TRUNG TAM LUYEN THI HOA HOC . DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) BO PHAN LOAI GIAI CHI TIET HOA HOC HOU CO 12 TRUNG TAM LUYENTHIHOA HOC DIA CHI : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) ir - Lan 2/2019] Este X tao boi mét a-amino axit ¢6 cdng thite phn tir CsHi1NOz, Y va Z li hai peptit mach h@, c6 tong sé lién két peptit li 7. Dun ndng 63.5 gam hén hop E chia X, Y, Z véi dung dich NaOH vita du, thu duc dung dich chita 2 mudi (ctia Gly va Ala) va 13,8 gam ancol. Dat chay toan bé hn hop mudi 6 trén can ding vira dit 2,22 mol Os, sau phan img thu duoc NaxCOs, CO2, H20 va 7,84 lit N> (dkte). Thanh phan phan wam theo khéi long cua peptit co phan wt khdi Ién hon trong hén hop E la: A. 46,05% B. 835% €,50,39% D. 7.23% Huéng din gidi GlyNa:x™ — fx+y=0,352 x=0,27 [Mg =73,92 gree > > > —o ),21 AlaNa:y™ ” |2,25x +3,75y=2,22 43 |e =0,7 X:NH,CH(CH, )COOC,H, :0,3"" > Ny. =19>() 4 vow sxonan_, JY *(Ala), 0,2" X: NH,CH,COOC,H, : 0,23" —"=A2me_,, ~ > %m, =7,23% ~ Z:(Gly),(Ala), 0,01" Cfu 2:[Luong Thé Vinh HN - Lan 3/2019] Cho m gam hén hop E gém este hai chire Y mach he va este don chire X tae dung vira di: véi dung dich NaOH, thu dirge hon hop Z chita hai mudi va mot ancol T duy nhat. Bét chay hoan toan Z can vita dit 1,08 mol Os, thu dure 14,84 gam NaxCOs; tong sé mol CO: va Hx0 bang 1,36 mol. Cho ancol T tac dung vi Na (dur), thoat ra 1,792 lit khi (dkte); biét dé dét chay hét m gam E can vita di 14 mol O2. Phan trim khdi luong cua Y co gia tri gin nhat voi A. 66%. B. 71%. C.62%. D. 65%. Huéng din giai 1.08.2 =0,16™" > X la este cia phenol 16 =0,06™" + ny =0,08™"TRUNG TAM LUYENTHIHOA HQC _ DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) {3 xm fears > > HO:y™ — [#2 52x4+y+0,14.3=0,22.2 +0,06+ 1,082 zJRCOONa : 0,22" i. = CH-COONa R'ONa :0,06™" C.H,ONa Ag, 1) = 4-108 = 0,32 >T:C,H,O, > Y:(CH, =CHCOO),C.H, > Yomy = 62,37% Céu 3:[Luong Thé Vinh HN - Lan 3/2019] Dét hoan toan m gam hén hop X gém hai andehit edn diing vira hét 0,375 mol O» sinh ra 0,3 mol CO> va 0.3 mol H20. Mat khée, néu cho m gam hén hop X tac dung véi hong dur dine dich AgNOINH, thu duge a gam két tia. Mién gid tri ciia a la? A.324 Iny Os) cn diing 160 ml dung dich NaOH 1M, thu duoc mét khi Z duy nhat (c6 kha nang lm quy tim am héa xanh) va hén hgp T g6m hai mudi. Néu lay 24,88 gam E tac dung voi dung dich HCl loang du, thu diroc dung dich chira x gam mudi. Gia tri cia x 1a? “a. 41,64 gam, B. 42,76 gam. C, 37,36 gam. D. 36,56 gam. Huéng din giai X:NH,CH,COONH,: x" {92x +146y =12,44 Y:Gly—Ala:y™" oy oe x =2.(0,1.111,5 + 0,06.125,5 +0,04.53, 5) 1,64 gam Cu 5:[Luong Thé Vinh HN - Lin 3/2019] Bét chay hodn tein m gam hén hop M (6 ting s6 mol 0,07 mol) g6m dipeptit X, tripeptit Y, tetrapeptit Z va pentapeptit T du mach ho can ding 15,288 lit khi Q2. Néu cho m gam hén hop M tae dung véi dung dich KOH vira dit r6i c6 can cdn thin thu durge rin E gém hén hop mudi ciia glyxin va alanin. Dét chay E trong binh chita 3,5 mol khéng khi. Toan bé hi sau phan tng chay sau khi duroc ngung tu hoi nue thi cén lai 75,656 lit hén hop khi. Céc phan ting xy ra hoan toan, cdc thé tich khi do 6 digu kién tiéu chudn. Trong khong khi O; chiém 20% thé tich, con lai la No. Gid tri gin mht cita m 1a? B. 11,40, C, 12,60 D. 13,90. Huéng din giai © [CaHLNO=X™ (9 956 41,5y = 0,6825 021 Dén chit: M)CH,: y™™ ), 7 -0,6825 +1,5x + y +0,5x +2,8= sarso{* a H,0:007™ [ees x C4u 6:[Chuyén Nguyén Quang Digu - Ding Thap -L1/2019] Hin hop E gém ba este X, Y, Z (déu mach hé, chi chira mét loai nhém chife; trong phan tir mdi este c6 sé lign két x khong qué 3; Mx < MyTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) 2nco, +nn,0 = 0,3225 Vi mol CO2 va H20 bang nhau nén céc musi déu no, don chire SEL, mr = 12,79 (g) va non = 0,185 mol => C6 1 mudi la HCOONa Khicho E tac dung véi NaOH thi: =“ -5mg =5,75(g)> ng =0,1 mol = Ba ancol trong G lin lugt la CHsOH, C:Hs(OH)2, C3Hs(OH): 5 ag x ny +nz =0,05 ny =0,015 Vi X chiém 50% vé s5 mol hén hop => CHsOH: 0,05 mol => 1°¥ "=! y= 0,01: @2ny +92n, =4,15 [ny =0,035 E gim la R:COOCH; (0,05 mol); Ra(COO)sC:H: (0,015 mol); Rs(COO)sC3H; (0,035 mol) BEL (Cy, +1).0,054 (Cx, +2).0,015+(Cx, +3).0,035 =0,2 (Xét cho cic mudi => Cp, =0; Cg, =I Cx, <0 ¥ 1a CHsCOO-C2Hs-OOCH => %my = 17,77% Cu 7:[Chuyén Nguyén Quang Digu - Dong Th4p -L1/2019] Hén hop E gém X (C7HisOsNz) va Y (CsH1sO4No, la mudi cia axit cacboxylic hai chtte) tic dung hoan toan véi dung dich KOH, thu duoc ancol etylic, hai amin no (don chitc, ké tiép trong day déng dng, cé ti khdi so véi khi hidro bang 16,9) va dung dich Z. C6 can dung dich Z, thu duge hén hop T gém 2 mudi khan c6 cing sé nguyén tit cacbon trong phan tir (trong dé cé 1 mudi ctia axit cacboxylic va 1 mudi cla a—amino axit). Phin tam khdi long ctta mudi cé phan tir khdi nh trong T 1a A. 25,5%. B. 74,5%, C. 66,2%. D. 33.8%. Huéng din gidi issma-of Chon D. (CH3;NH300C ~ COONH3CH COO — C>Hs : x mol (CH3NH2: x+y, CH3NH;00C- COONH,C2Hs: ymol > Hey Dat x = 3 va y= 1 => Mu6i gdm (COOK).: 4 mol va GlyK: 3 mol => %moiyK = 33,8%. Cfu 8:[Chuyén Nguyén Quang Digu - Dong Thap -L.1/2019] Peptit X mach hé durge cu tao tir hai loai a-amino axit A, B (déu no, mach hé, déu chita 1 nhém -NH2). Biét X tac dung hoan ton vi dung dich NaOH theo phan tmg sau: X +11NaOH — 3A +4B + 5H:0 ét chay hoan toan a mol X thu duge hén hop gdm No, H2O va 29a mol CO». Hén hgp cac peptit mach ho E gom tripeptit A2B, tetrapeptit A2Bz, pentapeptit A2Bs va dipeptit A-A. Dot chay het b gam E trong oxi thu diroe Np, 0.5625 mol H20 va 0,675 mo! CO2. Mat khic, cho 0,15 mol E téc dung hét véi dung dich NaOH du, dun néng sau khi phan (mg xay ra hoan ton, c6 can dung dich thu duoc chat rin khan chtta c gam mudi. Gia tri ciia ¢ gan nhdtt véi gid tri nao sau day? B.73 C.53 D. 56.TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Huéng din giai Chon A. Khi dét chay X, c6 sé nguyén tt Cx = 29 => X la (Glu)a(Ala)s. Quy ddi E thanh (Ala)2(Glu)x anol > [7° (6+5x)a _,_645x H.0:(3,5x+6)a 643,5x 0,5625 [AlwNa: 0,3 mol |[Glu(Na), :0,225 mol Cfu 9:{Chuyén Phan BOi Chau - Nghé An - Lan 2/2019] X, Y la hai axit cachoxylic déu don chite, mach ho (trong mdi phan tir X, Y chira khong qua 2 lién két x va 50 < Mx < My); Z li este durge tao bai X, Y va etilen glicol. Dét chay 13,12 gam hon hop E chita X, Y, Z can ding 0,5 mol O2, Mat khac, cho 0,36 mol E lam mat mau vita da dung dich chira 0,1 mol Br. Néu dun néng 13,12 gam E véi 200 ml dung dich KOH 1M (vira du), c6 can dung dich sau phan img thu dugc hén hop F gdm a gam mudi P va b gam mudi Q (Mp > Mo). Ti Ié ctia a: b gan mbit v6i gid tri nto sau day? A.20, B. 3.0. C35 D.25. Khi cho 0,15 mol E tic dung véi NaOH, mudi thu due } > c= 76,275 (g) Huéng din gi Chon D. | Theo dé X la axit no va Y la axit khong no (6 1 ign két C=C) g, {COnsx mol [A 18y = 13,120,532 {x=0,49 Ta co: ~ =>} H,0:y mol” | BE 52x 4y = 2ngoy +0,5.2 [y= 0,42 x 1 a+b+2c=0,2 013 a mol a= b+2c=0,49—0,42 7 . Dat] Y-b mol 4?" = }b=0,03 > Cy =2,72 = X la CHsCOOH 7 1 [R@tbee=036 | 0 0 cml [k(b+e)=0,1 a FEL, 0,13.2 + 0,03.Cy +0,02.