PREBOARD -TERM I (2021 -22) sit-até 1 (2021-22) CHEMISTRY THEORY (043) SET-1 Tarratenes Pati (043) Be-1 CLASS- XII / a: XIl Term 1/ 31af8-1 Maximum Marks! 31ftraetat 31: 35 Time) BAA: 90 minutes! Fete General Instructions: Read the following instructions carefully. a) The question paper contains three sections. b) Section A has 25 questions. Attempt any 20 questions. ©) Section B has 24 questions. Attempt any 20 questions. d) Section C has 6 questions. Attempt any 5 questions. g) All questions carry equal marks. h) There is no negative marking. ‘Braet fargerl freafatera facet at carat a 7S! ®) wea ca A tet Gs G) SS UA 25 wear Fl MS sft 20 eat Fat HT O) Gs hha 24 wear Bi MS sf 20 GRA BAT HTL a) as tha 6 wear BI MS 5 Tear a aT a) wah weal & sim ware eI B) HS TENTHS aiaat TT TI Space for Rough workSECTION-A This section consists of 25 multiple choice questions with overall choice to attempt ANY 20 questions. In case more than desirable numbers of questions are attempted ONLY first 20 will be considered for evaluation wee Ba Gs A Pareto 20 weet mt gel eel & fee Tm Paewer a Her 25 agenda wes G1 ae ‘aia ear a sits wet a are Pare oat f at apart & fore act geet 20 oe Fra ‘fear Sea 1. A compound formed by elements A and B crystallizes in a cubic structure in which A atoms are at the centre of the cube and B atoms are at corners. The formula of the compound is (a) AB (b) AB (©) ABs (d@) ABs 1. aah a aie B aeT ae War Wer cae a pelt ete & Pa A HIT et hohe a BAe ate B cya Rat oH at a ATE (a) AB (b) A.B (c) ABs (d) ABs 2. In CsCl structure the nearest neighbours of each Cs ion are (a)_ Six Chloride ions (b) Eight Cs ions (©) Six Cs ions (@) Eight Chloride ions 2. CsCl Rta A Tea Cs Set H fore Isr F (a) Be Fags HT (b) 316 Cs arr (0) B Cs 3 (d) 3116 eeitrss sreet 3. Which of the following does not exhibit Frankel defect (a) AgBr (b) AgCl © KBr (@ ZnS 3. farafafaa a a ata thee ate veftta att erat 8? (a AgBr (b) AgCI Space for Rough work(c) KBr (d) Zns 4, An element having bee structure has 12.08 X 107° unit cells. The number of atoms in these cells is (a) 12.08 X 107% (b) 24.16 X 10° (©) 48.38 X 108 (@ 12.08 X 10” 4, sa-hRa vee aoa Rie) area are aes A 12.08 x 10® wiiPoar Fl gat aisonnsit H oasis aa 8 (a) 12.08 X 108 (b) 24.16 x 102 (0) 48.38 X 108 (@) 12,08 x 102 5. Ky for water is 0.52 K/m Then 0.1 molal solution boils at (a) 100.52 °C (b) 100.052 °C © 100.04 °C (a) 100.104 °C 5, Greft & Fee Ky, ABT ATT 0.52 Kim B a 0.1 ater aT eter SaeratT B (a) 100.52° C (b) 100.052 C (©) 100.04° (@) 100.104° C 6. A solution of Sulphuric acid in water (a) is an ideal solution (b) Obeys Raoult’s law (©) Shows negative deviation (d) Shows positive deviation 6. ont a aerafter ara a ae (a) we steel aor gs (b) Usee & faa sr aera aT (c) aeorcares Ferereret Pear e (d) trarteares Fererorat ferearar & 7. Nitrogen is liberated by the thermal decomposition of (a) NHsNOz (b) NaNs Space for Rough Work© (NH4)2Cr207 (@) All the three. 