BOTAI NGUYEN VA MOI TRUONG CONG HOA XA HOI CHU NGHIA VIET NAM . Dée Lip - Tw do - Hanh phic $é:47 /2011/TT-BTNMT Ha N6i, ngay J fthang 12 nam 2011 THONG TU Quy dinh guy chuan ky thuat quéc gi noi trudng BQ TRUONG BO TAI NGUYEN VA MOI TRUONG C&n ctr Lut Tiéu chuan va Quy chuan ky thuat ngay 29 thang 6 nam 2006; Can eit Nghi dinh sé 127/2007/ND-CP ngay 01 thang 8 nim 2007 cia Chinh pha quy dinh chi tiét thi hanh mét sé dieu cia Luat Tiéu chudn va Quy chuan ky thudt; Can ott Nghi dinh s6 25/2008/ND-CP ngay 04 thang 3 nam 2008 ciia Chinh phi quy dinh chite nang, nhiém vu, quyén han va co cau t6 chite cia BO Tai nguyén va Méi trudmg, da duge sita doi, bé sung tai Nghi dinh s6 19/2010/ND- CP ngay 05 théng 3 nam 2010 cit Chinh phi va Nghi dinh s6 89/2010/ND-CP ngay 16 thang 8 nam 2010 cia Chinh phi; Theo dé nghj cia Téng Cue trudng Téng cue Méi trudng, Vu truéng Vu Khoa hge va Céng nghé, Vy truéng Vu Php ché, QUY DIN! Diéu 1. Ban hanh kém theo Théng tu nay quy chudn ky thuat quée gia ve mdi trudng: QCVN 40:2011/BTNMT - Quy chuan k¥ thuat quéc gia vé nude thai céng nghiép. Diéu 2. Théng tu nay cé higu lyc thi hinh tir ngay 45 thang 02 nam 2012 Dieu 3. Tong Cuc trudng Téng cyc Méi trudng, Thi truéng cdc don vi thuge BO Tai nguyén va Méi trudng, Giém doc Sé Tai nguyén va Méi trugng cac tinh, thanh pho trye thuge Trung wong va cac té chtrc, cd nhan lién quan cd tréch nhiém thi hanh Thong tu nay/. KT. BO TRUGNG Noi nhgn: ( ‘ONG - Van phong Trung wong va cé Ban eta Bang, = Van phng Quoc hoi; = Van phong Chi tich nude; ~ Van phing Chinh phils Toa an nhan dan tdi cao, - Vign Kiém sat nhin dan t6i cao; ~ Cae BO, co quan ngang bd, co quan thude Chinh phis - Co quan trung wong ca cée doan thé; - HDND, UBND cic tinh, thanh pho truc thuge TW; = $6" nguyén va Mai trudng cic tinh, thin phd tre ge TW: van ban (B6 Tu php); ng bao; Céng TTDT cia Chinh phi; ~ Cée don vj thue B6 TN&MT, Website ciia BO TN&MT; = Luu: VT, TCMT, KHCN, P¢ Sela Bye. VinunetcomunCONG HOA XA HOI CHU NGHIA VIET NAM QCVN 40:20114/BTNMT QUY CHUAN KY THUAT QUOC GIA VE NU'OC THAI CONG NGHIEP National Technica] Regulation on Industrial Wastewater HA NOI- 2014 VinangtscomunQCVN 40: 2014/BTNMT Loi noi dau QCVN 40:2014/BTNMT do Ban soan thdo quy chudn ky thuat quéc gia vé chat luong nude bién soan thay thé QCVN 24:2009/BTNMT, Téng cyc Méi truéng, Vu Khoa hoo va Céng nghé, Vu Phap ché trinh duyét va duoc ban hanh theo Théng tu s6..4:%.. /2014/TT-BTNMT ngay.. 2.3... thang 12 nam 2011 cla Bé truéng BO Tai nguyén va Méi trudng. VinunetcomunQUY CHUAN KY THUAT QUOC GIA VE NU‘OC THAI CONG NGHIEP National Technical Regulation on Industrial Wastewater 1. QUY BINH CHUNG 4.4. Pham vi digu chinh Quy chudn nay quy dinh gia tr t6i da cho phép cla cdc théng sé 6 nhiém trong nuée thai céng nghiép khi x4 ra ngudn tiép nhan nue thai 1.2. B4i tugng ap dung 1.2.1. Quy chudn nay ap dung déi voi t htc, ca nhan lién quan én hoat déng xd nuée thai cong nghiép ra ngudn tiép nhan nue thai. 1.2.2. Nuéc thai céng nghiép cia mét s6 nganh dac thi: duge ap dung theo quy chuan ky thuat quéc gia riéng. 