Kee Last Fit FOR ALL EQUILIBRIUM PROBLEMS, YOU MUST: 1) Write all equilibrium equations 2) Write all equilibrium concentrations 3) Write all equilibrium expressions SET A: a) a) What is the equilibrium constant expression for the reaction: BFels) +4 H20(q) ememte Feg0g (5) + 4Hp (g) Ans: [Hal“Ha0)4 b) The equilibrium constant, Ke, for the reaction 2NOCI (9) w= 2 NO (g) + Clo (a) is2.4x10°7 3 ‘What is the equilibrium constant, Ke, for the reaction: K= +s ¢ 18 Cla(Qg)+ 28NO @) =—— 28 NOCI g) 24 Mle Ans: 1.6 x10? ¢) Given the following equilibrium equations and their corresponding equilibrium constants: 0 2 CO2(g) + H20 (g) => +2 02 G) + CHZCO @) Ke= 61x108 Y Gg (9) + 2 Op (@) —— Wp @) + 2 HO 9) ke =1.2x1014 a Kg for the reaction: CH4 (g) + CO2 (g) == 200 (g) + HeO (g) setup: Aad senna a) ond saa “ha num ta “puaion Gii) _ GC (xlo Lo +2 KIO ) W) © oval * = 23KI0" Ans: 7.3.x 1072 2) A mixture of 9.22 moles of A, 10.11 moles of B, and 27.83 moles of C is placed in a one-liter container at a certain temperature. The reaction is allowed to reach equilibrium. At equilibrium the number: moles of B is 18.32. Calculate the equilibrium constant for the reaction: A@+ 286 == 3¢6 Fritial cme Qa No. a 27.33 . GAO =e : + lange we nO are CATS eT silpiua | 99210 = 15651 wpe a 13-32 vo atin “CCA ayn 8 tui (ontes) = Naam / 2 (CV. (ssiy? = (0: 832 TAXLBY (aaryliea2)* a Ans: 0.8323) a) Ata certain temperature, Ke is 4.13 x 10“? for the equilibrium: 2 IBr (Q)} ee ia (Q) + Bra (@) ‘Assume that equilibrium is established at the above temperature by adding only IBr (g) to the reaction flask. What are the concentrations of Ig (g) and Br2 (g) in equilibrium with 0.0124 molesfiter of |Brig) ? Setup: ° 2 Fb) = x) + , 8 G) satus e tual conc. | Msestil a e =Te eH + & va CME mI Qie Ony x ais _ CUR inbid = is we > LL SEAT CE Bry? -2 Cony) Pe 79-52% to = UWt- (Rys Me aseree Ans: 252% 103M . b) What was the initial Concefitration of IBr before equilibrium was established? See As te ax = .0lzy Wi Tod = -O10Y 42% _ = OIG ezUsrzX!lo 3) Tony Ans: 0.0174 4) 0.924 male of A (g) is placed in a 1.00 liter container at 700 ° C, where it is 38.8 % dissociated when equilibrium was established. 3 A (g) = *“5 B (9) +2C g) What is the value of the equilibrium constant. Ke, at the same temperature? ‘Setup’ Cc ft 3A 6) ss BH) RO GD) aikef une 0.924 e 40°23 + +54 se gd SS yn tme a " BES x saunas asd me Ay mitio® \ = G 0-3 59 A (2mello = foie oasgmelA(smelia® | . 2598s smh hl prmue eS 4 = Z vidihyivyen tay 354 pe O+S9% 0.239 phe = S66 Ans; 0.0241 2 TBIPLCI . (.s4b)"(-wa)? = 024! ~rAy? S66)?5) The equilibrium constant for the reaction og Ss Na (9) + O2 (g) is 2.60 x 10°3 at 1499 = C. 10.820 mole at NO (9) and 0.223 mole each Of Na (9) and Op (g) are mixsd in a 1.00 liter container at 1100 ° G, ‘what are the concentrations of NO (9), No(g), and O2 (g) at equilibrium? Setup: Se CCR) = (#233) Cores) (oy Laue = THO Kig-® Q> kj enc proceeding ppentamesuat, & Mu BBP 2N6 (9) => Nu, 'y) ~ oO (5 (-820 +2x)? 