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66 The The
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16
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Page 22
ammonia
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7 The Haber for the 33H 3 manufacture 22 C of OD
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7 The Haber process for the 3 manufacture of ammonia is represented by the following equation.
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NO = 8 O]
3 Use the Data Booklet N (g) is + 3H
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77
3H 2NH Section (g) A = –92 kJsodium mol–1
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10Na 2KNO K Ocan 22O Nmol
77For 7 How Organic
Most
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modern
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7 715For D
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11 The use of 7 the Data Booklet is relevant to this question.
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For How
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correct.
each many
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difficulties.
Choose azide, sodium
the oneNaN azide
you ? to
consider liberate
The use –
of the Data Booklet is +
relevant to this question. – –
Which statement is correct about this reaction 2 when the temperature is increased?
2
3
A D B H O C OD D OH
be Forcorrect.
each
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many
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temperature
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111be The use of the the Data Booklet is bag. relevant to
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be correct.
correct.
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when molecule. molecule.
the temperature D
temperature
D 4.0 is 4.0 is increased?
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be The
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use
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B
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relevant
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nitrate A AAmolecule.the D 4.0 4.0 is increased?
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AThe
Which 1.5diagram statement shows is B an
correct 1.6 about of this an
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reaction
C ! 3.22question.
3N nitrate
when A+ 2Na molecule.
the temperature
D
2NaN
HHNaHSO Section
3 3N + 2NaA under
3 2
33 What isisthe number ,of molecules inrates 500 cm 3of oxygen . frominroom conditions?
A The Bothdiagram forward shows and an example
backward ofrates an organic
increase. ! 2 nitrate
Section A
Section 2A
WhatBoth the number of molecules in 500 cm of oxygen under room conditions?
A 1.5
Both forward and B backward1.6 rates C
increase. 3.2 23N D 4.0
33For
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4 Sodium azide, NaN is an explosive used
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to 3 3N
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What is the number 3of molecules in 500 H cm of oxygen under room conditions?
3 A With forward NaCl and the ,, products
backward are 2NaN
2NaN 3!
increase.
33 ! 4 and
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22 + 2Na
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1 Granular urea, CON 3 of
H
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can
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rates
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3 What is the number of molecules in 1500 cm of oxygen
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2 4 2
For each
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and fournegative possible azide answers, ions. 3 and Choose the you consider to be
For each
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Both driver’sforward there airbag and are four
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50 four used
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D, are ,
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gases of power stations,
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1 Granular urea, CON 2 H 4 , can be used to 4
remove 2NO 2 2from 2 the flue gases of power stations,
A 3B,
converting it into harmless nitrogen.
1.25 xdriver’s
xit10
3For each
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first backward
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22
are
rate four
energies only possibleincreases.
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H Celements, O NO
1 Granular urea, CON H , can be used to remove NO from the flue gases of power stations,
A g1answers,
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be
For
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beFor Forcorrect.
correct.
3 each
each
each A
correct.
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A typical
typical 1.25
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question
question
The
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six it10 there
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22
airbag
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2 four
rate 4four
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contains possible
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of 5050 fourgg1answers,
ofof
answers,
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2
elements,Section
Section
sodium 3A,
azide.
azide. B,
A AAto
B,
C,
C, C,
and
and
D, areand
D.given.
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Choose
2Choose
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the one you consider
consider to
to
A 1.25 x 10 H C C O
3A, B, O C,and NO 2D. one
converting into harmless nitrogen. 2
For each question there are four possible answers, 3 and Choose + the
youyou consider to to be
3 BA
The typical
converting The
first six driver’s
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harmless rate contains
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of 50 four of sodium azide. A to D, are given.
be
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correct.
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converting
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B 3+ six
xthe 10
into 22 harmless
B Be
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O NO zzDN Hethe
be
3
For correct.
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question backward ionisation
22
there rate
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possible four elements,
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D. Choose the one you consider to
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be Forcorrect. 22 2 Choose
What are numbers
22 of electrons in xxthe 2sodium ion and the azide N22 ion?
Calculate
each question volume
there are of nitrogen
four possible this answers, produce A, at B, room C, and temperature.
D. the one consider
B
C The forward israte only increases.
1.34 xthe 10
What
Calculate is the best 22
volume explanation of nitrogen for this
this difference
will produce in at products?
room temperature.
correct. B
C The forward rate only increases.
1.34 10 22
Which element is most likely to be in +Group →of the Periodic Table?