7. argghara a Reds Scott sromet gare apa Prat Sra (@) NNO: (b) NaNs (©) (NH) (@) att 8. The outermost electronic configuration of the most electronegative element is (a) ns? np* (b) ns? np* (c) ns’np* (@) ns*np® 8, wad Raga aos (fqga) aca A Hae areht saaciie Paeare B (a) ns’np? (b) ns’np* (©) ns’np’ (@n 9. Which speci has the maximum number of lone pair of electrons on the central atom? (a) (ClO: (b) XeF; (c) SFs @ (br 9, Sabre ara oe Prat one a getaciet A waht oh (area ava) A si eT art (a) [Clos (b) XeFs (©) SF; @ (br 10. The ionization constant of phenol is higher than that of ethanol because (a) phenoxide ion is bulkier than ethoxide (b) phenoxide ion is stronger base than ethoxide (©) phenoxide ion is stabilized through resonance (d) phenoxide ion is less stable than ethoxide 10. Pate a arerera Penis lata A goer A afer gars Fates: (a) dbettrengs sireet weleergs Ht gern A arf ears (b) Seaterengs srreer waiiergs MH Geren A arora AMEE (c) Ratsierengs rea Hr Totehe & rea S Fear fever ora & (@) tates sire vatrangs 8 HA PRE 11. Which of the following is not true in case of reaction with heated copper at 300°C? (a) Phenol in to Benzyl alcohol Space for Rough Work(b) Secondary alcohol in to Ketone (©) Primary alcohol into Aldehyde (@) Tertiary alcohol in to Olefin LL. 300 Bat Afeaara wy aa aie & are Hie & are F eatetaa A S aha a Aer set (@ Staite & ara seat () each teateter & Aca (©) satis teatgtar & tiers ( qataw toatl B stat 12. Which one is formed when sodium phenoxide is heated with ethyl iodide? (a) Ethoxy Benzene (b) Ethy] phenyl alcohol (©) Phenol (@) None of these 12, Baar hateargs a Ue HratsIgs H Her TA aA Te wet AT Sera BP (a) Watereh aster (b) Ua range teat () Sater (@) FAS BS ae 13. Reduction of glucose by HI suggest that (a) presence of OH groups (b) presence of CHO group (©) cyclic structure of glucose (d) six carbon atoms are arranged in straight chain 13, HI Gare Fate See B Te Tora B A (a) OH sagt ft safe () CHO wag fr safer (© aa aH aaa (o) Be ard TAME] Se Awa A cases eae Space for Rough Work14, Which of the following statement(s) is/are correct? j) Information regarding the sequence of nucleotides in the chain of a nucleic acid is called its primary structure. (ii) In secondary structure of DNA adenine forms hydrogen bonds with guanine whereas cytosine forms hydrogen bonds with thymine. (iii) RNA molecules are of three types’ m-RNA, r-RNA and tRNA and they all perform different functions. (a) (ii) only (b) (i) and (iii) (c) Gi) and (ii) (@ Gi) only 14, ferwerferiaer a apter art aera Ber B/E? () Aires sre A fae A alrosiergs H eA SH a A rere Ht seh sre ALT BT AAT BI (UD) DNA #1 efeache Aeere HF OSeAher, Tarfeter a Me Tesla Aeey aac B tafe Brgchetey, orgie & are giggistat att seta 3 | (ID RNA 340] efter sere & gta F M-RNA, rRNA 3H ERNA Site eat ster 3eroT arta el (a) Fae (ii) (b) (i) 34 (iii) (©) Gi) HR Gti) (d) ae (iii) 15, Which of the following is an example of globular proteins? (a) Glycine (b) Albumin (©) Alanine (a) Both (a) and (b) 15, fasafener a a ater aterere ater a SeTETT HY (a) rage (0) tear (o) Renter (d) atett (a) ait (b) Space for Rough Work16. Which one of the following statements about packing