SR.SEC.SCHOOLJH = |, CHEMISTRY PRACTICAL FILE at CLASS - XH Note: - 1. Use Dhruv Practical file 2. Use Black Pen for Heading and Biue Pen for Writing 3. Draw diagram with pencil.Reaction 2KMi0,+3H,SO, + K.S0,+2MaSO,=3H,0+5(0} (2FeSO,(NH,),SO, 6H,O + HS0,+(0)—Fe{S0,), + (NH )'S0,l= + 13H, ‘Chemical Equation :- 2KMnO, * 8H,SO, + 10FeSO,+ (NH,), SO, 6H,0 + {,S0, + 2MnSO, + 5Fe(SO,), + IOGSH,),SO, + 68.4,0 Tonic Equation = MnQy+8H Se Mn 44.0 Fe? Fe Mey xs MnO,+ 810+ SFe* 5 Se Mats 44.0 TMV, = $n V Where’ Mi, ="Molatity of aio Soltiticn, M, = iMolarityof Unknown Solation V, = Volume of known Solution, V, = Volume of Unknawa Solition Strength = Molarity x Molecular Weight of KMnO, c Ma M= S MoV My = SVs Ny ach x 22x 2 ok 2, ie RSS Us ; te = 0.222 ™ Nol lan ty of Ktindy Solofin 0-222 | thee th = Molanidy x molar anagy wo ha oe aed é = 0 22a xise= 3.611 gh ieperiment No. rolarity and strength of the given Appararus:-Boren, PiPENE Tiwatior AW gnaicetor- KMin0 jsa self iidieaton Required Chemical procedure:-A) For preparation of MISO ESIISSSS M/40 Ferrous A book. {pyWash the wae ass thoroughly th jnbeaker with gentle SHANE {ayTransfer he clean sotution from beaks {syCarefully add distilled water © (@Fiktopperto the measuring flask and ‘Observations = Moiarity of mohs’s: H Obeservation Table moe 4 eae Results + Molanity of given Ferrous ammonium sulphate cyst (uyWeig aceurately2.45 gm of eres ‘ammonium sulphate erysials on the {2yFansfrsalt from ihe watch 885102 hemeasuriog flask, il the sol ‘Weight of mohr's alt = 2.45.6 salt Solution = Volume of Pipette ego wm) e 3s KMnQ, Solution is "aim:-To prepare MI40 solution of Ferrous Aunmoniuin Sutphate (Mohr's salt). Using this Solution and findout the KMn0, solution ask: Whine Tile Warch Glass. Analytical Balance, Measure Flask ind Point = Colonrlessto pennanent pinkcolour «, KMnO, Solution, Cone. H,S0,, Di. H,S0, 149 Ferrous Ammonium Sulphate solution: 250 mnt, beaker. Add to this beaker about gititted water ansfer the sticking sal completly inte the beaker. Dissolve! a 250m) measuring flask through funnel stands just belong the gradvated maik sake i vigorously sothat solution becomes Nijposensowe ‘Volume of mohr'ssait Sotution prepors MuaG Poca Rader | Wiineot ae a Pa Volwine Solution uses Neue i t no) vi (on) 0. oe ret {2)Denot heat the solution in thevivanon ask 2)D0 not rinse the titration ask Volume of mohr's salt Solution taken foreach titration = 20m ‘inicordant mMn04 Qol ulion= 3° SU Precautions =(1)Read upper menses in ath of de KMnO, Ba aise alt watch glass and record the weight in the no «5 ml of concéntrated sulphuric acid} ys’ | Il | | \ | yKMin0, solution. \ \ i i indicator-KMnO, coloursless. Observations: We: Precautions: (1) bs es Titration | "aims To prepare M/40 solution of Oxalic: eid using this 0! l Obeservition Table: _ inis selfindicator Procedure: (Al For preparation of M40. Oxalic Acid solution. Fi efeight accurately 0.7872 of Pee acid crystals onthe watch glass 2nd record the weightion. i a solution in th beaker it ake vigorously 50 that solution {gyLabe! the solutionas M40 0x26 acid solution son. determine, hemmolasity and strength ofthe given. gparatos- Bureue, pete aon sk, White Tie, Watch Glass. Analyseal Batannce, Measuring Flask. Required Chemicats:-Oxatic acid crystals, KM nO solution, i 80, End Point Colours topink -qeory:-KM 00 oridises oxalic ad i8 10 CO, in acidic mediom ata ferp.around 60° and itself get eedveed 10 soa 