(Cy +2+2)=0,49 => Cy =3 = ¥ 1a CH=CHCOOH Muéi thu duge gam CHsCOOK (0,15 mol) va CH==CHCOOK (0,05 mol) => a : b = 2,67, Cu 10:[Chuyén Phan Béi Chau - Nghé An - Lan 2/2019] Dét chay hét 25,56 gam hén hop X gom hai este don chitc la dong ding lign tigp va mét amino axit Z thude diy dong ding ciia glyxin (Mz > 75) can ding 1,09 mol O2, thu duge CO2 va H20 véi ti 1é mol tuong ting 48 : 49 va 0,02 mol khi No. Cing lugng X wén cho tae dung hét véi dung dich KOH, c6 can dung dich sau phan tng duge m gam rin khan va mét ancol duy nhat. Biét KOH ding du 20% so véi lrong phan img. Gid tri cua m li B. 31,880. C. 34,760. D. 34,312. Huéng din giai Chon A. neo, :1,0 = 48:49 = 0,96 Ta 06: 1 ie 2 EO eae Hance = 0,36 > 44nco, +18np,9 =59,88 Dax 98 MA Naminoaxit = 2ny, = 0,04 mol => Neste = 0,32 mol Sy =2,67 = Trong X c6 | este li HCOOCH3 Khi cho X tac dung véi KOH thi: nj, =0,04 mol; neyo =0,32 molTRUNG TAM LUYENTHIHOA HQC _ DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Vi KOH ding du 20% so véi hrong phan ting = nyo =1,2.0,36 = 0,432 mol 2 5m = 38,792 (g) Cfu 11:[Chuyén Phan BOi Chau - Ngh An - Lin 2/2019] X, Y (Mx < My) Id hai axit ké tiép thude cing diy dong dang axit fomic; Z 1a este hai chitc tao boi X, Y va ancol T. Dot chay 12,52 gam hén hop E chia X, Y, Z, T (déu mach hé) can ding 8,288 lit O» (dkte) thu duge 7,20 gam nurée. Mat khic dun néng 12,52 gam E cn ding 380ml dung dich NaOH 0,5M. Biét ring 6 diéu kién thuéng, ancol T khéng tae dung duoc voi Cu(OH)2. Phan trim s6 mol ca X cé trong hén hop Eli A. 60%. B. 75%. €.50%, D. 70%. Huéng din giai Chon A. X,¥:amol {82 s2a+4b+2¢=0,44 a 19 > 15 0,028 0, =1,05 1.03 Dat}Z-bmol > J2+26=nxs0n T:emol b=c=neo, = Mio = -0,01 = Hai axit X, ¥ lin luot la HCOOH va CHsCOOH Lai c6: 0,15.Cxy + 0,02.(1 +2 + Cr) + 0,03.Cr = 0,39 5 fe tny =0,15 fe = 0,12 Ta co: > => %nx = 60% ny +2ny =0,18 [ny =0,03 CA 12:[Yén Lae 2 - Vinh Phuc - Lan 3/2019] X, Y 1a 2 axit cacboxylic déu mach hé; Z li ancol no; T li este hai chite, mach ho duoc tao béi X, Y, Z. Dun nong 38.86 gam hén hop E chita X, Y, Z, T voi 400m! dung dich NaOH 1M (vita dit), thu duge ancol Z va hén hop F gém 2 mudi cé ti 1é mol 1: 1 Dan toin bo Z qua binh dug Na dur thiy khdi long binh tang 19,24 gam; déng thoi thu duge 5,824 lit khi He (dkte), Dét chay hon toan F can ding 0,7 mol O2, thu due COz, NazCO3 va 0,4 mol H20 Phan trim khéi lung cia T trong hon hop E la A. 8,88%. B. 26,40%. C.13,90%. D.50,82%. Huéng din giai > Cxy=1,2 Chon D. Khi din Z qua binh dung Na dur thi: mancot = Mozy + My 19,76 (g) mz, + Gia sit anol Z e6 x nhom chite Khi dé: Mz = 8x 2-2) Mz = 16: C3Hs(OH)> (0,26 mol) -Khi cho hnhop E: X + Y + T + Z + 4NaOQH ——>2F; + 2F2 + CsH«(OH): + H: mot x y t Z@ 04 + Vi 2 mudi cé tiIé mol | : I nénx=y Khi dot chay hoan toin mudi F thi: ny.,co, =0,5nyaoxt =0,2mol BLO agg, = 2 tM) +20» = 3ANarCOs BHO _ 9 6 mot => {CF =? - 2 Hip =2 = Trong F 6 chita mudi HCOONa va mudi cén lai 1a CH=CHCOONa véi sé mol méi mudi i 0.2 mol =X, Y, Z, T lan hrot ki HCOOH; CH:=CHCOOH; CsH«(OH)x; CH>=CHCOOC:H<00CHTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) yon = 2x +2t=0,4 x=0,075 Ta c6 hé sau: {ncicom, =2+t=0,26 > 12 =0,135 = Ym =50,82% mp = 46x+72x-+762+158t=37,36 _ [t=0,125 Cfu 13:[¥én Lac 2 - Vinh Phic - Lan 3/2019] Dét chay hoan toan 7,576 gam hin hop cdc este thuan bing O2 du, sau khi két thie phan img thdy thu duge COz va 0,25 mol H,0. Dem toan bd sin pham chay hap thy hét vao dung dich nude véi trong du thay cd m gam cho 7,576 gam hén hop este nay tham gia phan img véi NaOH thi thay c6 0,1 mol NaOH phan ing. Gia tri cuam ki A. 3,23 gam. B. 33,2 gam. C. 23,3 gam. D.32,3 gam. Huéng din gidi Chon D. [295 Anco, + 0,25 = 2M, +0,1.2 Neo, = 0,323 > KL. >m= HS 44nco, +0,25.18= 32mg, +7,576 0,348 Céu 14:[Phi Binh - Thai Nguyén - Lan 1/2019] X, Y (Mx < My) la hai peptit mach hé, hon kém nhau mot lién két peptit. Dun nong 73,16 gam hon hop E chita X, Y va este Z (CsH1i02N) vei dung dich NaOH vita di, chung cat dung dich sau phan img, thu duoc 4,6 gam ancol etylic va hén hop chita 2 mudi ciia 2 a-aminoaxit thudc cing day déng dang ké tiép nhau. Dét chay toan bé mudi cén ding 71,232 lit O2 & dkte, thu duge CO2, H2O0, N2 va 53 gam Na2COs. Phan tram khdi Ivong cua Y trong hén hop E gan nbit voi gid tri nio sau day? A. 16%. BL 57%. C.27%. D. 45%, Huéng din gidi Ta c6: Ngop =0,1 mol > 32,3 (2) Chon B. Quy déi hén hop mudi thu dirgc sau phin tng thanh C)H,O)NNa (a mol) va CH2 (b mol) ta c6: Ne,uonna = 20Na,c0, =I Naty =0.38mol > 2.25Sne.noxna + LSneu. =Mo, — {2.25a+1.5b=318 [na =b=0,62mol > Myusi =ITNCye1,0nna + 14ncu, =105,68(2) Quy dai hén hop X va Y trong E thanh C2H30N, CH: va H20. Cho E tic dung véi NaOH thi: BIEL nyuo =x +ny Be oy Tass Ma 0,16mo! X la este ciia Alanin v6i ancol CoHsOH khi do CTCT eta X la NH3CH(CH3) COOCHs, ta c6 1C:H,04 =0, Lol > SMe xich (uous X.Y) =11CH,0;NNa —Nz = 0,9 mol = k = 5,625 nz = X la pentapeptit (0,06 mol) va ¥ 1a hexapeptit (0,1 mol) véi 0,06.n + 0,1.m = 0,62 ~ 0,1 = 0,52 = n=2 vam = 4 = Y li (Ala)«(Gly)2 ¢6 %m = 56,86% Cfu 15:[Phit Binh - Thai Nguyén - Lin 1/2019] Cho cac chat hiu co: X, Y li hai ancol cé eting sé nguyén tir eacbon trong phan ti, Z la axit no, mach ho (Mz > 90) va este T (phi tir chi chita chire este) tao bai X, Y voi mot phan tir Z. Dot chdy hoan toan 0,325 mol hin hop E gom X, Y, Z va T thu durgc 20,16 lit CO> (dkte) va 17,55 gam H:0. Phan trim s6 mol cia T trong E gan nhat voi gid tri nao sau day? A. 7,80. B. 7,70. C.7,85. D. 7,75. Huéng din gidiTRUNG TAM LUYENTHIHOA HQC _ DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Chon B. Ta co: Ce = 2,78 va He = 6 > X, Y, Z, T lin luot 1a CHsOH, C2H4(OH):, (COOH); hode CH(COOH)s Dat sé mol ciia X, ¥ a. amol; Z lab mol va T la ¢ mol. +Néu Z la (COOH); a+ b-+e=0,325 a= Theo dé: {2a+3b+7¢=0,9 => {b= (khéng tha min) Ba+15b+4,5e=0,975 [c= + Néu Z li CH(COOH); a+b-+e=0,325 a=0,25 Theo dé: }2a+4b+8e=0,9 =>4b=0,05 > %n; 3a +2b+5e=0,975 025 Cfu 16:[Phi Binh - Thai Nguyén - Lin 1/2019] Hon hop E g6m mét axit cacboxylic no, hai chic Z (c6 phan trim khéi long cacbon lén hon 30%) va hai ancol X, Y déng dang ké tiép (Mx < My). Dat chay hoan toan 0,2 mol E cin vira du: 8,96 lit khi O2 (dktc), thu duge 15,4 gam CO:2 va 8,1 gam 20. Dun néng 0,2 mol E véi axit sunfurie de, thu dqgc m gam cae hop chat c6 chite este. Biét phin trim s6 mol tham gia phan tig este héa ctia X va Y tojong tmg bing 30% va 20%. Gia tri lén mht ciia m la A. 6,18. B. 6,32. C486, D. 2,78. 