Correction for Po-209 decay from standard reference date until sample counting

until sample counting

𝑓_( 𝑡𝑟𝑎𝑐𝑒𝑟)= 𝑒^(−(209𝑃𝑜) ∙𝑡(𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔 𝑑𝑎𝑡𝑒
𝑟𝑒𝑓𝑒𝑟𝑒𝑛𝑐𝑒 𝑑𝑎𝑡𝑒))

Activity of Po-209 tracer added, Bq

A (210Po)counting date [Bq/kg] = (
[𝑔]· 𝐴(209𝑃𝑜)[𝐵𝑞/𝑔])/((((𝑁
𝐴 𝑎𝑑𝑑𝑒𝑑( 𝑃𝑜)𝑐𝑜𝑢𝑡𝑖𝑛𝑔 𝑑𝑎𝑡𝑒,[𝐵𝑞]=𝐴_( 〖 209 〗
209

[𝐵𝑞/𝑔]∙𝑚[𝑔]∙𝑓_𝑡𝑟𝑎𝑐𝑒𝑟

Correction factor f1 for Po-210 decay during sample counting

𝑓_1=
𝑓_1= (1−𝑒^(−( 210𝑃𝑜)∙ 〖𝑡 〗
𝐴(210 𝑃𝑜),𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔 𝑑𝑎𝑡𝑒
_(𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔 𝑡𝑖𝑚𝑒)
(1−𝑒^(−( 210
𝑃𝑜)∙𝑡_(𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔
(
210
𝑃𝑜))/(𝑁 𝑛𝑒𝑡(209𝑃
))/(())/((
𝑡𝑖𝑚𝑒) 210
𝑃𝑜)∙𝑡_(
210
𝑃𝑜)∙𝑡_(𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔
𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔 𝑡𝑖𝑚𝑒)𝑡𝑖𝑚 )
)

Correction factor f2 for Po-210 decay between separation/deposition start date and counting start date

𝐴(21
𝑓_2= 𝑒^(−(210𝑃𝑜) ∙𝑡 (𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔 𝑑𝑎𝑡𝑒−
)
𝑑𝑎𝑡𝑒))

Correction factor f3 for Pb-210 (Po-210) decay between sampling date and separation date
𝜎(𝑘=2)=𝐴(210𝑃𝑜)∙2∙ √((1/√(𝑁 𝑛𝑒𝑡(209𝑃𝑜)))^2+(1/√
(𝐴(209𝑃𝑜)))^2 )
𝑓_3= 𝑒^(−( 𝑃𝑏) ∙𝑡(𝑠𝑒𝑝𝑎𝑟𝑎𝑡𝑖𝑜𝑛 𝑑𝑎𝑡𝑒−𝑠
210

𝑑𝑎𝑡𝑒))
 Formulas:
γ =𝑁(
𝑑𝑎𝑡𝑒−𝑠𝑡𝑎𝑛𝑑𝑎𝑟𝑑
209
𝑃𝑜)/(𝑡𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔 ∙𝑒𝑓𝑓 Chemical recovery

𝑑𝑒𝑡𝑒𝑐𝑡𝑜𝑟∙𝐴( 𝑃𝑜))∙100%
209

Activity Po-210, Bq/kg at the counting date (using Gross and Background c
g] = ((((𝑁𝑔𝑟𝑜𝑠𝑠( 𝑃𝑜) 𝑠𝑎𝑚𝑝𝑙𝑒)/𝑡𝑠𝑎𝑚𝑝𝑙𝑒)−((𝑁 𝑔𝑟𝑜𝑠𝑠(210𝑃𝑜) 𝑏𝑘𝑔)/𝑡𝑏𝑘𝑔) )· 𝑚(209𝑃𝑜)
210

((((𝑁 𝑔𝑟𝑜𝑠𝑠(209𝑃𝑜)𝑠)/𝑡𝑠𝑎𝑚𝑝𝑙𝑒)−((𝑁 𝑔𝑟𝑜𝑠𝑠(209𝑃𝑜)𝑏𝑘𝑔)/𝑡𝑏𝑘𝑔) )· 𝑚 𝑠𝑎𝑚𝑝𝑙𝑒 [𝑔])∙1000

09 〗 _(𝑃𝑜 ) )

Activity Po-210, Bq/kg at the counting date (using Net peak area),

𝑛𝑔 𝑑𝑎𝑡𝑒[𝐵𝑞/𝑘𝑔]=(𝐴𝑎𝑑𝑑𝑒𝑑(209𝑃𝑜)[𝐵𝑞])/(𝑚 𝑠𝑎𝑚𝑝𝑙𝑒[𝑔])∙(𝑁 𝑛𝑒𝑡

𝑔 𝑃𝑜) )∙1000
𝑡(
209

𝑒)
𝑔 𝑡𝑖𝑚𝑒)
)