For Which
each element
question there most are likely four2CON to
possible be H 4in
+
H
Group NO
answers, 22 O 2 IV
→ 2CO
ofA, the B, + yyand
Periodic
C, H
and OD. D. +
+Table?
Choose one you you considerconsider to to
H O
Calculate the 22
volume of 2CON
nitrogen 2 H
this 4 will NO produce 2 2CO at 2
room + Htemperature.
2O
2
temperature.
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For C each The question forward there rate are only four increases.
possible answers, A, B, C, Choose the one
1.34 xxxData 10volume
be
beFor correct.
Calculate
each
Which
correct. question
element the volume
there is most are of nitrogen
four
likely possible
to be2this in will
answers,
Group produce IV A,
of atB,
the 2
room
C, Periodicand D. Choose
Table? the one you consider to
31022 H O
2CON Hin +Group xNO NO 2CO ++yyyH H O ++Table? zN N22
B
CCalculate The forward
the rate ofonly nitrogen increases. 3this +will produce at room temperature.
1.34
Which element is most likely to be 2H 44+ 2IV →2of the 223Periodic 2O
beD correct. 22
2CON xxNO → 2CO +Periodic H + zzN
B O
C The forward rate only increases.
H
3 3
1.34 310
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the 22O D
DTable? dm333
C 3.0 x 10
A 9.2 dm 22
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C 3.0 x 10
A
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Chloride
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forward 3rate. 72.0
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1 Use of the Data Booklet is relevant to this question.
C
What are the values of x, y and z in a balanced equation?
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D A 9.2
There dm 3 no effect B on 13.9 the dm 3
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What of
3.0
ionisation
9.2
There the
isare
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xthe
the 10
Data
is 22 no
correct Booklet
effect B of on is 13.9 ofrelevant
ythe the dm backward
bond toathis angles Cquestion. 27.7
or forward
forward
shown
2 dm in rate.
inascending D 72.0 order dm(smallest first)?
What are the 22 values x, and zbond in balanced equation?
818 C
Use of 3.0 isthe xkJ 10 Data Booklet is relevant aato this question.
DWhat There is the is correct
22 no effect order on ofthe the backward angles or shown
2 rate. ascending order (smallest first)?
81
the values of x, yItyis and zvolatilein balanced equation?
1 D
InUse
What
D
B
NWhat leaded
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ionisation
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Hydrogen
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x
a x 10
the
10
poisonous Data
petrol2626values
correct chloride Booklet
there of
order 1st
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moreand
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z2nd
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anglesthis
than Section
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composed
3rd question.
of shown
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hydrogen
safely A4th 4thofinby lead,
ascending
iodide.
reaction 5th carbon
5th order
with 6th
and6th
sodium (smallest hydrogen
hydroxide. first)? only.
only. This
1 Use of the Data Booklet is relevant to this question.
1 InN 2 leaded
O ionisation
4 is a petrol
poisonous −1 there gas. is It an
can additive
be disposed composed of safely of by lead,
reaction carbon with and
sodium hydrogen
hydroxide. This
8 D
energy / mol 26
What is the correct −1 order of the bond angles shown in ascending order (smallest first)?
3.0 x 10
2 4 1st 2nd 3rd 2 4th 5th 6th
1 Use A of
4 isthe Data 10 Booklet is relevant 20 to this question.
energy ionisation / kJ mol
8 1 8 11
D
In
In
InWhat
Use
N
compound
N leaded
O
leaded
2leaded
O
energy 3.0of
is
is
thexathe
/a kJ 10
petrol
Data
contains
poisonous
petrol 26
correct
poisonous
petrol
mol
26
−1 there
there
Booklet
there order
29.7 gas.
gas.1st %is
is
is of
is
ItItcarbon
an
an
the
can
an
relevant
can additive
2ndbebond
be
additive
additive and disposed
disposed
to
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this
6.19 composed
composed
3rd
composed % shown
of
2
question.
of 3safely
hydrogen
safely 4th
of
of
in
of byby lead,
ascending
byreaction
lead,
reaction
lead, mass. 5th carbon
carbon
carbon withorder
with and
sodium
and6th
sodium
and (smallest hydrogen
hydroxide.
hydrogen
hydroxide.
hydrogen first)? only. This
only.
only.
This
This
D
compound contains 29.7 % carbon and 6.19 % hydrogen by mass.
