SELEKSI TIM OLIMPIADE KIMIA INDONESIA 2007 TINGKAT PROVINSI ih jawaban yang paling ae "30 pein} 2 terdapat dalam Senyawa A dan B farutan dapat dipisa fraksionasi, dan hal ini dimungkin: (D) warna kristal (a)titik didih (E) kelarutan (B) massa jenis (O)titik leleh Di alam terdapat 2 isotop Boron (B) yaitu eB dengan kelimpahan = {0,013 amu; serta "B dengan kelimpahan 80,22% dan massa = 11,009 amu. Dari data | ini maka massa rata-rata Boron di alam | adalah ... (A) 10,18 amu (B) 10,51 amu (C) 10,81 amu (D) 11,00 amu (E) 11,01 amu Tentukan produk yang dihasilkan bila 2,5 mol (CH) dibakar (sempurna!) CH, +0, + CO, + H,0 (A) 7.5 mol CO, + 4 mol H,O (B)3,0 mol CO, + 10 mol H,O (€)3,0 mol CO, +2 mol HO (0) 75 mol CO, + 10 mol H,O (E) salah semua 4, Bila garam epsom mempunyai formula MgSO,.xH.0 bila dipanaskan pada temperatur 250°C akan mengalami reaksi: MgSO,xH,O(s) -» MgSOx8) + xH,O(g) Bila Ey 061 g MgSO,.xH,0 dipanaskan ternyata terbentuk ‘eabanyak 2,472 g MgSO, Berdasarkann data tersebut, maka 19,78% dan massa hkan dengan teknik | dan B mempunyai perbedaan | > | formula garam epsom adalah (MgSO, = e/mol, dan H,O= 18 g/mol) (A) MgSO,.3H,0. (D) MgSO,.9H,0 (B) MgSO,.6H,O (EB) MgSO,.14H,0 (C) MgSO,.7H1,0 120 Komposisi dari ion adalah proton elektron neutron (A) ou iN 13 (B) i 10 13 OO - 2 N il (D) 12 10 12 ©) 5 MN i Persamaan reaksi manakah yang menunjuk- kan afinitas elektron ke-2 dari sulfur (A) S(s) + 2e + S*(s) (B) S(s) +e + S*(g) (C) S(s) + 2e + S*(g) (D) S(s) +e > S*(g) (E) S{s) +e S*(s) Yang manakah berikut ini yang mengambar- kan energi ionisasi? (A) Energi yang dibutuhkan untuk melepas- kan elektron yang terikat paling lemah dari keadaan dasarnya (B) Ini digambarkan sebagai X +e X-+ cnergi (C) la berkurang dari kiri ke kanan dalam satu periode dalam tabel periodik unsur. (D)la bertambah dari atas ke bawah dalam satu golongan pada tabel periodik unsur. (E) Tidak satupun jawaban di atas benar. Yang manakah zat berikut ini mempunyai karakter kurang ionik dalam ikatannya? (A)CCI, (C)MgCl, — (BE) BaC (B)KCI (D) NaCl —@©. Dariresksidibawah ini yangmoanekah yang | tidak mengerpai tata kovalen? arto H,- (By Se +H, > a5 (C)Cat AO, > C (0) Be + Br > Br, (E)Si+ 2F, > SIF, : Berikut ini. ah formula dot-elektron 2 roe caiiaepat untuk molekul SO, adalah: : A) 6: (E) Semua benar, karena bentuk resonansi H. Yang manakah berikut ini yang dapat ber- fungsi sebagai asam Lewis? (D) *NHs _ (B) :en7 (©) ?Brs* (C) CH;—-S—cHy _ 12. Berdasarkan pembentukan ikatan hidrogen, manakah senyawa-senyawa di bawah ini yang mempunyai titik paling tinggi? (A)CH,-OH ——(D) NH, (B) HO © (E) HS (C) H,0, ra di bawah ini, senyawa manakah (A) memiliki Sepasang ebeby a (B) memiliki 2 Pasang ebeba, (C) memiliki 3 Pasang ¢ beba (D) memiliki ikatan ganda 7" (E) tidak memiliki pasangan ea 15. Dalam senyawa CH,cHs ikatan yang terbentuk Melaluj o,; tery mengikuti orbital hybricn Overly (A) sp? ~ sp! (D) sp'~ sys (B) sp ~ sp? (E) semua be (C) sp — sp? Mar 16. Perubahan entalpi ( AH . APBEC > DIES dint pada kurva entalpi reaksi di bawah in ‘aH Kompleks teraktifkan ata | Berdasarkan kurva tersebut fakta bahwa entalpi D+E+F lebih tinggi dari entalpi A+B+C, Hal ini menunjukkan bahwa . (A) Reaksi ini adalah eksotermik (B) Reaksi ini adalah endotermik. (C) Energi aktivasi dibutuhkan untuk reaksi kebalikan yang lebih tinggi daripaés untuk reaksi ke kanan. (D) Reaksi ini tidak memerlukan katalis. (E) Kompleks teraktifkan untuk reaks) kebalikan adalah spesies yang berbed dari reaksi ke kanan. | 17. Reaksi pembuatan metanol berikut COs) + 2H(g) & CH,OH) AH=-1280 Z ieesatcoinetoom menghasitkan DH adalah :Jarutan HCI 0.) M dan HNO, Tx 104) mempunyai pH yang jauh berbeda dengan pH larutan ampuran (D) HF 0,1 M 10,2 M an (£) H,SO, 0,1 M py HF 02M a C10, M sam astat adalah asar femah dengan nila fetapan kesetimbangan asa, K,= 18x 10° Berikut ini, manakah yang kapasitas buf- fapaling kecil . al 01 M asam asetat/ 0,0) M natrium asetat. (B)0,1 M asam asetat/ 0,1 M natrium asetat. © (C)1,0M asam asetat/ 1,0 natrium asetat. {D)A, B, dan C mempunyai kapasitas buffer yang sama. (E)A.B,dan C tidak mempunyai kapasitas sebagai buffer. 