C ‘Trial Rosli Dhoby P2 2020 Section A [15 marks} 1. ‘The diagram below shows the Bor-Haber eyele for the formation of sodium fluoride. S74 mot! Na(s) + '4E\(2) ———*_ Nas) +107 KI mot | sr U Nate) Fie) 428 ks mor! 49613 mot"! | Na‘) + F®) 2. The radius and charge of each of six ions are shown in the table. [ton Y g we [x Y 2 [Redius(nm) [oa os joss joss joss | 0.5 ‘The ionie solids JX, LY and MZ are of the same lattice type. What is the correct order of their lattice energies placing the one with the most exothermic first? A IX>LY>MZ B JX>MZ>LY © LY>MZ>IX D MZ>JX>LY @ rr diagram show the apparatus for an electrolytic experiment of cells 1, Il, and III connected in series. What ‘are the products formed at the anodes of each cell? carton 80, Ca Cell Cell Cell MI A Mass of Cu increases Hp liberated > liberated. B Mass of Cu increases > liberated Cl liberated c Mass of Cu decreases > liberated. > liberated D Mass of Cu decreases > liberated Cl liberated4, Acdisproportionation reaction occurs when aspecies M' spon reduction. 2M"(aq) > Maa) + MGS) “The table below contains E~ data fo tancously undergoes simult copper and mercury species. EAN CuP(ag) + > Cu") +0.15 Cu'(aq) +" 7 Cuts) +052 He '(aq) +" > He") +0.91 Hg'(aq) +e — He +0.80 Using these data, whi Both CuCl) and H(1) undergo disproportion: Only Cu(1) undergoes disproportionation. Only Hg() undergoes disproportionation. Neither Cu(l) nor Hg(1) undergoes disproportionation. ation. paw 5, Use the data in the table below to answer this question. ‘ch one of the following can be predicted? EP IV ‘MnO: (aq) + 8H (aq) + Se" —> Mn’*(aq) + 41200) + 1,52 C07 (aq) + H4H"(ag) + 6" > 2Cr°*(ag) + THRO) +133 Fe*(aq) + & —> Fe*(aq) +077 CPi(aq) +e CP*(aa) -0Al Zn**(aq) + 2e° — Zn(s) = 0.76 ‘The most powerful oxidising agent in the table is Man?*(eq) Zn(s) MnO3(aq) Zn**(aq) wap 6. ‘The diagram shows how a property of Na Mg Al Si > A. Atomic radius B. Electronegativity C. First ionisation energy D. Melting point vvuain dati N ancous oxidation and , © Period 3 elements varies across the period. What is the property? isu wiul ValW, oxides of the elements are given in the table below. Y and Z are clements in Period 3 of the Periodic Table. The physical and chemical properties of the Oxide of element w x Y Zz Physical state Gas Solid Solid Solid Solubility in water Soluble | Soluble Insoluble | Insoluble Acidity Basic Acidic | _Amphoteric ‘What could be elements W w z A cl Si B Ss Al c Na Al D P Si 8. Which element has the highest first ionisation energy? A. Aluminium €© B. Phosphorus C. Silicon D. Sulphur 9. The following table shows the lattice energy and the hydration energy of three sulphate salts X, Y and Z for the three elements in Group 2 of the Periodic Table. Sulphate salts Lattice energy/J mot! Hydration energy/kJ mot! x -2489 -1650 Y -2374 1350 Zz “2484 =1480 Which of the following sulphate salts are arranged according to solubility in decreasing order? AXZY BX.Y,Z @e y.zx DZXY 10. The properties of three tetrachlorides of elements P, Q and R in Group 14 of the Periodic Table are as follow: * The tetrachloride of P decomposes when heated and liberates chlorine gas. © Aci © Thereis Which of the following shows the correct arrangement of the elements in order of increasing proton number? AL QR P B. P,R,Q C. P,QR D. R,QP ic fumes are liberated when the tetrachloride of Q is added to water }0 visible change when the tetrachloride of R is added to water. vvual cu wiur val11. Which species is not produced by a redox reaction between solid sodium iodide and concentrated sulphurie\ acid? A NaySOu B ELS ch D SO» 12. Which statement about astatine is correct? A. Astatine has a greater electronegativity than bromine B_ Astatine is a better oxidising agent than bromine CC Astatine has a greater boiling point than bromine D_ Astatine has a greater first ionisation energy than bromine 13. The halogens are important chemicals in our daily lives. Which statement about Clz, Brz and Iz is tru ‘A. The halogens can act as both oxidising and reducing agents. B. The strength of the van der Waals forces increases from Clz to I>. C. Ch, Brz and Iz are formed when their respective halides react with concentrated H2SOs. D. Ch, Brand I react vigorously with hydrogen gas in the presence of ultraviolet light. 14. Iron forms a complex ion with the formula (Fe(H2NCHsCH:NH2)2Ch]*. The systematic name of this complex is A. Dichlorodiethylenediamineiron(1) ion B. Dichlorobis(ethylenediamine)iron({1) ion C. Dichlorobis(ethylenediamine)iron(III) ion D. Bis(ethylenediamine)dichloroiron({Il) ion 15, Melting point/“C a — The graph above shows the melting points of a few transition elements. Why is the melting point of manganese low? A. Its electrons are not ready to form metallic bonds B. Manganese is a metalloid C. The atoms are not closely packed in the metal lattice of manganese D. There is a strong screening effect in the atoms of manganese wiut ualSection B [/5 marks} Answer all questions in this section. 16. This question is about lattice energy (a) Figure 1 shows a Born-Haber cycle for the formation of magnesium oxide. Complete Figure I by writing the missing symbols on the appropriate energy levels. [3 marks] Mg?