3.0 xthe 10
88 4
4 1 Use A N
What
What
A
Use 22 O
energy 1of
414
of is
is
is→ →the
thea
the
/
the 2 kJ
2x
x poisonous
→ order
Data
→ mol
order
Data 26 3 3 −1 of
Booklet
of
Booklet y
y B gas. 1st
increasing
increasing
B 2is2It → can z
relevant
→
isreducing z
relevant1 1 be
2nd
energy
→
energy → 3disposed
3 to of
of this
toanswers, 3rd
the
C
the C
Section
this of
listed
3
question.
listed3safely
question. → → A 4th
orbitals
1 →
orbitals
1 →by 2 2reaction
in
in 5th
the
the D D with
atom
atom 3 3 → →sodium
6th
of
of 2 2 titanium?
→
titanium?
→ 1 1hydroxide.
compound contains −1 29.7 % carbon and 6.19 % hydrogen by mass. you–21
to33××10
4 Analytical Section Aorbitals
488 xxchemists can detect very small amounts of amino 2acids, down to 10–21 –21mol.
For each
C energy
compound question
Iodide /2 kJ mol
ions
contains 3there −1are are
better
29.7 %four carbon zpossible and agents 6.19 %than A,
hydrogen chloride B,→+ C,by by and
ions.mass. D. Choose the 1one consider to
Analytical chemists can detect very small amounts of amino acids, down mol.
What is order
xcontains of yO increasing energy of the listed in the atom of titanium?
4 A
Use
compound
44 correct.
What
B
1
of is→ theAthe →
Data
order
10
Booklet
N of y29.7
O B (g)%
(g)
increasing
494 2+ →
iscarbon relevant
2NaOH(aq)
zz 22 114560
energy→and 33 to to 6.19
of this
→ CNaNO
Section
the
6940 % 33 →
question.
hydrogen
listed → (aq)
A 11 →
orbitals
9540 2NaNO inmass. the
13400 D(aq) atom 33+ + → H
of
16600 2titanium?
O(l) →1
×
N 2 4 + 2NaOH(aq) → NaNO 3 (aq) +22 NaNO 2 (aq) +→ H 2 O(l)
Analytical chemists can detect very small amounts of amino acids, down to 3 10 mol.
What
A 1 is→ theA22 → order 33 of 2y increasing
B 4494 2 → energy
4560→ of the
6940C listed → orbitals
9540 → in the
13400 D atom → of
16600 2titanium?
→
42For 4 8 Use
A
Use of
1of →the
the Data
→
Data Booklet
N
Booklet O B (g) 2is
is + → relevant
2NaOH(aq)
relevant 1 → 3 to this
→
thisSection
C NaNOquestion.
3
question. 3A
1
(aq) + NaNO D (aq) 3 H 2 2
→
O(l) 1
O(l) to 3 × 10–21 –21 mol.
Analytical chemists can detect very small amounts of amino acids, Hdown
be
4234Foreach How many molecules of an amino acid (M = 200) would this be?
A 494 4560 Section
6940 A 9540 13400 16600
In the preparation of soft margarine, glyceryl trieleostearate
What is the value Yof N22 2x
xO in4 inthe
(g) + 1¼ empirical
2NaOH(aq) formula → NaNO PbC 3(aq) H ? + NaNO NaNO 2(aq) ++16600 2
How many molecules of an amino acid (M = 200) would this be?
A 1½
×
Elements X and are the same group of the Periodic Table.
Analytical
In the preparation chemists of can
soft detect
margarine, very small
glyceryl amounts
trieleostearate of amino acids, down to 3 10 mol.
A
What
A A 3s
3s is 3p
the
3p A 1½ 3d
3d value 4s
4s of
N 2O
2 4in
4 (g)
494 the + 1¼ empirical
2NaOH(aq) 4560 formula→ 6940 NaNO PbC 3(aq) 8 HC,
89540 X
X ?+ 13400 2(aq) H
1660022O(l) –21
r
3 2Choose
How many molecules of an amino acid (M = 200) ?would this be?
2.920 g
question of a Group
there are II metal,
four possible X, reacts answers, with r
an A, excess
B, and of D.chlorine to the form one 5.287
you g
consider of a compound
to
22 In the preparation ofof soft margarine, glyceryl trieleostearate
What
D
2.920
each
A
What AA is
Sulfuricg
question
3s is 3pthe
theA
of 1½1½ 3da value
valueacid
Group
there
4s of of
is 22 x
able
are
x II in
494
in metal,
four
thethe
to act
1¼ 1¼empirical
possible
empirical 4560
X, as a
reacts formula
dehydrating
answers,
formula 6940
with –3 PbC
an
PbC A, agent9540
excess
B, H
8HXC, ?
