{b) Dilute sulphuric acid can be used t as ‘pickling’ to remove rust, iron( III) oxide, from iron in a process known Write tl a aa a irene del ee reset between iron(II1) oxide and sulphuric acid. which can be removed by reaction with 499 sulphuric acid. [4] AM Qad dM sy. > Le ilole Mh soy.: Vv Mo, Wass Vey Oy =. (c)_ State one product manufactured from sulphuric acid a LGM. onmsgetnnnnnnnn B10 Nylon is a polyamide produced by condensation polymerisation. (a) Describe the formation of nylon from monomers. Your answer should explain the terms polyamide and condensation polymer. we a _folyonselt means. helmaaty. (ON ade. Ao os alenstion pOYO_ means, aN meneMm2. M60 d_walo ag V dibooic aod... praduved Nyt amen, dian eieeteiaihSection A Answer all questions in the spaces provid The total mark for this soction is 45, ‘AY The following i alist of formulae of organic compounds. CH,COOH CHC HOH GH, Hy Which of the above formulae fit the following descriptions? (2) @.compound which dissolves in water to form an acidic solution {b) a compound whighie not a hydrocarbon NOH a {)_ two compounds whigsre from the same homologous series ole. 2d Gy. (d)_ two compounds which rpa€t to form an ester My (oot an Waco (e) a compound which ungergoes an addition reaction with steam Gilly. wa RR {i (a compound which is oyidised by acidified potassium dichromate(V') to give ethanoic acid ( On [i] A2 Silicones are used as waterproof sealants. (a) Name two elements in silicones. (b) Give one other use of stems Z Jub conts Oe [0 Level, P-1] [Mock-4] Lee Jl, P-fo A3_ Tho dagram below shows the outer shall slicttons of an atorn of olomont X, HH a, (9) To which group of the Periods Tablo doos X bolong? Grea vit - moll] (b) Draw a ‘dot and cross’ di agratn to show the bonding in the compound of X with carbon, Your diagram should oh }0W outer olectrons only, ee Bp 2} i {0 Level, P-1) [Mock-4} [Parvez sir) 0 Level, P-J ‘A4_ Two compounds were dissolved in water at 25°C. Tho temperature of each solution was measured immediately after tho compound had “temperature/'C tomporature water solution ammonium nitrate calcium chloride (a) Complete the table to show (i) the formulae of the two compounds. (ii) tho temperature changes after dissolving, 1 6 (b) State the type of energy change which takes place when ammonium nitrate dissolves in water. Give a reason for your answer. type of energy change .Endyt NOM Le reason... ‘emnperens _ASO.CAse.. {2} (c) Which ‘compound in the table can be used as a fertiliser? Explain your answer. Wibdlt.... compound .. AL. min onus! _conaipt. iho . explanation ...{ ; [Parvez sir] [Mock-AS. Potrol (gasoline) vapour is mixed with air before being burned in a car engine. (a) What are the major products of combustion of petrol in an excess of air? sob bo..8 C NM eee dE lt] ‘Tho amount of pot in the mitre can bo varied mounts of pollutant gases, nitrogen oxide and carbor , n monoxide, in the exhaust ‘omissions from cars depend on the mixture used, as shown in the graph below. ‘carbon monoxide concentration of pollutant gases nitrogen oxide 5 6 7 8 a 10 percentage of petro! in the airfpetrol mixture (b) (Explain why some carbon monoxide is produced in a car engine. ok. .coeugth...0¥ 00.35. oa (i) Describe how the concentration of carbon monoxide varies as the percentage of petrol in the mixture increases. coll slays, onstant..and then. increas SS 2 (©) Explain how car ‘engines produce nitrogen oxide. “beg, atl ong. um an. ae Agia. de Jy en Nod 1 igh. Janpoahnss inthe nut 8 pf seneeessnnenrnene ao: | [Parvez sir] [Mock-4] fo tevel, P-11(d@) Ael ee Moat onorgy when thera ih 7.2% petrol in the mixture, Suggest ho highest concentration of nitrogen oxide Is produced Siapee was tha Hah 1 of nitrogen oxide ts produced in the engine Layne Me We AMM Aldous {e) Pollution from cats is dacroasod by using catalytic convortors, ‘Tho structure of a convertor is shown balow. coramic support coated with stool casing jpowdorod catalyst hot gases to exhaust from pipe engine tomporaturo 700°C (i) Catalysts incroaso tho ratos of roaction. Give two other reasons why the roactions in catalytic convertors aro very fast hc. cael in, gooohered,. vam. 90. thas. incoeaged sun ladt hen todad ovation Z a: nnoxido can roact together to produce two less (ii)_ Nitrogen monoxide and carbon mo polluting gases. Name theso gases. Nilaog.. cand on Ubi wade, P