in solids is incorrect? (a) Coordination number in bee mode of packing is 8. (b) Coordination number in hep mode of packing is 12. (©) Void space in hep mode of packing is 32% (d) Void space is ep mode of packing is 26% 16, She Gare H BeaesH are HF Preafeea A S ate ar HUT Tea BP (a) WaaT BCC ahs H sree AAT 8 FI (b) Bearer & HCP aes A someeictore HT 1281 (©) eae a HCP ats H Reet eT 32% BI (@) ata & CCP ates A Rea eat 26% F1 17. The osmotic pressure of 0.1 M urea at 27°C is (a) 4.0 atm (b) 2.46 atm () 4.92 atm (@) 1.23 atm 17. 27°C FX 0.1 MARAT ST RTT ae a (@ 4.0 am (b) 2.46 atm, (©) 4.92 atm (@) 1.23 atm 18. What is the change observed when AgCI reacts with NH3? (a) White ppt is formed (b) colourless Solution is formed (©) Yellow ppt is formed (@) No change is observed 18. Ha AgCl, NHs & satire aT &, at Far Tater Ga Sara B? (a) Bbq saeta ata F (b) Sorter wearer ate & (c) Stor staat aera & (a) AS oar gh Se aT 19. CHsCH2CH2C]_ “KOH _y BME _oMv/lt_Dy in this reaction D is (a) Propanone (b) Hexane Space for Rough Work(c) 2,3 dimethylbutane (@) Allylic bromide 19, CHICH:CH:C EOF gH MEE 0 a sofia a DE (a) sieetet (b) eer (©) 2, s-xreftengacazat (@ viataa stones 20. Equilibrium mixture of glucose consists of (a)50% of a-D Glucose & 50% f-D Glucose (b)36% of a-D Glucose & 64% f-D Glucose (c)64% of a-D Glucose & 36% B-D Glucose (d)20% of a-D Glucose & 85% B-D Glucose 20. Teeter & gore frat Ht gta E (a) o-D 7eRPTSt FT 60% 3H 50% f-D FeHIT (b) a-D TeRRISt FT 36% 31 64% f-D ToT (0) a-D TeRHIST FT 64% HN 36% p-D TaHIT (d) a-D erst aT 20% 3H 85% f-D TAFT 21. Phenol can be converted in to benzene by using (@) Zn (b) Na (©) Mg (@) NaBH 21. Baier an soater areas acter A GRafeta Rear ot waver (a) Zn (b) Na (c) Mg (d) NaBHs Space for Rough Work22. Which of the following is an example of Sandmeyer’s reaction ? (a) 2HCHO SH, CH;OH+ HCOONa ) (Opnecr —22_, (S)-c © (©) +cHCL“S, (S)pCHs @ (©) 0H + Cor sai, o1'-(O)- cooH 22. freafettre a a ater or asara Fy afar ar ww Saree BP (a) 2HCHO 4, CH;OH + HCOONa ) (Opnrvcr —99_, (S)-c © (©) +cHC_AS, (|S)pCHs @ (S}on + co, ou _, on-(O)- coon 23. Isotonic solutions have same (a) Molar concentration (b) Molality (©) Mole fraction (d) None of above 23. FREY Paes A Baas (a) AteR Gixat (b) tetera (c) Arar 3381 (d) gat a arg sft ae 24. The relation between atomic radius (r) and edge length (a) of a body cantered cubic unit cell is (a) r= a/2 (b) = Val2 (©) = V3al2 @ r= V3al4 24. eae] Fsar (x) site Pret A lang (a) & ate ar adr ww Ue garg HATH fare B (@) (b) r= Va/2 (©) (@r=3a/4 Space for Rough Work25. The chemical name of Anisole is (a) Propanone (©) Acetoxy benzene 25. dirtater ar cera a & (a) Stair c) Wehtctaeh Sater Space for Rough Work (b) Acetone (a) Methoxy benzene (b) Tatetat (d) Feith aster 10SECTION-B This section consists of 24 multiple choice questions with overall choice to attempt ANY 20 questions. In case more than desirable number of questions are attempted ONLY first 20 will be considered for evaluation ast Be GSH faret aft 20 weal at get axe & fore Tara Fewer Ure 24 agiaaedta ver