450. Reaksi brominasi ascton berlangsung sebagai berikut: - CH,COCH, (aq) + Br,(aq) > CH,COCH, (aq) + H" (aq) + Br(aq) Untuk menentukan laju reaksinya, diperoleh “data (konsentrasi mula-mula M) sebagai - berikut: M a awal iM) Laju CHLOW(g), CH gy (A)8°(CH,)< S*(CH,OH) < 8"°CHD (B) SCH) H,0,() AH= -188 ki Hyg) + 40,@) > 4,00) AH= -286 ki Nilai AH untuk reaksi: C5,()+ 6H,0,(1) > CO,(g) + 6H,0() + 280) adalah (A)-1175 kJ (D)-3921 kJ (B)-1551 kJ (E) 4000 kJ (C)-1665 kJ dengan jalan (A) merubah mekanisme reaksi (B) menambah besar harga energi aktivasi (C) menambah konsentrasi produk (D) mengurangi perbedaan energi reaksi dari reaktan dan produk (E) semua betul Reaksi kesetimbangan: H,C,0, + 2H,0 = 2H,0°(aq) + ¢,07 (aq) Asam oksalat, H,C,O,, adalah asam diprotik dengan harga tetapan kesetimbangan K, = 5,36x 10° dan K,=5,3 x 10°, Maka harge tetapan kesetimbangan reaksi (K) tersebut adalah .... (A) 5,36x 107 — (D) 2,00 x 10" (B) 5,30 x 10° (E) 2,00 x 10°" (C) 2,80 x 10 : ‘Senyawa CH ,CH,OH mendidih sedangan Cie ang sara. Perbedaan titik didih ost sebabkan oleh: atom relatit ¢ ‘ eo ° petpedant panas pembakaran p) pe (gpa ems y= WOCH,CH,CH, : be rdasarkant konsep kepolaran dan ikatan pideoge”- maka urutan kenaikkan kelarutan att yersebut di atas dalam air adalah; peers XS <2 (pyr<2<¥ (BR)Y AgS(s) (B)Ag*(aq) + S*(aq) > AgS(s) (C)Ag™(aq) + S(aq) — AgS,(S) (D)Ag’(aq) + S*(aq) > Ag,S(s) Magnetite, which has the formula Fe,O,, is comprised of iron(Il) oxide and iron( JI!) oxide. What is the ratio of iron(I1) ions to iron(II) ions in magnetite? (ul (B12 (C23 (D)32 CH, +50, + 3CO,+4H,0. What is the total mass, in grams, of products when 2.20 g of propane is burned in excess oxygen? (a)220 ~ (B)3.60 (€)6.60 -(D)102 What volume, | acid (18.0 M1 12, We a Al pe OE A Me ne mage a sample? (A) 1.28 (B)2.56 Osu (D)9As ‘Under which conditions is the solubility of oxy- gen gas in water the greatest? Pressure Temperature (A) high high () high low © low High @) low low . Which pure compounds form inter-molecular hydrogen bonds? LHF 1. us ul CH, (A) Lonly (B) only (C)landlonly — (D) Hand Ll only |. What is the molar mass of a gas if 10.0 grams of it occupy 4.48 liters at 273 K and 101.3 kPa (1.00 atm)? (A) 2.00 g/mol (B)25.0 g/mol (C)50.0 g/mol (D) 100. g/mot . Which process requires the greatest amount of energy for 1 mole of H,O? (A) breaking the O-H bonds (B) melting (C) evaporating (D)subliming Ifthe circles represent molecules, which diagram provides the best molecular level representa- tion ofa pure solid in the process of melting? (A)18 What can be concluded about the substance represented by this phase diagram? 0 4 6 & ‘Fempernture (C) (A) The normal boiling point of the liquid is BOC. ®B) The solid is more dense than the liquid. (©) The solid sublimes at temperatures above 20°C (©) The vapor can be converted to liquid by compressing it at temperatures below 20°C. 19. A chemical reaction is carried out twice with the Same quantity of reactants to form the same Products but the pressure is different for the two experiments. Which does not change? {A)K,, (B) heat released (aT, (D) work done 20, Which of these conversions has a positive AS°? L combustion of charcoal M. condensation of Br.(g) MW. _ precipitation of AgC\s) (A) Lonly (B) I only (C) llonly (D) Hand {11 only 21. Given these reactions: A> 2B AH=40Ks B+C AH=-s0K 2C-+D AH=-20k) Calculate AH for the reaction; D+A>4C, (A) 100 kJ (©) 40k) (B)-60kKI (D) 100k) “2. Hydrazine,N,H, contains a N-N single bond and 4 N-H bonds. Use bond energies to calcu- the final tem, 21.70, wha tema sete Properties of Water C418 S.g".K- ah 333 ig! (A)2.47g (B)8 63g (103g (D) 110g 24. Which reaction is Spontaneous Peratures at standard pressure and tion? (A) exothermic reaction with a decrease jg entropy (B) exothermic reaction with an increase » entropy (© endothermic reaction with a decrease entropy () endothermic reaction with a increase entropy 25. When 100 mL of 1.0 M HCI is added t piece of CaCO, CO, is produced at a cenay rate. Which of the changes below will NOT = crease the rate of this reaction? (A) adding 100 mt. of 2.0 M HC! in place 100 mL of 1.0 MHC} (B) heating the 100 mL of 1.0 MHCI before adding it to the CaCO, ©) adding 100 mL of 1.0 M HCI to 2020 powdered CaCO, () adding 150 mL. of 1.0 M HCI in place! 