*(a) + OF(9) Energy (6) Table 1 contains some thermodynamic data. ‘Enthalpy change /kJ mot! Enthalpy of formation for magnesium oxide 602 Enthalpy of atomisation for magnesium +150 First ionisation energy for magnesium +736 Second ionisation energy for magnesium #1450 Enthalpy of atomisation for oxygen 4248 First electron affinity for oxygen 142 ‘Second electron affinity for oxygen 4 Table 1 Calculate a value for the lattice energy of magnesium oxide [2 marks] lattice energy: vvainicu wit Udl17. A student set up the cell shown in Figure2, \ fo Copper. Copper 0.15 mol dav? ~1.0 mol dm? CuSOs(aq) CuSO,(aq) Figure 2 (a) The student recorded an initial voltage of +0.16 V at 25°C (9 Explain how the salt bridge provides an electrical connection between the two solutions. [1 mark] (i) The standard electrode potential for the Cu2*/Cu electrode is Cu (aq) +2e—> Cus) B= 40.34 V Calculate the electrode potential of the left-hand electrode in Figure2. Electrode potential: Gii)Both electrodes contain a strip of copper metal in a solution of aqueous Cu2* ions, State why the lefi-hand electrode does not have an electrode potential of +0.34 V (1 mark] (iv) Give the cell diagram for the cell in Figure 2. Include all state symbols, [0 mark} © ©) When the voltmeter is replaced by a bulb, the E° of the cell in Figure 2 decreases over time to 0,00 V Suggest how the concentration of copper (Il) ions in the left-hand electrode changes when the bulb is alight. Give one reason why the E of the cell decreases to 0,00 V [2 marks} Change in concentration of copper (Il) ions in the left-hand electrode Reason why the £ decreases to 0.00 V vvuainicu wiul val(6) Use data from Table 2 to identify the species that can be used to reduce VOz" ions to VO" in aqueous solution Table 2 Electrode half-equation ee/V ‘VO2*(aq)+ 2H"(aq) + e-->VO"(aq) + H20(!) +1.00 Vo™(aq) + 2H*(aq) + e->V"*(aq}+ H20(l) 40.34 Cla{aq) + 2e-2CI-(aq) 41.36 Fe?*(aq) + e->Fe**(aq) 40.77 Zn*(aq) + 2e"->2n(s) 0.76 @ Explain your answer. [2 marks] Reagent Explanation (ii) Heating NHsVOs produces vanadium(V) oxide, water and one other product. Give an equation for the reaction. {1 mark} (iii) Venadium(V) oxide is the catalyst used in the manufacture of sulphur trioxide from SO2 Give one equation to show how this reaction occur. [1 mark] veuainicu wiul ValSection € [30 marks] two questions in this section rable with the following aspect 18. soe {o) Explain the chemical characteristic of Group 14 elements in periodic T eel (@ — Uydrolysis of tetrachloride -sguato st . oa roxide of elements with +2 oxidation state i) Acidcbase properties of ovide oa with Zoi eal aie (Wit reference tothe stature and boning, expan Wh . eal Poi is very unstable. 19 (@) Solution A contains the compound [Cu (OIC {@ State the type of bonding between the oxygen and hy dro inthis compound. {1 mark] (7 State why the chloride fons inthis compound are not cons dred to be ligand [1 mark] (i excess of ammonia was aed toa sample of solution & 10 form solution B. aoe onic equation forthe reaction that oecurs when solution A is converted into solution B and state the colour of solution B. [2 marks] {a Aqueous sodium carbonate was add to anther sample of station ‘Ato forma green solid C. Identity the green solid C. [imark] © (a) Reagent D was aed fo another sample of solution A to form a yellow solution. Coa engent D and write anionic equation forthe reation that occurs when the yellow solution is formed from solution A. [2 marks] Faplain wy colorimetry cannot be used to determine the concentration of solutions containing [CaCI] In your answer, refer to the electron configuration ofthe metal fon. [2 marks} (0) in an aqueous solution, Fe" jons act asa catalyst inthe reaetion between T-and S208 ions. Give one reason why the reaction is slow in the absence of the cataly Wate balanced equations to show how Fe" ions act as a catalyst for this reaction. [6 mad 20. (a) Chlorine is used to decrease the numbers of microorganisms in water. When chlorine is added to water, there is a redox reaction, as shown by the equation Clot 120 2 HCIO+HCI (i) Deduce the oxidation state of chlorine in HCIO and HCI [1 mark} | (i) Give two hal-equations to show the oxidation and reduction processes that oceur in this red | reaction, (Gii)Chlorine is reacted with cold, aqueous sodium hydroxide in the manufacture of bleach. “Give an equation for this reation between chlorine and sodium hydroxile [1 mark] (iv) Potassium chlorate (VI, KCIO4, is used in fireworks. When potassium chlorate (VII) decompos produces potassium chloride and oxygen. Give an equation for the decomposition of potassium [2 marks] chlorate (VII). Use the data in Table 3 to calculate the enthalpy change for this reaction. [2 marks] Substance ‘OH i/ Wi mol? KClOd(s) 434 Kcl(s) -436 (b) Radi a (b) Radium, a radioactive clement, is Periodic Table. Compare the thermal stability of radium located below calcium in Group 2 of thi plain your answer. [4 marks] hydroxide with that of calcium hydroxide. (c) When a 0.6284 g sample of a Group 2 hydroxi ; oup 2 hydroxide, formula M(OH)2.1120 is heated, it is dehydrat the anhydrous hydroxide M(OH), losing 0.0594 g in the form of steam. Identify the metal _ “me [5 marks] | Vvuainicu witrt val