Fl aS aifea dear a aiftrs seat a rare fare oret & at aeararer & fore araret geet 20 wx Prag Fear smear 26. Total number of voids in 0.5 mole of a compound having hexagonal close packed structure is (a) 6.022 X 10° (b) 3.011 X 10% (©) 4.516 X 10 (@) 9.033 X 10% 26. seatota weit apie aaa are atte H 0.5 ater a Ritcrat Ht Hor Hears: (a) 6.022 x 10" (b) 3.011 « 102 (0) 4516 X 10° (d) 9.033 * 108 27. The molarity of NaOH solution formed by dissolving 4g of it in 250 ml of water is (@) 04M (b) 0.8M (c)0.2M (01M 27. NaOH % 4g #7 250 FAM. get A ated a sere are aaa A Aleta B- (a) 04M (b) 08M (9) 02M @) 01M 28. A 5% solution of cane sugar (molar mass =342) is isotonic with 1% solution of a substance X, The molar mass of X is (a)171.2. gmolt (b) 68.4 gmolt (c)34.2 gmol" (d) 136.2 gmol™ 28. Treat A fief Hr 5% Slot (Alex FeuHTAT =342) Var TERE X H 1% Shot H Te BATT BX or Alor gear & (a) 171.2 g mol" (b) 68.4 g mo!" (©) 34.29 mo!" (d) 136.2 g mot" 29. Propene subjected to hydroboration and oxidation yields (a) Propane (b) Propan-I-o1 Space for Rough Work W(0) Propan-2-01 (@) Propanone 29, sitar ergstatareret ike siterettator Garay & srelter F (a) star (b) stte-1-3iter (c) Sta-2-3iter (a) seater 30. Fluorine is a good oxidising agent in solutions than chlorine because (a) Bond dissociation of F2 is less than that of Chlorine (b) Floine has less negative electon gain enthalpy than that of chlorine (©) Fluoride ion has greater hydration enthalpy (@) Both (a) and (c) 30. Fetter A Goat A vaste aaa F wa sreor seta & Fai (a) Fo & ates Rett, setter Bt goa Ht ar BL (o) Faster A vets Ht geen A wa aaNet sAagia oe arta ena 81 (Fags aaa A aaa aria enftar afta eet 81 (a) ata (a) 3 (c) 31. Atomicity of sulphur in rhombic sulphur is @i (b)2 (8 6 31, BREST Bee A eR A VATS S (a)1 (b) 2 (8 6 32. Which one of the following order is correct for the bond energies of halogen molecules? (@) h>Ch> Bro (b) Bn > Ch>b ()h>Bn>Ch @Ch>Bn>b 32, fresfatae a ater a1 wa Soloter SUS Hy dey Salsit & fore wal 8? (a) > Cle> Bre (b) Bra > Cla > kk (c) Iz > Bre > Clz (d) Cle > Bra > Ie Space for Rough Work 233. In XeF2, XeF4, XeFs the number of lone pairs on Xe are respectively (a) 2,31 (b) 1, 2,3 (c) 4,1,2 (d) 3, 2,1 33. XeF:, XeFi, XeFe A Xe WX VTA SHS (BASHA Bret) HY AAT HA: F (0) 2.3.1 (b) 1,23 (6) 4.1.2 @3.21 34. Which one of the following is not an allylic halide? (a) 4-Bromopent-2-ene (b) 3-Bromo-2-methylbut-l-ene (c) 1-Bromobut-2-ene (d) 4-Bromobut-1-ene 34, freafetacr a & ata om viata teres ate BP (a) 4a 82-2: (©) 5-atal-2-Penger eqe-1 Sr (0) L-aitat qe -2-Set () 4a ee -1-5et 35. Conversion of ethyl bromide to ethylene is an example of : (a) Hydrohalogenation (b) Intramolecular dehydrohalogenation (©) Dehydration (@) Hydration 235, uta atangs a gemgata a oftadiar war Serer: (@ wegitatorert (b) saaroree Seregigatsetert (©) faster (A) erie 36. Glucose gives silver mirror test with Tollen’s reagent, It shows the presence of (a) Acidic group (b) alcoholic group (©) Ketonic group (@) aldehyde group 36. Cheha asters & are separ Peat ation ohare Sar F| He