X? and with of 13400
NaI.
D.chlorineChoose to the form one 5.287
you g
consider of a compound
to
How C many amolecules
12 of an amino
20 acid (M = 200) would this be?
A 3s 3pB 3d 4s 736 1450 7740 10500 13600 18000
In the preparation of soft margarine, glyceryl trieleostearate
–3
–3rNaOH(aq)
What
What
2.920
Forcorrect.
each A is is
g
question the B
the
of 1½ value
minimum
Group
there 2xare II in736
volume the
metal,
four 1¼ empirical of
possible X,1450 0.5 reacts mol formula
answers, dm 7740
with PbC
an A, 8HXC,
10500
excess
8B, needed
and ofD. 13600
D.chlorine to
Choose dispose 18000
tothe the form of
one 0.02youmol
5.287 g of
consider of N a22O ?
compound
to
How many molecules of an amino acid (M = 200) would this be?
A 3s 3p 3d 4s
2be In the preparation 22.of soft margarine, glyceryl trieleostearate
What is the minimum volume of 0.5 mol dm NaOH(aq) needed to dispose of 0.02 mol of N O 4?
4
beForbe 2.920
with
each
correct.
with B formula g
question
formula ofB 2 a Group
XCl
XClthere . 4 are II 736metal,
four possible
3 X, 1450 reacts answers, 7740
with –3 r16
–3 an A, B, 10500
excess C, and of 13600
chlorine Choose 18000
to form one 5.287
you g
consider of a compound
to
A
AB
B What
2.920
Forcorrect.
each B
What 5
5 3s
3s g is
question
is3p
3p Bof the
the 2 4s
4s a minimum
3dGroup
there
minimum
3d 4 Bare
B II volume
volume
736 6
metal,
four
6 possible
3 ofof
X, 1450 0.5
0.5reacts mol
mol answers, dmdm
C
Cwith
7740 rrNaOH(aq)
NaOH(aq)
an A,
NaOH(aq)
16 excess
B, 10500 C, and needed
of
needed D. D
chlorine
13600
D Choosetoto20
20 dispose
dispose –1
to the
18000 form of
one
of 0.02
5.287
you
0.02 mol
mol g
considerofof NN
a 2OO to 4??
compound
A 9 B 22..200
2 6 33CC 3 1800
16DD 6220 360 000
The
What table is the shows minimum the first
volume six ionisation
of 0.5 mol energies
dm of X and needed Y in kJto mol
dispose . of 0.02 mol of N 2O44?
A B
with formula XCl .
9cm 200 1800 360 000
A BB B
B5 5 3s 3p B 2
24s 4sXCl 3dthe 4 B 736 3 1450 7740
C 10500 13600
D 20 20X. 47000 18000 2
be1be correct.
with formula 44B
2CH 33(CH ))33CH CHCH CHCH anCH(CH
22))780 CO 223CH
CC 1090 2350 4610 37800
A D 53s 12 Blime, 22
C2350 D
A B 3s 3p 4s 3d B 6612.5 C 16 D
98cm 200 1800 360 000
3
32 3 3 3
CH (CH CH CHCH CHCH CH(CH CO CH22
The
correct.
A B
with
A table
3s
8formula
8 3p gives 3d
XCl B 1090
successive cm 2350
ionisation C 4610
C energies16 40 cm 6220
for
3 element 37800
D D 20 80 cm 47000 3
A 9 B 200 223½ C 1800 D 33 360 000
AAC BB 12.5 cm C 40 cm D 80
7
cm
CH (CH ) CH CHCH CHCH CH(CH ) CO CH
C 33 3 4 1090 2350 33added 4610 6220 37800 4700033
16 What C
CA
InAC
What C some 3s 89is
is cm4s
cm
4s C
metal 3
areas
3
metal 3p
3p 3d
3d B X?X? 200
CH
4 B1090
Ca(OH)
3 (CH
12.5
12.5 2
3½
))3CH3 CH
,C
cm
cm is 3
1800 CHCH
to C
4610
C soil 4040 D
CHCH
to cm
cm 6220
improve
3
360 000
CH(CH
crop37800DD
)of
growth.
