CONFIDENTIAL 8 Section C [30 marks} Answer any two questions in this section. 18 @)_—X is an element in peri ji period 4 of the Periodic Table. The stable oxides of X are XO, X20) and X;O,. An aqueous solution of "is yellow. : @® Based on the information given below, construct a labelled Born-Haber cycle for X,0; solid, [6 marks] ‘AHI ‘Standard enthalpy change of formation of X:Os TTT Standard enthalpy change of atomisation of oxygen FUATS ‘Standard enthalpy change of atomisation of X WAISS Tonisation energy of X atom to Xion +5282.0 Electron affinity of oxygen atom to O* ion 650.0 Lattice energy of X20 y Gi) * Calculate the lattice energy of X20s. [2 marks} () The standard enthalpies of formation of gaseous dinitrogen tetraoxide, N:O., and gaseous nitrogen dioxide, NO>, are +9.67 Jmol and +33.9 kImol” respectively. Construct Hess's Law cycle and calculate the enthalpy of dissociation of gaseous dinitrogen tetraoxide to gaseous nitrogen dioxide. [3 marks] (©) Liquid Hiydrazine, NaH, is used as a rocket fuel due to its enthalpy of combustion is very exothermic, The thermochemical equation for the combustion of hydrazine is as follows: NH () + O2(g) ————> N:@ + 2#0(g) 4H=-534.010 10.0 g hydrazine is burnt in a bomb calorimeter. Calculate the temperature change ifthe total heat capacity of the bomb calorimeter and its contents is 58.6 kJ °C. [4 marks] Scanned with Car