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 Extra Ques+ons:
Q. Account for following: HF is not stored in glass boAles but is kept in wax coated boAles?
Ans. HF forms fluorosilicate ion on reacHon with glass.Hence, it is stored in wax coated in
boAles. CBSE 2013

Q. Why does fluorine not play the role of a central atom in interhalogen compound ?
Ans. Fluorine does not have d - orbitals and can not show higher oxidaHon state.
Therefore, it does not play the role of a central atom in the interhalogen compounds.
CBSE 2011

Q. F2 is the most reacHve of all the four common halogens. explain

Ans. It is due to low bond dissociaHon energy and high hydraHon energy and high electron
affinity.
Delhi 2011

Q. Arrange the following in increasing order of oxidising power:

HClO, HClO2, HClO3, HClO4
Ans. HClO>HClO2>HClO3>HClO4
Delhi 2010
Q. Complete the following reacHon:
PbS + O3 ——>
CBSE 2019
Ans. PbS + 4 O3 ——> PbSO4 + 4 O2

Q. Sulphur has greater tendency for catenaHon than Oxygen?

Ans. As, S-S bond energy is more than O-O bond energy and due to smaller size of O the
lp-bp repulsion is high resulHng in lower tendency for catenaHon. CBSE 2012,2009
Delhi 2012,2011

Q. Predict the shape and the asked angle (90 or more or less) in the following case:
SO 32- and the angle in the O-S-O
Ans. the shape is pyramidal and the O-S-O angle is more than 90

mores
. ' Delhi 2012

±
.
Q. All the bonds in SF4 are not equivalent. Explain, why? CBSE 2012
Ans. As sulphur is sp3d hybridised. It has trigonal by-pyramidal structure in which one of
the equatorial posiHon is occupied by an lone pair of electrons. That’s why, all bonds are
not idenHcal.

Q. Draw the structure of O3 Delhi 2010

Ans.

Q. OF6 compound is not known. Why? Delhi 2010

Ans. Due to the absence of d orbital in O, it limits its covalency to 4, thus OF6 is not
formed.
Delhi 2010
Q. SF6 is less reacHve than SF4. Why ?
Ans. SF6 is sterically hindered so, it is less reacHve than SF4.

Q. Why are the two S-O bonds in SO2 molecule of equal strength? CBSE 2010
Ans. Due to the resonance in , the two bonds equally share the double bond character
and thus are idenHcal.

S s

Delhi 2013

Q. SO2 is an air pollutant. Account for this statement:

Ans. As it is water soluble, when mixed with rain it causes acid rain and problems such
as irritaHon in eyes.

.
. @ ignited