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1595063 i 1)? ERAGE AH G Vo (2D ARASALSA (Des RK + TW 1595063 B = (452458: PRB 106 (2017) #08 ALB (21) P 35K + 102129879 (22) 35a 2 RI 102 (2013) #08 A 20 8 (S1)Int. CL €09J175/04 (2006.01) C09J7/02 (2006.01) COBGI8/40 (2006.01) (30) 4 Heit + 2012/08/31 aa 191609 2012/11/06 244075 20130129 A 2013-014312 (T)PAEA + BRE LMA IRA A (8 A) NITTO DENKO CORPORATION — (JP) az (72)86 9A A: Het AME SASAKI, SHOGO (JP) 3 #8 3% ISEKL, TORU (JP) : ###]& JO, SOUYA (KR) + 95 8 49 UCHIDA, SHOU (JP) + #44 RF SAWAZAKI, RYOHEL (IP) + 2 af a ANDO, MASAHIKO (JP) (AYRES RA (56) 8 BR JP 2011-208106A u BRARS RES PPC ARR 10K BARI HSA (54) 4 Be PROS RAL MARAIS Ri RM URETHANE-BASED PRESSURE-SENSITIVE ADHESIVE AND SURFACE PROTECTIVE FILM USING THE PRESSURE-SENSITIVE ADHESIVE (57) ARARK- BA AWLE > TMA BAER RLSM MARA AR Be Py BRR A + UE A HB A GE BAGG] ARS II PR ABH Ao HID RAR MR DAMM HEAR PRA LAE PR ABE MH: RoR EMR AA HER: EAH MAR GEAR RAHA BORA + BE By 8 Py ak BAG GAR SPRAIY © Bohs RAO SG A A A a RR EAE RE TE AREA ZOE P BRAG ALE A AG SE PAG RA AE AS AS Ah BH S HBA)M S FER HMAC SO n(B) 2 8 SR hh MATS REP RAG BES; IS HAF (A)@# LF 3 fl OW KB HE $34 4-F-E Mn A 8000-20000 2 $ HAF(Al) © Provided is a urethane-based pressure-sensitive adhesive that is excellent in reworkability, initial wettability, and transparency, and is preferably excellent in adhesive residue-preventing property, that preferably has a large wetting rate, and that is preferably prevented from showing external appearance unevenness due to orange peel. Also provided is a surface protective film using such urethane-based pressure-sensitive adhesive in its pressure-sensitive adhesive layer, the surface protective film being excellent in reworkability, initial wettability, and transparency, and being preferably excellent in adhesive residue-preventing property, the surface protective film preferably having a large wetting rate, and the surface protective film being preferably prevented from showing external appearance unevenness due to 1595063 TW 1595063 B orange peel. Further provided is an optical member or electronic member to which such surface protective film is attached. The urethane-based pressure-sensitive adhesive of the present invention is a urethane-based pressure-sensitive adhesive including a polyurethane-based resin, in which: the polyurethane-based resin includes a polyurethane-based resin obtained by curing a composition containing a polyol (A) and a polyfunctional isocyanate compound (B); and the polyol (A) contains a polyol (Al) having 3 OH groups and a number-average molecular weight Mn of 8,000 to 20,000. RRA 10 4 BE A) BAA f Lee + RHA 20+ EMA 2 10+ + + fea ARSE 1 (ll Be Be wap Hx : coos Fok Zs< 12006.01) (anee) co86'ELO 2006.01) KARR AMSA RRARZRERE