ferret Soe et Ht aeitel F Space for Rough Work 1B(a) secre aR (b) Seager waR (0) Flan TAR (a) Ciesees aR 37. Which statement is not correct about alcohol? (a) Molecular weight of alcohol is higher than water (b) Alcohol of less number of carbon atoms is less soluble in water than alcohol of more number of carbon atoms (c) Alcohol evaporates quickly than water (@) None of the above 37. Coalgior & ak A ater a aerate aat B? (a) Goaigion ar srerfaer ay orelt B arfeten ele & (b) araet Toei Ar ana eee aT Voie, Haat ATTA HY sefkren Bea act Cowteter BP quen a toh aa quart eter e, (0) temigiar, sar S Seat anos a ares () soar Ha aS aT 38. Which of the following compounds is oxidised to prepare methyl ethyl ketone? (a) 2-Propanol (b) | Butanol (c) 2-Butanol (@) t-Butyl alcohol 38. fareaferttaa A & aptat or citar frenger Ufo Atcha dare ae & fore steeper ete ey (a) 2a (b) Leqeratior (0) 2 eqeriter (d) Leqerge seat 39. Methanol and ethanol can be distinguished by the following: (a) By reaction with metallic sodium, (b) By reaction with caustic soda (©) By reaction with alcoholic KOH (d) By heating with zinc and inorganic mineral acid 39. Aerie sik stale a fasafafaa care sfetfted fan at waar ze: (a) rg eis & are af fer gan (b) aafRem ater & aren af ren aT (Q temeiee KOH & are Here a Space for Rough Work 14(0) Steen 3th sraréftten afer srra & are a 40. Which of the following properties of glucose cannot be explained by its open chain structure? (i) Glucose does not form hydrogen sulphite with NaHSOs (ii) On oxidation with HNO glucose gives saccharie acid. (iii) Glucose is found to exist in two different crystalline forms which are named as a and (a) Gi) only (b) @ and (iii) (©) Gii) and (iii) @ @ and (ii) 40. vapor & fateerferhar A a Fase aor at seh TA aferan eae GANT at AAS A Ae a (i) FERPA NaHSOs % BUT BIAS AH HSE aT SATA F (ii) HNO, & Bret SiferaeRTeT Hea TR FopHtaT SeReH FES eae (iy Tage Mt teva arera Panetta at a aren TTS PSE a 3H Baa Pe are (a) Fae (ii) (b) (i 3th Gili) (©) (ii) 3h (iit) @) (DFR, 41. The structural feature which distinguishes proline from natural a-amino acids’ (a) Proline is optically inactive (b) Proline contains aromatic group (©) Proline is a dicarboxylic acid (d) Proline is a secondary amine 41. raareare Pattee St starsat at orepiee o-vfet was B ster ett 8? (@) Senge Safers oo B fate (b) Sremrger Hater aayE sta E (0) Satga Ue siseraiieaion sae (d) Srerga va afacra atta & 42. In DNA the linkages between different nitrogenous bases are : (a) peptide linkage (b) phosphate linkage (hydrogen bonding (@) glycosidic linkage 42. DNA & faites angela amt & dre eter & (a) Serge Hat (b) isthe ade (0) ergghore arreey (¢) sorgahfaten arate Space for Rough Work 1543. In DNA, the complimentary bases are: (a) Adenine and thymine; guanine and cytosine (b) Adenine and thymine; guanine and uracil (c) Adenine and guanine; thymine and cytosine (@ Uracil and adenine; cytosine and guanine 43. DNA a, arare ara & (a) OSetter site arrester, varefter ste eget (b) CSefter ate arerefier; Tartar ate BVT (c) Cetter Bz