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In My

Judgment
by Adam Neville

Water and Concrete:


A Love-Hate Relationship

P
apers about concrete, when they refer to water, usu- And yet, with an increasing scarcity of water in many parts
ally consider only one relationship at a time. The most of the world and ecological considerations of impure water,
common of these is the relation between water-ce- in making concrete we have to consider the use of treated
ment ratio and strength. Another example is water domestic sewage and industrial waste waters, as well as water
content and its influence on workability. At the more scien- used to wash out concrete mixers and trucks, and ready-mix
tific end of the scale, much work has been done on the hy- concrete yards. Such waters must not be discharged into the
dration reactions of cement and the state of water in the re- natural surface waters. The obvious solution is to recycle
sulting products of hydration: chemically combined, physi- the wash water by reusing it as a part of the mixing water.
cally adsorbed, and so-called free water. As the wash water contains alkalies from portland cement
But water is not just a liquid used to make concrete: it is and also solid material in suspension, we need to know what
involved in the whole life of concrete, for good or evil. Con- is acceptable. The entire issue of suitability of water for mix-
crete in the environment is usually in contact, permanent or ing and curing was discussed in a previous article.1
intermittent, with water, in liquid or in vapor form. Most The second aspect is the quantity of water in a unit vol-
actions on concrete in service, other than loading, involve ume of concrete. This can be expressed in liters per cubic
water, either pure or carrying salts or solids. There are nu- meter of concrete (or gallons per cubic yard). This is the so-
merous relations between water and concrete, and even mul- called water content, which greatly influences the workabil-
tifaceted interactions between these two materials. ity of the resulting mixture.
I do not recall ever seeing a discussion, or even enumera- The third aspect is that it is also possible to express the
tion, of all of these relations in a single paper. And yet, this quantity of water in the mixture as the water-cement ratio,
would be appropriate because water and concrete are the two nowadays always by mass, in decimal form (except by the
materials most used by mankind: water in the first place and Japanese, who prefer percentages). Fortunately for those who
concrete in the second. I shall give the relevant quantities at work outside the U.S., gallons per sack (which is an expres-
the end of this article that will briefly explore the connec- sion using inconsistent units) is just a thing of the past. That
tion, or indeed the numerous connections, between concrete the water-cement ratio greatly affects the strength of con-
and water. This should dispel the notion that concrete is a crete has been well known since the pioneer work of Duff
dry subject! Abrams more than 80 years ago. I have recently written a
short article on the usefulness of the water-cement ratio (w/c).2
Part I: During construction
The opening observation, and perhaps the most obvious one, Water of hydration
is that you cannot make concrete, as usually defined, with- When concrete is mixed, the cement and water do not long
out water. Thus, the first topic is mixing water. stay simply as neighbors. Cement powder is hydrophilic;
chemical reactions of hydration take place and various prod-
Mixing water ucts of hydration are formed. They all contain water, but it
There are three aspects of mixing water that should be con- does not all exist in the same form. Some of the water be-
sidered. The first of these is its quality. The water should be comes chemically combined, that is, it becomes a part of the
“good,” such as city supply water but, if it is not, what are compound, such as calcium hydroxide. Some of the water is
the effects of impurities on the properties of the resulting physically adsorbed on the internal surfaces of those prod-
concrete: setting time, gain of strength, discoloration, and ucts of hydration that are in the form of gel. It would not be
long-term durability? Relatively little is known about the appropriate in this article to discuss in detail the various forms
limitations on the suitability of water for mixing. of water in hydrated cement paste; suffice it to say that the
energy of binding of water varies. It is therefore convenient
This point of view article was selected for reader interest by to distinguish evaporable water and nonevaporable water,
the editors. However, the opinions expressed are not necessarily but the division is not absolute and depends on the method
those of the American Concrete Institute. Reader comment is of “evaporating” the water from a sample.
invited. Not all the space in the mixture as placed becomes filled
with solid products of hydration (the term “solid” including