250 ml measuring ask through 2 Funnel measuring flask y | pcan atten qukerneasorng fast inesfin ends USPS Te graduated rhask on Be 6). i ee ops Ftd water wm aPIPNS ne omt the meniscus touches he eraavated becomes homogencdvs. sen of oxalic acd =0.787 Em Volune of oxalic acid sotution prepared = | egutt Molar given ENN, som yamgth of Kno {2)Dusing making upotthe volume ihe tast drop of water should be {4 Oxalicacidso? should ay WT daring titration. oe pol ny a Se Borene Reading | ‘Volume of Geol) KMnos Motertyofoxalic acid solution = M40 ‘Volume of exalic aid solution taken foreach rsraon © 20: Concordant Volume vy (nd) Bom, 2 B-BS36 gait ever pour hotsoftrothe measuring Nase (}Oxatie acid so should narbe bestest beyond 70s ded very carefilly. ——-# Senne Sonnets> Salt Analysis. Ss ime eee retail pelts Feat wibé holder,Burnes, Test ibe brush Glass rod Etc. Sobich .. ercaner volte (ayhysical State —$ 8 odour =.-PRAPACH. Seah — cysotubitity- ge\uble ™ (9! jredicabin given Salt. pparatus-Testibe, Test tube stand, ysical Proper! Dheservation Fable: Inference ‘Experiment Week group anion absent i Isat + Dit H,S0, No Reaction and no gasis evolved CO," NO,", $0,", S* ee No Reaction andao gasisevolved | Strong BO'P, absent anionise 2, | sate+ Cone. 1,80. Cir, Be, MO, ete. 3, bats DIHCL+ BaCl, Solution white PPrTis formed ‘f sutphate (SO,*)or Phosphate b:p0,2) maybe presentio yeralgromp 4, | Above PPT. + Cone: HNO, PPRisdfifolved . Phosphate (PO, >)conficm: 1 ‘5, {above solution + (NH, MSO. Cale yeh PA. Phosphate (PO, confirm ‘Ne. {sau Sotoion # CORIO, “Violet PPT. [paver confirm | | ‘Agnmmonical smelt evolved Zeta group present 4 solt + NaOH + Heat ‘Aarononiuin (NH,")may de ig. [faves slasssoa inves 9 Gone. HCI. | White Fores Of NH,CHIs fonned ‘Ammonium (NH,.) present nd on the mouth of above test tue F i ' jg._| saicemaon + K,Hel, (Nessler’s Red/ Brown PPT. is formed Ammonivers(HTEL, ) confi wwagent) ‘Ajpmoriiuin (NH, )eonfi J Deep lve colour Ho. {san + Cvs0, Solution * NaOH |r m0 fe Ramil Phosphate (PO,?) Presentin ven salt ‘asnmonium (UH, ) Presentin given saltRadical in giver'Salt- sta Fu ves Tene eS apport TestTube. Tes ES Qobic (2) Colour = anysical Property = OD physical State ~ sah +ail H,SO, Vinegar likesmellsis formed 9, \1parteali+ 2 part sie re ee smell isbecomed ery on your palm +2 0p 10% rubit [fost | sates teu FeO, Solnnon eea/Brown Precipitat becomes ye | sae NaOH + Heat No Ammonical smell gait DIL HC! White PPT is formed PPT dissolved cast part + KS Solution Yellow BRET. is Formed second Part + K,C10, Sotiion “Yellows PBs Formed white PPT. is Formed petenie (CH,COOY Presents BL salt. iven salt [Result cena Ren) Reman, ss rod Ete, 2 white Qoluble fn Hod ‘Acitate (CH,COOY may be resent in week OUP Acitate (CH,COOY cern Aciate C00) Contin jf ‘Zexo group Absent I group present maybe Lead (Pb) eed ( Po'?ynay De present Lead ( Pb) confinned Lead ( Pb") confined Lead ( Pb“) confinedSalt Analysis pparatu oyysical Property = : (1) Physical State (3) Odour = Obeservation Table: kx Geen eee sate + Dit H,SO, 2. | gait + Cone. H.SO, It 3, ban» DiI + BaCl, Soturion 4. | Above PPT. + Cone. HNO, ove solution * Cone. HCL ah Solution + Lead Acetate Saltt NaOH * Heat sait+ Dit HC} H,S ga passin above Solution bove PPT.