Sample Paper ‘Time :90 Minutes ‘Max. Marks :35 The Question Paper contains three sections. Section A has 25 questions. Attempt any 20 questions. Section B has 24 questions. Attempt any 20 questions. Section C has 6 questions. Attempt any 5 questions. All questions carry equal marks. There is no negative marking. ae ken SECTION-A This section consists of 25 multiple choice questions with overall choice to attempt any 20 questions. In case more than desirable number of questions are attempted, ONLY first 20 will be considered for evaluation. 1. Which of the following exists as covalent crystals in the solid state? (@®) Todine () Silicon (© Sulphur (@ Phosphorus 2 Ingraphiteelectrons are: (2) localised on each carbon atom (6) spread out between the sheets (©)_ localised on every third carbon atom (@) present in antibonding orbital 3. Afluorine atom (F) affects pur ofan electron ina covalent bond which is (@) Weakest () Strongest (© Neutral (@) Constant 4. Acrystlline solid (@) changes abruptly from solid to liquid when heated (>) has nodefinite melting point (©) undergoes deformation of its geometry easily (d) _ hasan irregular 3-dimensional arrangements, 5. An deal solution is formed when its components (@)_haveno volume change on mixing (©) _havenoenthalpy change on mixing (©) have both the above characteristics (@) have high solubility. 6 Schottky defect defines imperfection inthe latie structure of () solid ©) gas © tiguid (@ plasma 7. TUPACname of CH,CH,C(Br) = CH-Cl is (@) Zbromo--chlorobutene (©) _I-chloro-2-bromobutene (©) 3-chloro-2-bromobutene (@)_ None of the above 8 Proteins are condensation polymers of (@) aminoacids (6) _B-aminoacids (©) cehydroxy acids (@ _Behydroxy acids 9, When two halogen atoms are attached to same carbon atom then itis (@)vie-dihalide () gemdihalide © aerhalide (@) a, B-halide 10. Which ofthe following noble gases react with fluorine to form compound? (@) Krypton () Xenon (© Radon (@_Allofthe above 11, Anetheris more volatile than an alcohol having the same molecular formula. This is due to (@) dipolar character of ethers (b) _alohols having resonance structures (©) inter-molecular hydrogen bonding inethers _—_(d)__inter-molecular hydrogen bonding in alcohols. 12, The space lattice of graphite is (@) cubic (6) tetragonal (© thombic (2) _bexagonalGP 4437 S02 (Chemistry) 13. The process of converting alkyl halides into alcohols involves, (@) addition reaction (6) substitution reaction) dehydrohalogenation —(@)_ rearrangement reaction 14, Which of the following factor do not affect solubility of solid solute in liquid? (@) Temperature (©) Pressure (© Nature of solute @ Allofthese 15, Which of the following has strongest hydrogen bonding? @ Bihylamine (©) Fshanal (©) Bthylaleohol (© Diethyl ether 16. What is hybridization ofP in PCI, ? @ x ©) pe © wa © x 17. Which ofthe following is correct about H-bonding in nucleotide? @ A~AandT—T (6) G—TandA—C © A~GandT—C @ A~TandG—C 18, Ethylene dichloride can be prepared by adding HCI to @ ethane (©) ethylene (© acetylene (@ ethylene glyco! 19. Haloarenes are ortho and para directing due to (@) Resonance in aryl halide (©) -Leffect ofhalogen atom (© effect ofhalogen atom @ Both a) and) 20, Onheating lead nitrate forms oxides of nitrogen and lead. The oxides formed are @)_N,0,P00 (6) NO,,PbO (© NO.PbO (@ NO.PtO, 21. Which one of the following is non-ideal solution (@) Benzene + toluene (0) mhexane-+ n-heptane (©) Ethyl bromide + ethyl iodide @ ca,+cHa, 22. Collectively the elements of group 15 are called ~ @)pnicogens (©) pnicopens (© sicopen (@ None of these 23, Insulin production and its action in human body are responsible forthe level of diabetes. This compound belongs to which ofthe following categories? (@) Acarbohydrate (6) Ahormone (© Acoenzyme 24, Which one ofthe following elements s most metallic? @ P ) As © 25, Which ofthe following elements does not show allotropy? (Nitrogen (©) Bismuth (© Antimony SECTION-B @ @ @ An antibiotic B Arsenic This section consists of 24 multiple choice questions with overall choice to attempt any 20 questions. In case more than desirable number of questions are attempted, ONLY first 20 will be considered for evaluation. 26, Which ofthe following liquid pairs shows a positive deviation from Raoult’s law ? (a) Water Nitricacid (b) Benzene - Methanol (©) Water- Hydrochloric acid (@ Acetone - Chloroform 27. The vapour pressure oftwo liquids “P* and “0” are 80 and 60 torr, respectively. The total vapour pressure of solution obtained by mixing 3 mole of P and 2 mole of @ would be (@) T2torr (b) 140 torr (© 68torr 28, Arrange the following compounds inthe increasing order of their densities. : ; oO ® « d. 1 @ DOn Forwhichsolventrate of 2 willbe maximum? (@) Benzene ) 100% 0 © 100% aectone (©) 75% 1H,0+25% acctone 32, $-S bond isnot present in @ 8,03 ® s,0% © sof @ soF 33. Which ofthe following is nota cystine solid? @ Ka ® ca © Glass © Roombics 34, For the compounds CHC CH,Br.CHatand CHE, the correct order of increasing C-halogen bond lengths @ CHF RCI>RBr>RI (6) RBr>RCI>RI>RF (©) RIDRBr>RCI>RF_——(@)_-RCI>RF>RI>RBr GP 4437oes OMR ANSWER SHEET Sample Paper No -1 Use Blue / Black Ball pen only. Pease do not make any atray marks on the answer sheet. Rough work must not be done on the answer sheet. Darken one circle deeply for each question in the OMR Answer sheet, as faintly darkend / half darkened circle might by rejected. [start time End time “Time taken 1. Name (in Block Letters) Moree 3. 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