricsat Set [Swe ca oF & Rem — |ivtricaat | oases fou 02% ot 300) oon |aasr jomse [toro [isss | sae 00 vows |ecss [oan joons | 1160 | ior 300 woies [oon [oosse [omsse | a58 cary Yoo [oars [aoass |oosee |onase [toa? [ates | 26a It may be noted from the above table that the copper based nano suspension lubricant exhibits improved friction resistance. [0096] | Tribological testing with ASTM 4 Ball wear tester The wear preventive and anti-friction properties of the lubricants mixed with nano particles are being evaluated using ASTM 4 ball wear tester. As per ASTM D 4172, the wear preventive properties of the nano suspension lubricant can be characterized from the test results tabulated below. Table 1.4: Variation in wear scar diameter with the copper based nano suspension lubricant Lubricant sar in micro meters Base lubricant 554 Base lubricant +0.05 % Cu nano particles 485 Base lubricant +0.1 % Cu nano particles 432 18WO 2017/060918 PCT/IN2016/050208 It may be noted from the the wear scar diameter has substantially reduced with increase in the weight % of the surface modified copper nano particles dispersed in the lubricating fluid. This indicates improvement in wear preventive properties of the copper based nano suspension lubricant. [0097] X-Ray Diffraction (XRD) analysis Metallographic studies are conducted to assess the reduction in wear due to use of the nano suspension lubricant according to an example implementation. After conducting wear tests, the balls of wear test are subjected to XRD analysis for analysis of the Possible deposition of the copper nano particles on surfaces of the worn balls. Fig. 2 graphically illustrates the XRD analysis test results for the copper based nano suspension lubricant according to an example implementation. The graph 200 shown in Fig. 2 depicts the amount of deposition of the copper nano particles present in the nano suspension lubricant onto the worn out surfaces of the metallic balls. In x-axis a diffraction angle of the X-ray diffraction is plotted and in the y-axis the amount of deposition of the copper nano particles on the surface of the worn our metallic balls is depicted. The diffraction angle is measured in degrees and the amount of deposition is expressed in an arbitrary unit of number of cycles of measurement in the XRD. From the Fig. 2 it may be noted that along with iron(Fe), Nickel(Ni), Chromium (Cr) and ‘oxygen(O) copper (Cu) can also be seen at peaks of the graph 200. This suggests deposition of the copper nano particles on the surface of the worn out balls and form a protective coating thereby offering resistance to wear. [0098] Friction test as per ASTM D 5183 standard The friction test has been conducted to determine the coefficient of friction of the copper based nano suspension lubricant under the following prescribed test conditions using the ASTM 4 Ball wear tester. The test is conducted under the following test conditions: + Temperature 75#2°C + Speed 600 RPM ‘+ Duration 10 min at each load starting from 10 kaf + Load 98.1 N (10 kaf) per 10 min increment to a load that indicates incipient seizure, i.e., sudden increase in friction force value over steady state on the friction trace. Table 1.5: Variation in coefficient of friction of the copper based nano suspension lubricant with increasing loads at a constant speed 19WO 2017/060918 PCT/IN2016/050208 al veizine load Base lubricant 2% vT Base inbricant 70.08 % Cu 1 part jisant *0.1 9 Cu nano part Thus, the test results depicted in the Table 1.5 suggest that the coefficient of friction deceases with increase in the surface modified copper nano particles dispersed in the lubricating fluid and thus at 0.1 weight % of the surface modified copper nano particles dispersed in the lubricating fluid the results are optimum. [0099] Tests conducted on roller test bench Tests have been done using roller test bench with a two-wheeler mounted on it. Hydraulic load is applied on the rollers of the test bench and the rollers in turn apply braking action on the rear wheel. Tests were carried out with the lubricating fluid without nano particles and the lubricating fluid mixed with 0.05 weight % & 0.1 weight % of the surface modified copper nano particles. The hydraulic loading is done by means of water forcing through a dynamometer at a particular pressure. The pressure may be regulated by operating a gate valve. To increase or decrease the load, the gate valve is opened or closed thereby regulating the pressure. The tests were carried out at constant speeds of 40, 50 & 50 KMPH at various gate openings of the dynamometer. The initial gate opening is fixed at 40 KMPH and 2 kgf, 3 kgf & 4 kgf load respectively and the speed is increased with a corresponding increase in load. [00100] The rated brake power of the engine is 5.733 KW(7.8 HP) and the testing was carried out up to a maximum load 8 kgf @ 60 KMPH which corresponds to 3.5 kW of brake power or 62 % of Maximum brake power. The following sample results compare the results of the lubricating fluid and lubricating fluid mixed with the surface modified copper nano particles. From the results tabulated below it can be observed that when the two-wheeler uses the lubricating fluid mixed with surface modified copper nano particles better mileage and brake thermal efficiency is obtained. 