URETHANE-BASED PRESSURE-SENSITIVE ADHESIVE AND SURFACE PROTECTIVE FILM USING THE PRESSURE- SENSITIVE ADHESIVE Cc] ASWRK-BOKMLE > DH RE SASS we RET GHA RAEER RESET ERA > REBT Ub RG BZ 5] eB ERAS IS IER ASE A ° Sk HR RB ROR RRS AEP RAE RE AES BAKO Het SHER REBELS ER Be AR ERA REBT LARe IR ABR Th > ASEH He BS — RD OS ek A GR OE RE: 7B AB 2 fie A AS RR RS ORIG FARE ARERR GAS TR (ARS SR MBB SWB) ZAG WR Be ZR A | RS TER(A)S RG 3H OW2E BB 78195} F BMnS 8000 ~ 200002 S EAK(AL) © ow crass tse ole i2006.01) 1595063 G32] Provided is a urethane-based pressure-sensitive adhesive that is excellent in reworkability, initial wettability, and trangbarency, and is preferably excellent in adhesive = - residue-preventing property, that preferably has a large wetting rate, and that is preferably prevented from showing external appearance unevenness due to orange peel. Also provided is a surface protective film using such = urethane-based pressure-sensitive adhesive in its pressure-sensitive adhesive layer, the surface protective film being excellent in reworkability, e initial wettability, and transparency, and being preferably excellent in adhesive residue-preventing property, the sur: ace protective film preferably having a large wetting rate, and the surface protective film being preferably prevented from showing external appearance unevenness cue to orange peel. Further provided is an optical member or electronic member to which such surface protective film is attached. The urethane-based pressure-sensitive adhesive of the present invention is a urethane-based pressure-sensitive adhesive including 2 @ polyurethane-based resin, in which: the polyurethane-based resin includes a polyurethane-based resin obtained by curing a composition containing a polyol (A) and a polyfunctional isocyanate compound (B); and the polyol (A) contains a polyol (Al) having 3 OH groups and a number-average molecular weight Mn of 8,000 to 20,000. Q 1595063 (sel) CASE (tia : 38 (1) CARL SEERA] © 1 2M 2 Ewe 10 RARER (AREA CBS aA Lt) ¢ create 3. ” 1595063 Be SS ae (ARBSAA MF HOE ERB) (BHAA) RR AMSA RRR CRORE URETHANE-BASED PRESSURE-SENSITIVE ADHESIVE AND SURFACE PROTECTIVE FILM USING THE PRESSURE- SENSITIVE ADHESIVE CEH] e@ 75 8 A (RBA DS — Te GH A > AL A SMA RMS ZR LAERE SOM PRB AES Bl HE-AMLERRA PMO RELKER- AAD LRA RE REGS ZEEE + TT OU I ze HS RRSRLLCS TARMAC ZRA > SAAR ME RAK TRE ARSA CREREE - hRHZRA RRS BM ERESAR REAR OM RESRERE TAMER LR RB REZ AB ° @ (xn BUSLCD - GREL MARS CMR RR CD DRBF RES 256 BRE FE + DFE DNL + Se + ERR WS SSH LA ER PT TRO BRA RE CSM EL ML BRA RE ALS eT ee i - ARARGRERBR: StPRARET HELMS w HMR PEP MRTRS BERALHE FRAO Fa Te] — 221i ORI > TSI REP R PRS HT RE creases ae 1595063 eS TAGS + RUMME ~ PERG RR Ze TH PR EIR * ABHFLPRMTENRARER ZA ARE SBA RARER ZMBARWZIE - CRS -LRARAREER CELLS