34 Concrete International
gel water). The excess space forms capillary pores that, at waters are discussed in a later section. This precludes the
least to begin with, are full of so-called free water. It is called use of seawater for curing reinforced concrete elements.
that because free water can be fairly easily removed from It is worth observing that the requirements for mixing wa-
the capillary pores; the pores can also be refilled. The pres- ter and curing water are not identical. For example, pure
ence of at least some water in the capillary pores is essential water, such as distilled water or other desalinated water, is
for the hydration of the hitherto unreacted cement to take perfectly suitable for mixing, but it would attack hardened
place. The minimum vapor pressure is 80%. concrete, as discussed later on. Conversely, many waters
It is useful to note that the products of hydration of ce- containing some organic compounds that might interfere with
ment have a very low solubility in water; indeed, it is the the hydration of cement are harmless when used for curing.
essence, as well as the origin of the name, of hydraulic ce- The only exception is the case when these compounds may
ment (and portland cement is its prime example) that it is cause discoloration of the surface of concrete that will be
stable in water. Thus, at this stage, hydrated cement paste exposed to view.
and water exist side by side, at least to a large extent. In passing, I should mention that, in the past, when high-
alumina cement was used in construction, strong cooling by
Bleed water the application of water was recommended by the cement
In addition to the various forms of water of hydration, in manufacturers: the argument was that prevention of a large
concrete as distinct from cement paste, there may also be temperature rise on hydration of cement would obviate the
trapped bleed water. This water appears to travel upwards process of so-called conversion of the products of hydration
through the concrete mass but, in reality, it is the solid par- with the concomitant loss of strength. We now know that
ticles, which are heavier than water, that are subject to sedi- conversion cannot be prevented, and in most countries high-
mentation by gravity. If the bleed water reaches the top sur- alumina cement is no longer used in construction.
face of a concrete element, it may evaporate. The rate of In considering the cooling of the surface of a concrete el-
evaporation and the rate of “supply” of bleed water, between ement by curing water, we should pay attention to a possible
them, influence the development of plastic shrinkage and differential in temperature between the surface and the inte-
possibly plastic-shrinkage cracking. rior: if the differential induces a large temperature gradient,
If the bleed water, on the way up, is trapped underneath there may develop excessive thermal stresses and possibly
large aggregate particles, this forms voids that may adversely cracking.
affect the durability of concrete in later life by providing a It is well known that the supply of water to concrete by
preferential path for the ingress of aggressive agents. The means of curing is essential for the progress of hydration of
bleed voids are originally water-filled but, with time, the cement in mixtures with medium and low water-cement ra-
bleed water may become used up in continuing hydration of tios. In most cases, this aspect of water curing overshadows
cement or migrates outwards. But even when it stays as wa- the temperature aspects, but both show a clear interaction
ter, it provides a preferential path in the case of ingress of between curing water and the quality of resulting concrete.
aggressive agents into the concrete.
Whether a given mixture bleeds more or less depends on Part II: In service
some properties of the mixture, but whether the bleed water The important role of water in concrete continues in service,
becomes trapped depends on the aggregate size and, above and there are many aspects of this role.
all, shape. Flaky particles are much more likely to intercept
water in its apparently upward motion than equidimensional Drying shrinkage
particles. Thus, we have an interaction between aggregate When discussing the loss of water from fresh concrete, that
shape and water in the mixture. is, before its setting, I mentioned plastic shrinkage. Now,
If the bleed water readily reaches the top surface of a con- the loss of water from hardened concrete may also lead to
crete element and evaporation takes place, this lowers the drying shrinkage. It is not, however, all the water whose loss
temperature of the concrete near the surface, which has to leads to shrinkage: the loss of free water does not result in
supply the relatively large heat of evaporation of water. This shrinkage. It is only when, following the departure of free
may be beneficial in a hot climate, especially as the tem- water, adsorbed water is lost to the ambient medium that
perature of the concrete at the time of setting affects its longer- contraction takes place. Under some circumstances, drying
term strength development. The temperature at the time of shrinkage can lead to shrinkage cracking, which, in my opin-
setting affects also the development of thermal cracking: if ion, is the greatest shortcoming of concrete and the most
a concrete element adopts its final dimensions at a higher common cause of problems in concrete structures exposed
temperature, then subsequent lowering of temperature may to air; this means all structures except those under water or
induce cracking. fully embedded in wet soil. Drying shrinkage thus repre-
sents a particularly important relationship between water in
Water curing hardened concrete and its deformation and deterioration.
The temperature of the concrete, once it has set, at its sur-
face is affected also by the application of externally sup- Creep
plied water, that is, curing water. If this water evaporates, Creep of concrete, which is a time-dependent deformation
heat is abstracted from the concrete. Moreover, if the curing under steady load, also involves movement of water, although
water is cold, the concrete is cooled by heat transfer. This this is more complicated and less well established than in
may be beneficial in a hot climate. Conversely, curing with the case of shrinkage. Nevertheless, we know that when con-
cold water can be dangerous if the temperature drops and crete is drying while under a sustained load, the contraction
there is a risk of frost. Generally, water curing should start known as drying creep occurs. This drying creep is larger
very early and be continuous and prolonged. than when no water movement in or out of concrete under
It is obvious that curing water must not contain ions that load takes place; the deformation under the latter conditions
can attack concrete or the reinforcement within; aggressive is called basic creep. Thus, water plays a significant role in

