Your Name: ________________________________________________

CHEM 1411; CHAPTER 6 PROBLEMS

TO BE SOLVED AND RETURN NEXT SATURDAY (04/16/2016) @8:00AM

_______1. Calculate the standard enthalpy change, ΔHo, for the formation of 1 mol of
strontium carbonate (the material that gives the red color in fireworks) from its elements.

Sr (s)  C(graphite)  3
2
O2 (g)  SrCO3 (s)
The information available is
(1) Sr (s)  1
2 O2 (g)  SrO (s) H  - 592 kJ
(2) SrO (s)  CO2 (g)  SrCO3 (s) H  - 234 kJ
(3) C(graphite)  O2 (g)  CO2 (g) H  - 394 kJ

_______2. The combination of coke and steam produces a mixture called coal gas, which
can be used as a fuel or as a starting material for other reactions. If we assume coke can
be represented by graphite, the equation for the production of coal gas is

2 C (s)  2 H2O (g)  CH4 (g)  CO2(g)

Determine the standard enthalpy change for this reaction from the following
standard enthalpies of reaction :
(1) C(s)  H2O (g)  CO (g)  H2 (g) H  131.3 kJ
(2) CO (g)  H2O (g)  CO2 (g)  H2 (g) H  - 41.2 kJ
(3) CH4 (g)  H2O (g)  3 H2 (g)  CO (g) H  206.1 kJ

________3. One reaction involved in the conversion of iron ore to the metal is

FeO (s)  CO (g)  Fe (s)  CO2 (g)

Calculate the standard enthalpy change for this reaction from these reactions
of iron oxides with CO :
(1) 3 Fe2O3 (s)  CO (g)  2 Fe3O4 (s)  CO2 (g) H  - 47.0 kJ
(2) Fe2O3 (s)  3 CO (g)  2 Fe (s)  3 CO2 (g) H  - 25.0 kJ
(3) Fe3O4 (s)  CO (g)  3 FeO (s)  CO2 (g) H  19.0 kJ

_____4. How much heat is released when 75 g of octane is burned

completely if the enthalpy of combustion is -5,500 kJ/mol C8H18?
C8H18 + 25/2 O2 → 8CO2 + 9H2O
Your Name: ________________________________________________

a. 7200 kJ
b. 8360 kJ
c. 4.1 × 105 kJ
d. 3600 kJ
e. 5500 kJ

______5. Calculate the amount of heat released in the complete combustion

of 8.17 grams of Al to form Al2O3(s) at 25°C and 1
atm. ΔH for Al2O3(s) = 1676 kJ/mol
4Al(s) + 3O2(g) → 2Al2O3(s)
a. 254 kJ
b. 203 kJ
c. 127 kJ
d. 237 kJ
e. 101 kJ

______6. Given the following at 25°C and 1.00 atm:

ΔH0
1/2N2(g) + O2(g) → NO2(g) 33.2 kJ
N2(g) + 2O2(g) → N2O4(g) 11.1 kJ
0
Calculate the ΔH for the reaction below at 25°C.
2NO2(g) → N2O4(g)
a. +11.0 kJ
b. +44.3 kJ
c. +55.3 kJ
d. -22.1 kJ
e. -55.3 kJ

______7. Calculate ΔH0 for the following reaction at 25.0C.

Fe3O4(s) + CO(g) → 3FeO(s) + CO2(g)
ΔH (kJ/mol) -1118 -110.5 -272 -393.5
a. -263 kJ
b. 54 kJ
c. 19 kJ
d. -50 KJ
e. 109 kJ

______8. How much heat is released when 6.38 grams of Ag(s) reacts by the
equation shown below at standard state conditions?
4Ag(s) + 2H2S(g) + O2(g) → 2Ag2S(s) + 2H2O(l)
Your Name: ________________________________________________

Substance
Ag(s) 0
H2S(g) -20.6
O2(g) 0
Ag2S(s) -32.6
H2O(l) -285.8
a. 8.80 kJ
b. 69.9 kJ
c. 22.1 kJ
d. 90.8 kJ
e. 40.5 kJ

_____9. Which of the following is not a state function?

a. temperature
b. pressure
c. work
d. volume
e. enthalpy

Use additional paper if it’s necessary to show all your work for full credit
Your Name: ________________________________________________

