CH3OH(l) ---> HCHO(g) + H2(g)

ni: 100 - -
Δ: 70 70 70
nf: 30 70 70
 Teb(CH3OH) = 64.7 °C

a)

75°C

Gas
Teb (64.7°C)
Líquido
25°C

ΔH(F1):

Comp n (mol) a b c T1 (°C) T2 (°C) Cp (kJ/mol) ΔH (kJ)

CH3OH(l) 100 0.07586 0.000168 0 25 64.7 3.311308 331.13077

ΔH(Rx):

Comp n (mol) ΔHf (kJ/mol) ΔHf (kJ)

CH3OH(l) 70 -238.6 -16702
HCHO(g) 70 -115.9 -8113
H2(g) 70 0 0
Total= 8589

ΔH(F2):

Comp n (mol) a b c T1 (°C) T2 (°C) Cp (kJ/mol) ΔH (kJ)

CH3OH(g) 30 0.04293 8.3E-05 -1.87E-08 64.7 75 0.50096 15.028785
HCHO(g) 70 0.03428 4.27E-05 0 25 75 1.8207 127.449
H2(g) 70 0.02884 7.7E-08 3.288E-09 25 75 1.442638 100.98464
Total= 243.46243

Calor latente:

Comp n (mol) ΔHv (kJ/mol) ΔHv (kJ)

CH3OH 30 35.27 1058.1

Q°(Reactor) = ΔH(F1) + ΔH(Rx) + ΔH(F2) + ΔHv

Q°(Reactor)= 10221.693 kJ/min