December 2000 35
the time-dependent deformation of concrete under sustained (due to the extremely low w/c) means that water still present
load. This is quite separate from the role of water in shrinkage within the hardened paste cannot readily escape. The high tem-
when no load is involved. perature during a fire causes vaporization and the concomi-
The mechanisms of the two types of creep are still not tant increase in the volume of the original liquid water. The
well understood. Alas, there has been only limited progress change in phase and a high-vapor pressure can lead to burst-
in this respect since the last major book on creep of con- ing of the outer zone of the concrete. In consequence, under
crete (as distinct from a collection of symposium papers) particular circumstances, what was intended to be a high-
was published in 1983.3 Creep continues to be studied, but performance concrete may result in a performance inferior
not so much in order to understand its mechanism as to to that of ordinary concrete.
develop mathematical models for prediction, none of which When fire is fought with cold water, the concrete whose
has consensual support.4 In my view, an understanding of surface temperature has become very high in the fire, finds
the mechanism of creep, including the role of water, should itself suddenly subjected to quenching. This may have se-
precede reliance on complicated mathematical expressions. rious consequences for the serviceability and strength of
concrete.
Wetting and drying The preceding brief discussion shows that, although
Dry concrete in contact with water will rapidly imbibe it. its w/c is very low, high-performance concrete exhibits a
The water gradually penetrates deeper and deeper into the large sensitivity to water.
concrete element: quite rapidly, total saturation is possible.
The process is reversible, but not at the same rate: drying Autogenous healing
is extremely slow, so that those parts of a concrete element It is well known that the presence of cracks in concrete is
that are more than, say, 500 mm (20 in.) from a drying virtually unavoidable. However, when concrete at the
surface may never become completely dry, or at least not surface of a narrow crack is in contact with water, static or
in the lifespan of the concretor! Wetting and drying is a slow-moving, healing of the crack is possible. This occurs
means of ingress of salts because a solution enters, but by hydration of the hitherto unhydrated cement or by the
only water evaporates. formation of calcium carbonate from the leached-out
calcium hydroxide, if carbonation takes place.

“ In high-performance concrete,
when the water-cement ratio is
extremely low, autogenous shrinkage
Aggressive waters
Concrete in service may be exposed to aggressive waters. In
many countries, the most common deleterious ion is sulfate,
combined with one of several cations. In other waters, acids
and chemical by-products from industrial processes may be
present. In some locations, the water in contact with con-
crete is seawater or brackish water. The chlorides present in
may develop, which has only recently such waters, if carried into the interior of the concrete, often
lead to corrosion of steel reinforcement.
It is important to remember that only salts in solution
become recognized as a significant attack concrete: a heap of calcium sulfate sitting on a dry
floor is harmless. So is a heap of common salt, that is, so-
factor in the behavior of concrete.