7% Huéng din gidi Chon €, Khi dét chiy E, ta o6: C= 1,75 va He = 4,5 => X, Y lan luot la CHbOH va CoHSOH. » [Pxy +n, = 0,2 Taco: 1 =! nz—Ax y=Aco, ~My =~0,1 [ny =0,05 mol FEL 015.Cy y +0,05.C, =0,35 voi Cz=3 > Cxy CHOH:x mol [x +y=015 _, {x =0,1 SH,OH:y mol” |x-+2y =0,2~ ly =0,05 Dun néng E véi xe téc thu duge khéi luong hop chit hiru co lon nhat nén phan tig xiy ra theo ti 1é mol la I: 1 > HOOCCH2COOCE; (0,03 mol) va HOOCCH2COOC2Hs (0,01 mol) > m = 4,86 (g) Cau 17:[Nguyén Khuyén ICM -12/2019] Dét chay hoan toin m gam hén hop E gém ba este don chite X, Y, Z (trong dé X va Y mach hé, Mx < My; Z chita vang benzen) can vita dit 2,22 mol O2; thu durge 20,16 gam HO. Mit khac m gam E tae dung vita du véi 200 gam dung dich NaOH 9,2%, ¢6 can dung dich sau phan img thu dugc (m + 5,68) gam muéi khan vi hon hop T chia hai ancol cé sé nguyén tur cacbon lién tiép nhau. Ti khdi cua T so véi He bang 9,4. Biét ba este déu khong tham gia phan ting trang bac. Phan tram khéi luong cia Y trong E cé gia trj gin nat v6i gid ti ndo sau day? A. 31%. B. 29%. C. 32%. D. 30%. Huéng din gidi 33 (thda) = Z la CH2(COOH). Chon D. Hén hop E gém X, Y (este don chic, mach hé): a mol va Z, (este cia phenol): b mol Khi cho E tac dung voi NaOH thi: ny,oy =a+2b =0,46(1)TRUNG TAM LUYENTHIHOA HQC _ DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Hai ancol lién tiép nhau e6 Mr = 37,6 => CH30H (3x mol) va C:HsOH (2x mol) > a= 5x (2) EL, m+18,4 = m+5,68+ my.) +18b > 12,72 =32.3x + 2x.46 + 18b (3) Tir (1), (2), (3) suy rax = 0,06 ;a = 0,3 ; b= 0,08 5 2a+2b+2n, 1, Xét phan ing d6t chy: 22° 4n-, =——__#° = 9.04 mol #45 m= 38,88(2) =96,86 => Trong mudi cé thé c6 CH;COONa, C:HsCOONa, CH2=CHCOONa m+5,68 0,46 CH=CCOONz. Trong 3 muéi trén thi chi ¢6 CH=CCOONa théa man: (kxy = 1).0,3 + (kz = 1).0,08 = 0.92 (kz = 5, kx.y = 3) Hén hop E gm CH=CCOOCHs; CH=CCOOC2Hs; CxHsCOOCsHs. Vay Y¥ la CH=CCOOC2Hs: 0,12 mol = %my = 30,35%. Cu 18:[S@ Ha N6i L1/2019] Cho hén hop X gom cac peptit mach hé, déu duge tao thanh tir céc amino axit c6 dang H2NCsHmCOOH. Dun néng 4,63 gam X v6i dung dich KOH du, thu duge dung dich chira 8,19 gam mudi. Néu dat chay hoan toan 4,63 gam X cin 4,2 lit O: (dkte). Din toan bé san pham chay (CO2, H20, N2) vao dung dich Ba(OH)2 du, sau phan img thu duoc m gam két tia va khdi luong dung dich giam 21,87 gam. Gia tri cua m gan mhit voi gid tri nio sau say? >M, i = A. 30 B. 28. C.35. Huéng din giai Chon D. Quy ddi hén hop X thnh CsHaON (x mol), CH (y mol), H2O (z mol) > 57x + L4y + 187 = 4.63 (1) Khi cho X tac dung voi KOH thi: 113x + 14y= 8,19 (2) Khi cho X tac dung véi O2 thi: 2,25x + 1,5y = 0,1875 (3) Tir (1), (2), (3) suy ra: x = 0,07 ; y = 0.02 ; z= 0,02 = neo, = 0,16 mol = m, =31,52(g) Céu_19:[So Ha Ni L1/2019] Axit hiu co don chite X mach ho phan tir c6 mot lién két d6i C=C va c6 déng phan hinh hoc. Hai ancol Y, Z 14 déng dang ké tiép (My < Mz). Dét chay hoan toan 0.26 mol hén hop E gém X, Y, Z cin 13,44 lit O: (dkte) thu dirge 10,304 lit CO2 (dkte) va 10,8 gam H20, Phan trim khéi lugng cia Z trong hén hop E la A. 32,08%. BTM. C.32,43%. D. 48,65%. Huéng din giai Chon B. Nhin thay: nyo > neo, va C = 1,76 = 2 ancol dé 1a CH,OH vi C3H;0H {Mx —Mancot = RCo: —My,0 = —0,14 nx = 0,06 mol Ta 6: 2 Ma =. Ny + Manco) = 0,26 Maggot = 0,2 mol 9222 = 02> Yom =7,77% Cx =4 ny +nz=0,2 PEC 40,26 “O46= | x >| yee 0, Cancot = 1,1 ny +2n, Céu 20:[Chuyén Nguyén Trai - Hai Duong - L1/2019] X, Y, Z la 3 este mach hé (trong 46 X, ¥ don chtte, Z hai chitc). Dun néng 28,92 gam hén hop E chita X, Y. Z véi dung dich NaOH vita dit thu duroc han hop F gém 2 mudi c6 ti 1é mol la 1: 1 va hon hop 2 ancol no, cd cé cing s6 nguyén tir cacbon Dan toan bo 2 ancol nay qua binh dug Ne du, thay khoi luong binh ting 12,15 gam. Dat chay toan béTRUNG TAM LUYENTHIHOA HQC _ DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) F thu durge CO2: lon nat trong E la AL 53,96%. B. 35,92%. C. 36,56%. D. 90,87%.. Huéng din giai 53 gam H20 va 20,67 gam NaxCOs. Phin trim khdi lung cita este c6 khéi lung Chon D. Khi d6t chay mudi F thi: negox, = Ayaat =Nox =2Mx4,co, = 0,39 mol Khéi lugng binh tng: myyco)—My1y = Mancot ~ 0,39 =12,15 = Mypee = 12,54 (g) 32,2 < Manat <64,3 = Hai ancol €6 1a C2HsOH (0,03 mol) va C2H4(OH): (0,18 mol) =31,98 (g) va hai mudi trong Z ¢6 sé mol bing nhau va bang 0,195 mol => MF = 82 = Hai mu6i trong F la HCOONa va mudi cén lai 1a CoHsCOONa Xét hén hop ban dau co X, Y (0,03 mol) va Z (0,18 mol) Dua vio s6 mol ta suy ra Z la C2HsCOOC2H,OOCH => %m = 90,87% Cfu 21:[Chuyén Nguyén Trai - Hai Duong - L1/2019] Dun néng 0,1 mol hon hop M gém hai peptit mach hé X, ¥ (X it hon ¥ mét lién két peptit) véi dung dich NaOH vira du, thu duoc dung dich chita 0,38 mol mudi cua A va 0,18 mol mudi cua B (A, B li hai amino axit déu no, ho, co | nhém COOH va 1 nhom 1 NFb; Ma < Ma). Mat kha, dt chay hoan toan 10,32 gam M can vira di 0,5175 mol O2 Phan tir khéi ca Y 1a A, 303. B. 387. C. 359, D. 402. Huréng din giai Chon D. Tac: nxn =n +ng =0,56—>k =5,6 => X li pentapeptit (0,04) va Y la hexapeptit (0,06). Quy déi M thanh C;H;ON (0,56 mol); CH; H:O (0,1 mol) Trong 10,32 gam M c6 C2H:ON (5,6x mol); CH (y mol); H2O (x mol) §337,2x + 14y =10,32 = 0,025 _ Cy, 0,54 mol 12,25. 