“Demand” has an element of WANT but we use demand because is more formal, while “Require” has a sense of NEEDS and is also use as a formal way. For example: I would say: I may demend to see the dentist or I may require to use the bathroom. The difference between “work”, “study” and “studies”. First work and study are doing the rule that say for those verbs that are with the pronouns “I”, “we”, “they” or “you” in present simple is collocate in present but if the verbs are with “she or he” we have to add an “s or es” depending of the verb.