SOAL ESSAY UAS ANALITIK 3 2021

1. The concentration of pesticide residue whose is volatile and thermal stable properties was
conducted by chromatography technique using internal standard. Sample soil of 1.000 g is
extracted with 20.00 mL of hexane. After filtering to remove the soil, a 1-ml portion of the extract is
diluted to 10 ml isooctane and add internal standard. Injecting the diluted extract and standard
with the same condition revealed the data in the table below.

Peak
Compound Analyte concentration height, Peak height,
(ppm) analyte internal standard
1 0,05 18,8 50
2 0,10 48,1 64,1
3 0,15 63,4 55,1
4 0,20 63,2 42,7
5 0,25 93,6 53,8
Sample 1 (98oC) 58,9 49,4
o
Sample 2 (198 C) 70,5 55,1

Determine the concentration of pesticide residue in soil sample 1 (ppm).

2. Based on the data in problem no 1 suggested and give the short explanation of your answer:
a. a type of appropriate chromatography
b. stationery phase and trade name
c. mobile phase
d. detector
e. predicted chromatogram.