saretter; erreratter sie erecretter (cd) Ret SH Setter; erect HT raret 44. A solid has a structure in which “W’ atoms are located at the corners of a cubic lattice, *O’ atoms at the centre of edges and ‘Na’ atoms at the centre of the cube. The formula for the compound is : (a) NawOr (b) NaWO3 (c) Na,WOs (d) NaWO4 44, cH ote A ea, Bret w Te] we oa aT a wy Aaa aa EO TTA Papa habe A ait wat & Fe A Na TeaMy) after few Be: (a) Nawo2 (b) NaWOs (c) NazWOs (d) NawOx 45. Assertion (A): When NaCl is added to water a depression in freezing point is observed Reason(R): Lowering of vapour pressure of solution causes depression in freezing point a) A and R both are correct statements and reason is correct explanation for A. b) A and R both are correct statements but R is not correct explanation for A. ) A is correct statement but R is wrong statement. d) A is wrong statement but R is correct statement 45, AB ERRIaT (A): Ta NaCl Bt Teh A era Stra & att eae A way Hera CaM STAT RUT (R): Ferra a area ra HH gta A feat Ht araetaa Sta E (@) A3ike R abet wet aaret & HR, AH fore Be Tae eI (b) ASR R ata el set F AH R, A HY TY AAT aT LAT () A Be rere & AR R Aa eT SL (d) A Tete Here F After R HET Hera 46. Assertion (A) : Molality of a solution changes with temperature Reason(R): Volume of a solution changes with temperature Space for Rough Work 16a) A and R both are correct statements and reason is correct explanation for A. ) A and R both are correct statements but R is not cortect explanation for A. ©) Ais correct statement but R is wrong statement. d) A is wrong statement but R is correct statement 46, a1fbtareret (A) : ehh ferererar At attereren crater Ber aaah F SHOT (R): STATA 3 rer era aT HA SEAT (a) ASR R erat wer zaret & ATR, A fore Bet FIAT FI (>) AST R chet Bel wert 8 Aiea R, A AY ET eT aT HAT BI (c) A Bel Beat & Ae R Tad HATS (@) A Herel Herts AST R BET HT S| 47. Assertion (A): S2 is paramagnetic as O2 Reason(R): S2 has unpaired electrons in molecular orbital just as O2. a) A and R both are correct statements and reason is correct explanation for A. b) A and R both are correct statements but R is not correct explanation for A. ©) A is correct statement but R is wrong statement. d) A is wrong statement but R is correct statement 47, HAHA (A): Sz, Op. FBT A areas ROT (R) : So HO A ANE OF 3TOr fees apatra a araPoara scaler BIg El (a) ASR R ateit Ber gare F SHR, AR fore TET ETAT BI (b) A HAT R etait Bet awe F ART R, A AY Tel CATE aT FLAT BI (0) A BG) were 8 Af R ae HAT BI (QA aot Hee F Ae R AE HAT SI 48, Assertion (A): D(+) Glucose is Dextrorotatory in nature Reason(R): D represents Dextrorotatory nature of Glucose a) A and R both are correct statements and reason is correct explanation for A. b) A and R both are correct statements but R is not correct explanation for A. ©) Ais correct statement but R is wrong statement, 4) A is wrong statement but R is correct statement. 