5,6x +1,5y =0,5175 y=0,135 1s => ALi Gly va Ba Val 18 Sn =3 va = Y la Gly)sVal 06 M = 402. Cu 22:[Chuyén Ha Long - Quang Ninh - Lin 2/2019] Z la 3 este déu no mach ho (khéng chita nhém chite khae va Mx < My Masco! = 62: C2Ha(OH)2 (0,2 mol) = np = 2nr=0,4 mol. Vi 2 mudi c6 ti Ié mol la 5 : 3 suy ra A: 0,25 mol va B: 0,15 mol ‘C, =1: HCOONa Cy =2:CH,COONa Khi dét chay F thi: ny, co, =0,2 mol—*5 40, 25C, +0,15.Cy =0,55 ={TRUNG TAM LUYENTHIHOA HQC _ DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) X, Y, Z lan lugt la (HCOO):C2H4; HCOOC2Hs00CCHS; (CH:COO):C2Hs => X c6 6H. Cu 23:[Chuyén Ha Long - Quang Ninh - Lan 2/2019] Hén hop E gém X, Y va Z la 3 peptit déu mach hé (Mx > My > Mz). Dét chiy 0,16 mol X hoic Y hoac Z déu thu duge sé mol CO2 Ién hon sé mol HO li 0,16 mol. Néu dun néng 69,8 gam hén hop E chira X,Y va 0,16 mol Z véi dung dich NaOH vita di thu doe dung dich chi chira 101,04 gam hai mudi ciia alanin va valin. Biét nx < ny. Phan trim khéi Iuong cua Z trong E gin nit véi gid tri nao sau day? A. 12 B. 10. C.19. D.70. Huéng din giai Chon D. . X, Y, Z duge tao ra tir Ala va Val déu li amino axit don, no, mach hé. Khi dét chay thi: nx = ny =nz= ny, ~(nco, ~nH,0) = aN, = 0,32 = AN :Mpeptit = 0,64:0,16=4:1 > X, Y, Z déu la tetrapeptit Khi cho E tac dung véi NaOH thi: nyson = 4(nx + ny + nz) = Mant Nyal Va My,9= Nx + Ny + nz, SEL me + myson = Modi mH,0 Mx + ny + nz = 0,22 > nx +ny= 0,06 Ta c6: 11 Ina + 139nvai = 101,04 > naia = 0,76; nvai = 0,12 mol Vi nya Z khng c6 Val C6: nya = 2(nx + ny) > $6 mat xich Val trung binh trong X va Y 142. Vi Mx > My = sé mit xich Val trong X Ién hon, +X 663 Val, ¥ co 1 Val = nx = 0,03 = ny (loai) vi nx nx = 0,02 mol; ny = 0,04 mol (thoa) => Z la (Ala)s: 0,16 mol >%m = 69.2% Cfu 24:[Ng6 Quyén - Hai Phing - Lan 2/2019] X, Y, Z la 3 este déu mach hé va khéng chira nhom chite khae (trong 46 X, ¥ déu don chite, Z hai chite). Bun néng 19,28 gam hdn hop E chita X, Y, Z véi dung dich NaOH vira dui thu duge hén hop F chi chiza 2 mudi c6 ti 1¢ 56 mol 1 : 1 va hon hop 2 ancol déu no, 6 cing s6 nguyén tir cacbon. Din toan bé hén hop 2 ancol nay qua binh dung Na du, thay khdi luong binh ting 8,1 gam. Dat chay todn bé F thu doc CO»; 0,39 mol HO va 0,13 mol NasCO3 Phan trim khdi lugng ciia este c6 khdi long phan tirnhé nhat trong E la A. 3,96%. B. 3,78%. C.3,92%. Huéng dn giai chay mudi F thi: nego, =Msactt =Non = 2Mxe,co, = 0,26 mol Khéi Ivong binh tng: Marco: — Mn, = Macoi — 0,26 = 8,1 => Mancot = 8,36 (g) => 32,2 < Manor < 64,3 => Hai ancol 46 la C:H Mr = 82 = Hai mudi trong F la HCOONa va mudi cén lai ki C3HsCOONa Xét hén hop ban dau c6 X, ¥ (0,02 mol) va Z (0,12 mol) => X va Y c6 mol bang nhau (vi sé mol hai io sé mol > este c6 PTK nhé nhat la HCOOCHS 0,01 mol > %m = 3,84% Cu 25:[Ng6 Quyén - Hai Phong - Lin 2/2019] Hén hop P gom ancol A, axit cacboxylic B (déu no, don chitc, mach ho) va este C tgo ra tir A va B. Dot chay hoan toan m gam P can ding vira di 0,36 mol Oz, sinh ra 0,28 mol CO;. Cho m gam P trén vio 250 ml dung dich NaOH 0,4M dun néng, sau khi kétTRUNG TAM LUYENTHIHOA HQC _ DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) thie cdc phan ig thu duoc dung dich Q. C6 can dung dich Q cdn lai 7,36 gam chat rin khan, Nguéi ta cho thém bét CaO va 0,96 gam NaOH vao 7,36 gam chat rin khan trén réi nung trong binh kin khong c6 khong khi dén phan dng hodn toan thu duge a gam khi. Gia tri cia a gan hat voi gid tri nao sau day? B.29. C21 Huéng din gidi eboxylic B 1a RCOOH. Khi dét hdn hop P thi :ng-+ne =1,5n, 2 Ro, = 0,06 mol = nysor(as) =PNaow — (Ny + Nc) = 0,04 mol => Mucoons = Ratios —“OPwonias. _ 94 m8 RCOONa la CH2=CH-COONa np tne Trong 7,36 gam rin Q chita CH>=CH-COONa (0,06 mol) va NaOH») (0,04 mol) Khi nung 7,36 gam hén hop rin Q véi 0,024 mol NaOH ta cé G0." (CH: =CH-COONa+ | NaQH = —©°"_ 53H, +Na2CO; 0Snol (00H 024) mot ‘obit (NaOH dw) 'y |,06.28 = 1,68(g) Cau 26:[Ng6 Quyén - Hai Phong - Lan 2/2019) Hén hop X gom dipeptit CsHioN2Os, este da chtte CaHOu, este CsH1102N. Cho X tac dung vita dit véi 800 ml dung dich NaOH 0,1M, cé can dung dich sau phan tmg thu durac m gam ran khan va 1,25 gam hén hop hoi Z (chira cdc hop chat hiu co). Cho toan bé luong Z thu duge tac dung véi Na du thay thoat ra 0,448 lit khi He (dkte). Con néu dot chay hoan toan Z thi thu duoc 1,76 gam CO». Gid tri cia m la A.745. B.7,17. C.6,99. Huéng din giai D. 7,67, Chon A. Xir li hin hop Z, nhan thay: ne =Meo, = Mey = 2m, => Cae chat trong Z c6 s6 nguyén tir C bang véi sé nhém OH. . «7. (CH,OH:x mol x+2y=Meo, =0.04 [x =0,01 Tir2 este ban dau Z gm > > CH, (OH), :y mol” [32x +62y =1,25 y=0,015 Khi cho X tc dung véii NaOH thi: aon =2Ray-au +2 Mea10, +Pe,,0,8 > Peay au = 0,02mol Gly— Ala :0,02 mol ‘AlaNa +GlyNa. X4(HCOO),C,H,:0,015mol > hénhgp rin {HCOONa => m=7,45 gam H,NC,H,COOCH, : 0,01 mol H,NC,H,COONa Cfiu 27:Hén hop X gém 4 este mach hé, trong dé cé 1 este don chire A va 3 este hai chire (déng phn cita nhau). Bat chay m gam X cin ding 14,784 lit Oo (dkte), thu dirac 12,768 lit CO> (dkte) va 7,92 gam H:O. Dun néng m gam X véi 300 ml dung dich NaOH IM, c6 can dung dich sau phin img thu duroc chat rin Y va phan hoi chi chita mét ancol Z. Cho toan bd Z vao binh dung Na du thay khéi luong binh tang 5,85 gam. Nung toan bo Y véi CaO (khong c6 khOng khi), thu due 0,09 mol 1 hidrocacbon duy nhat. Biét cdc phan tmg déu xay ra hoan toan. Phan trim khéi luong ctia A trong X nhit véi gid tri nao? A. 42%. B. 29%. C. 34%. D. 37%.TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Huéng din gidi - Khi dét chay X, ap dung BTKL va BTNT O ta 6: mx = 11,88 (g) va nox) = 0,26 mol co: ny, =70m = Aeet=0, 13 mol => Mancot = Mbxang + Zn, = 5,98 (g) => Maneat =46: CoHsOH - Khi cho X tac dung véi NaOH thi: nson du = nxcou ~ 0,5nx - Goi A la este don chitc (a mol) va B li este hai chite (b mol) - Vi Khi nung Y chi thu duge 1 hidrocacbon duy nhat nén A cé dang RCOOGHs va B li R(COOCIHs)2 bi fe =0,26 {i = 0,05 mol ,17 mol > vaR=R’+1 a+b=0,09 b=0,04 mol — 0,05.(R'+ 1+ 73) + 0,04.(R’ + 146) = 11,88 > R’ = 26 (-CH=CH-) Vay A la CH2=CHCOOCHs ¢6 %m = 42.1% Cfu 28: Thuy phan hoan toan 7,06 gam hén hop E gim 2 chat hitu co X, Y mach hé (Mx < My) bing dung dich NaOH vita di, sau phan ing thu duge | ancol duy nhat va 7,7 gam hon hop gdm 2 muoi trong do cé | muoi cia axit cacboxylic va 1 mudi cla glyxin. Mat khac, dot chay hoan toan luong E trén can 0, 315 mol O2, thu duge 0,26 mol khi CO2. Bict 1 mol X hoac 1 mol ¥ tac dung 161 da véi | mol KOH. Phan trim khoi luong cua X tron; in nhat véi gia tri nao sau day? A. 30,5%. B. 20,4%. C244%. D. 35.5%. Huéng din gidi Chon C. Tir cdc dit kign ca dé bai, ta suy ra X 6 dang La RCOOR’ va Y la H2N-CH2-COOR* Nhan thy: musi me nén R’ <23 => R? 1a -CH; nén ancol duy nhat dé 1a CH;OH STKE, mp +40ne = maudi + 32n¢ => ne= 0,08 mol Khi dat chay hon toin E, p dung bao toan nguyén t8 O ta tinh drac: 43,9 =0,27 mol 3,25 _ [X:CHz = CH-COO—CH; (0,02 mol) Y : H2N-CH, ~COO-CH; (0,06 mol) Khidé ta e6: !