0 -0Slo = (223 -x ) (-ba0F2x ) = OFlby M a Tol -[M,3 -o1223 -x = 1U2Z— 1 Y = 6OS58B TNO\+20: B20 42x = B2042(-164 ) ee Ans: INO}= 1.45M. [Na] = 0.058 m [ClgJ= 0.058 mSETB: 1) {mixture of 1.16 mole of A, 1.35 mole of B and 0.641 mole of C is placed in a oneuiiter container at a certain temperature. The reaction was allowed to reach equilibrium. At equilibrium. the number ot moles at Als 1.95. Calculate the equilibrium constant, Ke, for the reaction: i 2A@ =~ 2 B @+C @ Setup: Xitel cone. hate me Une x7 LEVEL = (5 0)* C2ue) Cas)? fat aa Ans: 0.020 2) 0.822 mole of S03 (g) is placed in a 1.00 liter container at 600 K. 36.7 % of the S03 (Q) are ‘decomposed when equilibrium is established. 2 S03 (9) ==> 2 S02 9) + 02 @) ‘What is the value of the equilibrium constant , Ke, at the same temperature? bled jetup. 2 $4 fy) = 286 6) - 0 ty ) Emtec. 9.9422 ° P Boz i Fang be GC — 05402 | aoe + Aa) j Suet Bab ou POE Zoned (2S) grwe = #S20 Ks (SO,3L O23 Cred? ist) = Sop yo? 136 5% (+520)? CU 3 ML Ans: 5,05 x 1023) For the equilibrium: 2 BrCl (g) =—* Bre (g) + Cig (g) - at 205 * C, the equilibrium constant, Kc, is 0.143. If 1.34 moles each of Bro (g) and Cip (g) are introduced in a comainer which has a volume of 11.0 liters and allowed to reach equilibrium at 205 * C, what would be the concentrations of Br2 (9), Clz (g), and BrCl (g) at equilibrium? ‘ ) Semp: a Bc(P (4) = By 8) + a : us ra ° sited unt ° ee 2 Zt ae n~A—S = as =e Change vo cone onl2 = % ele ce | 2% ' we(B thd 5 Yas = (eee) (2% )2 (8. Uy* = 10693 (853 SAGA. viaz-e er 10693 =(ESaTM ans: [Cla]= 0.0529 M Br = 2x 20.0643) L139 > pe ele 4) a) Whatis the numerical value of the equilibrium constant, Ke, for the reaction 3.N2 g) +3 02g) =— > 6 NO @ if the equilibrium constant for the reaction: 2NO@) =— > N2@) + 02 (9) isa5x10% _ — 3 t Kis Gaawy * (02860) ‘(23x10 '* (Bs KIO" _ Ans: 23 x101 b) What is the equilibrium constant expression for the reaction: 2 Ni (s) + 2 CO2 (g) _———> 2 CO (g) + 2 NiO (s) ~ Ans: K= (CO)2qc02] Setup. 5) Forthe reaction: 2 (g) + O2 (g) —» 2 NO3 (Q) atg923°C , Kean ° 0.0500 mole of NO2 (g). 0.122 mole of Op (g) and 0.300 mole of NO3 (g) are mixed in a 1.00 titer container at 923 * C,in what direction will the reaction proceed?