S RECHO GREENCITY PULP AND PAPER LTD. Make a Green Choice — NANNING GRECHO TRADING CO., LTD. Material Safety Data Sheet- MSDS (Surface Sizing Agent) 4 Chemical Product and Company Identification a) Product name : Surface Sizing Agent. b) Recommended use of the chemical and restrictions on use: Used to improve the paper sizing, stiffness, surface strength. cc) Company name: GREENCITY PULP & PAPER LTD./ NANNING GRECHO TRADING CO., LTD. d) Address: R1118/11F, TOWER A, L'SEA ASIA INT'L NO.9 ZHONGJIAN ROAD, NANNING, GUANGXI, CHINA Tel : 0771- 2712236 ; Fax : 0771- 2712236 ; Email: info@greencitypp.cn 2 Hazards Identification: a) Harm description: Not applicable. b) Details for health and environment effects: The product need not to be identified as per the calculation method of the latest valid version of EU Universal Classification Standard on Configuration ©) Classification system: According to the latest version of EU standard; extended with data from company and relevant document 3 Composition/Information on Ingredients Description: From styrene and acrylic acid ester polymer composition, this material is non-toxic non-hazardous ingredients: CAS:7732-18-5 ‘Water HzO 7021% EINECS:231-791-2 CAS: 24981-13-3 Styrene acrylate copolymer 301% 4 First-aid Measures a) Inhalation: Remove person immediately to fresh Seek medical attention if symptoms develop or persist b) Skin contact: Immediately wash skin thoroughly with soap and water. ©) Eye contact: In case of contact with eyes, rinse immediately with plenty of water for several minutes, 4) ingestion: Get immediate medical attention if symptoms persist 5 Fire Fighting Measures a) Suitable extinguishing media: Carbon dioxide, powder extinguisher or water spray. Use foam and water spray for conflagration. b) Protective equipment: No special protective clothing and oral respiratory protection device 6 Accidental Release Measures a) Personal protection: nontoxicity, wash after small leakage, add suitable defoaming agents when there are many foams. b) Environment precautions: wash after small leakage while collect after a lot leakage. ¢) Containment and clean-up methods: liquid absorbing and binding material (sand, diatomaceous earth, acid binders, universal binders, saw dust). 4) Additional details: release no hazardous materials. page 1 of total 5 pages#5RECHO GREENCITY PULP AND PAPER LTD. Make @ Green Choice — NANNING GRECHO TRADING CO., LTD. 7 Handling and Storage a) Safety handling methods: avoid heat and direct sunshine. Insure the ventilating device at the workplace. b) Avoid fire and explosion: no special location. ¢) Storage: Store and container demands: keep in cool place. d) Use ordinary storage device: keep far away from the food. e) More details on storage: keep in container tightly closed and in cool and dry place. 8 Exposure Controls and Personal Protective Equipment Information on technology equipment design: No particular details; a) Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. b) DNELs (derived no-effect level): Not provided c)_ PNECs (predicted no-effect concentration): Not provided d) Additional detail-valid checklist during production as basis. ) Personal protection: i. General protection and hygiene measures:apply to the general protection measures dealing with chemicals, f) Respiratory protection:If ventilation is not sufficient to effectively, respiratory protection must be provided 9) Hands protection: Impervious gloves to protect from the product/ substance/additives, \. For lack of test, no suggestions on gloves material for the product/preparationimixing chemicals, uw. Pay attention to the impervious time, percolation rate and degradation parameters of the glove materials. h) Gloves materials i) The suitable gloves depend on materials, the quality and producer, because a lot of materials make up it and the resistance must be examined rather than estimate. j)_ Impervious time of gloves material k) The exact break through time of the gloves has to be found out by contacting the manufacturer of the protective gloves and has to be observed when using it 1) Eyes protection:wear safety glasses or chemical goggles‘ if splashing is possible) 9 Physical and Chemical Properties a. Changeable conditions Melting pointirange: Not provided Boiling pointfrange: 100°C. Flash point: Not provided Flammable (solid, gas): Not provided Flammable point temperature: Not provided Self-igniting: The product is not self-igniting Hazardous explosion: This product does not present an explosion hazard. Explosive limits: Not provided Lower: Not provided Upper: Not provided Oxidizing property: Not provided Vapor pressure: Not provided ‘erpaeg: page 2 of total 5 pages#5RECHO GREENCITY PULP AND PAPER LTD. Make @ Green Choice — NANNING GRECHO TRADING CO., LTD. i. Relative density: Not provided .Vapor density: Not provided Evaporation rate: Not provided + Solubility in/miscibility with water: Soluble = PH: 2.0~5.0 + Segregation coefficient(Octanol/water): Not provided -Viscosity:s 20(mPa.s 25°C) Dynamic: Not provided 10 Stability and Reactivity a. Void thermal decomposition: comply with the specification. b. Hazardous reactions: will not occur cc. Hazardous decomposition products: such products not known. 