© |fi=675— = %mx = 24,36% Cu 29: Cho hén hgp X gdm 3 este don chite. Dem dt chay m gam X thi can vira di 0,465 mol O2san phim chy thu due H20 va a mol CO2.Thiyy phin hon toin m gam X trong 90 ml dung dich NaOH 1M (vita di) thi thu duoc 8,86 gam hén hop mudi Y va mét ancol Z no don chire, mach hé. Dot chay hoan toan hn hop mudi Y trén thi edn diing 7,392 lit (dkte) khi O2. Gid tri cua a la A. 0,335, B. 0,245, C..0,290. D.0,380. Huéng din giai Chon D. swort = 0,09 MOI=> Nya,co, = 0,045 mol EEE my +Mo, = Meo, FMeo, + Myo > 44M, +189 = 14,65 (I) 1,705 (2) 0528 ee 4¥2n, =3my..co, + 2Meo, + M,0 > 2Meo, +My, 245, 1 ‘5 Gi $6 C trong ancol lat = ncjaoo= 0,9t Reo, ir (1), (2) suy ra {TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Mey) FM eeu) =0,2940,9t. Khi t= 1 thi no, CAu 30: Chat X la este no, hai chire; ¥ la este tao béi glixerol va mt axit cacboxylic don chite, khong no chra mot lién két C=C (X, ¥ déu mach ho va khong chita nhém chite khéc). Ddt chy hodn toan 17,02 gam hén hop E chira X, ¥ thu dugc 0,81 mol CO2. Mat khac, dun néng 0,12 mol E can ding vira da 300 ml dung dich NaOH 0,95M. Cé can dung dich sau phan tmg, thu duge hén hgp chira ba mudi 6 khdi hreng m gam va hai ancol cé ciing sé nguyén tir cachon, Gié tri cia m 1A A. 28,14, B. 27,50. C.19,63, D.. 27,09. Huéng din gidi ),38 mol théa man. Chon D. nx +ny =0,12 nx =0,075 Khi cho E tac dung véi NaOH thi: [2 .2"* = Bx [2nx +3ny =0,285 ~ [my =0,045~ ny 3 cae ‘CyHoq-204 :5x mol (14n + 62).5x+ (14 m+86).3x =17,02 Khi dét chiy E = x=0,01 y (ene 3x mol [Sxn-+3xm=0,81 lad vim = 12 => n=9 => X la CHyCOO-C3He-OOCC3Eh va Y 1a (C2H3COO)3C3Hs Hén hop mudi gm CH;COONa (0,075); C3H7COONa (0,075) va C2HyCOONa (0,135) => m = 27,09 (g). Cu 31: Hon hop M gém 3 este don chtre X, ¥, Z (X va Y la dong phan ciia nhau, mach hé). Dot chay hoan toan 5,3 gam M thu dirgc 6,272 lit CO2 (dkte) va 3,06 gam H20. Mat khae, cho 5,3 gam M tac dung vira dit véi 0,07 mol dung dich NaOH, thu due ancol T, chat hu co no Q va m gam hén hgp hai mudi. Biét Q cho duge phan tg tring guong. Gia tri cia m gain nhit véi gid tri ndo sau day? B.6,18 C.6,42 D. 6,36 Huéng din giai Chon A. 2S snp, = 0,315 mol2=2 5 ny = 0,05 mol Trong M cé mét este ciia phenol ‘ (er 0,05 {ea voi .07-* {nz =0,02 mol Cx 28> {¢ => HCHCOOCH=CHCH; 2 HCOOC¢H4CH3, Muéi thu dure gam HCOONa (0,05 mol) va CHsCsHsONa (0,02 mol) > m=6 gam Cau 32: Hén hop X gdm glyxin, axit glutamic va hai axit cacboxylic no, don chite ké tiép nhau trong day dng ding. Cho m gam X tac dung vita dii véi 500 ml dung dich NaOH IM, thu dure 41,05 gam hén hop mudi. Mat khéc, dét chay hoan toan m gam X can ding 17,64 lit khi O2, Cho san pham chay qua dung dich H2SOs dc, du thi thu duge 20,72 lit hin hop khi CO2 va No. Thé tich cdc khi do 6 dkte. Thanh phan % theo khéi lvgng cia axit cacboxylic co phan tir khéi nhé hon trong X 1a A. 28,64%. B. 19,63%. C.30,62%. D. 14,02%. Huéng din giai k, = (1 =1).0,03 + (ks -no0a-o.11f§ HCOOCH.CH = CH; FEE 0,03.Cxy +0,02.Cz Chon C.TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Khi cho X tac dung véi NaOH thi: oy,9 =9ys01 =Mcoon = 0,5 mol“ 5m, = 30,05 (g) COs:x mol [x += 0,925 85 Dat {HO: y mol > }—*"2 52x + y= 2,575 > ),875 No:zmol |B, 44x 41gy+287=55,25 [2=0,075 Gly :a mol a+b=2ny, =0,15 a=0,1 Dat /Glu:b mol > 4-0,5a+0,5b=n¢o, —My,9 =-0,025 => 4b 0,05 sn=4 CyH2,02:emol |a+2b+e= e=0,3 = Axit cacboxylic nho hon trong X 1a HCOOH: 0,2 mol =>%m = 30,62%. C4u 33: Cho cée chat hiu co: X la axit cacboxylic khéng no (chita 2 lin két x); Y 1a, axit cacboxylic no, don chife; Z la ancol no; T la este mach hG, tao tir X,Y va Z (chita $ lién két 2). Cho 26,5 gam hén hop E gém X, Y, Z, T tac dung vita dit voi 250 ml dung dich NaOH 1M, thu durge 20,9 gam hén hop mu6i F va 13,8 gam ancol Z. Toan bé Z tac dung véi Na dur, thu duge 5,04 lit He (dkte). Nung F véi NaOH dur va CaO & nhiét 49 cao, thu duoc hén hop khi Q c6 ti khdi so véi Ha la 8,8. Cae phan img xiy ra hoan toan. Phan trim theo khdi long ciia X trong T gin nhAt véi gid tri nao sau day? A. 14,4%. B, 11,4% C.12,8%. D.13,6%. _Hué6ng dan giai Theo dé, X la axit khéng no, c6 1 lién két C=C don chite va T la este ba chtte duge tao thanh tir 2 phan tir chat X, 1 phan tir chat Y va 1 ancol Z ba chite. Tir phan img cua Z voi Na => ny =0,15 mol > M, = 92:C,H;(OH), Khi cho E tac dung véi NaOH: 2" nyo = ny y =0,1 mol = ny = 6 250 ! Ta c6: Mo= 17,6 > c6 khi CHs = Mudi thu duge gsm HCOONa hodc CH3COONa va RCOONa. [68a + (Mg +67).b=20,9 yy, a=0,1 + Xét mudi HCOONa (a mal) va RCOONa (b mol) |S 9. onan 05 mol Vay X la C2HsCOOH: 0,05 mol > %mx = 13,6% CAu 34: Hop chat X mach hé tao béi axit eacboxylic Y va ancol da chite Z. Dét chay hoan toan Y thu duroc 1,792 lit CO> vi 1.44 gam nude. Lay 0.15 mol Z vio binh chita Na dur, két thie phan img sinh ra 3,36 lit Ho; dng thoi khdi Iwong binh ting 11,1 gam, Dot chay hodn toan 0,05 mol hén hop E chia X, Y, Z cin 5,376 lit Oo, thu duoc 4,704 lit CO» va 3,6 gam nude. Cée khi do dktc. Phin trim khéi long cuia Y trong E 1a: A. 11,63% B.23,26% Chon dap an B 0,15 mol Z+ Na — 0,15 mol Hs D.21,51% Huréng din giai => Z laancol 2 chitc.TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BATRI THAY NGUYEN VAN THAI (DT :09.789.95.825) -HANOL Y +O, 0,08 mol CO2 + 0,08 mol H20 = Y la axit no, don chite, mach hé. 0,05 mol E+ 0,24 mol O; — 0,21 mol CO; + 0,2 mol H0. Dat sé mol ciia X, Y, Z trong E ln lugt a x, y, z [reytz=o.s x=0,02 Neo, Myo =X—Z=0,21-0,2= 0,01 >fy=0,02 |H—ENEO 5 4x +2y+2242.0,24=2.0,2140,2 (2=0,01 342C, ).0,02+C,.0,02+3.0,01=0,21 mol> Cy 60.0,02 (76+ 2.60-2.18).0,02 + 60.0,02+76.0,01 Cfiu 35: X, Y 14 2 axit cacboxylic déu no va mach ho (Mx < My} > > > %m, = 100% = 23, 26% Dét chay a mol X ciing nhu Y du thu duge a mol H2O. Z va T 1a 2 este déu mach ho va khOng chira nhém chire khée. Dun hén hop E cht X, Y, Z, T véi 240 ml dung dich NaOH 1M, thu durgc 16,14 gam hén hop 2 mudi va hén hop F gdm 2 ancol ké gam nude. % khéi luong ciia Y trong E gan nhat véi: B. 6%. C.10%. Huéng dan giai Chon dap an B $6 H cua X,Y 2a =2= X laHCOOH, Y la (COOH): a F +02 0,26 mol CO2 + 0.44 mol H20 3 MP = Nyy Meo, =0,18 mol 86 C trung binh cia F= = 2ancol la CH30H va C2HsOH {re con * Beyy,o1 =0,18 mol fre =0,1 mol you * Pea — Jrew 26 mol ,08 mol Muéi gsm HCOONa (a mol), (COONa)> (b mol) {Myon =a+2b=0,24 mol _ {a =0,06 [68a +134b=16, 14g b=0,09 Két hop vai sé mol 2 ancol ta co E gom: CHLOOC-COOC:Hs: 0,08 mol HCOOCHS: 0,02 mol HCOOK: 0,04 mol (COOH)2: 0,01 mol 2 %M coor, Nyon t2e40n = Me.n,on = 90.0,01 ———_____ 199% = 6,2% 132.0,08 +60.0,02 + 46.0,04 +90.0,01 -p thude cing day déng ding. Dét toan bo F thu duoc 5,824 lit COs (dkte) va 7.92 D. 12%.TRUNG TAM LUYEN THI HOA HQC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) CAu 36: Hén hop E chtta 2 axit cacboxylic va 1 este déu mach hé, khéng phan nhanh va khéng chira nhom chire khac. Dot chay 25,48 gam E can ding 0,73 mol O2 thu duge 7,92 gam nuéc. Hidro hoa hoan ancol Z cé6 khi 25,48 gam E thu duge hon hop F. Dun néng F véi dung dich NaOH vita dii thu duge mot Iuong 7,36 gam va 2 mudi X, Y cé ti 18 mol tuong img 1 : 2 (Mx < My). Dun néng 2 mudi voi V6i t6i xtit thu duroc 4,704 lit (dktc) hén hop khi cé ti khoi so véi He bang 15,5/3. Phan tram khdi Iuong cia axit 6 khdi luong phan tir lén trong E la: A. 11,582%. B.11,384%. C.13,423%. Huéng din giai Chon dip an D V6i t6i xiit 2 mudi thu duoc 0,21 mol khi A, B. DA 0,21 fn, =0,07 mol > .14 mol ny tn, 22,4 nym, =1:2 >m, = 007A 0,4n- 85 40,21 A+2B=62 => A=2(H,),B=30 (C,H,) 25,48 g E + 0,73 mol O2— 0,44 mol H2O + CO2 Bn, 25481920. 