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Haloalkanes & Haloarenes 3
Haloalkanes & Haloarenes 3
Haloalkanes & Haloarenes 3
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Boggy
Polyhalogen Compounds
Carbon compounds containing more than one halogen atom are usually referred to as
polyhalogen compounds. Many of these compounds are useful in industry and agriculture.
It was used earlier as an antiseptic but the antiseptic properties are due to the liberation of
free iodine and not due to iodoform itself. Due to its objectionable smell, it has been
replaced by other formulations containing iodine.
The chlorofluorocarbon compounds of methane and ethane are collectively known as freons.
They are extremely stable, unreactive, non-toxic, non-corrosive and easily liquefiable gases.
Freon 12 (CCl2F2) is one of the most common freons in industrial use. It is manufactured
from tetrachloromethane by Swarts reaction. These are usually produced for aerosol
propellants, refrigeration and air conditioning purposes.
Most freon, even that used in refrigeration, eventually makes its way into the atmosphere
where it diffuses unchanged into the stratosphere. In stratosphere, freon is able to initiate
radical chain reactions that can upset the natural ozone balance.