1. Given the following equations and Ho values, determine the heat of

reaction (kJ) at 298 K for the reaction:

B2H6(g) + 6 Cl2(g) 2 BCl3(g) + 6 HCl(g)

BCl3(g) + 3 H2O(l) H3BO3(g) + 3 HCl(g) Ho/kJ = -112.5

B2H6(g) + 6 H2O(l) 2 H3BO3(s) + 6 H2(g) Ho/kJ = -493.4

1/2 H2(g) + 1/2 Cl2(g) HCl(g) Ho/kJ = -92.3

2. Given the following equations and Ho values, determine the heat of

reaction (kJ) at 298 K for the reaction:
Your Name: ________________________________________________

2 OF2(g) + 2 S(s) SO2(g) + SF4(g)

OF2(g) + H2O(l) O2(g) + 2 HF(g) Ho/kJ = -276.6

SF4(g) + 2 H2O(l) 4 HF(g) + SO2(g) Ho/kJ = -827.5
S(s) + O2(g) SO2(g) Ho/kJ = -296.9

3. Determine Ho/kJ for the following reaction using the listed

enthalpies of reaction:

N2H4(l) + 2 H2O2(g) N2(g) + 4 H2O(l)

N2H4(l) + O2(g) N2(g) + 2 H2O(l) Ho/kJ = -622.3 kJ
H2(g) + 1/2 O2(g) H2O(l) Ho/kJ = -285.8 kJ
H2(g) + O2(g) H2O2(l) Ho/kJ = -187.8 kJ

4. Calculate the value of Ho/kJ for the following reaction using the
listed thermochemical equations:

P4O10(g) + 6 PCl5(g) 10 Cl3PO(g)

Your Name: ________________________________________________

1/4 P4(s) + 3/2 Cl2(g) PCl3(g) Ho/kJ = -306.4

P4(s) + 5 O2(g) P4O10(g) Ho/kJ = -2967.3
PCl3(g) + Cl2(g) PCl5(g) Ho/kJ = -84.2
PCl3(g) + 1/2 O2(g) Cl3PO(g) Ho/kJ = -285.7

5. Given the following equations and Ho values, determine the heat of

reaction (kJ) at 298 K for the reaction:

2 SO2(g) + 2 P(s) + 5 Cl2(g) 2 SOCl2(l) + 2 POCl3(l)

SOCl2(l) + H2O(l) SO2(g) + 2 HCl(g) Ho/kJ =+10.3
PCl3(l) + 1/2 O2(g) POCl3(l) Ho/kJ = -325.7
P(s) + 3/2 Cl2(g) PCl3(l) Ho/kJ = -306.7
4 HCl(g) + O2(g) 2 Cl2(g)+2 H2O(l) Ho/kJ = -202.6
Your Name: ________________________________________________

6. Calculate the heat of combustion (kJ) of propane, C3H8 using the

listed standard enthapy of reaction data:

C3H8(g) + 5 O2(g) 3 CO2(g) + 4 H2O(g)

3 C(s) + 4 H2(g) C3H8(g) Ho/kJ = -103.8

C(s) + O2(g) CO2(g) Ho/kJ = -393.5
H2(g) + 1/2 O2(g) H2O(g) Ho/kJ = -241.8

7. Given the following equations and Ho values given below, determine

the heat of reaction at 298 K for the reaction:

2 N2(g) + 5 O2(g) 2 N2O5(g)

2 H2(g) + O2(g) 2 H2O(l) Ho/kJ = -571.6

N2O5(g) + H2O(l) 2 HNO3(l) Ho/kJ = -73.7
N2(g) + 3 O2(g) + H2(g) 2 HNO3(l) Ho/kJ = -348.2
Your Name: ________________________________________________

8. Given the following equations and Ho values, determine the heat of

reaction at 298 K for the reaction:

C(s) + 2 H2(g) CH4(g)

C(s) + O2(g) CO2(g) Ho/kJ = -393.5
H2(g) + 1/2 O2(g) H2O(l) Ho/kJ = -285.8
CO2(g) + 2 H2O(l) CH4(g) + 2 O2(g) Ho/kJ =
+890.3