AB CF oc’ eae wrikte OC= 273k ok 473k . 773 k Om t= 373k N ied Gas Law Pra: “= @-a273¢0 = o/k Combi Example #1: This type of combined gas law problem (where everything goes to STP) is VERY Vy Th p, 2.00 L of a gas is collected at 25.0°C and 745.0 mmHg. What is the volume at STP? STP is a common abbreviation for "standard temperature and pressure.” You have to recognize that five values are given in the problem and the sixth is an x. Also, remember to change the Celsius temperatures to Kelvin. When problems like this are solved, | write a solution matrix, like this: Piz Pes Vie Ve= T= Te= and fill it in with data from the problem. Here is the right-hand side filled in with the STP values: Pas Pp = 760.0 mmHg V; Voz x T= Te= 373K You can be pretty sure that the term "STP" will appear in the wording of at least one test question. It is recommended that you memorize the various standards conditions. Here's the solution matrix completely filled in: P, =7450 mmHg Pp = 760.0 mmHg Vy =200L Ve= x Fos K of, = 298K T= 273K Insert the values in their proper places in the combined gas law equation: P1Vs/Ts = PoV2/T2Abbreviations atm - atmosphere mm Hg - millimeters of mercury torr - another name for mm Hg -I3 e ofl Pa- Pascal (kPa = kilo Pascal) ' K-Kelvin °C- degrees Celsius ok 100 ak 203K Conversions K + 273 1 cm (cubic centimeter) = 1 mL (milliliter) 1 dm? (cubic decimeter) = 1 L (liter) = 1000 mL Standard Conditions 0.00 °C = 273K 1.00 atm = 760.0 mmHg = 101.325 kPa = 101,325 Pa @12 1. Agas has a volume of 800.0 ml. at minus 23.00 °C and 300.0 torr. What would the volume of the - Ygas be at 227.0 °C and 600.0 torr of pressure? 5 = 300.0 00.0 ~ 000.0 xV2- Vv = t = 606.0 bot 400.0 xf60.0 . GOB? KNa~ 1 300.0 Tore P,= 600.0 & 35.0 Spo.0 Vi = 200,0m Va = 2 Te asok 100 X500.0 _ $00 =V. (= aso The 422.6+273 coo * YY. 2, $00.0 liters of a gas are prepared at 700.0 mm Hg and 200.0 °C. The gas is placed into a tank under high pressure. When the tank cools to 20.0 °C, the pressure of the gas is 30.0 atm. What is the volume of the gas? gle skp | - make pressure units iV pre. vor Same Py = 7ob.owmllel Py = 30.0 atm 200.00mM ea hm Vy = S00-0L. Vo= ? Tod ws! . Ty = 473 0h T= 293K 1921 xS00,.0 = 20:0 *NE_ 4 syL 473.0 242 3. What is the final volume of a 400.0 mL gas sample that is subjected to a temperature change from 22.0 °C to 30.0 °C and a pressure change from 760.0 mm Hg to 360.0 mm Hg? , N, P, = tao'wlly = vbommbbe Tad A060 $6000 NE = BT my -9 39s 303 Y= 400 0mL. Va = T= 295K. Ty = 403K 4. What is the volume of gas at 2.00 atm and 200.0 K if its original volume was 300.0 L at 0.250 atm and 400.0 K. v. * . O a. 0 0, 766.5 yVa_ hoot Ys V2 34aml. Wye 283 ~ 273 « ) Task The 273k 7. The volume of a gas originally at standard temperature and pressure was recorded as 488.8 mL. What volume would the same gas occupy when subjected to a pressure: .Oatmand 34 fw L. temperature of minus 245.0 °C? 5 wh (5013 P= hooady Py = 106.0 abe “i48i tae Ya 7? TTR he DI. 8. Ata pressure of 780.0 mm Hg and 24.2 °C, a certain gas has a volume of 350.0 mL. What will be the volume of this gas under STP. P, = 780.0nnly p= Tobe 80-0 390.0. Pane t Sa 2730 ada , Vi, = 950, mt Ve=? ‘ a 36,0 mL TF AW2IA Tp argh