20WO 2017/060918 PCT/IN2016/050208 Table 1.6: Test results for roller test bench with the copper based nano suspension lubricant SPEED | MILEAGE | LOAD | N_ | Brake] tf [nm] % (KM/H | (KM/LITRE | (KG) | RPM | power | kg/hr Change R) ) kW From base lubrican t Lubricating 7863 73 fluid 40 8275] 2.01 5| os82 | 0.358] 01 Lubricating fluid +0.05 % surface modified Cu nano 7863 14. particles 40 93.91} 2.03 5| 0.587 }osis} 90] 13.48 Labrie fluid +0.1 % surface modified Cu nano 7863 13, particles 40 88.13] 2.02 5| 0.585 | 0.336] 94 65 Lubricating 7. fluid 40 76.23 3.01 | 786.35 | 0.869 | 0.388 | 91 Lubricating fluid +0.05 % surface modified Cu nano 18. particles 40 79.01 3.03 | 786.35 | 0.876 | 0.375] 70] 3.64WO 2017/060918 PCT/IN2016/050208 Lubricating fluid +0.1 % surface modified Cu nano 19. particles 40 81.85 3.06 | 786.35 | 0.883 } 0.362] 54] 7.34 Lubricating 20. fluid 40 6351 4.08 | 786.35 | 1.178 | 0.466 | 22 Lubricating fluid +0.05 % surface modified Cu nano 21. particles 40 64.48 4.03 | 786.35 | 1.163 | 0.459] O1 15 Lubricating fluid +0.1 % surface modified Cu nano 22, particles 40 70.29 4.05 | 786.35 | 1.171 | 0.421] 25] 10.67 SPEED | MILEAGE Brake % (KM/HR | (KM/LITRE | LOAD | N | power | tfe chan ) ) (KG) }RPM} kW [ker | na | ge Lubricatin 982.9 147 g fluid 50 69.05) 273] 4] 0987 | 0536] 3 Lubricatin g fluid 40.05 % surface modified 982.9 168 Cu nano 50 7173| 277) 4] 1.002 | 0476] 4] 12.57WO 2017/060918 PCT/IN2016/050208 particles Labricatin g fluid 40.1% surface modified Cu nano 982.9 174 particles 50 7849] 280] 4] Loto | 0472] 4] 13.67 Tubricatin 982.9 20.6 g fluid 50 61.03) 432] 4] 1.562 | 0.606] 1 Tubricatin g fluid +005 % surface modified Cu nano 982.9 219 particles 50 65.53] 430] 4] 1552 | 0566] 8] 7.37 Labricatin g fluid 40.1 % surface modified Cu nano 982.9 2. particles 50 67.94} 430] 4] 1552 | osas} 9 11.32 Labricatin 982.9) BS g fluid 50 sosi] 6.00] 4] 2.168 | 0.729] 2 Lubricatin g fluid 40.05 % surface modified 982.9 24.5 Cu nano 50 3.06) 5.93] 4] 2140 | 069s} 4] 4.42WO 2017/060918 PCT/IN2016/050208 particles Labricatin g fluid 40.1% surface modified Cu nano 982.9 2643 particles 50 5654] 5.97] 4] 2.158 | O655} 8] 11.27 ‘SPEED | MILEAGI Brake % (KM/HR | (KM/LITRE | LOAD | N power | tfc chang ) ) (KG) | RPM} kW | ke/tr | na fe Lubricati 1179. 164 ng fluid 6 50.75 415] 52] 1.801 }os7s| 7 Tabricati ng fluid 40.05 % surface modified Cu nano 1179, 20.6 particles 60. 65.34 404] 52] 1.753 | 0.680} 2] 16.27 Labricatt ng fluid 40.1% surface modified Cu nano 1179, 209 particles 0 65.66 409] 52] 1.772 | 0677} 6] 22.34 Lubricati 2.61 18.7 ng fluid oo 39.69 6.04] 117952] 8 Jis9] 2 Labricati ng fluid 2.61 19.7 40.05 % 60. 41.83 604] 1179.52] 9 | 1063} 4] 544 24WO 2017/060918 PCT/IN2016/050208 ‘surface modified Cu nano particles Labricatt ng fluid 40.1% surface modified Cu nano 2.60 219 particles 0 46.67 602] 1179.52] 7 |0954} 3] 17.16 Lubricati ng fluid * the bike could not run at this speed and load with the lubricating fluid Labricati ng fluid +0.05 % surface modified Cu nano 3.46 20.4 particles 60. 32.73 8.00] 117952] 6 | 1363) 4 Tubricati ng fluid 40.1 % surface modified Cu nano 3.50 25.2 particles 60 39.93 809] 117952] 8 | iia} 4 [00101] It can be noted from the table 1.6 that at lower loads and speeds, the percentage change in brake thermal efficiency is medium and at higher loads and speeds it is quite high. It is also observed that the lubricating fluid mixed with 0.1 weight % of the surface modified copper nano particles gives best mileage at all loads and speeds. It can be inferred that the optimum amount of the surface modified copper 25WO 2017/060918 PCT/IN2016/050208 nano particles to be added to the lubricating fluid for best performance of the two- wheeler corresponds to 0.1 weight %. Further increase in the weight % of the surface modified coper nano particles in the lubricating fluid, may increase viscous effects of the copper based nano suspension lubricant thereby increasing pumping