dium chloride, except that it is deliquescent so that, if the air
is humid, the salt will eventually produce a solution in which
chloride ions will be present; they will then penetrate into
Water in high-performance concrete the concrete, but they can do so only in water.
In high-performance concrete*, when the water-cement ra- Even pure water is not good for concrete in service: in
tio is extremely low, autogenous shrinkage may develop, pipes and conduits, pure water leaches calcium hydroxide
which has only recently become recognized as a signifi- from the hydrated cement paste. Rain, at least away from a
cant factor in the behavior of concrete.5 Autogenous shrink- polluted atmosphere, is a reasonably pure water, and it also
age, like drying shrinkage, is due to the loss of water from leaches calcium hydroxide. If rain is followed by exposure
hydrated cement paste, but the loss is caused by the water of the concrete surface to the sun, the leachate forms efflo-
being used up in chemical reactions of continuing hydration, rescence that, although not harmful in itself, is unsightly and
and not by movement to the atmosphere. mars the appearance of the concrete.
High-performance concrete also presents a special problem The other extreme of rainwater is the so-called acid rain,
as far as water in the hydrated cement paste is concerned in which is a highly harmful consequence of some industrial
the case of fire. The very low permeability of such concrete exit gases dissolved in water in the atmosphere and carried
by wind. Acid rain contains mainly sulfuric and nitric acids
*High-Performance Concrete (HPC) is concrete that meets special com- and can have a pH as low as 4.5 or even 4.0. These acids
binations of performance and uniformity requirements that cannot always etch the surface of the concrete.
be achieved routinely using conventional constituents and normal mixing,
placing, and curing practices. Thus, a high-performance concrete is a con-
crete in which certain characteristics are developed for a particular appli-
Corrosion of reinforcement
cation and environment. Examples of characteristics that may be consid- Corrosion of embedded steel, whether of the general type or
ered critical in an application are: ease of placement, compaction without chloride-induced, occurs only if the concrete is sufficiently
segregation, early age strength, long-term mechanical properties, perme- wet so that the pore water acts as an electrolyte. This per-
ability, density, heat of hydration, toughness, volume stability, and long mits the development of an electrochemical cell. Thus, wa-
life in severe environments. (Editor) ter is necessary for corrosion to proceed.