2 80 7CO
cm
cm 47000
2 CH226th
CH (CH22of CHCH CHCH CH(CH 222)as CO 222CH
AC C 83s cm 4s C 3 3p 3d 4 B 1090 12.5 3½ 2cm 2350 4610
C 40 cm 6220 37800
D 80 cm 47000
529
151 A CC C 3s
What
Which
Which 3sisof 4s
4s
ofD D33
metal 3p3p
these
these 3d 3d X?samples 44 1400
samples 331st
1400
3 contains
3½
3½
2of 33 gas 2860
2860
gas 2nd contains
contains 4590
4590 3rd thethe 7480
same 7480
same 4th number
number 9400
9400 777of
5th 53200
53200
atoms
atoms 22 as as 1g 1g of of hydrogen
hydrogen
95215 5 1 9 A
What
DWhatD
Which household
4s is
is 3sof metal
D33p
metal these 3d X?
bleach
X? CH
CH
4
samples 1400(CH
33(CH )
of
22of
3 CH
)333CH 2860
gas sodium CHCHCHCH
1st
contains 4590 chlorate(I),CHCH
CHCH
2nd
the 7480
same 3rd CH(CH
CH(CH
NaClO,
number 9400
22 )
4th CO
)7of
7CO
of its CH
22CH
53200
atoms active
5th ingredient.
as ingredient.
1g 6th of hydrogen The
54 9 CH (CH ) CH CHCH CHCH CH(CH ) CO CH
2 ADrD household D bleach 1400 contains 2860 sodium 4590 chlorate(I), 7480 NaClO, 9400 as 53200
its active The
2252 Use
9 21 (M
AA
AUse
Which
(M
Which
Which D:
concentration
The
r of
H
ofGe
household
: H
4s
barium
68
barium
household 2
2the
2, ,
the
of2)?
3s D
2)?
statement
of 3 3 Data
3p Data
these
these
isotope
3d
of bleach
bleach Booklet
Booklet
samples
NaClO CH
4
correctly
samples
is
4 1400
4 medically
CH 3(CH
contains
contains
(CH is
in is22))relevant
3relevant
3CH
describes
of 3
the
CH
2860
gas
gas sodium
sodium
bleach
useful to
contains
CHCH
contains
CHCH
a this
tobecause this
4590
reason
can question.
question.
the
chlorate(I),
the
chlorate(I),
be CHCH
why 7480
same
same
determined
itmass
lime
undergoes
NaClO, number
NaClO,
CH(CH
improves
number 9400 by
a 225400
as
2)35
as of 7COcrop
reacting
natural
53200
atoms
its
atoms
its active
growth?
active a
radioactive
asas
2CH37 was analysed in a
known 1g1g
ingredient.
of
ingredient. of
amount
process
hydrogen
hydrogen The
The
with
to give
ofCHCH CH(CH )35
777CO 222CH
DD 4s ,3s 3p 3d
22222 aqueous
A sample of chlorine containing isotopes of mass numbers and
Use ofionisation
22,,the Data Booklet is22mol relevant to this this question.
D
(M 4s
:sample
H 3s 2)? 33p 3d
A barium
Arrr :sample
concentration of
X NaClO 33800 in 3
3H
the bleach can be determined by 2reacting
reacting a knownknown amount with with
Use
2 concentration
(M
concentration
AUse
(MA H
of
of
:barium
H 2the
2)?
the2)? Data
ofof
Data
of of chlorine Booklet
chlorineNaClO
Booklet
CH 3 /containing
(CH
in
containingis
containing
is ) relevant
3 22–1
the
relevant
CH O1600 bleach
CHCH
isotopesto
isotopes
to
can
this
2400
question.
be
question.
of
CHCH
mass
determined 4300 numbers
CH(CH
numbers by
)
35
CO
and
and
CH
10
a37
a37 400was12analysed
was analysed
amount in a
in a
CH (CH ) CH 68
CHCH CHCH CH(CH ) CO CH
hydrogen NaClO peroxide, in the bleach. isotopes can be determined by reacting known amount with
an isotope of a different element, X, which can be used to detect tumours. This transformation
AA rsamplebarium
mass-spectrometer. of chlorineenergy kJ 2 950 of1800 mass 2700
numbers 480035 and 6000
37 was 300
analysed in a
3 2 3 2 7 2 2
2
CH 3 (CH 2 3 2 7 2 2
2))H CH CHCH CHCH CH(CH 2)% CO CH12
44 B AB
Inaqueous
A
aqueous 22 22
mass-spectrometer.
which calcium
Lime
calcium g g of of
specieshydrogen
hydrogen carbon
acts carbon as are adioxide
peroxide,
dioxidethe
catalyst
peroxide, numbers (M(M H
which
r
H : :2CO
OO CO 2 . .
of2 , ,
speeds 44)44)
electrons up and
the neutrons
release of equal?
nitrates into the soil.