100 mL of 1.0 MHCt 26. 2N,H(g) + N,O(g) > 3N,g) + 41,09 isappears at arate of 0.12 molL-min,# at all tem, Concent, (B) 0.12 mol- Lin"! (C)0.18 mol- L>-min” (D)0.36 mol L“-min(a)Rate=HAIB) (B) Rate = A{A){B] (C)Rate = KA}[BP (D) Rate = A[AP(BP 2NO(g)+ Cl(g) > ZNOCL AH =—38k If the activation energy for the forward reaction is 62 kJ, what is the activation energy for the reverse reaction? (A) 24k3 (ek What is the order of a reaction if the rate constant has the units L.mol"'.s!? (A) zero (B) first (C) second (D) third (B) 38k) (D) 100k An iron catalyst is used in the Haber process in which gaseous N, and H, react to produce NH,. What is the role of this catalyst? (A). It provides a pathway with a lower activation energy. (B) It increases the equilibrium constant of 3 the reaction. (© I raises the kinetic energies of the z reactants. (D) It interacts with the NH,. 2NO,(g)+ 7H,(g) 2NH,(g)+ 4,00) What is the correct equilibrium expression for this reaction? [NH]? ia i No,7 tar? e 2 7 “ek, =fNO2 Ha) (NHS? 2 o]* B ox, «lad L.01 (No, P [Hs] _UNH, ]?[H,0]* — OK = [N02]? (C) increasing the vofume of the container (D) adding an inert gas to increase the pressure 33. Which weak acid has the strongest conjugate base? (A) acetic acid (K = 1.8*10") (B) formic acid (K,= 1.8* 10+) (C) hydrofluoric acid (K,= 6.8*10) (D) propanoic acid (K,= 5.5*10°*) 34. What is the pH of a 0.20 M HA solution (K,= — 1,0* 10) that contains 0.40 M NaA? (A)3.15 (B)3.35 (5.70 (D)6.30 35. A0.1 M solution of which salt will have a pH less than 7? (A)NaCl (B)NH,Br (KF (D)NaO,CCH, 36, What is the [Mg?*] in 0.10 M NaF that is satu- rated with MgF, at 25°C? Ksp MgF, 6.4% 10° (A)0.050M (B)1.9*10"M (C)1.2«10°M (D)6.4«10M 37. Which change represents an oxidation? (A)NO* +N, (B) VO — vO (©Clo- + cr | (D)CrO> + Cr,0* 38. What is the oxidation number of Mo in MoO,Cl,? (A)O (+3 os (+6 39. What is the coefficient for H* when the half equation is balanced with the smallest whole number coefficients? ESS EO 5 SOM A tae: (a)2 Ba 6 (8 ‘What is the E° value for the voltaic cell con- - structed from the half-cells? Zn+2e > Zn EP=-0,762 volt ~2. 43. 45, 46. 47. 48. eUNO (A) Lonly Ee AG® description (A) + - spontaneous (B) = > spontaneous © * + nonspontaneous (D) S - nonspontaneous During the electrolysis of a dilute solution of sulfuric acid, what substance is produ-ced at the anode? (A) hydrogen (B) hydrogen sulfide (C) oxygen (D) sulfur dioxide Which metal is the most reactive? (A)silver (B) lead (©) iron (D) cesium Which element has the largest first ionization energy? (A)Li (B)B (C)N (D)Na All of the energy levels listed are allowed EXCEPT (A)3f (B)4d (C)Sp (D)7s A sulfur atom has the electron configu- ration:1s*2s?2p'3s?3p‘. How many orbitals in this ground state atom are occupied by at least ‘one electron? (A)12 (B)9 (C)8 — (D)S The shapes of s and p orbitals are deter-mined by which quantum number(s)? Ln it (A) l only (B) only (C) lf only (D) Hand 111 only What are the elements called for which the 4f subshell is being filled? (A) transition metals (B) metalloids (C) lanthanides (D) actinides Ii.m, ._ Which ionic compound has the smallest lattice energy? (A) NaF (B)Mgo (C)AIN (D) MgCl, Which species have one or more atoms that vio- late the octet rule? - IL SF, 33. 