36 Concrete International
Conduits for drinking water However carefully constructed, concrete walls and floors are
Drinking water is not an aggressive water in usual terms, rarely entirely monolithic and crack-free, and they may be
but it causes leaching of concrete that, under some circum- subjected to differential strains. If we wish to build a water-
stances, may make the water harmful with respect to human retaining structure, we need, in addition to concrete of the
consumption. This situation arises primarily in small-diam- right quality, appropriate detailing of reinforcement and pos-
eter conduits with a dead end, in which the rate of flow of sibly a provision of water stops. This is the domain of struc-
water is low so that the contact between the water and the tural design and not just concrete technology. May I empha-
portland cement paste is prolonged. In consequence, with size the term “watertight”: this is not the same as impermeable.
waters of a very low alkalinity, that is, a very low calcium
carbonate content, the pH level of the water in the conduit Freezing and thawing
may rise above 9.5. Also, the amount of aluminum entering The deleterious action of repeated cycles of freezing and
the water may become excessive. thawing on concrete is well known in many parts of the world.
The amount of aluminum leached and carried by the water For the purpose of this article, it is sufficient to note that
may be particularly high in the case of concrete or mortar freezing and thawing involve water. The water may be that
made with high-alumina cement. This cement could be used originally present in the mixture or it may be water that
in repairs or linings when rapid rehabilitation of corroded ingressed into the concrete; what is significant is that it is
water mains is undertaken; however, such a use is question- water that leads to damage, and it does so with a vengeance.
able or inappropriate. Damage by repeated cycles of freezing and thawing is quite
I propose to develop the topic of the use of concrete in distinct from damage of fresh concrete by the action of frost
conduits for drinking water in a future article. on fresh or very young concrete. Here, the expansion on con-
version of liquid water into ice disrupts the concrete; gener-
Water-resistant concrete ally, the damage is irreparable. So is, of course, damage by
It is sometimes asked whether attack by aggressive waters cyclic freezing and thawing.
can be prevented by using water-resistant concrete. I am not What is relevant to the present article is that both frost
using the term “waterproof,” which is not recommended in action and freezing and thawing involve water: it is water
British Standards, if only because impermeable concrete is that is the culprit.
probably unattainable. What is possible is concrete that has
a high resistance to water penetration. Carbonation
Why is this? By its nature, concrete is a porous material. Carbon dioxide in the atmosphere can react with some prod-
Porosity and permeability are not the same, but many pores ucts of hydration of cement, notably calcium hydroxide.
in concrete are interconnected so that transport of water into However, it is not gaseous carbon dioxide that reacts: the
and through the concrete is possible. Not only flow, but also presence of water is necessary so that the actual agent is a
other transport phenomena are involved. The better com- weak carbonic acid. It is evident then that water is the essen-
pacted the concrete and the fewer gross voids in it the more tial element in carbonation of concrete, which reduces the
difficult it is for water to travel through the concrete. Fur- alkalinity of the hydrated cement paste and can lead to cor-
thermore, the exact structure of the hydrated cement paste rosion of reinforcement.
determines the ease with which water can move through the
concrete. Particularly important are the amount and Alkali-aggregate reaction
interconnectivity of pores; these are usually assessed by their Two types of reaction exist: one involving silica, the other
size distribution: the same volume of fine pores allows less carbonate, either of these being present in the aggregate; the
movement of water than when the pores are few in number source of alkalies is the cement. It could be thought that con-
but large and interconnected. sideration of this deleterious reaction is not within the scope
Under many circumstances, the movement of water of this article; however, this is not so: the alkali-aggregate
through concrete is very small, but concrete, as we make it, reactions proceed only in the presence of water. Even if the
is not waterproof in the same way as a plastic membrane. In reaction has developed to the point of causing some dam-
most cases, this situation creates no problems. However, if a age, drying out the concrete and maintaining it dry will ar-
virtually waterproof concrete is required, then we have to rest all further reaction; the damage is not reversible but it is
consider the use of waterproofing admixtures, possibly those certainly stoppable. Thus, once again, water is an essential
that are also hydrophobic, or we may resort to special con- element in the process of deterioration of concrete.
cretes such as polymer concrete.
It is worth remembering that much depends on the ambi- Cavitation and erosion
ent conditions to which a given concrete element is exposed. Although concrete is used extensively in hydraulic works,
For example, in the case of a basement wall with waterlogged including spillways and closed conduits, flowing water can
ground on the outside and dry space inside, there will be cause severe damage by cavitation. Cavitation can occur
some transport of water through the thickness of the wall. If when the flow of water is not steady and not tangential to
someone believes that installing a powerful air conditioner the surface of the concrete at all locations, but when there is
in the basement will solve the problem, there will be disap- a divergence between the direction of flow and the surface
pointment: the greater the difference in relative humidity be- of the concrete. Under such circumstances, vapor bubbles
tween the two sides of the concrete wall the more water will can form when the local absolute pressure drops to the value
be transported. Likewise, the greater the head of water on of the ambient vapor pressure of water at the ambient tem-
the outside (that is, if the basement is very deep) the more perature. These bubbles travel downstream and, on entering
water will be transported. an area of higher pressure, they collapse with great impact.
In any case, the exposure conditions and the quality of the This collapse enables high-velocity water to enter previ-
concrete are not the sole determinant of watertightness. ously vapor-occupied space and exert an extremely high

December 2000 37
pressure on a small area of concrete surface. Such repeated concrete placed per annum per head of world population —
application of high pressure results in pitting of the sur- woman, man, child — is about 2 1/2 Mg (2.8 tons).
face, making it more uneven and rough, thus exacerbating The figure for water is less readily determined and depends
further damage. of course on what uses of water represent consumption. Also,
Erosion of concrete surface is another type of damage of some of the water is treated and sold to households and indus-
concrete in contact with flowing water. The damage here is try; other water, for example, that used for cooling, is taken
caused by solid particles carried by water, rather than by the from a river and returned to it. It may be of interest that in
water itself. Thus, water is no more than the transporting England, the total consumption per annum per capita is about
medium. Nevertheless, both in cavitation and in erosion, 130 Mg (143 tons), but there is a considerable variation
water is a factor in the development of damage. worldwide.