7.92 _¢ 93 mol PME ye, =2.0,93+0,44-2.0,73 =0,84 mol > coon =0,42 mol= 2M, X,Y 1a mudi chire = X li (COONa): (0,07 mol), Y 1a C:Hs(COONa)2 (0,14 mol) 0,23 Két hop sé mol 2 mudi ta co F gom: (COOH)2: 0,07 mol CaHs(COOCHS)z: 0.115 mol C2Hs(COOH):: 0,14-0,115 = 0,025 mol (COOH), :0,07 mol => E gom: }C.H, (COOH), : 0,025 mol C.H,(COOCH,), :0,115 mol = n,, =0,07.2+(q+2).0,025+ (t+ 6).0,115 =2.0,44 = 5q+23t=0 0TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) (COOH), :0,07 mol = E gim: }HOOC-C =C-COOH: 0,025 mol CH,00C -C=C-COOCH, :0.115 mol IM oe cne- coon =—_—— 05996 = 11, 185% 90.0,07+114.0,025+142.0,115 Cau 37: Cho hén hop E gém tripeptit X cé dang Gly-M-M (duoc tao nén tir cc a-amino axit thudc cing diy déng ding), amin Y va este no, hai chéte Z (X, Y, Z déu mach ho, X va Z eting sé att cacbon). Bun m gam E véi dung dich NaOH, c6 can dung dich sau phan img, thu duro phan rin chi chita ba mudi va 0,04 mol hin hop hoi T g6m ba chat hitu co 6 ti khoi hoi so véi H» bing 24,75. toan bé mudi trén can 7,672 lit O2 (dktc), thu diroc 5,83 gam NaxCOs va 15,2 gam hén hop CO: va H2O. Phan tram khéi luong cia Y trong E la: A. 11,345%. B.12,698%. C. 12,720%. D. 9,735%. Huéng din giai Chon dap én B T gom amin Y va 2 ancol tao ra tir Z C,H,,NO,Na: amol C,H,,0,Na,: b mol => Mudi gém cé: fe | LIm0l = 6 yg mus =0,22 mol Dat, d Lin lugt la sé mol CO2 va H20 ng, = 207? = 0,3425 mony. co, = 283 = 0,055 mol * 22,4 106 44c+ 18d =15,2 a jBSEE2 5 2¢+d+3.0,055 =2. 0,3425+0,22> \d=0,27 Ago A+ 26=0,11 mol 0,09 n, na +mb—0,055 = 0,235 mol { Tyo = na +(m—2).b=0,27 mol = 0,09n +0,01m=0,29 > 9n+m=29 242k b=0,01 Goik li s6 C etaM > n= = 6k+m=23>k=3,m=5 X la Gly-Ala-Ala (0,03 mol) Do X, Z ciing sé nguyén tir C > Z la Css, (0,01 mol) Z la este cia mudi CsH404Na2 nén ancol li CHsOH (0,01 mol) va C2HsOH (0,01 mol) =m, =24,75.2.0,04-32.0,01-46.0,01=1,2g => %my = sg gn = 12,698% (75+89.2-18.2).0,03+1,2+174.0,01 Cau 38: Peptit X C,H,O,Ns mach hé tao boi mét c-amino axit no chifa 1 nhom -NHp va 1 nh6m - COOH. Bé phan ting hét 19g hon hop E chita X, este Y (CoHan204) vi este Z (CaHem4Os) cdn 300 ml dung dich NaOH IM thu duge hén hop mudi va 2 ancol c6 eiing so cacbon. Lay toan bd hon hgp mudiTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) nung véi v6i ti xut duoc hén hgp F chita 2 khi c6 ti khdi so véi Ho 1a 3,9. Dat chay 19 gE can 0,685 mol Q2 thu duge 9,72 g H20. Biét X, Y déu la este thuan chire. Phan tram khoi ong cua X trong hon nat véi hop E "A 19%, B. 23%. C. 28%. D. 32%, Huéng din gidi Chon dap an A 19 gam E+ Oo: ny, =0,54 mol; Dat ng, =x mol; ny, =y Ml Nev or, =5 mol (BTN) BTKL; 44x + 28y =19+ 0,685.32 qa) Ta 06: myo, =0,3 mol,E +0,3 mol NaOH = Neoojexe) = 0,3 -2y(mol) Bao toan nguyén 16 O trong phan img chay: 7¥4(0.3-2y)2+0,6852=2440,54 (2) Tw (1);(2) >x ),03 MOL=> Moo ey) =0,24 mol Neo, —Nyo +My, =N, — Ny => a, = 0,12 mol O,:a mol — [a+b=0.12-0.01 O,:b mol ~ (2a+3b=0,24 Do sau phan img thu duoc 2 ancol c6 cing sé nguyén tir C > n>5;m2>6 =n, >0,45;m, >0,12 ma n, +m, +0,01.x =0,69 > x <6=>x=6= (Gly), :0,01 mol =>%m, =19% Céu 39: Hén hop H gdm 3 este mach hé X, Y, Z. Trong dé My a=0,09;b=0,02 oH Chon dap an C Ta c6: n,,, = 0,06mol;n, Sau khi hidro héa > Dét chdy hodn toan thu dirge sin phim: 378 , 6.72 9 24 mol= iy, = 18 0,06 San phim sau hidro héa gém cae este no, tae dung voi NaOH chi chira 2 mudi va hon hop F gém 2 ancol cé ciing s6 cacbon => 2 ancol chi cé thé la O7mol = A, > 0,06 mol ete 0,035mol = Morar = b=0,06 CoHsOH: a mol; C3H\(OH)x:b mol > [2*=° =>a=0,05;b=0,01 \a+2b=0,07TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Hén hop H gém este don chite (x mol) va este hai chute (y mol) x+y=0,06 > x=0,05,y=0,01 x+2y=0,07 = X laste don chite; Y Li este don chite va Z la este hai chite: n, = 0,01 mol Ta C6: Neo, = Myo N, =0,03+0,07(mol) = no, =0,25 mol =0,25 -0,06.2=0,13;Mycgon, =0,07 HCOOC,H, :u mol = Jeste la: RCOOC,H, :v mol RCOOC,H,OOCH: 0,01 Trong phan img hidro héa: n, =0,03=> R chi cé thé chira t6i da 2 lién két x Néu R chi chia | lién két t > u=0,03;v =0,02> R =C,H, > %m, =35,3% Cau 40: Cho hén hop hai ancol X, Y (Mx < My) la dong dang ké tiép. Thue hién hai thi nghiém sau v6i cling khéi long cia hén hop. Thi nghiém 1: Cho hén hop qua bét CuO dur nung néng nhan thiy khéi rong chat rn thu duoc c6 khéi long giam 4.8 gam so véi khéi lvong CuO ban dau. Phan khi va hoi thoat ra (khéng ¢6 xeton) cho tie dung het véi dung dich AgNOs/NHs du thay xuat hién 90,72 gam ket tia Thi nghiém 2. Dun vai dung dich H»SOs dc & 140°C thu dige hdn hop 3 ete c6 tng khéi rong 6,51 gam, Dem héa hoi hin hop 3 ete nay thu duge thé tich hoi ding bing thé tich cua 2,94 gam nito (do ¢ cling diéu kién nhiét 46 va dp suat) - Biét cae phan tmg 6 thi nghiém (1) xay ra hoan toan. % chat Y chuyén héa thanh ete 6 thi nghiém (2) la A. 33,33% B.66,67%. C.75,00% D. 80%, Hu6ng din giai Mein Chon dap an B Thi nghiém 1: R(CH,OH), +nCuO—*>R(CHO), +nCu+nH,O Ap dung ting gidm khéi luong cé: — Chting 16 2 ancol la CH3OH (x mol) va C2HsOH (y mol) fxty=03 |4x +2. Thi nghiém 2: 6,51 gam ete trong ting véi 0,105 mol ete Dat so mol X, Y phan img tao ete Lin Ivot laa, b > Nhe phining= A+ b= Mee = 0,21 MOL, Nyy = Nye > Mancol phin img = 32a + 46b = 6,51 + 18.0,105 = 8,4 ,105molTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) a=0,09 b=0,12 0,12 1% = 79) Og 100%= 66.67% Cu 41: Hén hop X gom | andehit va | axit (s6 nguyén tir C trong axit nhiéu hon sé nguyén ti C tong andchit 1 nguyén tit). Dét chay hoan toan 0,1 