55, 57. . Which family of compounds is used most In which specie: the shortest? (A)CH.NH, (C)(CH)N* ‘arbon-nitrogen bon (B)CH.NH (D)CH,CN In which species is resonance Most useful jp explaining the observed bond lengths? (A) NF, (B)NH (C)NO," (DNO, Which description best represents the hybrig, ization of the C, and C, atoms? (A) C, - sp’, C, - sp* (B)C,~sp'.C, =p? ih te (C)C, - sp’, C, - sp? ea (D) C, - sp*, C, —sp Polar molecules include which of those liste? L.CO, I.COCI, 1.CH,Cl, (A) Lonly (B) Land II only (C)landHfonly — (D) land Ill only Which is an example ofan aromatic com- (A) acetylene (B) benzene (C) polyethylene (D) propanone Which can exist as geometric isomers? (A) I,1-dichloroethane (B) 1,1-dichloroethene (C) 1,2-dichloroethane (D) I,2-dichloroethene Which substance is formed when K,Cr.0 added to C,H,OH in acid solution? (A)C.H, (B)CH,COOH (OKC HO (D)C,H,OC,H, Which functional group, present in simple, is responsible for their high solubility in wate’? (A)-OH (B)-COOH (C)-CONH, (D)-NH, quently as flavoring agents? (A) acids (B) alkenes (C) esters {D) ethers In addition to carbon, hydrogen and which element is found in all amino acids? ) chlorine {B) nitrogen Phosphorus (D)sulfr1. Jikaasam klorida 6 M ditambahkan pada suatu contoh padatan ternyata dihasilkan suatu gas tak berwarna, Apakah Kemungkinan padatan tersebut? (A) kalsium nitrat (B) tembaga (II) Klorida (C) potasium sultat (D) sodium karbonat 2 Apakah perubahan yang pertama kali teramati bila 1,(s) dipanaskan perlahan-lahan pada tekanan satu atmosfer? (A) padatan meleleh (B) padatan menguap (C) padatan pecah menjadi atom-atom. (D) warna padatan menjadi menua 3. Dua senyawa anorganik murni meleleh berturut- turut pada 112°C dan 114°C, Jika sejumlah massa yang sama dari kedua senyawa tersebut _dicampurkan, pada suhu ee aie Hate 4. Apakah yang menjadi alasan utama perasias raksa (daripada memakai air) dalam barometer (A) kerapatan raksa lebih tinggi daripada ar (B) raksa mempunyai titik didih lebih ting; daripada air, © raksa kurang reaktif'secara kimia dibandig air, () raksa memuai pada penurunan tekane udara sedangkan air tidak, S. Bagaimanakah membedakan dua contob padatan putih, timbal (11) klorida dan perk Klorida, satu sama lain? (A) tambahkan 10 mL air dingin pada kedia contoh. Perak klorida akan larut. q (B) tambahkan 10 mL air panas pada keds contoh, Timbal (I!) klorida akan larut. (© tambohkan 10 mL natrium klorida pads kedua contoh, Timbal (11) klorida aka menjadi hangat dan menghasilkan go> lorin. (©) tambahkan 10 mL seng klorida pads keds padatan. Perak klorida akan berubah menjadi logam perak. : “Manakah cara yang benar untuk ~ eairan dalam tabung reaksi?TS Berapakah massa san molekcal ir (dalam gram)? ws (E3,0x10* ®iixte> @)17x10™ Bike azo nitrogen ditunyukkan sebagai Dulatan ita dan atom oksigen sebagai bulatan pati, ah massa molar gas tersebut (dalam g/mol)? (A)28 (B)31_ (C)S4 (D) 36 Suatu campuran 0,100 mo! N, dan 0,200 mol O, dikumpulkan di atas H.O pada tekanan atmosfer 750 mmHg dan suhu 22°C . Berapakah tekanan parsial O, ( dalam mmHg) dalam campuran? (diketahui tekanan uap H,O pada suhu 22°C adalah 22 (A)478 @B)485_—(C) S00. D)SIS Suatu padatan tidak larut dalam air, tidak listrik, dan tidak meleleh dibawah 1000°C. Padatan tersebut adalah ... (A)Pt (B)SiC (cscl, W)C,H, *. Dari sifist-sifat cairan berikut: 1. Tekanan uap U. Tegangan permukaan Sifat cairan manakah yang meningkat bila suhu dinaikkan? (A) hanya I (C)I dan Hl benar (B) hanya ll (D) bukan keduanya Manakah pernyataan berikut yang benar me- ngenai zat yang ditunjukkan oleh diagram fasa berikut?a x | 19. Persamaan manakah yang meounjukkan reaksi untuk entalpi pembentukan standar, SH,°, untuk B,H{(g) pada 298 K dan 1} atm? (A) SB(s) + 9H(g) > BH, (g) (B)2B(s) + 3BH,(g) > B,H,(e) (C)B,@) + Hg) > Bg) (D) 5B(s) + H.(g) > B,H,(@) 2. CH(g)+ O.