1.2.3. Nu6c thai céng nghiép x4 vao hé théng thu gom cia nha may xi ly nuée thai tap trung tuan thd theo quy dinh cla don vi quan ly va van hanh nha méy xt ly nuéc thai tap trung, 1.3. Giai thich thuat ng Trong Quy chudn nay, cdc thuat ngir duéi day due higu nhw sau: 1.3.1. Nu6e thai céng nghiép la nue thai phat sinh tir qua trinh cong nghé clia co sé san xuat, dich vu céng nghiép (sau day goi chung la co sé céng nghiép), tt nha may xt? ly nuéc thai tap trung co ddu néi nude thai cla cos cong nghiép. 1.3.2. Ngudn tiép nhan nuéc thai la: hé théng thoat nude dé thi, Khu dan cu; séng, sudi, khe, rach; kénh, muong; hd, ao, dim; vung nuéc bién ven bo ©@ mue dich st dung xe dinh. yy VinangtscomunQCVN 40: 2014/BTNMT 2. QUY DINH KY THUAT 2.1. Gia tri t6i da cho phép cia cac thong s6 6 nhiém trong nuec thai céng nghiép khi xa vao ngudn tiép nhan nuéc thai 2.1.1. Gia tri t6i da cho phép ctia cdc théng sé 6 nhiém trong nuéec thai céng nghiép khi x4 vao ngudn tiép nhan nu@e thai dec tinh ton nhu sau: Cmax = C x Kq x Ke Trong do: - Cmax Ia gia tri ti da cho phép clia thong sé 6 nhiém trong nuéc thai céng nghiép khi x4 vao nguén tiép nhan nude thai. - C la gia tri clia théng s6 6 nhiém trong nuéc thai céng nghiép quy dinh tai Bang 1; - Kq la hé s6 nguén tiép nhan nue thai quy dinh tai muc 2.3 tng voi luu lwong dong chay etia séng, sudi, khe, rach; kénh, murong; dung tich cla hd, a0, am; muc dich sir dung ctia ving nuéc bién ven bo; - Kf la hé sé lwu Ivgng ngudn thai quy dinh tai muc 2.4 tng voi téng lwu lwong nue thai cia cdc co sé céng nghiép khi xa vao nguén tiép nhan nude thai; 2.1.2. Ap dung gia tri ti da cho phép Cmax = C (khéng ap dung hé sé Kq va Kf) d6i voi cdc théng sé: nhigt d6, mau, pH, coliform, Téng hoat 46 phéng xa a, Téng hoat 46 phéng xa B. 2.1.3. Nu@e thai céng nghiép x4 vao hé théng thodt nude dé thi, khu dan cu chua cé nha may xi ly nuée thai tap trung thi 4p dung gia tri Cmax = C quy dinh tai cOt B Bang 1. 2.2. Gia tri C cla cac théng sé 6 nhiém trong nwée thai cong nghiép dugc quy dinh tai Bang 1 Bang 1: Gia trj C cia cdc théng sé 6 nhiém trong nwéc thai céng nghiép Don Gia tC TT Thong sé “i r L 7 1 | Nhiét d6 ba 03 40 40 2 | Mau PUCO 50 150 | 3 [pH 7 6dén9 | 554609 4 | BODs (20°C) ‘mg/l 30 50 ye 4 VinangtscomunQCVN 40: 2011/BTNMT 5 [CoD mg/l 75 150 6 | Chat ran \o Iveng mg/l 50 100 7 |Asen mg/l 0,05 01 8 | Thuy ngan mg/l 0,005 0,01 9 [Chi mg/l 0,1 05 10 | Cadimi mg/l 0,05 0,1 41 | Crom (VI) mg/l 0,05 0,1 412 | Crom (It!) mg/l 0,2 1 13 | dng mg/l 2 2 14 | Kém mg/l 3 3 15 | Niken mg/l 0,2 05 16 [Mangan mg/l 0,5 1 17 | Sat mg/l 1 5 418 | Téng xianua mg/l 0,07 0.1 419 | Téng phenol mg/l 01 05 20 | Téng dau