mol X thu duge 8,064 lit CO2 (dkte) va 2,88 gam nude. Mat khae, cho ton bd long X trén véo dung dich AgNOs/NHs thay xuat hign m gam két ta. Gid tri Jon nit ctia m c6 thé la: A164 B. 28,88. C. 32,48 D. 24,18 Huéng din giai —+ Phan trim s6 mol Y phan img Chon dap an B. Dat sé mol ciia andehit va axit lin hrot la a, b. 8,064 No, =0,36mol, my, = ),16 mol 22,4 : => Sé nguyén tir C trung binh =—S% ny OL = Andehit c6 3 nguyén tir C, axit c6 4 nghiém tir C = [a+b =01 = free \3a+4b=0,36 |b=0,06 Dat sé nguyén tir H trong andehit va axit ln lot la x, y. => 0,04x +0, 06y =2.0,16 = 0,32 => 2x +3y =16 »y=4 => Céng thite cia andehit ¢6 dang: CsH:Op, ciia axit ¢6 dang: C/H4O, => CTPT cita andehit 1 C:H20 (CTCT:CH = C — CHO) Dé m 16m nhat thi axit cling c6 phan tmg voi AgNO3/NHS tao két ta <> Axit c6 n6i 3 dau mach <> CTCT eiia axit la: CH = CCH2COOH = Gid tri lon abat cua M= M6. coors, * Mas + Magene-crycoosst 194.0,04 + 108.2.0,04 + 208.0,06 = 28,88 gam 42: Thuy phan este X trong moi trudng axit, thu duge hai chat hu co mach ho, trong phan tu chi chia m6t trong loai nhém chite va déu khéng lam mat miu dung dich brom. Cho 0,05 mol X phan ting hét véi dung dich KOH (dur) ri e6 ean thu duroe m gam chat rin X1 va phan hoi X: e6 0,05 mol chat hitu co Y li ancol da chire. Nung X; trong O> (dur) thu duoc 10,35 gam K2COs, V lit CO2 (dkte) va 1,35 gam H,O. Biét s6 mol Hh sinh ra khi cho Y téc dung véi Na bing mét nira sd mol CO: khi dét Y. Gid tri cua m la A. 18,80. B. 14.6, C.11,10 D. 11,80 Huéng din giai =x Chon dépénD. Y cé hom —OH bing sé nguyén tirC; ng co, = ),075mol; nj... =0,075molTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) (COOK), :0,05 KOH:0,15~0,05n +Khin=1 > He=1— Loai + Khin=2 > He=2— Mu6i CH(COOK): x 005s | yoin=1 hoc n =2. Xi chia CH,(COOK), 0,05 + m=11,8 gam KOH: 0,05 CAu 43: Cho X, Y, Z la ba peptit mach hi (c6 s6 nguyén tir cacbon trong phan tir twong tng la 5, 7, 11); T la este no, don chitc, mach hé. Chia 268,32 gam hén hop E gém X, Y, Z, T thanh hai phan bing nhau. Dét chay hoan toan phan mét can vita dit 7,17 mol O2. Thay phan hoan toan phan hai bang dung dich NaOH vita di, thu duve ancol etylic va hin hop G (gém bon mudi cita Gly, Ala, Val va axit cacboxylic). Dot chay hoan toan G, thu dirge NasCOs, No, 2,58 mol CO» va 2,8 mol HO. Phin tram khdi luong cia Y trong E la A. 18,90%. B.2,17%. C.1,30%. D. 3,26%. Huréng din giai Chon dap an C C.H,ON:amol a, 1, CH, :bmol ‘ dai E: Lp}CP2 2xou Quy Ast OF ,0-emol HCOOC,H, :dmol S7a+14b+18¢-+74d=134,16 2 ya 3bu2a=717 32 C,H,O,NNa:amol +} CH, :bmol HCOONa :dmol ‘Theo bai ra ta 06 he sa 7 = darbed=2244 9.58/87) ~ 2a+b+f=28 2 Do b >d = este la: CH3COOC>Hs: 1,2 mol Goi s6 mol 3 peptit lan lugt la x, y, z mol = mat xich trung binh cia 3 peptit = = Cé pentapeptit > X: GlyAla; Y: ValGly; Z: (Gly)s [Sx+7y+llz=1 x=0,01 Taco hé: {x+y+z=0,1 > 4y=0,01%m, =1,30% [2x+2y+5z=0,44 z=0,08 Cfu 44: Dun néng hin hop etylen glicol va «-amino axit X (Calan+102N) voi xiie tae HCL, thu due hén hop san pham hiu co, trong dé c6 chit httu co Y mach ho. Dét chay hoan toan 12.45 gam Y can diing 0,35 mol O:, sin pham chy gm CO2, H20, HCI va Nz duge din qua dung dich KOH de, du lurong dung dich ting 22,25 gam, Nhan dinh nao sau day la ding? A. Tong sO nguyén tir hidro trong hai phan tir X, Y bang 15.TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) C. X c6 tén gol la a-aminopropionic. D. Y tac dung t6i da voi NaOH trong dung dich theo ti lé mol 1: 2 Huéng din giai Chon dap an B KOH dic dur hip thu C2, HO, HCI omy -12,45+920,35-22,25 = 05 mol Ms 2B a 12,45 Néu Y chia IN thi n, =2n,, =0,1mol=>M, == 124.5 = Y e6 dang HOCH:CH200C-R-NH:Cl ' => R=-17> Loai Vay Y chita 2N= ny =n, = 0,05 mol > My, -B& 249 Y e6 dang (NH3CI-R-COO):C2Hs > R= 14 (CH) = Y 1a (NH3CICH:COO),C>Hy va X 1a Gly. + Asai. Téng s6 nguyén tir H trong X, Y 1a 19. + B ding, D sai (NH3CICH»COO),CoH; + 4NaOH — 2H»NCH»COONa + C;H,(OH)2 + 2NaCl + 2H,0 + Cssai. X c6 tén goi li a-amino axetic. (Cu 45:Dot chay hoan toan 17.44 gam hén hop X gdm ba este déu don chtte (trong dé o6 hai este li déng phan cia nhau) can ding 0,76 mol O2, thu duge CO: va 10,08 gam HzO. Mat khée dun néng 17,44 gam X véi 300 ml dung dich NaOH 1M. (ding du), thu dvge mét ancol Y duy ahit va 22,25 gam hon hop ran Z. Phan trim khoi Inong cia mudi cé khoi lrong phan tir lin nhat trong hon hop Z la A. 18,2%. B.20,4%. D.9,7%. Huéng dan giai Chon dap an C 10,08 — 0,56 mol 18 Tyo Py mqo, =17.44+ 32.0, 76-10, 08 =31, 682 = neo, = 0,72 mol _2.0,72+0,56-2.0,76 = 0,24 mol 2 M, =") 72,67 ehita HCOOCH3 Om Néu san pham cia X + NaOH chi tao ancol va mudi thi: > mayon =17,44-+ 40.0, 3 - 22,25 = 7,198 => Ne cry =0,2247 mol < 0,24 >Voly. = X chia ca este etia phenol. { PP 32M 4, on +1849 = 7,198 205 mol = . [Peron +x, =0,24 mol 0,035 molTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Néu X chiia 2 este eiia phenol: | 20: *0.205mol C,Hagoa-2103 :0,035mol 8,86 > Loai > to, = 2.0,205 +0,35n = 0,72 mol > = X chi chita 1 este ciia phenol (0,035 mol) va 2 este ciia CH30H (0,205 mol) x (eae: xmol y.(n=2)=0,24 ), 56mol => y.(k=1)=0,16 y>0,0352k<5,6=k= = n=8,y=0,04,x =0,2 =X gom CH;COOCsHs (0,035 mol), CsHsCOOCHS (0,005 mol), HCOOCHS (0,2 mol). Mudi 6 khdi long phan tir lén nhat la CcHsCOONa. atte ycoons = AOS 100% =3,2% 22,25 Cfu 46: Cho 0,3 mol hén hyp X gdm 2 este don chite tae ding vira di v6i 200 ml dung dich NeOH 2M dun néng, thu doe hop chit hiru eo no mach hi Y ¢6 phin img tring bac va 37,6 gam hin hop muéi hitu co. Dét chay hoan toin Y réi cho sin phim hap thu hét vao binh chira dung dich nude voi trong dr, thay kh6i hung binh ting 24,8 gam. Khoi hong cua X la 1.308 gam B.336 gam €.322 em D. 35,0 gam Huéng din gia Chon dip an C Ta c6: nx = 0,3 trong X c6 chira 1 este cia phenol (A) va este can Iai 1a (B) (4): RCOOCH,R" Mat khae Y 6 phan img trang bac nén A va B c6 c6ng thite (B)R,COOCH = CHR, wo pas [Mat My = 0,3 ofan Myo =n, =0,1 Ta 6 hé: { >" ‘2m, +m =0.4 \ny =0.2 2 Khi dat chiy chit Y no, dom chite, mach hér (RxCH2CHO: 2 mol) ludn thu doe ng, n= = Ming, +18, = 24,8 > Meo, = 0,4mol ma C, = ae =2: Y la CHsCHO BTKL=>mgmgasi+ My + myo ~ Myson = 32,2 gam Cau 47: X, ¥ (Mx < My) li hai peptit mach hé, hon kém nhau mét lién két peptit. Bun néng 73,16 gam hén hop E chita X, Y vi este Z (CsHi1O2N) v6i dung dich NaQH vita du. Chung edt dung dich sau phan img, thu duoc 4,6 gam ancol etylic va hon hop chita 2 mudi cia 2 a-amino axit thudc cing day dng ding ké tiép nhau. Dot chay