Activity of Po-210 (Pb-210) at the sampling date, Bq/kg

𝐴(210𝑃𝑜)𝑠𝑎𝑚𝑝𝑙𝑖𝑛𝑔𝑑𝑎𝑡𝑒= (𝐴 (210𝑃𝑜)𝑐𝑜𝑢𝑛𝑡𝑖𝑛𝑔 𝑑𝑎𝑡𝑒)/(𝑓1 ∙𝑓2∙𝑓3

𝑎𝑡𝑒−𝑠𝑒𝑝𝑎𝑟𝑎𝑡𝑖𝑜𝑛
)

Combined uncertainty

+(1/√(𝑁 𝑛𝑒𝑡(210𝑃𝑜)))^2+(0.0001/(𝑚(209𝑃𝑜)∙√3))^2+(0.0001/(𝑚 𝑠𝑎𝑚𝑝𝑙𝑒∙√3))^2+((𝜎𝐴(209𝑃𝑜))/

𝑡𝑒−𝑠𝑎𝑚𝑝𝑙𝑖𝑛𝑔
Nuclides: Po-209 Po-210
Half-life T1/2, yrs 125 0.379
Half-life T1/2, days 45698 138.376
Decay constant l, yrs-1 0.00554 1.82834
Decay constant l, days-1 1.52E-05 0.005009
Decay constant l, sec-1 5.80E-08
Tracer: Po-209 MODEL CAL3003 Standardized solution, dilution BATAN
Reference date 3-Sep-97
Tracer activity, Bq/g or Bq/ml 0.423
Uncertainty (k=2) 0.012
Analysis:
Samples: 1A 1RA
Description
Sampling / Reference date ### Sunday, August 26, 2018
Deposition (separation) date 1/7/2019 8:00 1/7/2019 8:00
Counting start date 5/7/2019 9:00 9/7/2019 9:13
Sample mass, g 5.00 5.00
Tracer Po-209 mass , g or volume, ml 0.2000 0.2000
Tracer activity, Bq/g on a Counting date 0.3751 0.3744
Uncertainty of tracer activity (k=1) 0.0103 0.0102
Counting:
Counting time t, sec 86400 86400
Background counting time, t bkg, sec 1 1
Counting efficiency, eff 0.3 0.3
Peak area N, Po-209 248.00 248.00
Peak area N, Po-209 in Background 0.00 0.00
Peak area N, Po-210 433.00 67.00
Peak area N, Po-210 in Background 0.00 0.00
Calculations:
Activity of Po-209 added, Bq 0.075 0.075
Chemical recovery γ, % 12.8 12.8
Activity of Po-210 at the counting date, Bq/kg 26.20 4.05
Combined uncertainty (k=2), Bq/kg 4.28 1.12
Time passed between separation and counting 120.0 243.1
Time passed between sampling date and separa 0.3 0.4
Correction factor f1 for Po-210 decay during c 0.997500 0.997500
Correction factor f2 for Po-210 decay between 0.548094 0.295975
Correction factor f3 for Pb-210/Po-210 decay 0.991498 0.988633
Results: 1A 1RA

0 0
Activity of Po-210 (Pb-210) at the sampling da 48.33 13.86
Combined uncertainty (k=2) 7.89 3.85
unc % 16.33 27.77
Reference sample: IAEA-414
Activity of Po-210/Pb-210, Bq/kg
Uncertainty (k=2)
95% Confidence interval
 Pb-210
22.300
8139.5
0.03108
8.52E-05

tion, dilution BATAN

5RA 3RA A 3/1

Belanak
### ### Sunday, August 26, 2018
1/7/2019 8:00 1/7/2019 8:00 1/11/2019 8:00
10/7/2019 9:57 11/7/2019 10:10 1/16/2019 12:10
5.00 5.00 5.00
0.2000 0.2000 0.2000
0.3743 0.3741 0.3758
0.0102 0.0102 0.0103

172800 172800 172800

1 1 1
0.3 0.3 0.3
248.00 248.00 248.00
0.00 0.00 0.00
451.00 18.00 42.00
0.00 0.00 0.00

0.075 0.075 0.075

6.4 6.4 6.4
27.23 1.09 2.55
4.41 0.53 0.85
273.1 304.1 5.2
0.3 0.3 0.4
0.995008 0.995008 0.995008
0.254639 0.218005 0.974417
0.991498 0.991498 0.988297
5RA 3RA A 3/1

0 0 Belanak
108.37 5.05 2.66
17.57 2.47 0.89
16.21 48.95 33.56

2.1

1.8-2.3
 A 3/2
Laosan
Sunday, August 26, 2018
1/12/2019 8:00
1/16/2019 12:10
5.00
0.2000
0.3758
0.0103