(g) > 2CO,(g) + 3H,O(g) AH®=~1427,7kI Bila entalpi penguapan untuk H,0(1) adalah 44,0 kJ/mol, berapakah AH? untuk reaksi pembakaran di atas jika yang terbentuk adalah H,O(\) | bukannya H,O(g)? (A)-1295,7k3 (©-1471,715 (B)-1383,7k3 (D)~1559,7kJ Suatu cincin emas seberat 3,81 g dipanaskan hingga 84,0°C dan dimasukkan ke dalam 50,0 g H,O yang bersuhu 22,1°C. Berapakah suhu akhirnya? (Diketahui kalor jenis Au = 0,129 J/g °C; H,0 =4,18 J/g °C) (A)22,2°C (C)26,5°C (B)24,0°C (D)53,1°C 2. Hitunglah perubahan entalpi, AH, untuk pem- bakaran 11.2 L gas hidrogen, yang diukur pada 0°C dan tekanan | atm, membentuk H,O(g). (Diketahui AH,’ H,0(g) =~241,8 ki/mol) (A)-60,5 kJ (C) 484K) (B)-121k (D)-2710k) 23, Reaksi manakah yang berlangsung dengan kenaikan entropi terbesar? (A) HQ) +0,g) > H,0,() (B)Br,() + Fg) > 2BrF(e) (C) Cu*(aq) + Zn(s) > Cu(s) + Zn**(aq) (D)4NH,(g)+70,(g) > 4NO,(g) + 6H,O(@) 24. Diketahui reaksi berikut: N,H,() > N,(g) +2H,(g) AH®= ~50,6 kJ. Reaksi tersebut .... (A) spontan pada semua suhu (B) tidak spontan pada semua suhu _ (C) spontan hanya pada suhu rendah (D) spontan hanya pada suhu tinggi 25, Semua pernyataan berikut diharapkan dapat ‘irrevesibel, ‘mempengaruhi laju: . 280,(g)+0,(g) = 2S0,(g) AH<0 nghasilkan nitrog ety amaan berikut ee AB) (8) > 2N(e) + 6H Bila laju pembentukan'N, poy go® adalah 3,0 mols, berapaken ign sem ah laju penguranga, 02 (A)2,0mol/L.s (©4,5 mols (B)3,0mol/L.s (D)9,0 mols } Manakah satuan dari tetapan laju untuk ray orde kedua bila laju dinyatakan dalammolt«) (ays? (C) L.mol, = (B) mot! (D) mols Untuk reaksi: (CH,),CBr(aq) + OH (aq) > (CH,), COH(aq) « Br(aq) ditemukan bahwa bila konsentrasi (CH,) cj, diperkecil menjadi setengah kali akan men. babkan laju reaksi menjadi setengah ali semuiy tetapi bila konsentrasi OH diperkecil menjag setengah kali tidak berpengaruh pada laju reais Bagaimanakah hukum lajunya? (A)laju=k [(CH, ), CBr]! [on | (B)laju=k [(CH ); CBr} [on™ | (C)laju=k [(CH, ), CBr]? (D) laju=k [(CH, )3 CBr] Suatu katalis mempercepat reaksi kimia dengan cara. (A) menggeser kesetimbangan (B) menaikkan energi aktivasi (C) menurunkan entalpi reaksi (D) menyediakan jalan reaksi alternatif . Energi aktivasi untuk suatu reaksi dapat diter tukan dengan mengukur laju reaksi pada (A) suhu yang berbeda (B) konsentrasi katalis yang berbeda (C) konsentrasi pereaksi yang berbeda (D) kurva waktu vs reaksi Perubahan manakah yang akan memperbest jumlah SO, pada kesetimbangan? I. menaikkan temperatur Il, memperkecil volume III, menambahkan He untuk memperbesit tekanan — ©ldan il oat (Dy dan ___olimpiade eeoy Hagaimanakah tetapan Aesotlinbangan woth peaks DEensia) + 30,(8) 9 22RO()+ 280g) a © __afzno][so.] Xo*sfens]fo, 7 @) 2 Iso, ?? x - ae [so, fens} [0 ‘Berapakah pH larutan HINO, 0,001.5 M? ial (Ess (22 (D)IS Dalam larutan asam format (K, * 1,7x10~, Konsenteasi ion hidrogen [H°} * 2,3x10°. Berapakah konsentrasi asam format dalam mol? {A)72x 10" (C)53x 10° (B)3.18 107 (D)3,9x 10" [H’] dalam larutan yang mengan- dung [HA] =4,0x107 dan [A"]=2,0x10 a= 3,0x10°) f (C)6,0x 10" {A)ESx 10° (B)3,0x10* (D)3,8x 10" 40 (AYCIO, (B) De Wil reaksi CIO, + fr» CI, + By dsotaraskan, berapakah perbandingan tir / C10)? (AVL (aL CME dd) 5h Diketahul potensialreduksi standar Zn"(aq) ¢ 2e > Zante) re 0760 V. TH(ag) te > Th) t= 0,6V Rerapakah potensial sel standar, By nth reas: Za(a) + 2TH (aq) oe Zo ag) + 27K) (A)0a27V (C)-0,091V (B)0,091V (D) 0,427 Diketahui potensial reduksl standar Cr'(ag) + @ > Cr*(aq) BY 0,408 ¥ Cur(aq) Fe Cur(ag) B= +0, 101V. Fe'"(aq) te» Fe(ag) i +0,769V Berdasarkan potensial reduksi standar di atas, reaksi manakab yang berlangsung spontan’? 1. Ce*(aqytFe!"(aq) > Cr"(agyFe**(aq) 11,Cu®*(agy? Fe®(aq) > Cu'(ag)! Fe!(aq) (A) hanya I () Idan (B) hanya I (D) tidak keduanya Larutan AgNO, CuSO, dan AuCI, dielektrolisis seperti dalam gambar berikut, Jika proses elektrolisis dihentikan sebelum ada jon-ion yang mengendap sempurna, bagaimanay ah perbandingan jumlah mol (n) endapan Ag, Cnn? My Cudan Au? nH (D) OM? Baw | A), Moy "Baa bilangan kuantum (1, l,m, m,) eh, (yb, Bysshe }. Sekumpulan ‘manakah yang tidak diizinkan oleh aturan -mekanika kuantum?iA) towp {C) radioaktivitas Moor, {B) toikiometni (D) spetra atomik {A)N,OLP 46. Manakah pernyataan yang benar mengenai )M,,F,,0, ore ukuren atom dan ion-ionnya? $4. Moleku! manakah yang mensang... (A) Kation lebih kecil dibanding atomnya, sigma (o) dan dua hater ag HE aay sedangkan anion lebih besar ACH, oor (B) Kation dan anion keduanya lebih kecil (B)CH, Men dibanding atomnya. = (© Kation dan anion Keduanya lebih besar | °° to iae: pe dibanding atomnya. 