mo khoang mg/l 5 10 21 | Sunfua mg/l 0,2 05 22 | Florua mg/l 5 10 23 | Amoni (tinh theo N) mg/l 5 10 24 | Téng nit mg/l 20 40 25 | Téng phat pho (tinh theo P) | mg/l 4 6 Clorua 26 | (khéng ap dung Khi x4 vao mg/l 500 1000 ngudn nuéc man, nuéc lo) 27 | Clo du mg/l 1 2 28 Tora now enet Leech eed Earl 0,05 o4 ‘éng hoa chat bao vé thyc cd Te ne pho hu SO : i - 30 | Téng PCB mg/l 0,003 0,01 31 | Coliform vikhuan/ | 3900 5000 100ml 32 | Téng hoat 46 phéng xa a Ball 0,1 0,1 33 | Téng hoat a6 phong xa B Ba/l 1,0 1,0 VinangtscomunQCVN 40: 2011/BTNMT Cét A Bang 1 quy dinh gid tri C cla cdc théng sé 6 nhiém trong nuréc thai cong nghiép khi x4 vao nguén nude dugc dang cho myc dich cdp nuéc sinh hoat; Cét B Bang 1 quy dinh gia tri C cla cdc théng sé 6 nhiém trong nue thai céng nghiép khi xa vao ngudn nude khéng ding cho muc dich cép nwéc sinh hoat; Mu dich sir dung cia nguén tiép nhan nue thai duc xac dinh tai khu vue tip nhan nude thai. 2.3, Hé sé nguén tiép nhan nwéc thai Kg 2.3.1. Hé sé Kq ting voi Ivu lwgng dang chay olla sng, sudi, khe, rach; kénh, muong dugc quy dinh tai Bang 2 dudi day: Bang 2: Hé sé Kq teng voi lwu tugng dong chay cia nguén tiép nhan nuéc thai Luu lwgng dang chay cia ngudn tiép nhan nuoc thai (Q)| by 3 He sé Kq Bon vi tinh: mét khéi/giay (m/s) aQ<50 oo | 80 500 1.2 Q duge tinh theo gia tri trung binh lwu Ivong dong chay cila ngudn tiép nh€n nuéc thai 03 thang khd kiét nhdt trong 03 nam lién tiép (sé ligu cla co quan Khi tveng Thuy van). 2.3.2. Hé s6 Kq tng voi dung tich cla nguén tiép nhan nuéc thai !a hd, ao, dam dugc quy dinh tai Bang 3 du6i day: Bang 3: Hé sé Kq tng voi dung tich cua ngudn tiép nhan nude thai 7 Dung tich ngudn tiép nhan nude thal (V) i ‘Don vi tinh: mét kh6i (m*) Hg 86 Kq VS10x 10" : 06 T 10 x 10° 100 x 10 1,0 VinangtscomunQCVN 40: 2014/BTNMT V duge tinh theo gid tri trung binh dung tich cia hd, ao, dam tiép nhan nu@c thai 03 thang khé kiét nhat trong 03 nam lién tiép (sé ligu ctia co quan Khi tuong Thuy van). 2.3.3. Khi ngudn tiép nhan nude thai khong co sé liéu vé Ivu Ivong dong chay cia séng, suéi, khe, rach, kénh, muong thi ap dung Kq = 0,9; hé, ao, dam khéng cé sé ligu vé dung tich thi 4p dung Kq = 0,6. 2.3.4. Hé 86 Kq déi voi nguén tiép nhan nue thai la ving nude bién ven be, dam pha nuéc man va nuéc Ig ven bién. Vung nuée bién ven be ding cho muc dich bao vé thuy sinh, thé thao va giai tri duéi nudc, dam pha nuéc man va nuéc Ig ven bién ap dung Kq = 1. Ving nuéc bién ven be khéng dling cho myc dich bao vé thuy sinh, thé thao hode giai tri duéi nuée ap dung Kq = 1,3. 2.4. Hé sé Itru lugng nguén thai Kf Hé sé luu lugng nguén thai Kf due quy dinh tai Bang 4 dui day: Bang 4: Hé sé Iu Ivgng nguén thai Ke Lwu lwgng ngudn thai (F) ; on vi tinh: mét khdiingay dém (m°/24h) teens F<50 12 50 5.000 0.9 Luu lvgng ngudn thai F duoc tinh theo Iu lung thai lon nhat néu trong Bao cdo danh gia tac dong méi trudng, Cam két bao vé méi trvong hoac BB dn bao vé méi trueng. 