22O
24 A garden 2soluble ininwater’.
offertiliser is said to )3333have a phosphorus andcontent of 30.0 a ‘P
In which species are the numbers r
22. of
2 electrons and neutrons equal?
CH 3(CH rCH ,CHCH CHCH CH(CH 2))7the CO 2CH O
A garden tosoluble water’.
offertiliser is 33said to have 2a phosphorus andcontent of 30.0 7% ‘P
mass-spectrometer.
aqueous 68 g hydrogen peroxide, 2:O
of Ge ggoccurs Ywhen CH an (CH electron CH enters CHCH the a nucleus CHCH and CH(CH
changes 7CO 222CH
proton into a neutron.
BA
In
The which 22
mass-spectrometer.
calcium
diagram species carbon
shows are dioxide 1000
thethe mass numbers (M CO
2spectrum
1800 of 44)
electrons 2700 4800
neutrons equal? 6000 300
AA garden 22 of fertiliser
carbon is
dioxide said 2
(Mto
22 rrrhave
::spectrum
CO a,,O phosphorus
44) of sample
content
of zinc.
of
Use
30.0 2 %
data
‘P Oto
to
2
5225 calculate
soluble inthe
the
water’.
relative
4 BA
In which calcium
22 species are the 3 numbers CO of 22 44)
electrons neutrons equal? 2 7
A garden fertiliser is said to have a phosphorus content of 30.0 % ‘P O soluble in water’.
4 2 B B
InThe which calcium
diagram species carbon shows dioxide mass (M spectrum of a sample
and neutrons of zinc. Use
equal? the data 2 5
calculate the relative
Aatomic
garden Ophosphorus content of22(g) 30.0 % ‘P2– 222O555 soluble in water’.
2 The diagram shows are NaClO(aq)
the
the numbers
mass + H of 2 (aq)
electrons
+ of a→ NaCl(aq)
sample of +
zinc. O (g)
Use + H
the O(l)
data to calculate the relative
fertiliser is said to
F4, have Ha
2 C What
The
atomic
How
B 8 98 9 g could
diagram
many
Lime g of
mass
of methaneis be
peaks
methane shows
of
an thethe
effective (M
formulathe
sample.
corresponding
(M r : : CH 19
massCH19
pesticideof
4 , , 16)
a16) chloride
spectrum to and2
2 Cl 2
2 + of
were
protects X?
a 2323
sample
recorded?
the ++ of zinc.
plants from2
2 Use 18
the
damage. 18 2
2 data2–2– calculate relative
ACA magnesium
magnesium
9Be gBe B BNaClO(aq)
r
99F
4 + to (aq)
+ C C→ →11 NaCl(aq)
Na Na +O O (g)
D D+++H H O(l)
O O
is suitably hydrogenated 9so that, on average, Naone of O2its Dside-chains isis converted
converted into into the
22 23 18
is suitably hydrogenated so that, on average, +++one of itsD side-chains the
NaClO(aq) 2O 2O(l)
B How 48 many ofmass methane peaksof the (M
thecorresponding Brrr :: CH
sample.
corresponding
NaClO(aq) CH19 16) ++to H H 22ClO Cl +(aq)
2
22+(aq) were → NaCl(aq)
recorded?
NaCl(aq) + ++ (g) H 8
228O(l)
What 94
is the percentage by 44mass of phosphorus in the 68
fertiliser?
C atomic
How magnesium
many mass peaks of sample. to Cl were 11
recorded?
What is the percentage by ,mass of phosphorus in the fertiliser?
A Be F C O2–
Which statement theabout the composition 22 were
of an atom of X is correct?
23 18
is suitably hydrogenated so that, on average, one of its side-chains is converted into the
B 8 gBe of methane (M 19
© UCLES atomic
How 2016 99many mass peaksof sample.
corresponding 9701/12/F/M/16
recorded?
2Na
B 8 4 g of methane 19 4 16) 23 18 2–
C
What magnesium
could be the identities 19 of X and Y? 2311 18 8O
What is the percentage by mass of phosphorus in the fertiliser?