losses of the engine and hence decreasing mileage of the engine, [00102] Test for deceleration of the two-wheeler The friction in moving parts of an engine of the two-wheeler is directly related to acceleration and deceleration of the two-wheeler. A high acceleration and low deceleration of the two-wheeler infers lesser friction in the moving parts. The test method of assessing the reduction in friction of the moving parts is being done by noting the acceleration and deceleration of the two-wheeler. The two-wheeler is accelerated to 60 KMPH speed and the power of the two-wheeler is switched off. The time required by the two-wheeler to decelerate from 60 KMPH to 0 KMPH is noted down. The results are tabulated below. ‘Table 1.7: Variation in deceleration time with the copper based nano suspension lubricant De mi time in seconds Toad Base lubrivant Base lubricant > | Base lubricant > particles ai Sai sees [sss 35H 3 586 73s 5 4 636 68 7. It may be observed from Table 1.7 that the copper based nano-suspension lubricant has taken more time for deceleration than the lubricating fluid without any nano particle dispersed in it. This suggests that the friction in the moving parts of the two-wheeler while using the copper nano suspension lubricant is less and thus loss of energy due to friction is reduced. [00103] Field test on actual road conditions Field tests have been conducted in actual road conditions at different speeds and different loads on the two-wheeler. 10 observations were made at each load and 26WO 2017/060918 PCTYIN2016/050208 speed taking a sample of 250 mi of petrol in each observation. The results of the test are tabulated below. Acceleration (Pickup) of the two-wheeler in road conditions with 160 kg load (2 persons) Table 1.8: Variations in acceleration time with copper based nano suspension lubricant “Recelenation Wase ma seconds (0-60 KMPH} With base lubricant eas “Aeselezation with base fubrisant"0.08 % ca nano particles 5B “Acceleration with base lubsicaat0.1 9s cu aamo particles tie Fr (om table 1.8 it may be observed that the acceleration time has reduced and hence the pickup of the two-wheeler has increased. There has also been observed substantial increase in mileage of the two-wheeler with use of the copper based nano suspension based lubricant. The test results illustrating the same have been tabulated below in table 1.9. Table 1.9: Variations in mileage with copper based nano suspension lubricant eats fess done atl a onions o Spi] Wha] Sagi |S aaa |S [SaaS | aawa |S [Tan |S |S ae sal 18 nnlaor | nfddip [nadow matalemtone [int |nokew |iasé 2 |mion [int |eadae inte wo pov a pews G eae) pes) es ae eta | ee =e ul et ie WER [a [ae a ae fae | eum [ta [oa [ome [ew [am Pine fis Jae [eam Jae see i. yl cd at sagt tag os ce ae is [00104] Exhaust gas analysis on four stoke bike A typical exhaust gas analysis on a 4 stroke bike with the copper based nano suspension lubricant is presented in the table 1.10. 27WO 2017/060918 PCT/IN2016/050208 Table 1.10: Variations in emission properties for the copper based nano suspension lubricant Results of Exhaust gas analysis, Tabreant CO COL HC NOX ‘Base Inbrisant TSeT% Siam 455 PPM TERPS Base Iubricam 70.05% [287 7% ‘SGPPM 28 PPM isbricamt DP Cu IS PPM From table 1.10 it may be noted that the emission of poisonous gases such as, CO2, HC and NOX are substantially reduced when the lubricating fluid is mixed with the surface modified copper nano particles. Example 2 MoS, based nano suspension lubricant [00105] The nano suspension lubricant described herein can be based on a number of different exemplary compositions. In example 1, metallic copper can be used as a nano particle to be dispersed into the lubricating fluid. Likewise, metallic sulphides such as, molybdenum sulphide is used as a nano particle in the nano suspension lubricant. Typically, the surfactants used for modifying the surface of the metallic sulphides are cationic surfactants. The cationic surfactant molecules carry a positive charge at the hydrophilic end of the surfactant molecule. Examples of cationic surfactants include quaternary ammonium salts, cetrimonium bromide (CTAB), etc. Thus, according to an example implementation of the present subject matter, the nano suspension lubricant includes surface modified molybdenum disulphide nano particles from about 0.05 weight % to 0.1 weight % dispersed in the lubricating fluid. The lubricant fluid includes about 90 % to 99 % base oil, such as, petroleum fractions, mineral oils, vegetable oils, synthetic oils, solvent refined mineral oils, hydrocracked mineral oils, polyalphaolefins, polyalkyiglycols, synthetic