450 Cones Hee »3<« WA) Soma apgicbens of galvenie calle Wan Ddarnmnation of Re Rermodynomic portions of o reaction toy em F menusemedti- ~Rernadjnome Dartions ore Vikes AG, AW, AS Sep poe Remedyronte panded Lee ons LAI Re veaon Posle oc nd te- ows Jost & the readtion tt Diredtion of reaition. CUTE Be vendor to enotRenuc or endatherme, - Consider Re Jaiowsieg conten. Zn e Qh" = Cu + te" VY Case Whi TK radion Can be tarred out cheney ay placrg apiece of Zr vo CaSou- THE enegy of the racion oppean in Ra Porm of heat enqys AHO A¥ Cosel FEE vedion con be corned out eledroche- mnically nag oOvonc cel. We thin case part of the chemol energy oppears in Hor Porn of hak energy (qi measured ‘oy oO Collorinater ge other port wwe Dorm of dedi energy \W) b> clediccall exergy N wy (Usk be Re surrouedig) WW ay <4 }——s Ca shed ae rdebive omaurts oF WZ Ig) depends ow Be curred withdroon Prom the coll ¢ >> Becourei- As We curred nereaser (LI) Mecreaser & (gy ecroae) ry st due be conversion of part of Be clediaal ena me heok (QE) due ts Re igtirnall call resistance. UL As Re current decreases :(W0) increaaes cee Ag Ra caren expprodes Wo 5 (W) becomes mamimum 2 heat Lost be te surounding becomes cam 2 Be we a » saad b be Woking reversibly + = Yee nest of a reaion (AG) is defined on Re rordmum Work donk hey Morimim usork dont. < 9p buani ak ty Ra rmoscimum cheditoll enagiy- obtand Jon Be wh during is reversthle operation (Whyael VW suceunking ep Seaplane) eC AG Arle ue lel Cibo See Zee W I sSESHERCOUS FY 3WAMGtin teats a whee Nye Her & rend on: ~ work. a, => Hear Det & ihe socom oy unouileble at ae a 3G > AS:- a __acaerl ge SE Se =2F texpeote ooefPiaes: - Nistésy- + Moiese ePRaeney vv collated by vat Mee Vieng Oo a : = NG AE Wa. zy themolgname dersetion of Meret egeetion. ~ Consiber Re Palsy cee ad abR —acC+dD. “Re cheniead edebiad (W) wshd io Ha Pre engg Pe wakes Us Wo Rr bro. Wut! 4, atanderd chenieal peteciad. aad adiay of Ha dmalvad subtence RaoGes ocr Tap Temp. in Kalvin. -6-othe Yow enngy SRL coll readionr ENG: EG ya” © Franca. fel « Pra) salen e boas] - [align elas) + (Woe bray] fetis +g ag bag] er bn Se qo Nest Hof ey equation © AG AGS oS ou eo ees == Ac. oe Dees easy ve sor: “Nag 2a “NG 2 DEP IDG e EF OD Qhethie We OV ae cd pep. -26F TLR GA Oy OeWA)Determinslion of Re euibbbrivn constant of o eenalion Prom emf dala = Wher equilloiun ‘weds AG=0- gic Mer Ad = KK oy Prise whee: eke equllar wr conshat oo bG, ark « 9. -2eF «Tbk asa + 2eF RT. Gael. KI roi 2. & hic ZF wohees SS & = stander cal Voltege. & EW) + have = Ng KM; Re yield increases; the ale of readin incases & Conversion inueaser. , t=-Paleme We emf of Be calls Zm\tel,\ Agchal Ag . ob 25°C 1s oll ond bs timp coxffiart bo 4.02410 Wie WAR Calh rendion and dra te coll &) GdaDate AK AG AS . et) GLleaDoke eutlarium Constat of Hx reaihion. VIE He col ws vaed on a sowre of chdtical energy Cobeadade ty max. energy fReeres. Wats (eal of DLR OSV Cloag oF Aglty halts -2-22¥. Solitons. 2) Anode cadions Be Ie Grobe readtion : ahd + Bo —> ahead Oveadd ceadtion . Ze s2hgal 52 Ag* 5 ads a nel ai Aghia Bo&) AG=-2EF =b2) (olt) (965 00) 2 -9H2 7 AS. 2 ca 2 (2)(86500){-l02K15") = -NR.596 Flee. AW: AGs a 2 AG. TON 2-195 + (254299) (-39.526) 2 ~ 218922. 68 J. Ye) Eo, REDS. ) ier €o: al, + Sleutide + 046 4022 > 0.98V ogg amNlesr24 fy, Giaaar = Ke 15209 xo wy: 5a + loo = 54d h~'Poblens- Vexavalled Chromium (tare) is Wo be ediacad ino. wot Solution by Sea vor according bs Re ceadtions 24 BG = ZO BFE" Wee required dekicnine AW of Re cendion by emf mtanurten oho i 2) Wate and draun Re cequired, gelveas alt. ) Cadet: AW ©2570 trder Re Corditionss £0*9. ool, £O*2 000M, Che “*J= 0-00lM te) GQodats Re aqullerion Contant of Re resithion. iu} Glade Be was eragy ePRaery of He al Dakar Amovst of bead Yost Prom the eoth 6 the suroudin Under rntestele Conditions ws 250 cal, : (Gol, gf oncle = 0 LUV (es) gF cathods = ABBV, Solition Cy Reb Fe C25, of pt)Onoda an Be AR 6 Colode 1 2 Ovals ae 2G Say 20 v) AWsg +4 q+ - 28° oof SQ: -2EF. : 5 €: eee! Dog cen (oy 6 roy Te COD = h33V. AG = AUG) (1-33)4 36500) oo + -lo7Au59-5 T° A yd —s 4-27 s DG = -259918.9 cal. = DH = 2594629, col ve) Ee RTI: 228k. ar 2 (Bo saa x 2053 Dy ke Kady : Huh prolact o> . oad. = AG BIT oy) = ™ Hoo aig loo = 99.9%Reskheme Yor Re Jetourg eo Cas 2hgcls— CaCl, lov). 2 Ag ; Wnts Z deous Ba coll reprstting $Pe reiction, coleubt Re erme of Me coll at 25°C ning. He given data. &) Glodlake nH, AGG 2 OS oF 25° ae ard cd, Agch Chel, Ag are 124,24,82 S loz No % (alo, of -ve clediedes o-bo2v > leloy of te eleckedi -0:222 ¥% Sdebroae ’ Caledchy| ON Ag. co ew ae aoe er oad 2Ay Oh deo Rhy a oveabls Cha Angh —» 2Ay: oe CALAN CLT Egy + lange (ele - dog t Cad CAyed. OS WSF eee te Ga, <= Chas 2eh \ \ a ok o\ Wao). 5 (eal ero. Eqy 2 (o.to2)(e.222)~ 2359 elteeet = 6-694V te) AG:-2EF > (+2) (0-694) (4 6500) 2 AVRIL J frmeke AS= EVSpat- CVA 2 (2)(to.2) 4 2 - Blas) 124 2-64 black =e 291 Tl male ie 4 TAS + (454.293) (+ 28.1b) > ~ 9395.92 T Imole. AM: g +bG = BIS ALA = M4 2324-4.2 Th ~I3-