8 Wa (| Merobeana (D) Kation lebih besar dibanding atomaya, ost. sedangkan anion lebih kecil. 56. Senyawa manakah yang merupakan aldehesy 47 Bila atom-atom: Li, Be, B, Na, disusun ber- erie resto dasarkan kenaikkan jari-jari atom manakah % ee susunan yang benar? 57. Berapakah jumlah isomer yang terdapat pay {A)Li.BeB,Na— (C)Na,Li,Be,B dibromobenzena (C,H,Br,)? (B) Li, Na, B, Be (D) B, Be, Li, Na (A) sata (C)tiga (B)dua (D)empat 48__Jenis peluruhan radioaktif manakah yang meng- hasifkan inti anak dengan nomoratom lebih tinggi? | $8. Apakah nama untuk senyawa dengao strskny. é (Aye BB Oy OP sebagai berikut : 49. Spesi manakah yang atom pusatnya TIDAK oe 4 dikelilingi oleh 8 elektron valensi? cu—cn, (A) BF (cyPcl,; Se (BYNCI, (D)SF, eae 30. Manakah pasangan berikut yang keduanya yew, ‘ACO, dan H,0 —_ (C) SO, dan SCI, al i e =butene (B)BF, dan PCI, (D)CS. danNO. eee : 1. ton nitrit dapat dinyatakan sebagai berikut: (C)2-metit-3-sopropil-L-butena ‘Struktur msnakah yang mung- | , be Reg) (D)2,3,4trimetil-1-pentena kin untuk menggambarkan ==—=y- | $9. Apakat hibridisasi atom karbon 1, 2, } betura bentuk resonansi dari ion fy fi=5-3 turut yang dituajukkan oleb struktur bert sitrit tervebut? 9 (A) hanya 4 (C)} dan It (B) hanya I! (D) kedunnya salah Mado to" ‘a > (A) sp (C) sp, 90" (B) sp’. sp. sp’ (D) sp’, 997.57» ©. Bite puti tetur menggumpaan prove? (A) teekondensasi (Cyretbidrais ‘(B)serdenacurast (Dreyer1 2 i | a 4. 7 SAMIR rs ole 2220 | ste oe ep O42 Piss — 38 — Ista | = 5 e\f7 |e is 5 2a Ihe Gr || mn |} Fe |! co |} wi |! cu || 20 eae os 200 || sae || sss || sass |Lsseo || ass J] enat Hl Be | a Zire lays | «la | « a lee mo || Te || ru || an || Pa || ag || ca = els sss || coe || ors || 22s |] 1054 J] sor || 2a wall yl 2 7% \{75 |{ 7 lf 7 |{ 78 |{ 79 If 60 = Peis w || re || os |] tr || pt |] aw |) Ao a renee |{ soe JL gaa |L o22 || ws. | ss70 JL some ao het | & 706 |f 107 | woe If 108 Jf 110 |[ 7 If a1 76 — & || oh || Hs || me || os |} Us || vu Gun | xe) || 2x2 || cs || asm |Larn |Lom JL am on fs || wo | et lf ez |[ @ lf e lf eo |[ @ lf @ |f @ |[ © If 70 If | ce |} Pr || wa || pm || sm |] eu || ca |] me || by |] He |) er |] tm |) vp |) ow | 349.1 || sao || 1252 || vas |[_sea || 520 || 1573 || eso || sez || voce || ors JL sees JL erse JL eze0 | oy iT a2 lio im ifs Ie 1 7H x IT @ If If so | 21) wo Tr |] pe |] U |] ap | Pu |] am || cm | mu |) ot |] as || Fm |] ma || Ne |) | 2220 || ce JL amo || asm |L aan |Lcey JLo |Laen JL asn JL sm Jl asn |Lcsm || cam J] ce DIRECTION When you have selected your answer to each question, blacken the corresponding space ox the answer sheet using a soft, #2 pencil. Make a heavy, full mark, but no stray marks. If yo, decide to change an answer, erase the unwanted mark very carefully. There is only one correct answer to each question. Any question for which more than one response has been blackened will not be counted. Your score is based solely on the number of questions you answer correctly advantage to answer every question. Which element is a gas at 25°C and | atm pres- sure? (A) chlorine (B) phosphorus (C)silicon (D) sulfur “Which combustion product is produced THE LAST by gasoline-powered vehicles? (A)CO, (B)H,O (NO, (D)S0, Which clement has the highest electrical con- ductivity at room temperature? (A)Ge (B)Se (C)Sn ()Te How should a student prepare 100 mL ofa 1.0M. H,SO, solution from a 10M solution? (A) Add 90 ml. of H,Oto 10 mi. of 10M H.SO,. (8) Add ail ae aera It is your (C) Add 10 mL of 10 MH,SO, to 80 mL of HO, stir and dilute to 100 mL after allowing cool. (D) Add 80 mL of H,0 to 10 mL of }OMH,SO, stir and dilute to 100 mL after allowing to cool. Which letter in the dia- A—, gram depicts the hottest portion of a Bunsen bumer flame? (AVA @®) B oc @)D What isthe power technique ots the odor of a vapor ina test tube?