Part III: Special properties Conclusions


It may now be useful to consider some properties of con- I do not suppose that I have considered all the topics under the
crete that are significantly affected by the presence of free heading of “water and concrete,” but I hope to have shown
water in the concrete. the intimate relationships between the two materials in the
life of concrete. These relationships are numerous and they
Thermal insulation exist from the construction stage, right through life in service,
Concrete is a relatively good insulator, and lightweight con- including exposure to aggressive conditions. Sometimes the
crete is especially effective. Of particular interest is thermal relationships are for good, sometimes for evil, but they are
conductivity; this is defined as the ratio of the flux of heat to inevitable. I hope that the consideration of all of these rela-
the temperature gradient. Because the conductivity of air is tionships in the present article may help us in understanding
lower than that of water, the conductivity of a given con- the nature and behavior of concrete: such a wide-ranging ap-
crete depends on the degree of saturation with water of the proach is likely to be beneficial, as all too often studies are
limited to a very narrow single relation under a single set of
voids in the concrete. The effect is particularly significant in
conditions.
lightweight concrete, which has a larger proportion of voids
Let me summarize in terms of the title of my article. On the
than ordinary weight concrete. For example, an increase in
one hand, it is not possible to make concrete without water:
moisture content of 10% increases the conductivity of con-
water is not just an “optional” ingredient. Furthermore, appli-
crete by 50%. It follows that, if the insulating properties of cation of external water in curing and sometimes in cooling is
concrete are of importance, it must be dried out and not al- highly beneficial to concrete. This is the love element of the
lowed to become saturated. We can see thus that free water relationship.
in concrete, either from the original mixture or ingressed On the other hand, a great many mechanisms of deteriora-
later, has a considerable influence on the thermal insulation tion and damage to concrete involve water as an essential fac-
properties of concrete in service. tor. In those cases, water represents the hate element.
My wife of 48 years’ standing, who has contributed a great


deal to my “concrete thinking,” would not allow me to liken
Concrete and water are the two this love-hate relationship to marriage. Let me just say that
there is no doubt that, for the foreseeable future, we shall need
materials most used by mankind, not only water but also concrete: the two will have to live
together.
water being the leader and concrete
References
the runner-up.


1. Neville, A. M., “Water — Cinderella Ingredient of Concrete,” Con-
crete International, V. 22, No. 9, Sept. 2000, pp. 66-71.
2. Neville, A. M., “How Useful is the Water-Cement Ratio?,” Concrete
Electrical resistivity International, V. 19, No. 9, Sept.1999, pp. 69-70.
Electrical properties of concrete are of importance in some 3. Neville, A. M.; Dilger, W.; and Brooks, J. J., Creep of Plain and
applications. The resistivity of concrete is greatly affected Structural Concrete, Longman Group, London, 1983, 361 pp.
4. Adam Neville Symposium: Creep and Shrinkage — Structural Design
by its degree of saturation. For example, air-dried concrete Effects, SP-192, A. Al-Manaseer, ed., American Concrete Institute,
has a resistivity of the order of 10,000 ohm-m; 6 the resistiv- Farmington Hills, Mich., 424 pp.
ity of oven-dried concrete is about four orders of magnitude 5. Aïtcin, P.-C., “Demystifying Autogenous Shrinkage,” Concrete In-
higher.7 The topic is fairly complicated, but what is of es- ternational, V. 21, No. 11, Nov. 1999, pp. 54-56.
6. Whittington, H. W.; McCarter, J.; and Forde, M. C., “The Conduction
sence is that electric current is conducted through moist con- of Electricity Through Concrete,” Magazine of Concrete Research, V. 33,
crete primarily by electrolytic means, that is, by ions in water No. 114, 1981, pp. 48-60.
in the capillary pores. Other things being equal, the less water 7. Monfore, G. E., “The Electrical Resistivity of Concrete,” Journal of
in these pores, whatever its provenance, the higher the resis- the Portland Cement Association, V. 10, No. 2, 1968, pp. 35-48.
tivity of the concrete.

Quantities of concrete and water used


ACI Honorary Member Adam Neville is the author of the
In addition to everything discussed so far, there is another spe- book Properties of Concrete, the fourth edition of which ap-
cial relationship between concrete and water: as I mentioned peared in 1996. Arising from his work as a consultant in con-
at the outset of this article, they are the two materials most crete, he has recently published in Concrete International a
used by mankind, water being the leader and concrete the run- number of papers developing applied knowledge to produce
ner-up. The consumption of concrete, that is, the quantity of better concrete in practice. He is a qualified arbitrator.

38 Concrete International

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