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  • 1286482-Solution and Colligative Properties Lecture 2

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    1286482-Solution_and_Colligative_properties_lecture_2

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    1286482-Solution and Colligative Properties Lecture 2

    Uploaded by

    gaurav nigam
    Djfjfjfjjf kdjd jdhd kssk spspj ehdh vcv mcnv woeru udjddh lals ksjs bccb Kafka cj djfjdj jffjf jdhd jcjccj

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    LECTURE 2 CLASS 12% CHEMISTRY IIT-JEE/NEET/BOARD LECTURE-2 Solute U/ Solvent i 4 (Smaller) Carger) Change 44 Y doe nok, phase 1. Solidinliguid- Collligative properties are RLV, EBP, DFP, Osmotic pressure 2. Liquid in liquid- Bubble point, dew point, Ideal and non ideal solution, azeotropes, distillation 3, Gasinliguid- Henry's law COSCO E a 1. Molarity a vel L ee " SF mol 2. Molality m of solvent (Kg) Le Menten = ity = ————____ moe 2. Molality =F ivent ka) Ww) 3. % w/w ele 99 ‘Msolution % wie = 100 Vsolution SST (og weer! _ Cow/v)x10 40/4 1. Msolute . % ae oF oli BW g HOG so 2 %w/v=(% w/w) d phy a 3, Ma lOxCewlw xd) Msolute 12 gio 4 ma 1000 11000d—M Mzctuce 5. Gsoutd 1000 _ 1000 ~~ a Geatvend> Meotoent Cy — 0 of \o o is Mh Shia. (eile lado ) [ENSSHEE An aqueous solution contains 28% w/w of 1. O11, If density of solution is 1.25 g/ml then calculate w/v, Molarity, Molality, Mote fraction P° 40 ~~ water, Benzene, Toluene etc. Non — volatile substance : Substances which can not vaporize => P° = 0 Non ~ volatile substance : Substances which can not vaporize => P° = 0 solid, urea, sucrose, Glucose , Na (\ (BREEN «Compare vapour pressure 20 C7H;0H HR bay < sH,OH Me Ss ou S ou Grp TE On increasing temperature KE of molecules increases due to which their tendency to vaporize also increases and vapor pressure increases. pbb vgole)-e Hyo(y) =P MT Gove] T2T, POF DW, ‘ all worst GaP? Gem Toh. en as Hola) = h,o(v) DM © ines ca? dam Toh To Yyn% t Yer A dup of Uy 'S Gnvakd + vapor z BGSproan =O toy big AGY ty Vb aGy AGQ = ASy \yAdp-Sadt = V MS Nwaw (S-) dt Neus )elp as dt=vedp , Yy DVR LAG =VAe -SAT AT Pays Pr ber me = Fl dp Vg = RT As dat > 5 d a o} em, =OU-TeS AS= OH ait Ede B= BAT) Uassiom Uahepn a on( fi . /o i ir If Jere ‘VP « Temperature loa(V2). 2#_ (24 Srp 2303R\T, Tr, AOM=A®@ = AH=+ve By Clausius Clapeyron Equation d(mp) AH dT ‘RT? ate nh AT TRO Re Temperature at which vapor pressure equals the external pressure is known as boiling point . MA Ps OO CA Umpuatuce at waitin yapur presoure Lywars Hie CALLA! PLLosune 19 AU WH as UMS point . Ne If external pressure is 1 bar then it is standard boiling point 1 VP «55 Wy Water: 100°C or 373K 373-15 q Wap Tek Hd 458 mm QZ I5k< (NS — Calculate VP of water at 27°C. HLO@) = HzO) . DKD WYK loo odo Qe 7 Point at which first drop of liquid vaporizes i.e., first drop of vapor is formed. Practically only liquid is present. 2 ye UZ i TL Piso] Pa r Ley \y * os a 27 RaL~ | 7 Babe pad mm Point at which last drop of liquid remains. At Dew point pfactically only vapors are present. lta fy Properties of the solution which depends only upon no. of solute partides and are independent from their nature are known as colligative properties. These are also known as(democratic properties.) NGF Colligative properties are defined for non — volatile solute and for dilute solutions. ure Nad, ven Cree Ge e im \@ Relative lowering in vapor pressure eT Y= Ke \ Gi) Elevation in Boiling point ro) Yee& Give ression in freezing point ~ pyGenatc pressure All Colligative properties are related to each other ie by knowing anyone we can calculate others, depends upon molarity. VP of solution containing non — volatile solute myle cday Dusk ptven ne Naf prews= p? BI@Nayp NP = Ps Ps y= -P* Pos aPoap® = mx Msdvedt (000 ° @ P=’s 3, —© pe Ps = max Malet ~ [006 pa

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