PT. WAHANA DUTA JAYA RUCIKA MATERIAL SAFETY DATA SHEET Name Of Product : RUGLUE Substance of Chemical Family : Ketone Description ‘ Clear Colorless Stable and medium boiling Liquid with pleasant odor. Slightly soluble in Water, miscible with most organic solvents. 1. Hazard Identification Human health hazards Narcotics at high vapor concentrations, irritating to eyes and respiratory system. Safety hazards Highly flammable.In use, may formflammable/explosive vapor - air mixture. Environmental hazards Annex | substance under review by EU Commission 2. First Aid Measures Symptoms & effects Headache , dizziness , nausea , narcosis. Irritation of the skin,eyes and respiratory tract.Dryness of the skin. First aid - inhalation Remove to resh air.If rapid recovery does not occur ,obtain medical attention. First aid - skin Wash skin with water using soap if available. If persistent irritation occurs, obtain medical attention. First aid - eye DO NOT DELAY.Flush eye with water.Obtain medical attention immediately. First aid - ingestion Do not induce vomiting.Give water to drink,providing patient is concious. If rapid recovery does not occur, obtain medical attention. Page 1 of 5PT. WAHANA DUTA JAYA RUCIKA Advice to physicians Dermatitis may result from prolonged or repeated exposure.Causes central nervous system depression 3. Accidental release measures Personal precautions Avoid contact with skin and eyes.Ventilate contaminated area thoroughly.Do not breathe vapor.Extinguish naked flames.removes ignition sources.No smoking.avoid sparks.Evacuate the area of all non-essential pesonnel. Shut off leaks, if possible without personal risk Personal protection Wear neoprene or nitrile rubber,gloves,and PVC one-piece suit with integral hood. Safety boots - rubber,knee length.Wear full face-piece respirator with organic vapor canister NPF 400.In a confined space,wear self contaminated breathing apparatus open circuits type NPF 2000. Environmental precautions Prevent contamination ofsoil and water.prevent from spreading or entering into drains,ditches or rivers by using sand,earth or others appropriate barriers. Clean -up methods - small spillage Absorb or contain liquid with sand , earth or spill control material.Shoves up and place in a labeled , sellable container for subsequent safe disposal .Put leaking containers in labelled drum or over drum.Flush contaminated area with plenty of water.Retain washings as contaminated waste. Clean -up methods - large spillage Transfer to a labeled,sellable container for product recovery or safe disposal. Treat residues as for small spillage. Other information Risk of explotion.Inform the emergency services if liquid enters surface water drains.Vapor may form an explosive mixture with air .See section 11 for information on disposal. ¥ Handling & Storage Handling Avoid prolonged or repeated contact with skin.Avoid contact with eyes.Do not breathe vapor.Only use in well - ventilated areas.Extinguish any naked flames.Remove ignition sources.Avoid sparks.Do not smoke .Do not empty into drain. Page 2 of 5PT. WAHANA DUTA JAYA RUCIKA Handling temperature is ambient Storage Keep away from direct sunlight and other sources of heat or ignition.Do not smoke in storage area.Keep container tightly closed and in a well-ventilated place. Storage temperature is ambient Product transfer is earth all equipment Recommended materials For containers or container linings,use mild steel or stainless stell.For container paints,use zinc silicate. Unsuitable material areplastics,alumunium,natural,neoprene or nitrile rubbers. 5. Exposure Control /Personal Protection Engineering Control measures . Use lokal exhaust ventilation Occupational exposure standard ACGIH Component Name Limit Type Value Unit Methyl Ethyl Ketone TWA 590 mg/m STEL 885 mg/m Respiratory protection : Where local exhaust ventilation is not Practicable,wear full face-piece respirator With organic vapor cartridge NPF 20. Hand protection by using neoprene or nitrile rubber gloves. Eye protection by using monogoggles. Body protection by using standard issue work clothes.Safety shoes or boots chemical resistant 6. Physical & Chemical Properties Physical state 7 Liquid Color : Clear Odor : Characteristic Initial Boiling Point 7 7¥C Final Boiling Point : 80.5°C Melting Point 7 - 86°C Page 3 of 5PT. WAHANA DUTA JAYA RUCIKA Vapor Pressure Density Dynamic Viscosity Vapor Density ( air = 1 ) Surface Tension Conductivity Flash Point Explosion limit - upper Explosion limit - lower Auto ignition Temperature Solubility in water n-octanol/water partition coeff : Realitive Evaporation rate ( ASTM D3539, nBuAc = 1) Other properties 7. Stability/Reactivity Stability Conditions to avoid Material avoid Hazardous decomposition Products . Toxicological information Basis for assessment Acute toxicity-oral Acute toxicity-dermall Acute toxicity-inhalation Eye irritation Skin Irritation Respiratory Irritation Skin Sensitization ( Sub ) chronic toxicity 9.5 kPa @ 20°C 805 kg/m? @ 20°C 0.42 Mpa.s @ 20°C 2.4 @20°C 0.024 N/m? @ 20°C 2 PS/m x 10 @ 20°C -4 °C 11.5 % (v/v ) 1.8 %(v/v) 515 °C 250 kg/m? 1.8 - 2.0 log Pow 3.7 Molecular weight 72.11 Stable under normal use condition. Reacts with strong oxidizing agents Heat, flames and sparks Strong oxidizing agents None known Information given is based on product data LD50 > 2000 mg/kg LD50 > 2000 mg/kg LD50 > 5 mg/l Irritant Stight Irritant Irritant Not a skin sensitizes Repeated exposure cause liver damages in rats. Repeated exposure affects the nervous system in rats. Page 4 of 5PT. WAHANA DUTA JAYA RUCIKA 9. Ecological information Basis for assessment Mobility Persistence/degradability Bioaccumulation Acute toxicity-fish Acute toxicity-daphnia Acute toxicity-algae Acute toxicity-bacteria Acute toxicity-other organism Sewage treatment Other information 10. Disposal Consideration Precautions Waste Disposal Products Disposal Container Disposal Information given is based on product data Dissolves in water.Lost within a day by Evaporation and dissolution.Large volume may penetrate soil and could contaminated groundwater. Readily biodegradable.Oxidizes rapidly by Photochemical reactions in air and water. Does not bioaccumulate LC50 > 100 mg/l EC50 > 100 mg/l IC50 > 100 mg/l IC50 > 100 mg/l IC50 > 100 mg/l Practically non-toxic, EC50 > 100 mg/I,to organism in sewage treatment plants Poses a significant risk of oxygen depletion in Aquatic system Refer to section 5 before handling the Product or containers Recover or recycle if possible.Otherwise Incineration Recover or recycle if possible.Otherwise Incineration Drain Container thoroughly.After draining,vent in a safe place away from sparks & fire. Send to drum recovered or metal reclaimed. Residues may cause an explosion hazards.do not puncture,cut or weld uncleanness drums. Page 5 of 5