48, arfdrarerat (A): 3 (+) Toraitar pier Ht aferoT Gare ‘SRT (R): A agater AM aferor Yaa weplA ar safeties ara (a) ASI R atett Ber gare E BHT R, Aa Pere TET ETS BI Space for Rough Work v7(b) AHR R ahait Bet aHeIeT F fee R, A AY ET CATT aT HAT (c) A Ber Beat F AHA R Tera HAT TL (A Tete Hee F Aho RET HT VI 49. Assertion (A): Ethanol is weaker acid than Phenol Reason(R): Ethanol is soluble in water. a) A and R both are correct statements and reason is correct explanation for A. b) A and R both are correct statements but R is not correct explanation for A. ©) Ais correct statement but R is wrong statement. 4d) A is wrong statement but R is correct statement. 49. aifttarera (A): Staite fihater At goer A aaa ara E ROT (R): ate Ger A aera B1 (a) AS R chet wel sare F SR, Aa fore BET FIAT F (b) A SHR R Sle Wel Hee F Ae R, A AT AA caTEAT aE HAT (0) A Bl area & Ae R aoe He VL (@) A Trotet teat & afaber RET HUT SL Space for Rough Work 18SECTION-C This section consists of 6 multiple choice questions with overall choice to attempt 5. In case more than desirable number of questions is attempted Only First 5 will be considered for evaluation asa Be Us A 6 agenda wea 8 fae Her Faawed 6 a ere aT BI Ae ito Hea a aH ‘Seatt aor rare fever Strat & att aatarert & fore araret geet 6 oe free fre Sea 50. Match the compounds given in Column I with the hybridisation and shape given in Column II and mark the correct option. Column I (Column 1 (A) XeFe (1) sp'd’ — distorted octahedral (B) XeOs, (2) sp'd? - square planar (©) XeOF (3) sp? — pyramidal (D) Xe as square pyramidal (a) A(I)BG)C@) DQ) (b) AI) B (2) C4) DGB) ©@A@)BG)CU)DQ) @A@B(NCQDE) SO. aeteray 1H Fore are attarent ant aor SH Serene oh Bre Galera He afore MH Fea are B TT wal fared at feet ae) aio 1 ‘wor IL @) XeFs (1) sp'a® - Farper arsemnareheT (b) XeO3, (2) spa? - at aaa (c) XcOFs (3) sp? - afte (d) XeFs (4) spt - aot Rrafaser @ AW)BECaDEA Space for Rough Work 19&) AMBACHDEB) © A@BE)CHDEA) @ A@B)CADG) 51. Na and Mg crystallize in bee and foc type crystals respectively, then the number of atoms of Na and Mg present in the unit cell of their respective crystal is (a) 4and2 (b) 9 and 14 (c) 14 and 9 (d@) 2 and 4 51. Naik Me wae: Healer Caen aoa Ik wows Hisar wane a Prec A Brace ga PT Na a Mg & GATOS A Gea Sa ills recA gas aAlftoar a wits 8 (a) 43ik2 (b) 9 3ie 14 (0) 14 389 (6) 2384 52. Molatity of aqueous HCI will be, if density of solution is 1.17 g/cc (a) 36.5 molL! (b) 32.05 molL"! (©) 18.25. moll" (@) 42.10 moll 52. Uf facet HT Seed 1.17 gice. Fa TAT HCI FH Ate eat (a) 36.5 molL" (b) 32.05 molL” (c) 18.25. molL* (@) 42.10 molL” CASE-1 Read the Passage and answer the following questions 53-55, A substitution reaction takes place and halogen atom, called leaving group departs as halide ion. Since the substitution reaction is initiated by a nucleophile, itis called nucleophilic substitution reaction. The nucleophilic substitution of Haloalkanes can proceed via SN! mechanism or SN? mechanism. Unimolecular (SN!) is Generally carried out in polar protic © POZO wg © Space for Rough Work 20solvents like water, alcohol and acetic acid. It takes place in two steps through carbocation as the intermediate and it is a first order reaction, Bimolecular