esters, and the like. The lubricating fluid also includes about 1% to 10 % additives, such as, antioxidants, detergents, and antiwear agents. The molybdenum disulphide (MoS,) nano particles are coated with sorbitan monooleate surfactant in a similar method as employed for coating the copper nano particles with lauric acid in the example 1 to obtain surface modified MoS, nano particles . The 28WO 2017/060918 PCT/IN2016/050208 surface modified molybdenum disulphide nano particles from about 0.05 weight % to 0.1 weight % are dispersed in the lubricating fluid by stirring for about 1 hour in an ultra sound sonicator. The MoS, nano particles used have a size less that about 100 nanometers. In an example, Silane can be used for being coated on the MoS2 nano particles for surface modification of the MoS, nano particles. [00106] Evaluation of stability of lubricating oil suspension containing the surface ‘modified MoS, nano particles using light scattering techniques Dynamic light scattering (DLS) is a technique used to determine the size distribution profile of small particles in suspension or polymers in a mixture. The stability of any suspension is measured in terms of relative change in average particle size of the dispersed particles in the suspension. In a good suspension the size of the particles remain more or less same over a period of time. The stability of the surface modified MoS, nano particles in lubricating fluid is tested using DLS. The stability of the suspension in terms of average particle size is investigated over a period of 2 months. The variation of the MoS. nano particles surface modified with Sorbitan Monooleate is shown in the following table. Table 2.1 : The average particle size of the surface modified MoS; nano particles over a period of 60 days Day ‘Average pariicle size of surface modified MoS, nano particles expressed in nanometers (nm) +" Day 308.1 15" Day 293.3 30" Day 376.8 60" Day 392.2 ‘As may be understood from the table 2.1, the average particle size of the surface modified MoS, nano particles over a period of 60 days did not have substantial change. This indicates good steric repulsions between the surface modified MoS, nano particles. Thus, in case of MoS, nano particles, the Sorbitan Monooleate keeps the suspension of the modified MoS, nano particles in the lubricating fluid stable. [00107] In an example implementation, the MoS, based nano suspension lubricant described herein can be used for lubrication in vehicles the automotive industry. Thus, 29WO 2017/060918 PCT/IN2016/050208 to determine the suitability of the MoS. based nano suspension lubricant in the automotive industry evaluation of physico chemical properties of the MoS. based nano suspension lubricant becomes necessary. The physico-chemical properties of a lubricant include viscosity index, total acid number, total base number of a nano suspension lubricant that determine the suitability of the nano suspension lubricant for use in vehicles, such as in engines of two-wheelers and four-wheelers. In particular, the physico-chemical properties of the nano suspension lubricants are evaluated to investigate the suitability of the surfactant and the surface modification process to the automotive environment. [00108] Further, a nano suspension lubricant exhibits different physico-chemical properties depending on a kind of base oil used in the lubricating fluid. Accordingly, test results are illustrated below for the MoS; based nano suspension lubricant including lubricating fluids having different compositions for the base oil [00109] Tests for Physico-chemical properties In an example implementation to analyze the physico-chemical properties of the MoS» based nano suspension lubricant, different tests such as Kinematic viscosity test, total acid number test, total base number test, and copper strip corrosion test are performed. [00110] Kinematic viscosity test Viscosity of the nano suspension lubricant is closely related to its ability to reduce friction. Viscosity index is a parameter that indicates the variation of viscosity with temperature. The Viscosity index is calculated as per ASTM D 445 standard by measuring viscosity of the MoS, based nano suspension lubricant at 40 °C and 100 °C. A high value (normally > 90) of the viscosity index indicates that the nano suspension lubricant has good lubricating properties. Table 2.2 Viscosity index for the MoS, based nano suspension lubricant with SM petrol engine oil (SAE 20 W 40) as the lubricating fluid Lubricant used Viscosity index Petrol engine ol SM grade | >170 (SAE 20 W 40) +0.05 MoS, Petrol engine ol SM grade | >110