ASIT AS A BA R GZ R T > BRD > RE VEER ZR GAAS ZR ATER > RTT > RR SU A TREAD ZIM > AM DNS ee + ETT FDRG SE RES ESHER EER ZA RAMA Reg IRS @ A T° (ERR A Se aR CSR RRM RS (55 FPS I PR A BA PRT PRI» ATH» SEE RE OE A CLRARBR CARRERE > ALB HFL PRN RE CHE AREER RAM RMR MARIZA ° AS TG FR A SAS ZR: PARR BREA BE OY ZR > HET GS (EF Ld OR Oe BH BE ES BARMZAE CRAWABRERG BAS - (RRWRARRAZERE RS RE: ROMMRe 2 kB PRG > HUT ALS A GW Pe RR (5 RO BAR BFF CK 1) Ail: AM 2RPREARS MOAR SA ZR RERS CRB > tL» PA SER Ze RRR AAG + US AED BNO HBS EL CH > ARIA DEA CHE FASS > SRB HF FS TH Ze TRL OR AT aS FeRy > SERA EIR 2 Oh A ES A te Re BOR MEARE ° HE DR DREDS > RETA HS 4B Be SE AS LZ Ae OR ES A BE AT PSRLUBAKA (RARER: RRRERE > SME RH Rl RHR CRARERARAARY MAEKAERER ems toe 22. 1595063 4M - STRRLAME RURAL MERE OAL AR ARE AL EL As AE SH RE AY Se A PBA RH BAS MTR MIAMLE Ri: AMR ORM BERLE Ze bot ES ORC ee A ZALES MSR EL SOR RINE 2 TEBE SE Lt: MRARRE LSE RET MLR Kh LAAT RS bE OR REBELS EET ee + ko SAR RAOLSM ERE ASRS RO REE ROR @ - smi - AA KLE RBS TEER Ze - o 10> SR REE EY II RE ee #0 Lene ce AR: KML ARGABEMEMRRERAL I A Sho PSSA Rb eA 2 RR EB HEA PR ARIS IE EATER) @ (xam) (SEFC HR 1] AR ERIS BN 2006-1827959 9H (ae) (HEOH AF ARAB SM ARH EA MAEM RO MT i DORE BEER RESET OMAR me KEMMRAERA REREM GLA RRA TY S Sh» ASH PRICE DHE Gk Ee RRR» HURL SE A OE HRTRERBEMS AOAC DMM OR ccrnsoa de 3. 1595063 REPEAL LER REBT RRA A > RH TILA SCHR: BN RB CRE MAR RR Ze RE HE > [AR RP A Be HE AE ZA RR AGS A RS RR AB ze EASA A PRK FMM ASRS AS BAS BER ARB 9) (B)iZ 48 Ge WH kT 9 SH eB + wt SCR (A) AAA 3 OE BBE 4 5} F Mn fs 8000 ~ 200002 4 7G BR(Al) KRREZ EMBER ERMSCR(APZERSTBANZS F70B BLE « PREZ AHR : LRMSTRABAAA IML) EONS A WRB 19 F BMnF 5000 F ZB BAZ) » PREZ SHER LRITRAPZERSRBAVZSA Ab 30H BML EF ° BE Z BRE EMR A AES AG HEB ~ RREZ RHEE ERASLAAAK ERAT ANZS e Alb H0.01RB%~ 10H B% ° PORE BT RH ER I RH BE SR RRE ZRH ERG RANK ERAETRAZE ALLA SBE%~50BR% ° aR ag Alt HALAARERAS : Wh FB BG SES AE BA BE HF RS AH AR BHA 6 SHS EAGT AR BD Ze TH PRE * crise see -4 & 1595063 ABB LEPC AAR RE RE (BZ BR] KURA > TH MM IT te + AA «EO TE A MEPL GMMR TEER CEST MEA Bee SMG LAR RLNMTRS LR RE RES BH KB. 5 RA eH ER — eT RR + RP MARMEMS: LOAM MMMM BUEER heme Tr OP A E+ HE TE ARE ETT GLY - Sh > RS RM ERR RU © .ngemLeMeRE TA Cini BRIT] UBL GRA BEB ae eH RH Canis) Ae FE EG 9% BSE HH) ABUL PRE RLSM SSR MR RAIS - ROE PH EME AEE Al oh LOR eS OM AN 2 REE SO ~10H% > HERVE R%~ 100HR% > KM REBION B%~ @ com) HH B 95H R%~ 100K % - ME BOSM%~100 HE % + AGA RPE ZB RR EPS OA I SPA LIEN + BUELL AE + SOA * ES eR REM FLT ME SS (ARS AER MRM LAD (BY A YOR He OR SR STORE (A) & 8 AA 3 (OW SE HB HY 3} Mn FG 8000 ~ 200002 % FEAR(A1) > SICAMAL) AHS — HE >» TNA MALL » STAD ZS TEM ADS OH bh BEE IS TOM AGILE > creseonsse os

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