3. PHUONG PHAP XAC BINH 3.1. Lay mau dé xac dinh chat lugng nuéc thai 4p dung theo hong dn ctia cac tiéu chuan quéc gia sau day: - TCVN 6663-1:2011 (ISO 5667-1:2006) ~ Chat lvong nwéc — Phan 1: Hwéng dan lap chyong trinh ldy mau va kj thuat ly mu; - TCVN 6663-3:2008 (ISO 5867-3: 2003) - Chat lvgng nude - Lay mau. Huong dan bao quan va xi ly mu; - TCVN 5999:1995 (ISO 5667-10: 1992) - Chat lvgng nude - Lay mau Huong dan ldy mau nude thai, ber VinangtscomunQCVN 40: 2044/BTNMT 3.2. Phwong phap xac dinh gia trj cac théng sé kiém soat 6 nhiém trong nwéec thai céng nghiép thc hién theo cac tiéu chudn quéc gia va quéc té sau day: - TCVN 4557:1988 Chat lvgng nue - Phuong phap xac dinh nhiét 46; - TCVN 6492:2011 (ISO 10523:2008) Chat lvgng nwée - Xac dinh pH: - TCVN 6185:2008 - Chat lveng nude - Kiém tra va xac dinh mau sac; - TCVN 6001-1:2008 (ISO 5815-1:2003), Chat lwgng nuéc - Xac dinh nhu cau oxy sink héa sau n ngay (BOD) — Phan 1: Phuong phap pha loang va cay 06 bé sung allylthiourea; - TCVN 6001-2:2008 (ISO 5815-2:2003), Chat lveng nue - Xac dinh nhu cau oxy sinh héa sau n ngay (BOD,) — Phan 2: Phuong phap ding cho mau khéng pha loang; - TCVN 6491:1999 (ISO 6060:1989) Chat Jung nue - X4c dinh nhu cau oxy hod hoc (COD); - TCVN 6625:2000 (ISO 11923:1997) Chat wong nude - Xac dinh chat rn lo Iteng bang cach loc qua cai loc soi thuy tinh; - TCVN 6626:2000 Chat lugng nue - X4c dinh asen - Phuong phap do phé hép thy nguyén ti (ky thuat hydro); - TCVN 7877:2008 (ISO 5666:1999) Chat lugng nude - Xac dinh thuy ngan; - TCVN 6193:1996 Chat Iugng nu@e - Xae dinh coban, niken, déng, kém, cadimi va chi. Phuong phap trAc phd hdp thu nguyén tir ngon Ida; - TCVN 6222:2008 Chat long nu@e - Xac dinh crom - Phuong phap do phd hap thy nguyén ti; - TCVN 6658:2000 Chat lvgng nude - Xac dinh crom héa tri sau — Phuong phap trac quang dling 1,5 ~ diphenylcacbazid; - TCVN 6002:1995 Chat Iugng nuéc - Xac dinh mangan — Phuong phap trac quang dung formaldoxim; - TCVN 6177:1996 Chat long née — Xae dinh sat bang phuong phap trac phd ding thudc thir 4,10-phenantrolinigg VinangtscomunQCVN 40: 2014/BTNMT - TCVN 6665:2011 (ISO 11885:2007) Chat lvgng nuée- Xae dinh nguyén té chon loc bang phd phat xa quang Plasma cap cam ng (ICP- OES): - TCVN 6181:1996 (ISO 6703-1:1984) Chat Ivgng nue - Xac dinh xianua t6ng; ~ TCVN 6494-1:2011 (ISO 10304-1:2007) Chat lwgng nude — Xac dinh cc anion héa tan bang phuong phap sc ki léng ion — Phan 1: Xac dinh bromua, clorua, florua, nitrat, nitrit, phosphat va sunphat hoa tan; - TCVN 6216:1996 (ISO 6439:1990) Chat lugng nue - Xac dinh chi s6 phenol - Phuong phap trac phd dung 4-aminoantipyrin sau khi chung cat; - TCVN 6199-1:1995 (ISO 8165/1:1992) Chat long nue- Xac dinh cdc phenol don hoa tri lwa chon. Phan 1: Phuong phap sac ky khi sau