11 Toxicological Information. Acute toxicity: a. Main irritation effects: On skin: possible. On eyes: possible Allergization: possible. b. More txoicity information: According to the calculation methods of General EU Classification Guidelines (the latest version), this product doesn't have classification limits. According to our experience and information provided, no harmful effects would happen if we use it complying with the specification d. Possible effects on the following: Toxicity dynamics, metabolism and its distribution: Not provided Drastic action(acute toxicity. inflammation and corrosive action):Not provided Toxicity under repeated exposure: Not provided CMR functions (carcinogenesis, mutagenesis and harmful system): Not provided 12 Effects on the Environment: a. Information about elimination (persistence and degradability): Not provided b. Environmental system nature: Mobility and bioaccumulation potential: Not provided ©. Ecotoxic effects: + Aquatic toxicity: Not provided d. General notes: + Water hazard level (German regulation) (self-evalution): a little harm on water. Do not allow undiluted product or large quantities of it to reach ground water, water course e._ Endurance, bioaccumulation and toxic characteristic: Not provided 13 Disposal Considerations a. Product: Recommendations: Smaller quantities can be disposed of with household waste. b. Unclean package: + Recommendations: Dispose of according to official regulations. Or sewage system c, Hazardous decomposition products: Not known. to reproductive page 8 of total 5 pagesSS RECHO GREENCITY PULP AND PAPER LTD. Make @ Green Choice — NANNING GRECHO TRADING CO., LTD. 44 Transport Information a. Land Transport ADRIRID (Cross-territory): + ADRIRID level: Not available Hazard number (Kemler): Not available Hazard mark: Not available UN number: Not available Product description: Not available Limited quantities number: Not available Transport type: Not available + Tunnel restriction number: Not available b. Maritime transport IMDG: + IMDG level: Not available UN number: Not available Label: Not available Packaging group: Not available EMS number: Not available Marine pollutant: No Proper shipping name: Not available ©. Air transport ICAO-T and IATA-DGR: ICAOJIATA level: Not available UN/ID number: Not available Label: Not available Packing group; Not available Proper shipping name: Not available 15 Regulatory Information Sara Section 335(extremely hazardous substances): The ‘compositions are not on the list. Section 313(specific toxic chemical listings): The compositions are not on the lst. TSCA (Toxic Substances Control Act): 7732-18-5 Water, distilled, conductivity or of similar purity Proposition 65 Chemicals known to cause cancer: The compositions are not on the list Chemicals known to cause reproductive toxicity for females: Not provided Chemicals known to cause reproductive toxicity for males: Not provided Chemicals known to cause developmental toxicity: Not provided Cancerogenity categories EPA (Environmental Protection Agency) Not provided IARC (International Agency for Research on Cancer) Not provided NTP (National Toxicology Program) Not provided TLV (Threshold Limit Value established by ACGIH) Not provided NIOSH-CA (National Institute for Occupational Safety and Health) Not provided OSHA-CA (Occupational Safety & Health Administration) Not provided Label guided by EU: Observe the general safety regulations when handling chemicals. European Community Directive: the product does not need to abide by EU Directive/ Identification Instructions of the Regulations on Hazardous Raw Material National regulations: Water hazard level: water hazard level 4(setf-evaluation): slightly hazardous for water page 4 of total 5 pages#5RECHO GREENCITY PULP AND PAPER LTD. Make @ Green Choice — NANNING GRECHO TRADING CO., LTD. 16 Other Information This information presented here is believed to be accurate and pertains only to the product when stored in a sealed condition, The MSDS was updated in accordance to Globally Harmonised ‘System (GHS) guidelines. As prescribed above, the information is to our best present knowledge correct and complete and is given in good faith but without warranty. It remains the user's own responsibility to make sure that the information is appropriate and complete for his special use of this product. Jun Neng Papermaking Material Factory shall in no way be liable for any claims, losses and damages of any third party, or for lost profits, or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, from the use of this product. End of document. page 5 of total 5 pages