pß; Èidkdhl

CHEMISTRY iaj wNHdi 01-C

B.Sc. Engineering (Hons)
UNIVERSITY OF MORATUWA

2021 Theory / Revision

100
01. (a) (i) mßmQ¾K jdhq kshuh weiqßka fvda,agkaf.a wdxYsl mSvk kshuh jHq;amkak lrkak'
(ii) tla;rd Ndckhl 270C § He jdhqj 12g la wvx.= fõ' Ndckh oDv jk w;r tys mßudj 16.628cm3 fõ'
I. Ndckh ;=< we;s jdhqfõ mSvkh .Kkh lrkak' .Kkfha§ Tn isÿ lrk Wml,amk we;akï tajd meyeÈ,sj
i|yka lrkak' (He=4)
II. by; Ndckfha WIaK;ajh ksh ;j ;sìh§ thg O2 jdhqj 2mol la we;=,a lf<a kï túg Ndckh ;=< we;s He
jdhqfõ wdxYsl mSvkh .Kkh lrkak'
III. O2 jdhq j we;=,a l< miq Ndckfha iuia: mSvkh fldmuK o@
IV. ±ka He yd O2 wvx.= mßudjg iudk jQ ;j;a oDv Ndckhla thg iïnkaO lr WIaK;ajh 270C ys u mj;ajd
.;af;a kï" kj moaO;sh ;=< iuia: mSv kh .Kkh lrka k'
V. by; ixhqla; Ndckfha WIaK;ajh 270C ys isg 1270C olaj d jeä l<fyd;a" Ndckh ;=< kj mSvkh
fldmuKo@
VI. by; ixhqla; Ndckhg ±ka NO jdhq j fu!, X m%udKhla we;=,a lr WIaK;ajh 1270C ys mj;ajd .;a úg
iuia: mSvkh 5.6×108 Nm-2 la úh' fuys§ NO yd O2 jdhq my; wdldrhg m%;sls%hd fõ'
2NO(g) + O2(g) ® 2NO2(g)
kuq;a ish¨u O2 iuÕ m%;sls%hd ùug ;rï fh¥ NO m%udKj;a fkdjq neúka hï O2 m%udKhla moaO;sfha b;sß
fõ' X yS w.h .Kkh lrkak'

(b) r;a l< Ni W;afm%arlh u.ska óf;aka yd yqud,h heùu uÕska yhsv%cka jdhqj ksIamdokh l< yelsh'
fuys§ isÿjk m%;l
s s%hdj my; ±lafõ'
CH4(g) + H2O(g) º CO(g) + H2(g) DHq=+206 kJmol-1
(i) my; i|yka o;a; Ndú;fhka ldnka fudfkdlaihsâ (CO) jdhqfõ iïu; nkaOk ú>gk tka;e,amh
s .Kkh lrkak'
DHqD(H-H) = +436 kJmol-1
DHqD(C-H) = +410 kJmol-1
DHqD(O-H) = +460 kJmol-1
(ii) C-O yd C=O ys iïu; uOHkH nkaOk ú>gk tka;e,ams ms<sfj,ska +360 kJmol-1 yd +740 kJmol-1 fõ' ldnka
fudfkdlaihsâ ys iïu; nkaOk ú>gk tka;e,amsh fuu w.hhka folgu jvd úYd, jkafka uka±hs meyeÈ,s
lrkak'

02. (a) A hkq wj¾K iaMáluh >khla jk w;r th c,fha ødjH fõ' A c,Sh ødjKhlg (NH4)2S tla l< úg iqÿ meye
wjlafIamhla f,i (B) ,nd foa' fuu wjlafIamh HCl ys øjKh lr th WKqiqï lr thg c,Sh NH 4OH ødjK
iaj,amhla tlalrk ,§' tys§ iqÿ wjlafIamhla f,i (C) ,enqKs' th jeämqr NH3 ødjKhl ødjK.; ùfuka wj¾K
c,Sh ødjKhla (D) iEfoa'
;jo A ixfhda.h idkaø H2SO4 iu. r;a lsÍ fï § (E) r;= ÿUqre jdhqjla msgjk w;r th WKq idkaø NaOH iuÕ
m%;sls%hdfjka c,h iy G iy H ixfhda. ,nd foa' G iy H fukau A c,Sh ødjKh o Pb(NO3)2 iu. iqÿ wjlafIamhla
,nd foa'

ridhkh úoHdj999999999999999999 1 99999999pß; Èidkdhl B.Sc. Engineering (Hon's)

 (i) A ys wvx.= f,dayuh uQ,øjhfhka iEfok legdhkfha bf,lafg%daksl úkHdih ,shd olajkak'
(ii) A wldnksl iaMáluh ixfhda.h y÷kd .kak'
(iii) B , C , D , E , G iy H y÷kd .kak'
(iv) E iu. WKq idkaø NaOH olaj k m%;sls%hdj i|yd ;=,s; ridhksl iólrKh ,shd olajkak ' tu m%;sls%hdj kï
lrkak'
(v) ,jKfha wvx.= f,dayuh uQ,øjH ys m%fhdaackhla ,shd olajkak'

(b) óg Èk lsysmhlg fmr újD; l< hdmkh m,d,s cd;Hka;r .=jka f;dgqmf<ys .=jka hdkd .uka lrk ux ;Srej ieliSu
i|yd fhdod .;a øjHfha m%Odk ix>glhla jkafka Aggregate Base Course(s) (ABC) h' kuq;a fmr Èkfha wêl j¾Idj
ksid ux;Srefõ yg.;a .s,d neiSï ksid ux;Srej ieliSu i|yd Ndú;d l< ix>gl kshñ; ud;%dfjka Ndú;d l<do
hkak ms<sn| ielhla u;= jqKs' fï ksid fuys ABC ud;%dj ms<sn| läkï mÍCIKhla lsÍug wjYH jqKs'
ABC ys m%Odk ix>gl jkafka Pb3O4(s) yd PbO2 h' fï wkqj ux;Srefjka .;a idïm,hla r;a lrk ,È' idïm,fha
ABC muKla we;s nj i<lkak' fuu ixfhda. fjk fjku r;a l< úg PbO(s) iy O2(g) njg úfhdackh fõ' PbO2
yd Pb3O4 ys ñY%Khl 0.3282g iïmQ¾Kfhka ;dm úfhdackh l< úg ,enqkq >k wjlafIamfha ialkaOh 0.3122g fõ'
(i) fuys § ,efnk PbO j, j¾Kh l=ulao@
(ii) uq,a ñY%Kfha wka;¾.; PbO2 ujq, Nd.h .Kkh lrkak'
(iii) fuu ux;Srej ieliSug fhdod.;a A,B,C ixfhda.fha ;sfnk Pb idkaøKh fiùug wjYH jqKs' fï wkqj by;
idïm,hu ;kql wï,hl Èhlr c,h o tl;= lr 1000cm3 ødjKhla ;kk ,È' fuu ux;Srefõ .=jkahdkd .uka
lsÍug kï cd;Hka;r m%ñ;shg wkqj ;sìh hq;= Pb idkaøKh 300ppm fõ' fï wkqj fuu .=jka hdkd m:h kshñ;
cd;Hka;r m%ñ;shg wkqj ilid we;a±hs .Kkhlska fmkajkak' (PbO2 yd Pb3O4 ;kql wï, ;=< iïmQ¾Kfhka
Èhfõ hehs i<lkak')

pß; Èidkdhl B.Sc. Engineering (Hon's)99999999 2 999999999999999999ridhkh úoHdj