AC magnesium (M B : CH F , 2 Na O 2–
is suitably hydrogenated so that, on average, one of its side-chains is the
A C D
CH (CH ) CH=CHCH CH=CH(CH ) CO residue and two side-chains are converted into the
Be 3
CH (CH ) CH=CHCH CH=CH(CH ) CO residue and two side-chains are converted into the
r
is suitably average, 3 one of its side-chains is converted into the
C 20 4 g of neon 3 (M B
: Ne, 20)
9 F 11 8
hydrogenated so 2 that,with on
C 20 g of neon (M : Ne, 20)
What is the percentage by mass of phosphorus in the fertiliser?
When 4 25.0 cm of bleach is treated with 100 an excess 11 of aqueous H O 8 , 0.0350 mol of oxygen gas is
What is the phosphorus in the fertiliser?
AC XCl
Lime
4 is used to r r Breduce XCl the acidity of C the XCl
soil. D XCl
3 2 4 2 2 7 2
3 9 2 2
CH (CH ) CH=CHCH 2CH=CH(CH 2)100 CO residue
11
and two side-chains
8
320 2of 4cm percentage by mass of 7 2 excess 2, 0.0350are converted into the
DDA
C
When strontium
strontium
2
20 g
25.0 of neon
cm 33 of (M bleach
r B: Ne, 3 is 20) treated anC excess4 of aqueous D H 2O 5 2, 0.0350 4 mol of oxygen gas is
CH (CH )7ozone 4CH=CHCH
2CH=CH(CH 2)100 7CO residue and two twoD Dside-chains are converted
converted into into the the
When 25.0 of bleach is treated with an of aqueous H 2O mol of oxygen gas is
CH
D
CH 3(CH(CH
strontium g2)of
2222))%
4CH=CH(CH
CH=CH(CH ),)7,37itsCOCO residue.
2%residue. )100 2 residue
Aand DD side-chains are
C
When A 2 g
25.0 cmneon of (M bleach : B Ne, is3 20) treated with an C excess 4 of aqueous D H 2 O 5 2, 0.0350 mol of oxygen gas is
CH CH=CHCH CH=CH(CH 7CO
given off.
A Itstrontium
has electrons 222in outer Yp22orbitals.
C A 2004 2022g (Mrrr:B B 3 C 442 2 5 52
A B CC9701/01/M/J/04
neon : Ne, 20)
6.55 313.1 2% 26.2 % 30.0 %
! UCLES
!
333 4% 7
9701/01/M/J/04
2Section
A
CH 32004 (CH 6.55 CH=CH(CH rB ),13.1 CO residue. 26.2 % 30.0 %
UCLESDDA
given strontium
goff. 7lowers
4 32
C
9701/01/M/J/04
D D
UCLES 82004
8 ofof 4
ozone X (M (M r :O O 48)48) 2
9701/01/M/J/04
A B C D
given
! UCLES off.
!!
CH
UCLES
CH338(CH
given
D 3 (CH
2004
20048 6.55
Limeoff.
g of 2
222)% ) %
7 CH=CH(CH
CH=CH(CH
ozone (M the : pH O 2 ) 13.1
),13.1 7
of CO the
CO22%residue.80
48) 2 % residue.
soil. 26.2
9701/01/M/J/04 2 % 30.0 %
AA 3It 86.55
6.55 7ozone (MB O2233gives 7748) C yield 26.2
Page
26.2 22 %
of3%
4 DDat equilibrium? 30.0%
30.0 %
r 3
7ozone
%
7of Bhydrogen ,13.1
DD gg the of
of (M rr :: O
B
How
How many
many has 13
moles
moles electrons of of hydrogen in
48)
its outer are
are shell.
required
required 80 toto convert
convert 3one
3of one mole
mole ofof glyceryl
glyceryl trieleostearate
trieleostearate only ainto the
a into the
69 6 2 What
Which is set concentration
conditions of NaClO the highest in the 80
80
bleach? ammonia
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Which statement
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is2222(g) (g)
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A 10 cm of carbon disulphide was burned in 50 cm of oxygen. After measuring
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volume
measuredvolume
measured sodium
in
in of
one50again.
of
one the gatom
the
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resultantAll
resultant of
Allof this azide.
mixture
measurements
measurements
this isotope
mixture
isotope of
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81.
gases
81. were
werewhen when
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cooledat the
at theto
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room temperature
(to absorb ofHsuch O)nitrogen
What
and
B
What the
The would
would volume number be
be the
the of of final
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finalelectrons volume
measured in of
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measurements
this isotope ofis gases
81. were when
made cooled
at same room temperature
and
AB apressure,
Calculate the
The
higher volumenumber the pressurevolume of
is of gas 22of
electrons
2
volume
measured
nitrogen in one of this the
again. atomwill resultantAll of this
produce mixture
measurements isotope of
roomistemperature.
attemperature gases
81. were
temperature. made cooled
at the to
same room temperature
carbonate excess excess
Which
Calculate
temperature?