SN? carried out in polar aprotic solvents like acetone, DMSO, acetonitrile. It is second order reaction. It proceeds with inversion in configuration. It depicts a bimolecular nucleophilic displacement (SN?) reaction; the incoming nucleophile interacts with alkyl halide causing the carbon halide bond to break while forming a new carbon- OH bond. These two processes take place simultaneously in a single step and no intermediate is formed. As the reaction progresses and the bond between the nucleophile and the carbon atom starts forming, the bond between carbon atom and leaving group weakens. As this happens, the configuration of carbon atom under attack inverts in much the same way as an umbrella is turned inside out when caught in a strong wind, while the leaving group is pushed away. This process is called as inversion in configuration. CASE-1 arewier 96 sity frraferfarer weal & sar f 53-55 wfcearaet vas sftnan atch & fret telsrr sary, Sa olset aren BAK Her STAT a Range sree & ea A seer acer Bl OP wiser aT ane gan ee A aT. se anftenrh sferearse sfatizrer ser ster Bl Sorteser ar ana ofereUTIa SN; ae aT SNo Ta & HreaH B SVT ae Tea Sl Se a oe eater afew feroreas SRY ore, srewtEeT SIT Uitte sea a fren ore 8) ag Resa & wo A arabes H area S et aot A star F aie Fe Tee aa A Mera S) weiecla, SeawasH, weelergset Se ysta wsiieen Perr A afe- sarorferas SN? fever Gare Bl Be afer are a sefarioe Bi ag Fear A asa g He set ISAT & 2 PO,0--$--O4e¢> © ag we afa-srorfaen anita eerste (SN) wfaiarn a cata &: ses aah vets tergs & are Tee Bar aren & fared anda Sergs ater ge ora & Grafs wep ate aTgaT-OH erat wate BL Sahat ARATE Ven A eT Hy as ET eich & site ws HeaaHt ae ata Bl SAT Se ofearer ait eect & site aarfstenaht sy aprdet TeaATOy & Ser ar erat Sereda &, HTT ‘IRATO] A IgA a agR Byatt a ere ATA eV STAT BL BA Varela, are a ET area TAY] ar Pear Set ALE TAC STATS SA AS Sa A HS ST Ge BHAT B aTeT ey Space for Rough Work 2‘SreTe, Safer wiser are BaE HI ag eras Fear Stat 81 Ser ofr wt eae ar else Et F 1 53) Which of the following is most reactive towards Sx2 reactions? (a) CHX, (b) RCH2X. (©) RCHX (@) RsCX 53. freafetta Aa ate sx2 wiatirensit & af wad sities vferiareretror & (a) CHbX (b) RCH:X (c) RxCHX (d) RsCX 54. A levo rotatory compound 2-chloro,2-phenyl butane is undergoing nucleophilic substitution with (OH) following SN! mechanism. The product/s obtained is/are (a) leavo rotatory 2-phenyl butan-2-ol _(b) Dextro rotatory 2-phenyl butan-2-ol (©) 1:1 Mixture of both (a) and (b) (d) None of these 54. tr art Caer atte 2a, 2-Rhange eqs warieas anfraaett (Sy1) afters (OH- ) Ty WTe | aiseess ores see (a) arr qe 2-Freriger eaear-2-3tre (b) efter eat 2-ftrergr eae 2- 331 (c) 1:1 hath aor FAta70T (a) 3#R (b) (a) saat SHS aT 55. Which one of the following readily undergo bimolecular Nucleophilic substitution (Sy2) (a) CHsCHBr (b) CH2=CH-CH>-Br (c) CeHsCH2Br (d) (CH3)2CH-Br 55, faafetaar a a ate sirerett B ala aUrfaes anfsrararah PAE IA (S92) B aS S (a) CHsCHBr (b) CH2=CH-CHe-Br (c) CeHsCH2Br (d) (CHs)2CH-Br Space for Rough Work 2