toan bd mudi cin ding 71,232 lit Oz 6 dkte, thu doc CO2, H2O, Nz va 53 gam Na:COs. Phan tram khdi lugng cia Y wong hn hgp E gin nhat voi gia ui ndo sau day? A. 45% B.57% C. 16% D. 27% Huéng din giai Chon dap an BTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Z.1a CHsCH(NH2)COOC2Hs 0,1 mol |GlyNa:1 mol CH, : x mol AlaNa:0,62mol GlyNa:0,38mol my-y = 73,16 ~ 0,1.117 = 61,46 gam Coi hdn hop mudi gsm { > ng, =2,25+1,5x= 3,18 x=0,62mol = Vay 2 mudi la { CH,ON :0,9mol Quy ddi hén hop gdm X va Y vé: } CH, :0,52mol 61,46 —0,9.57—0,52.14 18 625 H,0 =0,16mol = ny. y ‘$6 mt xich trung binh trong X va Y la: x“ = pentapeptit (Gly)S.nCH2 : 0,06 mol + hexapeptit (Gly)6.mCH. : 0,1 mol = 0,06n + 0,1m = 0,52 > n=2; m=4 >%my = 56,86% Cfu 48: X, Y 1a hai chat htu co thudc day ding ding ancol anlylic, Z 1a axit cacboxylic no hai chitc, T 1a este tao bai X, Y, Z. Dit chay 17,12 gam hén hop E chita X,Y, Z, T (@u mach hé) cn ding 10,864 lit O> (dkte) thu duoc 7.56 gam nude. Mat khac 17,12 gam E lam mat mau vira da: dung dich chira 0,09 mol Br2. Néu dua néng 0,3 mol E vi 450 ml dung dich KOH 1M, c6 can dung dich sau phan img ri sau dé lay phan long chita céc chat hiru co di qua binh dung Na du thay khdi luong binh ting m gam. Gid tri cua m gin nhat v6i gid tri nao sau day? A700 C.9,00 D. 10,50 Huréng din giai Chon dap an B CH, =CH ~ CH,OH :0,09 mol ye , (COOH), -a mol i hin 7 Quy doi hon bop v8 4 Oy mol -H,0:¢ mol 90a-+14b-+18-=11,9 Theo bii ra ta c6 hé fat3b=0,125 2 .4=0,13;b=0,04;¢ =-0,02 a+b+c=0,15 Thay rang? ny, KOH cén dur sau phan img = m=m,— 5.(0,09.58 +0,04.14 0,09) = 8,535 gamTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Cau 49: X, Y la 2 axit cacboxylic déu mach hé, Z li ancol no, T la este hai chire, mach ho durge tao béi X, Y, Z. Dun 38,86 gam hén hop E chtta X,Y, Z, T v6i 400 ml dung dich NaOH IM (vita du), thu duge ancol Z vi hén hop F gdm hai mudi c6 ti if mol 1:1. Din toan bo Z qua bink dung Na du thay khéi luong binh ting 19.24 gam, déng théi thu duoc 5,824 lit khi Hz (dkte). Dét chy hoan toan F can ding 15,68 lit O2 (dkte), thu due CO2, NazCOs va 7,2 gam H20. Phan trim khéi luong cua T trong E gan nhit véi: ‘A. 48.88% B. 26,44% C. 33,99% D. 50,88% Huéng din giai Chon dip an D T Leste hai chire, mach hé duoe tao bai X, Y, Z nén axit X, Y don chite, ancol Z 2 chite 5,824 22,4 Dat Z la ROH)»: n, = 0,26mol ‘Mbish ting= (R+32).0,26=19,24 gam => R =42 (C3Ho) Vay Z la CsH(OH)> Mudi co dang R°COONa (0,4 mol) F +0,7 mol O: > CO2 + NaxCOs + 0,4 mol HO 0.42 nguyén tu H trung binh = =2 04 => M6t mudi la HCOONa (0,2 mol), mudi con lai CH3COONa (0,2 mol) HCOONa+ 40,“ +400, +4.Na,co, +4.0,0 27 2 207 27 C.H,COONa + (x + 1)0, a» + Jeo, + ; Na,CO, + 3u0 >No, =} 0,2+(x+1).0,2=0,7mol => x=2 HCOOH, T li HCOOC;Hs00C-CH=CH> HCOOH :0,2mol C,H,COOH : 0.2 mol C,H,(OH), :0,26mol Quy ddi E thanh: H,0:—amol => me = 46.0,2 + 72.0,2 + 76.0,26 ~ 18a =38,86 >a=0,25 > Som = 1580.25 100% = 50,82% 238,86 Cau 50: Hén hop E gém peptit X (CyH2s-10sN2); peptit Y (CmHam-a06Ns) va este Z (CaH2s02). Dot chay hoan toan 20,99 gam E can ding 1,1425 mol O2 san pham gom CO2, H20 va Nz duge dan qua nude v6i trong léy du, thu duoc 90,0 gam két tia. Néw dun néng 20,99 gam E can ding vira dui 250 ml dung dich NaOH 1M, thu diroc hén hop T gém 4 mudi: trong d6 c6 3 mudi cia glyxin, alanin va valin, Phan trim khdi long ctia Y trong E la A. 19,10% B.17,77% C.19,77% D. 15,78%TRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) Huéng din giai Chon dap an Quy déi Z trong duong véi CH: va O2 GH,NO: anol . CH, :bmot > Quy déi Ftseme dhtome v6i- ) 7.0): cmol O, :dmol Dit chiy E Calf,NO+ 20, 5200, +3H0+5N. ch, +30, £0, +1i,0 m, = 57a +14b+ 18c +32d =20,99 Mp, = 2,25a +1,5b=1,1425+d > = 20. 0,9mol *~ 100 Moy = a+d=0,25mol co: {Mav = Me +My =€= 0.0801 _, ny =0,08mol Oo \ny =3n, +5n, =a=0,17mol~ | m, = 0,01mol =>nC = 0,04n + 0,01m + 0,08n = 0,9 = 12n +m =90 Don >6 va m>10 nén n= 6 vam = 18 la nghiém duy nhat =Y la Gly(Ala)x(Val)> (0,01 mol) (75-+89.2+117.2-18.4).0,01 = %my = og 100% = 19,77% Cu 51: Hén hop X chita ba peptit déu mach ho, c6 téng sb nguyén tir oxi trong ba phan tir cua ba peptit khong qua 12. Khi dét chay moi peptit déu thu durge CO2 c6 sé mol nhié néng m gam X véi dung dich NaOH vira dui, thu duoc 39,96 gam hén hop X gém ba mudi cia glyxin, alanin va valin. Néu dét chay m gam X cin ding 1,35 mol Os, thu doe CO2, H20 va Nz. Gi tri ciia m la A. 25,56 B.27,75 C. 26,28 Huéng din giai Chon dap an B hon H20 1a a mol. Dun Khi dét chay mdi pepit déu thu durge CO, ¢6 sé mol nhiéu hon H,O 1a a mol. => X khéng chita dipeptit. 1g sb nguyén tir 0 < 12 => Téng sé nguyén tir N <9 Vay cae peptit trong X déu li tripeptit > ny =3nxTRUNG TAM LUYEN THI HOA HOC DIA CHi : 66 TRAN DAI NGHIA - HAI BA TRUNG -HA NOI THAY NGUYEN VAN THAI (DT :09.789.95.825) CH,NO:3x mol Quy déi X thinh: CH, : ymol H,O:xmol => my, =57.3x+14y+18x = 27,72 Cu 52: Hén hop E chita hai hop chat hitu co gdm chat X (C2HyO3N) va chat Y (CHsO3N2). Dun néng 18,68 gam E véi 400 ml dung dich NaOH 1M, c6 can dung dich sau phan ting thu direc 4,48 lit (dkte) mét khi duy nhat c6 kha ndng ma qui tim am héa xanh va hén hop Z gdm cac hop chat vo ca. Nung nong Z dén khoi luong khéng doi, thu duge m gam rin khan. Gia tri m 1a A. 27,22 gam B.21,44 gam C. 22,72 gam D. 24,14 gam Huéng din giai my =57.3x + 14y+40.3x =39,96g _ [x=0,12 1 np, =2,253x+1,5y =1,35mol 36 Chon dap an B X la CHsNH3HCOs (x mol) va Y la CHsNHNO; (y mol) CHsNH3HCO; + 2NaQH—> CHsNH2 + NasCO3 +2H:0 CH3NH3NO3 + NaOH > CH3NH2 + NaNOs + H20, 'm, = 3x+94y =18,68g [x =0,12 > > |, 2mol ~ | y = 0,08 0,4- 2x ~y =0,08 mol { Na,CO, :0,12mol Na,CO, :0,12mol Z: | NaNO, :0,08mol ——>} NaNO, :0,08mol NaOH :0,08mol NaOH :0,08mol 106.0,12 + 69.0,08 + 40.0,08 = 21,44 g Cfu 53: Hop chat hiu co X (chita C, H, 0) chi ¢6 mot loai nhém chite. Cho 0,15 mol X phin img vira dit v6i 180 gam dung dich NaOH, thu duoc dung dich Y. Lam bay hoi Y, chi thu duge 164,7 gam hoi nude va 44,4 gam hén hgp chat rin khan Z. Dét chay hoan toan Z, thu duge 23,85 gam NarCOs; 56,1 gam CO; va 14,85 gam HO. Mat khac Z phan tmg véi dung dich H.SO, long (dur), thu duoc hai axit cacboxylic don chite va hop chat T (chita C, H, O va Mr < 126). S6 nguyén tir H trong phan tir T bang A6 D. 10. Huéng dan giai Chon dap an C Dy. o, = ES =0,225mol = Moy = 0, 4501 * 106 TM, gat vaon) = 180-40.0, 45 = 162g = 86 mol H20 tgo thanh = WAT =162 91501 Neo, = “ 1,275mol, iyo BH m, =44,4+164,7- 180 = 29,1