In separate species the volume
experiment not of planar? carried this outtowill atproduce
the same at room and pressure, a 0.005 mol sample
A As BB Zr C Te D
and under conditions that carbon disulphide was gaseous.
4 A C D IIIis
B temperature?the oxidation sulfur dioxide sulfur trioxide catalysed bygaseous. nitrogen dioxide
A
and
Calculate
temperature?
and
Calculate
temperature?
Nitrogen,
and 33
pressure,
33 As
pressure,
pressure,
As N the
the 2, volume
under
volume
under
volume
and
under B carbon such
such
40
of
such
40
of Zr Zr
nitrogen
nitrogen conditions
conditions
monoxide,
conditions C
this
this that
will
that
52
will
CO,
that
52 TeTe
carbon
produce
carbon
produce
both
carbon have D
disulphide
atat
disulphide
disulphide room
room
M 53 53
r=
was
temperature.
was
temperature.
28. was gaseous.
gaseous.
A
C
Calculate
C The
33 The As
number
the
number Bof
of of 40Zr
neutrons
of
neutrons nitrogen insolution
in 3C
one
onethis atom
52Te of
will
atom of
produce
of this
this D
atHCl
isotope
isotope
3 33(aq)
room
53IIis
201.
temperature. NaOH(aq)
A B C D
of anhydrous calcium nitrate was completely thermally decomposed. The volume of gaseous
A B
ACC lower
9.2 33
9.2
The
33
The
33 As dm dm
number
number 3Ba(NO
3
33temperature
3
of neutrons
) B (aq)
B 4040Zr
neutrons
40 13.9 13.9 in
dm +in
dm 33oneone 3 atom
atom 52Te
52 C C
of this
Q
this isotope
27.7
27.7
isotope
dm dm 33 3353 53
53
is 201. 201.
D D R 72.0
72.0 dm dm 333
3
3
S
BF 3 2 B CH C C H D NH
AC 20
the cm reaction 3 between B 30 cm
nitrogen 3 3 3 monoxide C 50 and cm carbon monoxide D 70 in 3a catalytic converter
What
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products
A 20
What 9.220were
201
20 were
201
3 cm
dm
cm was 3 the
3
3
3thethe measured.
measured
measured B B
BB2 isof 30
13.9
30volumes?
201 cm
cm
volumes? 3 dm 3 3 C C
C 27.7 50
27.7
50cm 2 cm
cm dm4 3 3 D D 72.0 72.0
70cm cm
cm 3
dm 3 3
3
A
What
D 9.2 were cm
X dmX is an measured
isotope 13.9
30 201
cm
volumes? dm
Tl.Tl. 3 CC 50 dmdm3 D D 70 dmdm3
Abul Fazal Moles 1
A D 9.2 201 is anmeasured isotope of 201
The
What
DD boiling
201
82 82dm
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is point
the an
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isotope B of
of 13.9 77
volumes?
20181
81 K. dm
Tl.
Tl. C 27.7 D 72.0
C more8282 polar molecules 81
81 9701/1/M/J/03
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The
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produced
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vessels PP
P and
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the
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nitrate?
apparatus are are
are M M
are MMPPP and and
and
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MQQ ,,
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M, and are magnesium compounds.
The2004 increases in mass of 3 the collecting vessels P Q of apparatus
The boiling volume
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gas
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gas after
The increases in ofmass of the collecting vessels P and Q of the apparatus are M and M Q
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644UCLES What
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titanium?
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P Q
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UCLES
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9701/01/O/N/04listed
NaOH(aq) orbitals / cm in the atom of titanium?
respectively.
4
 What 2004 is the order
after
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adding the
9701/01/O/N/04listed
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4 What AQ, respectively.
R50 iscm
and theS afterorder
are burning burning
bariumof increasingB //compounds. cm cm
100 3
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adding of the NaOH(aq)
C NaOH(aq)listed
200 cm orbitals / cm D 250 cm3