(A) Hold the test ‘tube near the nose and sniff, (B) Use a micropipet to capture some of the and sniff that. Hold the fest tube above the nose and pour the gas toward it )) Hold the test tube near the nose and waft the gas toward it with a hand, For which compound are the empirical and mo- jecular formulas the same? (A)CH,COOH (B)C,4,(COOH), {QHOOCCOOH —_(D)CH,COOH What the volume of liquid A has the same mass 35 80,0cm’ of liquid B? Density (g/em’) of liquid A = 0.660 and liquid B & =159. (a)40.0cm' (B)97.0em’ ()160.0cm" (0) 193.0cm! o How many water molecules are in a 0.10 g sample of CuSO, 5H,0 (M, = 249.7)? (aylox1o" (B)2.4x 10" (€)2.4x10" (D)1.2x 10 10. Acetylene, C,H,, reacts with O, to produce CO, and H,O. What is the O/C,H, “ratio in the bal- anced “equation? (avi (B)32 (Os2 ()3/ , Mg(OH), in the from of Milk of Magnesia is used to neutralize excess stomach acid. How many moles of stomach acid can be neutralized by 1.00g of Mg(OH),? Massa molar Mg(OH), = 58.33 g/mol (A)O0I71 (B)0.0343 (0686 (0125 ‘12. A25.00mL sample of 0.0150 M H,SO, is titrated _ with a NaOH solution of unknown concentra- tion. The phenolphthalein endpoint was reached when 17.23 mL of the NaOH solution had been Mass of flask + oxygen = 125.10.g Mass of flask + unknown gas ™ 125.34 g (A) 22 g/mol (B) 38 g/mol (C) 44 pmol (D) 84 g/mol 14, Which pair of gases has the same average rate of diffusion at 25 °C? (A) He and Ne (C)N,Oand CO, (B)N, and O, (D)NH,and HCI . According to the phase diagram shown, in what state does the represented substance exist at 1.0 atm and 0.0 °C? 2.0) (A) solid only (B) liquid only (C) gas only (D) solid and liquid only 16. What is the most effective way to condense a gas? (A) Decrease the temperature and in-crease the pressure. (B) Decrease the temperature and decre-ase the pressure (© Increase the temperature and decrease the pressure. (D) Increase the temperature and increase the pressure. 17. Which liquid has the highest vapor pressure at 25°C? (A) butane, C,H, (B) glycerol, C, HOH), (C) octane, C,H, (D) propanol, C,H,OH 18. Which oxide has the highest melting point?(D) 2Na‘(aq) + 20H (aq) + CO.(aq)—> Na,CO,(s)+ 4,0 ‘2D. Which applies to any endothermic reaction? (A) AHO (B) AHO OaGo MGo | | | | | 21, When a bomb calorimeter is used to determine | the heat of reaction, which property of the sys- tem under investigation is most likely to remain | constant? | (A) number of molecules | (B) pressure | (©) temperature @®) volume | | | | | eS ee a 2. For the reaction shown, which is closet to the ; value of AH? 2Cr?"(aq) 4 Ni(s) + 2Cr(s) + 3NF*(aq) AH, CP” (aq) = 143 ki/mol AH)? Ni®* (aq) =~ (A) 124 kd (C) 89k) 54 kJ/mol (B89 (D)- 1244 i ‘An ice cube at 0.00°C is placed in 200. g of dis- tilled water at 25.00°C. The final tempe-rature afier the ice is completely melted is $.00°C, What is the mass of the ice cube? (AH,, = 340. g', C, =4.18 3g" °C") (A)23.6g (B)463¢ (©)50.0g (D) 800g 24. Which reaction occurs with the greatest increase 3B in entropy? (A)2H,0() + 2H,(g) + O.(g) (B)2NOw) > Ni@)~0.(8) (CG) + Of) + CO@) *@)Br(g)+ Cl (g) > 2BrClig) 2S. Forarate law of the form; Rate = k[A}"[BJ, the exponents m and n are obtained from (A) changes in rate with changing tem-perature, (B) the coefficients of A and B in the balanced ‘equation, {C) the concentrations of A and B in a single ‘experiment, (D) changes in the reaction rate for different concentrations of A and B. 26. What is the order of a reaction for which the suet ne nels 4 te wale the rate 31. ah Fate law of the oe ‘Shange(s) wl increase rows I Increasing the cones Tl Increasing the concentration ot 6 (A) Vonly (B) I onty (C) Both I and Hi (D) Neither f nor 11 Which does NOT chan, Sans Be with time forthe fy (A) the amount of reactant that disappear each halflife E 5 (B) the concentration of the reactant (©) the length of each half life (D) the rate of the reaction The rates of which reaction are increased whey the temperature is raised? 