khi lam giau bang chiét; - TCVN 5070:1995 Chat lugng nude - Phuong phap khéi lveng xdc dinh dau mé va sin pham dau mé; - TCVN 7875:2008 Nu@c ~ Xac dinh dau va m@ — Phuong phap chiéu hdng ngoai; - TCVN 6637:2000 (ISO 10530:1992) Chat lugng nuée-Xac dinh sunfua hoa tan- Phuong phap do quang ding metylen xanh; - TCVN 5988:1995 (ISO 5664:1984) Chat Ivgng nue - X4c dinh amoni - Phuong phap chung ct va chudn 6; - TCVN 6620:2000 Chat Ivong nude - X4c dinh amoni - Phuong phap dién thé; - TCVN 6638:2000 Chat lugng nuéc - Xac dinh nite’ - V6 co héa xc tac sau khi khiy bang hop kim Devarda; - TCVN 6202:2008 (ISO 6878:2004) Chat Ivong nue - Xdc dinh phét pho - Phuong phap do phé ding amoni molipdat; - TCVN 8775:2011 Chat lung nuéc - Xac dinh coliform ting sé - Ky thuat mang loc; - TCVN 6187-1:2009 (ISO 9308-1: 2000) Chat lugng nuée - Phat hién va dém escherichia coli va vi khudn coliform. Phan 1: Phuong phap loc mang ty VinangtscomunQCVN 40: 2011/BTNMT - TCVN 6187-2:1996 (ISO 9308-2:1990(E)) Chat lena nue - Phat hién va dém vi khudn coliform, vi khudn coliform chiu nhiét va escherichia coli gia dinh. Phan 2: Phuong phap nhidu dng (sd cd xdc sudt cao nhat); - TCVN 6225-3:2011 (ISO 7393-3:1990) Chat lvgng nude - Xac dinh clo ty do va clo tng s6. Phan 3 - Phuong phap chudn dé iot xac dinh clo tng 36; ~ TCVN 7876:2008 Nuc — Xac dinh ham lwong thuéc tri sau clo hau co’ - Phuong phdp sac ky khi chiét léng-léng; ~ TCVN 8062:2009 Xac dinh hop chat phospho hitu co’ bang sac ky khi - Ky thuat cot mao quan; - TGVN 6053:2011 Chat long nue - Bo tng hoat d6 phéng xa anpha trong nuéc khéng man - Phuong phap nguén day; - TCVN 6219:2011 Chat lvong nu@c - Do téng hoat dé phéng xa beta trong née khéng man. 3.3. Chdp nhan cdc phuong phap phan tich huéng dan trong cac tiéu chudn quéc gia va quéc té.c6 d6 chinh xac twong duong hoac cao hon céc tiéu chudn vién dan & muc 3.2. va cac tiéu chudn quéc gia, quéc té moi ban hanh nhung chua duge vién dan trong quy chuan nay. 4, TO CHUC THUC HIEN 4.1. Quy chudn nay ap dung thay thé QCVN 24:2009/BTNMT - Quy chuan ky thuat quéc gia vé nu@c thai céng nghiép ban hanh kém theo Thong tu s6 25/2009/TT-BTNMT ngay 16 thang 11 nam 2009 cla BO trudng BO Tai nguyén va Méi trudng quy dinh Quy chun ky thuat quéc gia vé méi trong. 4.2, UBND cae tinh, thanh phé true thudc trung wong céng bé muc dich str dung nguén nuéc va Hé sé Kq trong quy hoach si dung nguén nuéc va phan vung tiép nhan nude thai. 4.3, Co quan quan ly nha nuéc vé méi trvéng can ctr vao dac diém, tinh chdt cla nue thai cOng nghiép va myc dich sir dung ctia ngudn tiép nhan 4@ Iya chon cdc théng s6 6 nhiém dac trung va gia te] cor ban (gid tr] C) quy dinh tai Bang 1 trong viée kiém sodt 6 nhiém méi trveng. 4.4, Truong hop cac tiéu chudn quéc gia vién dn trong Quy chudn nay stra ddi, bé sung hoac thay thé thi ap dung theo tiéu chuan Mig np 10 Vinangtscomun