172800
1
0.3
248.00
0.00
23.00
0.00

0.075
6.4
1.39
0.61
4.2
0.4
0.995008
0.979311
0.988213
A 3/2

Laosan
1.45
0.63
43.74
Nuclides: Po-209 Po-210
Half-life T1/2, yrs 125 0.379
Half-life T1/2, days 45698 138.376
Decay constant l, yrs-1 0.00554 1.82834
Decay constant l, days-1 1.52E-05 0.005009
Decay constant l, sec-1 5.80E-08
Tracer: Po-209 MODEL CAL3003 Standardized solution, dilution BATAN
Reference date 3-Sep-97
Tracer activity, Bq/g or Bq/ml 0.423
Uncertainty (k=2) 0.012
Analysis:
Samples: B 1/1 B 1/2
Description Kerang Tenggiri
Sampling / Reference date ### ###
Deposition (separation) date 8/23/2017 15:30 8/23/2017 15:30
Counting start date 8/24/2017 9:49 8/24/2017 9:49
Sample mass, g 1.00 1.00
Tracer Po-209 mass , g or volume, ml 0.2000 0.2000
Tracer activity, Bq/g on a Counting date 0.3787 0.3787
Uncertainty of tracer activity (k=1) 0.0104 0.0104
Counting:
Counting time t, sec 78299.6 79200
Background counting time, t bkg, sec 1 1
Counting efficiency, eff 0.3 0.3
Peak area N, Po-209 213.27 117.00
Peak area N, Po-209 in Background 0.00 0.00
Peak area N, Po-210 328.68 104.00
Peak area N, Po-210 in Background 0.00 0.00
Calculations:
Activity of Po-209 added, Bq 0.076 0.076
Chemical recovery γ, % 12.0 6.5
Activity of Po-210 at the counting date, Bq/kg 116.72 67.32
Combined uncertainty (k=2), Bq/kg 20.77 18.24
Time passed between separation and counting, day 0.8 0.8
Time passed between sampling date and separation 0.1 0.1
Correction factor f1 for Po-210 decay during counti 1.00 1.00
Correction factor f2 for Po-210 decay between separ 1.00 1.00
Correction factor f3 for Pb-210/Po-210 decay betw 1.00 1.00
Results: B 1/1 B 1/2

Activity of Po-210 (Pb-210) at the sampling date, B 117.66 67.87

Combined uncertainty (k=2) 20.94 18.39
unc % 17.80 27.09
Reference sample: IAEA-414
Activity of Po-210/Pb-210, Bq/kg
Uncertainty (k=2)
95% Confidence interval
 Pb-210
22.300
8139.5
0.03108
8.52E-05

ed solution, dilution BATAN

B 2/1 B 2/2 B 3/1

Tuna IAEA 414 Udang
Tuesday, August 01, 2017 Tuesday, August 01, 2017 Tuesday, August 01, 2017
8/23/2017 15:30 8/23/2017 15:30 8/23/2017 15:30
8/24/2017 9:49 8/24/2017 9:49 8/24/2017 9:49
1.00 1.00 1.00
0.2000 0.2000 0.2000
0.3787 0.3787 0.3787
0.0104 0.0104 0.0104

79200 79200 79200

1 1 1
0.3 0.3 0.3
139 92 171.00
0.00 0.00 0.00
59.00 3.00 31.00
0.00 0.00 0.00

0.076 0.076 0.076

7.7 5.1 9.5
32.15 2.47 13.73
10.03 2.90 5.37
0.8 0.8 0.8
0.1 0.1 0.1
1.00 1.00 1.00
1.00 1.00 1.00
1.00 1.00 1.00
B 2/1 B 2/2 B 3/1

32.41 2.49 13.84

10.11 2.92 5.42
31.20 117.37 39.14
 2.1

1.8-2.3
 B 3/2

Tuesday, August 01, 2017

8/23/2017 15:30
8/24/2017 9:49
1.00
0.2000
0.3787
0.0104

1
0.3

0.076
#DIV/0!
#DIV/0!
#DIV/0!
0.8
0.1
#DIV/0!
1.00
1.00
B 3/2

#DIV/0!
#DIV/0!
#DIV/0! #DIV/0!
The significance of various levels of s
Confidence that result is real
84.13%
93.32%
97.73%
99.38%
99.87%
99.98%
100%
 A, Bq/kgunc. K=2 unc %
1 A 1/1 Kerang 167.12 31.01 18.56
2 B 1/1 Kerang 117.66 20.94 17.80
3
5 A 1/2 Tenggiri 81.91 16.82 20.53
6 B 1/2 Tenggiri 67.87 18.39 27.09 180.00

160.00
8 A 3/1 Tuna 11.01 3.71 33.71
9 B 2/1 Tuna 32.41 10.11 31.20 140.00

120.00
12 A 3/2 Udang 11.09 3.41 30.74
13 B 3/1 Udang 13.84 5.42 39.14 100.00

80.00
16 A 2/1 IAEA 414 2.89 4.14 143.32
60.00
17 B 2/2 IAEA 414 2.49 2.92 117.37
40.00

20.00

0.00
0 2 4 6 8 10 12 14
 Column D

4 6 8 10 12 14 16 18