1. Endothermic reactions Il, Exothermic reactions (A) Lonly (B) only (C)Both land! (1D) Neither I norit When a catalyst is added to the system repre, sented by this energy-reaction coordinate dy. gram, which dimension in the diagram ye changed? (A) 1 and 2 only (B) 1 and3 only (C)2and3 only (D)1,2,3 | Which statement is true for a reaction at equil> rium? ; (A) ll reaction has gone to completion (B) the reaction has gone to completion © ee ©) the snout eg he ma of reactant For the hypothetical reaction, 2A(s) + B(g) % 3C{g) whars the ulin ‘expression? i |: fcr (D) K TBI 1 ee 10 fa}? +18) 3, Acetylsalicylic acid (aspirin) behaves as an acid ‘according to the equation shown. Calculate K, forthe C,H,0, (aq) ion. (K, = 3.0x 10°) HIC\H,0,(29) + H,0 5 H,0°(aq) +C,H,0, (aq) (A)3.0x 107 (B)9.0x 10" (€)9.0x10" (D)3.3x 10° ‘What will happen to the pH of a buffer solution when a small amount of a strong base is added? ‘The pHwill (A) increase slightly (B) decrease slightly (C) remain exactly the same (D) become 7 When a solution of NH, (K, = 1.8 x 10°) is ti- trated with a strong acid the indicator used ‘should change color near a pH of al @®5 ©F OB "When solid silver ‘chloride (M, = 143.4)is: added ‘to 100ml. H,O, 1.9.x 10+ grams dissolves. What “isthe K,, for silver chloride? (B)3.7x 10% (D)1.8x 10" n which species does the underlined element we an oxidation number of +27 (D) Negative ions are formed. 2Ga(s) + 6H"(aq) > 2Ga°*(aq) + 3H,(g) The po- tential of the cell for the raction given is 0.54 V. If the concentrations of the ions are 1.0 M and the pressure of H,(g) is 1 atm, what is E? for the half- reaction Ga™(aq) + 3e"-> Ga(s) (A)-0.54V (B)-027V (Q027V (D054 V All of the following affect the number of moles of metal deposited during electrolysis EXCEPT the (A) current used (B) electrolysis time (C) charge on the ion (D) molar mass 43. The emission spectrum of hydrogen in the vis- ible region consists of (A) a continuous band of light. (B) a series of equally spaced lines. © a series of lines that are closer at low energies. (D) a series of lines that are closer at high energies. 41. 4 6 44, Which atom in its ground state has the most unpaired electrons? (A)Ge (B)As (C)Se (D)Br 45, An monoatomic ion that ground state has 18 electrons and a +2 charge (A) has 16 protons. (B) has the symbol Ar. (C) has 18 neutrons. (D)is isoelectronic with Ar 46. Which atom has the largest atomic radius? (A)Li (B)K (C)As (D)Br 7. What is the maximum number of electron that ‘occupy the n + 3 level? 8 - (DIScng ee 49, Which species contains only covalent bonds? | (A) 1,80, (B)NH,NO, | (C) NaOCl (D)K,CrO, 50. How many valence electrons are in the pyro- | 56. phosphate ion, P,0,? (A) 8 (B)52 (©) 54 (D)56 Which spesies has the largest F-A-F bond angle where A is the cental atom? | (A)BP, (B)CF, (ONF, (D)OF, The triple bond in carbon monoxide consists of (A) 3 sigma bonds (B)2 sigma bonds and 1 pi bond (C) | sigma bond and 2 pi bonds (D) 3 pi bonds 5] 5 u 58. 33 The boiling points ofthe halogens, F, Cl,, Br, | | and 1, increase in that order. This is best attri. buted to differences in | (A) covalent bond strengths. (B) dipole forces. (C) London dispersion forces, (D) colligative forces, 59, 60. Which species is polar? (A)co, ()s0, (B)SO, | @)o, | 57. wi formula repre; n-butane? (A)CH,CH.CH.Ch, (©CH),.cHCH, (B)CH.-CHCH CH, @CH),cH * How many structural js isomers have the formy CHCl? a (A)1 2 (3 (D)4 What is the hybridization of the carbon atom, acarboxyl group? (A) sp (B) sp? (C) sp’ (D)sp* A reaction in which a carboxylic acid an alcohol to from an organic com water is called (A) esterification (B) hydrolysis (C) neutralization (D) saponification Teacts wig POUN ang What substance is formed wher CF CP. gpg, lymerized? (A) Polyethylene (B) Polyurethane (©prve (D) Teflon Most enzymes are a type of (A) carbohydrate” (B) lipid (C) nucleic acid (D) protein Keseluruhan ujian terdiri dari 60 butir: pilihan berganda dengan tingkat kesulitan yan Olimpiade