ir] fo tevel, P-l} eee ae Level, P-AB Two naturally occunting ores of copper are cuprite, Cu,O, and tenarite, CuO. / (a). Give the oxidation stato of copper in each oro, oxidation state of copper in Cu,0 oxidation state of copper in. CuO... jowdered carbon. {b) Copper can be extracted from tenorite by healing the ore with p (i) Write an equation for this reaction. DAWO N22. DAWA. em (i) Explain, in trms of electrons, why the copper in tenorite has been reduced, wnt led yeas . nee. for 5 (e) A samplo of one of the ores was analysed and found to contain 4.489 copper and 1.12g oxygen. “Ms, is, Calculate the empirical formula for the copper oxide in the ore, and deduce the name of the ore. ate Gir 4 “8 = U.bTCO . oN o Molt 0 WL. poy WH \6 vi a (ad wht empnt ul fonvla [Mock-4] [Parvez sit] fo Level, P-1]/ [AT (a) Complete the table ion formula number of number of number of protons neutrons electrons ae Potassium | wt 4 0 ig ae oxide oa ¢ 6 i. ta (b) Ina sample of 100 atoms of potassium there are 94 atoms of ©°K and 6 atoms of aK. (i) Explain why these two forms of potassium are isotopes. gathun (il) Find the total mass of the 100 atoms of potassium. Hence find the average mass of one atom. joo clom mass = Mux 34) 4 6X 4) + an - > 3a Volum = 34 08 SY SVL (3)/ In separate experiments, powdered samples of metal X a ith soluti ind motal Y reacted with solutions 1 pickel(l) sulphate and of ion(l) sulphate. The following table shows how the elous of the solutions changed. nickel(tl) sulphate iron(tl) sulphate solution goes from motel X oasion tea solution stays pale green metal Y colaion goes from green to| solution goes rom pale colourless ‘green to colourless een to colour (a) Predict the order of reactivity forthe four metals, X,Y nickel and iron. most reactive least reactive (2) (b) Metal ¥ was placed in aqueous ‘copper(tt) sulphate. (i) What colour change was seen ? ion, donned, em (ii) Give one other observation. Fink, Solid edo. dbe.. (2 {e)_ Write the ionic equation, with state symbols, for the reaction between iron and aqueous niickel(II) sulphate. th top 2d 94) 1.N 42] [0 Level, P-1] [Mock-4] [Parvez sit]Section B ‘Answor three quostions from this section, ‘Tio tho oxtra shoots used loosoly to this booklot. Each quostion carrios ten marks {89 Tho diagram reprosonts an exporimontin which an elctc currents boing passed through dilute sulphuric acid, onygon —— dito / ae ~platinum — wctoses | i tis soltion. tt ot a ios rein He ady €2) iste rm atone acon teen 7 Deseribo the tost for oxyde" id gig gl [parversir) [Mock-4]~ » aRAAARARAAgAAAARAR o A ® AA oo vVovvvvvv@v@Ov vo v @©Oe ve & a@Onuan@nua@aa® = © » 2O© O©©@ @<<@€6@<6<<<<< ©< « << <««< SS SyPP RE Ag AG YA ES WLAsEsassyray by 4) ve CO@e a@aanaa@anana @a@aa 2 « oVvVVVOvVLVLEHOd wv A A A, TA 19.A A 3.4 A 208 29.A 31a 33.A, 35. A 37.8 39(@) [Parver sir} [Mock-4) {0 Level, P-2]1M hi jane ‘element, M, has the following properties. Less dense than wate Soft. “ Melts below 100°C. Occurs naturally a8 ts code, femula MC feof M reacts with water to form a soluble hydroxide. r (a) (i) Suggest to which group of the Periodic Table metal M belongs. (ii) Suggest how metal M can be extracted from its compounds. Explain your reasoning: Nts a \vigh ay Abe ygaghvily Sous (cl, starting wth the carbonate, M,COs fo stan, “lh De 1 solune dress (b) Outline a method to prepare crystals of Mt dulion, unk “hin, (ews Yb«. ool lp cer of MCI contains 1.42g of chlorine (0) 6729 in the sample, and hence suggest a value 3) umber of moles of chlorine atoms | Caleulate the nt ic mass of M. for the relative atomi fy lias 1 eb 2O. [Parvez sit] [Mock-4] be ae> x So Qo (o) Stato one similarity and one dtference botwoen the structures of nylon and protoin. (2) conlon..omide. linkagtse. “nvonebd (¢)_ Insulin is a protein used to treat people suffering from diabetes. In an experiment, insulin was hydrolysed into a mixture of amino-acids. {Suggest what conditions could be used to hydrolyse a protein such as insulin. ‘A chromatogram was set up with a sample of the mixture and samples of the amino-acids proline and lysine as references. we “Nes «te \ show that ji) Explain, with the aid of a diagram. how chromatography could be used 10 Mu proline and lysine are present in the minture i a fon is non-biodegradable. io whet does this mean? not bike de on V ” [parver si] [Mock-4] fo Level, P-1] aloha os