SION, Mark Andrew BscHE 2 Physical Chemistry 1(Lec) Midterm QUIZ #1 Instructions: Copy each problem and solve as neatly as possible and show complete solution. Solution should be handwritten and all values must include proper units with proper ‘conversion if needed in your solution, 1. The data for the adsorption of ammonia on barium fluoride are reported below. It fits the BET isotherm. Find the values of c and Vy. T=0°C and P°=3222 Torr. (Torr) 105 282 492 594 620 755 798 V(ee) 111 13.5 49 16.0 15.5 17.3 3S Given: PCtore) values Po + 9222 Torr 10°C ¥ (ee) values Re quired: vw © and Vm Solution: Pr oe 7 Pe v =P) sit 3-094996105 x10"? eee 7 10 3 7 Sean i 105064248 x10 u . shri 02 0962 8% a4 | 0.014267 12 3102 640 0. 01654279 S44 55 0. 01tGao1st CS OLE lal Le etek EST 14% a“ | 0.01995 1495 LL | Scanned with CamScannerSION, Mark Andrew Bscip 2 “4 = 4.699093090 X16 De O-0FGNL9 N41 905 re 09976576 051362 Inter pee stint, Ho ntercept Tao we ae “an ¥ 4 Ssaoamaga9 so = __t 4-629 959994 x0 a We (15.072) mw . : ce eee 439648 9444 xIo~ Tn = 19-0588 Ym © im 2155 «312151 slope ig er Ym © 6-096n290 905 =__¢") 2155-31219) Oak = 1Gg. 04904 6 s 165. 0471] Scanned with CamScannerSIONS Mark seca a een 2. The following data are for Xenon adsorption on ZSMS zeolite. Evaluate the constants from the a) Langmuir and b) Freundlich. Which of the isotherm fit the data best? Explain. P(Torr) a7 | 136 | 250 | 364 | 473 | 577 | 680 ‘mass(g) of ZSMS zeolite/mole of Xenon mez | oas77 0.6588 | 0.5692 | 0.5255 | 0.4946 | 0.4715 | | | Given: *P CO) vowed | + J (mags zeolite) more xenon) | Required = . @) Constants LAngmuil b) Fremadliech Constant | ©) Which iS0therm fit the best solution + to soe for ¥ . ' 3 y B Imo\ . ! = —0-S31 01046 18852 . 1 = ENO 4S7892 0. 8997 . \ S-51F AN 954 at 0 -G5%% 1 — = 17508 >.50a2 508 51722 * —1 = 1 VOL44GS 72 0-5155 . : 2 2 ONG 95 8IT 0 - 45440 po gs eee 0- 4315 Scanned with CamScannerw) = 0-013830% f "y j 44 88. 51040001 (3@ (22, 0872 150 lo4-% Sho 207. (883 4 24% .5015 bn 245. 3842 C%0 $0.02 a = 2. 2F 265214964 bs 0-80 s4750 oer intercept - za: sore =F qiaasesuaasd a Eye aa im b= 5.0% 8 93UI92 Kl0-$ Freundlich inset creme ac (as aoe aa 9-B50147GO2 = 0 4329 240% 4. MULGS4 ESE 0 10X41 9% 41 5.5214Goa% is ©. 4\¥39526 5 BATT DIES 0: SEOS LOUD 6.154 0aS 38% 6. 4 40508% 6-55 4 SY 2HF 0-30 400 sa74 fe See ee cece OES HIME Scanned with CamScannerO« - 250344946057 De b-546s 685 ay te 0.99012 $B 94924 intercept = 9.509 439769082 invercept = 0 In K ein k) = (2-50543aaGeoe2 Je k = 0. 0818051 e ae slop i tos a5 ars694IG n= 453294062 The isotMerm that fit the «= data best iv Langmuir 1S otherm ince its of value is closest to 4 Scanned with CamScannerVION, Mark snd Bsore gn are 3. The following data refers to the adsorption of n— butane at 298.15K by a sample of tungsten powder, the surface area of which as was shown to be 6.5 m’/g by the adsorption of the gas. Determine the area (in nm’) of surface covered by one molecule of n-butane. [ Relative pressure( )°P/P 0.04 on | 0.16 0.25 0.30 0.37 | Volume adsorbed(cm at 0.33 0.46 0.54 0.64 | 070 0.77 STP) s ae Ze oon , 5a values Y( vatues) g Rejuireas Surface Oreq sollition: 1S 2k Pp | ° | >) 0-04 | 0-12626 26.26 | 0-10 0-24ic 48 343 | 0.16 | 0-45 1733 G86 | ssc eee es ea etn tne | 0-15 0-5208 $3334 | 0-40 0-6 11244899 a 0.3% 0-7G 172% 34 | Scanned with CamScannerOs 0.045954 5 3092838 De 1 9009449403195 Te 0.999¢ 485 65% 304 b 0489595507287 ¢_ 3 Von (40-4334) intercept any Vn ce 904550 M0 a2 5 a5 - \ Vn Vin © = 0.04845 453042843 Vn O = 20. @ 3101305 slope = e-1 Yn © 1100744 F4ayys = on) 20 -GB 101305 Giz S > 99 4334109 © = 40-4354 ae (ee \ ) ws R To 2 = us mt, [ Maim)( 0-606 co + “ais eA (6 orrxto*” mots) S>) > (0-0rws KAM) (2179.15K (49299 x00 Mm) / bg a) (“S Scanned with CamScannerSION, Mark Andrew 4. The following data refers to the. T= of dinitrogen (Nz) ona pee Te black at 77K. Relative pressure( )°P/P 0.10 0.15 Volume of Nz adsorbed (cc at STP) L 24 ws | 1: 0.30 Le 9.0 205 Using the equation for the BET isotherm to calculate the volume of nitrogen adsorbed which corresponds to a monolayer. If 1 gram of carbon black was used in the experiment, calculate the Given: most af corvon piack > 19 SF ty 2 10°80 me Relative — fregcure. Required: + Vin a 2 Solution: Vor Ny surface area assuming the area occupied by one nitrogen molecule to be 16.2x10*-20 m* we 4.14448 1145x107 1.6678 95144 x10? 0-01684 4 146 0014104545 0-014 543859 0-020 406923 Scanned with CamScannerSiow, M coal BSCH eT nd = 0000944965404 0-00094945703 * De 9. 066 445195 56 Vn ( 30.4530) Ye 0.9999%93 49% Ym = 14-4 4013 co ul intercept = 1 i) bli Th > 4: $4013 & 0-000949G53q3 = — count NN ad Vin © Vn © ‘ 1 0.00044 965763 Vm © > 1053 -01l0%9 Sepe 7 bel Vine 0-060 49519530 = te (053 -011073 c-1 = 69-950935 42 t F 30.9540 b) Sowe — for < ie 2 POE fe g 14. 84013 rt * abe 2 (lh Poe ih “be t . eh (0:01485) \ (aan mt )( oben) ( (0-08005 EAM )( 223.156) ' G4. 4215 _m™ a | = bnswer eee esse eee Scanned with CamScanner