(Show your calculation to Byove mat your answers nt a guess.) / up: : Setup: 2nd, (9) os oo) => * NG 9/ Roo 10500 122 Q- c¢wa)> = _(osee)® = 295 (va, (0,) (10S 00 2-122) Gos 5 WE cetlim will potted spentomcarly 2 te te BAT Answer: Qc > Kc ( The reaction will proceed spontaneously to the lett)SETC: 1)” For the equilibrium: NO g) 2 No (g) + O2 (g) at 300 K, the equilit a cofitainer that has a volume of 6.00 liters and allowed to rei concentrations of N2 (g }, O2(g),and NO (Q) at equiltorium? rium constant, Ke, is 0.185, If 1.45 moles each of N2 (g).and O2 (g) are introduced in ‘ach equilibrium at 300 K, what are the Se me 2NO (9) = Wi? & OD) | la. ay | bare wy Taibel ime © | Chany ve CAE ¥1e 4 Cun \iol os alley 2-x) (202-2) (2x y+ X= 130 as s12yie Mir [Nol= 0.112M (NX. 3 = L632 24 Geom LNO}2 2% = 2.130 INO}= 0.260 2) 1.87 mole of A (g) are placed ina 1 ainey at 700 K. when the reaction reached equilibrium 2 AQ) 3 Bg + Cg What is the vaiue of t Setup, 43.3% of A (g) had decomposed ne equilibrium constant, Ke, at the same temperature? 2A ly) = 3B fy) + oY Total come en piss navi ne =e ros ah WOT O10 = VOC { 4) ae be 433, armel As 1 Gio mee A tacked foo wa" : amolioe 0. promot A cadeng zmits A 0:10 mote" A” runing (cmetee )s % mutey A 121) Mevos NC hes +6. > _ceUted 1 - {Ax Ans: = F271 mobs B gomed weds C formed «Yod = 2,6 39) 0.6393) a)_What is the equilibrium constant expression for the reaction: 2 Fe(s) + 2 NOp (g) =_—» 2 NO Q) + 2 FeO (s) Ans: K= (NO}NO2]2 b) What is the numerical value of the equilibrium constant, Ke, for the reaction: 2903 (g) ———-_ 2 S02 @) + O2 (9) if the equilibrium constant for thé reaction: 2 02 @) + 802g == 803 g) is27 x109 ? Setup: S Ke: 1—, = Py ylo (a-tx0" >) Ans: 1.4 x105 4) Amixture of 3.31 moles of A, 4.33 moles of B, and 5.95 moles of C is placed in a one-liter container at a certain temperature. The reaction was allowed to reach equilibrium. At equilibrium, the number of moles of B is 6.16. Calculate the equilibrium constant, Ke, for the reaction: A@==38@ +2 CQ) Setup Loach ce 3:3 as, ?. twicme: 1 os é > vnlea B J __ameisa © =e 1722 motes formed pom a mit B mee A o- 6) mak FA ceap “ \i bd mols Famed a meter B A &) Se BO) FOG) Toil _ 433 OIE ume = 0:61 41:63 +hoh , CWA ye un LM eld SIT ¢ 1225 quai eme| 3a3i-.6l2 270 ———— we = ABV LEV (6c? Or)? gare ~ TAs 2-7 . Ans: 45 x1035) For the reaction FAD = Bb @+ cw a 900 °C, Ke is 1.40 x 19-3 110.780 mole of A (g) and.0:244 mole each Of B (a) and C (9) are mixed ina £00 liter container at 900 * ©, what are the concentrations of A, B, and C at equilibrium? Setup: a= Ce) Cc) = (244) C244) ws = 0.097% ye (0.780 )* Sle ctatien will paocee/ Q ? tS ns tio? Spentantourty % Mu Of th dur to rads suck brides 2A) > By + Cw »2yy 1244 | Bibel coe e100 =x to 2 —s $V" = 2442 ve CMe SGOT Tea Ly ; i Egyk cones | ce CBIEC\ {A jt tyonis> = Ifo-zuy-%) Guy -x) (786 42x )% BHI = fruy x (786 +27) t= C.%wo e oS ~-X = 12YY~.2ag slow y tBl=- (cys 2uy-x ST Bopq . a Jor zl20)=c11g cay 7 TBO bax (Bl= 0.044 [C]=0.044 M =8-