+ Dil. HNO, pove Solution is Divided in Two Pa First Part+ 6 + Cooi + NH,OH * z Samay edie acc Rfial gBeicReien rN ae Qalid pdousler& (2) Colour = @ se Bore ae ~ Experiment [Obeservation Inference No Reaction and no gasis evolved No Reaction and no gas is evolved white P.P.Tis formed PPT isngtaissolve PPT isnot dissolve white PPT ¥s0Aarmmoniead smell No. PPT Black PPT is formed PPT. Dissolved ‘ve Solution become Chocolate brown PPT. is formed. “i [Pevertinent No. ASy aes tube, Test tube stand, Test ibe older Bumer, Test tube brush.Glass rod Ete. Bue souviiy BOWULLEM wate? maybe Week group anion abst. C02", NO,”, SO," S* ete wong group absentaionie Ch Brs I", NO; Sulphate (SOM Prabiphate (PO, )matebe FesBent in gencraligrobp. | Sulphate (SO,*)confinn Sulphate (SO,?) confirm Sulphate (SO,2) confirm Zio roupAbsent group Absent I group present Copiger (Co) ‘Copper (Cit*) Pigent Copper (Cu?) Confirm Copper (Cu) Confirm. Copper (Cu"?) Presentin giver sal | $9..| Second pat eRgooH+ iL «grees cm RResallz, Sulphate (SO,")Preseatin given sah easg To determine! neAcidicRedicot Bake RS) ingiven pparatus:-Testtube Test tube stand: Fesitube holdenBumes tysicalProperty = Tp Salle odorless peservation 1+ IH SO, gak+ Conc H.50." Het Light brown P piece of Coppertuming or Filet Dark Brown ‘e above Solution ywtion® Cone Brown Frest tube alt + fresh FeSO.50h /S0,atong wath the wall oi soit + NaOH * Heat to Amunonica gait Dil. HC! No. PPT tS gsspassinaboveserunen no. PPT pemowe HS gasbystonsboll* white} eee oe Sod NH,CI+NHOF White PPT+ Dil. HC! PPT. disolses $0-| Fast gq Parts + Bhve line NEO, (RO, )Peseatin ver 1s Solution Nirate salt Rene salt ‘No Reaction andno Ba8!5 fomesis very dense fy Ringis formed-at the junction ofthe nwo soration gelatinous PPT. is formed White PPT. is forined Blue PPT.is formed Salt es tube brush. Giassr08 Ee Coo eolousbe2® i ensandiity- BOWE Sn WUte>} evolved Week group anion abseat ie: €O,7, NO,, S0,*. S* icate (NO, nay bepresat in Strong FOU ungent gas is evolved irate (NO, Yeenfinn i Ssfvare (NO, Yeonfinn iisenell “Zero fraup AbsEAt group Absent ii group Absent Ml group present Alumifior hal?) may be ‘Abiiminin (AI) Presentin TE group Aduiminiven (AJ) confirm _Ataminivin (AP}ConNP" lbncuade: 2 @) Odour = phar. lobéservation Table: SN Experiment [Obeservation Inference He. |e alt + Dil H,SO, 1. gatt+ Cone. H,S0, Bring a glass rod dipped in NH,OH at mouth of above test tube Sat + Conc. H,SO, * Solid K,Cr,0, Heat Pass thé red fumes in NaQH Solution: ove yellow Scluticit CHOON. + (CH,COO),PD Salt+ NaOH + Heat Salt + Dil. HCI H,S gaspassin above Solution Remove H,S gas by strong boiling + Coot+ Cone, HNO, +4 + Cool + Solid NH,CI + NH,OH H,S gas Pass in This Solution Remove H,S gas by strongboiling + ‘Cool + NHOH +H J:€0, Atove Solution +*Na HPO, White PPT. + Dil HCI Above Solution + NH,OHINSOH Titan yetiow + No Reaction and no gas is evolved Jolourless Pungent smetling zgasis formed White fames of NH,Clis formed Dark Red/¥éllow fumes formed = Sateitan besbines yellow Colour ‘Yellow PPT: formed NoAmmonical smelt No, PPT. No. PPT. No PPT. [No. PPT. ‘NOPPT. White PPTis formed PPT cisolved Red /Oran; Formed Pink PPT. is |} ut group abEHE ‘Week group anion absenti CO," NO,”, SO5S* ete Chloride (CH) may bepresent in Strong group [Chloride (CI) present Chloride (CIPresent Chloride (C1 )Present Chioride (Cl) Confirm Zero group Absent Igroup Absent H group Absent IV group Absent V groupAbsent Mognisium(Mg"*) may be present in V1 group. Vigroup, Magnisium (Mg: K Result:- Chloride (Cl) Present in given salt ‘Magnisium @V4g") Present in given salt(@) Odour = lobeservation Fable: Pfiysicat Property = ayebysieal State Sox odorless bel 2 3 are % pone a at fst "Experiment_____—— Jowesecvation ____——} [Inference 1. | Sale DAIH,SO, Cotourtess and Odourless gas 15 Carbonate (Co,") may be ___ evolved with effervescent present in week gxOUP - 2. | passthe above gas in lime water Live water tums milky Colour Carbonate (Co, present 3, | Passthe gas fora tonger time Mili colour of ime water disappest Carbonate (Co,")is confign 4. | Salt 1,0 + MESO. White PPT. is formed cuconseaicn 2 ili Wg, | sate NaOH + Heat No Asmunonical sell EE oonniene & | sae Dit. HCI No. PPT. Lgpoup Aten i Z| HSeasessin ‘above Solution ‘No. PPT. se > | group Absent ‘i i 2 ee aH g. | Remove HS sasby seongboiting+ {No PPT. Hl Coat + Cone. HBG, +4 + Cool* bs Solid NH,C1+ NH,OH i | g, '| HS sesPassin Tis Solaton No:PPTE Mi groopihbeont Hp. | ‘tenventSenygvonpans” wir eee 4 Cool + NHOH PQHIE Bo", Sr, Ca"? may be i \ ff. | white BET. +107 i cgou PPT. dissolves V groupPresent \ ‘fiiigSoliition Divided! Three Parts | ig. | first Part + KC, Solution ‘Yellow PP.T.Not become Barium (Ba™) absent i {}\ $g. | Second Par = (NH),SO, White PPTis formed Strontium (Sr?) Confirm \ ‘Third Part + (SHO. White P.PT.is formed ‘Sgrontium (Se) Confirm Reesultsarbonate (Co;") 0" presentin given Salt Seromtiv (Sr) Present given salttebe stand Faerie holder Ba nysieal Property = (@ Colour =~ Te Bolick Gyoseet ANN ky lobeservation Table:- rex, Test tube brush Glass rod Bic. whrte esouviney- SOLWELE. Sm Experiment eee Biuret Test = y 1 | sample + HO + CuSO, + NaOH Blve/Violer Colour Solution Xanthoprotic Test = 2 | Sample + Dil. HNO, +4 Yellow Colour Sobution or PPT allow Solution + Solid NaOH Yellow/Orange PPT. is formed ‘Sample # NaOH + Sodium Nitro ‘Red / Yellow? Violet : Proside Cote 7 z 1 ) i i i H | | seeeseeseeseecee— Tua Protein Present in given food Sample Resul Inference Protein Present in given Sample Protein Present ia Giver lisample {Pooteisf Confirmin Given ‘Sampleee Sp : Food Test ki = 2 ue i z Aim: To determnina the food test in-givenSample.” | Eve ua, tk bun tone ea eabn bh mE IphysicatProperty = el nt ) Odour = Orly sa egsooany- Angoluble ™ be aoluble % HoSOy lobeservation Table: Su] Experiment __ [Obeservation Inference __ Solubility Test 1. | Sampte+ H,0 Insoluble Fat Present Sudan Test 2. | sample + Sudan tv" Heat Red Colovr is Formed Fat Present Acrolein Test | 3, |. Sample + KHSO, + Heat PungentSriell Eolve 5% | at eesent H ‘Feanshuscent Spot Test a. | Sample + Dip Filter Paper inthe Franstuscentor Greasy spot onfilter | Fat Confinn | Test cube Paper | | i 4 i \ Result: Fat Present in given food Sample | ! IApparatust-Test ube, Test ube stand, Test tube older Bummer, Festtube brash Physieal Property = (1) Physical State Qoled (2) Colour = @) Odour -(): dows hers (4 Solubility - [Obeservation Table: pgabeaae ee See : eames st [obescrvation [Inference —_ ae or Eee Benedict's Test Sample +H,0 + Benedict Solution Yellow! Red Colour Carbohydrate Present + Heat : Lodine Test Fe igectet LONE Sta: Violet Yetlow/Orange Colour Carbohydrate Present ‘Fotten’s Test i BL Seenke HOT toate Back PRF,/SilverMirior's Carbohydrate Present Heat forned Molisch’s Test Red/Voilet Rings formed at the Carbohydrate Present Samples Motischs Reagent ® junction of two solution Cone H,SO,along the wall of testube Picric Acid Test samiple’+ H,O* Picnic Acid * Red / Yellow Colour Carbohydrate Present NaOH + Heat Present in given food Sample