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Fotom prwel ot = p ed Corneal * FCC (Total 14394) at Paaierbu +3 teu Win Scc=1 | * BCC (Total 141) at octy” Cenbu 74 ° ECC (Totalelt3) oa Crmo='8 \ 2S SBE” SREE 4\5* OP? 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GO Boe” WE ea S % 2 \Z a = Al 4 2 & adn | ¢cc (asi) "3 £3 > JB ar E38 4 44470 RG > | Gop : neg! 8 4 44324 He &_ anon Ry PecfHee|ccP om i a (OB) a5 . VFce> Bec > sco wa Aho! Wh GR 62K Per eaea | eae NSITY OF CRYSTAL. G mass es gp 9 usta ae Volume _ | Pas Saye Ung YY Ls om feed Lj ge 7 let | ~ 10 Bem | Pm > lov!*m Ss | elo > Iolo. e Closeo PACKED -sravcture atom) Occupits max: Space G empty Space is minimum ron 4. _41-D cP Coosclination no» 972. peo 2 9-0. coe Se - a | — ow layer Seeond How orton ayer 3 "6 ploced above | plaud finst Xow | Qnotux Tague EN & Se 3D CP chung - ° Simpl close posing rede A OT Cs packing a cowoud with anetn layer 8 5 Close jacking - ie dt Shows horizoritas g ' . hm bertical wt toch! layer? CNIS altignmunt fe Heragenal Saha prceeng | | Covert iebiansaxe’ voids) | nigh Bbtahicdra) voids a 277 | 1 Coveud by spranss 4 a layer sothat the aphobs ay of | ea ene ; Og te ee th those of 4 layer wil > hie patie vb depedlusl in aituinals layos Thats why known oo shee AB-ype > @nem2 > Ext Znghgy(d ete # cusrc cuose pactiney [fce. [loves cdatsdval vid} put certhlasgon > Potivin Rnown a» ABC=ABC type - > enema sexo Cur hgy Au, de. 4 Vows © Tapia drial > bo by Y-atoms CNS 4. * Octahidxtal> fomud by 6 atoms in whicn foshenl ayondpoden syplaudvaboutancthen lasses}. Be oe anes fox! oy 8 sphwus in whien ¢ach afd O¢Cupy Connat 4 cube © Note? * No-6) Oclohudal voiod = ator] Sen =) acc= 2 fcec= 4 rere ed * tio tebohudral voi »[ Fn) re 4 ¥ Somme ‘imp heey points | © MO behaves as Coniston OF trsulatore aipencling pens | ‘Timperctwe | © GHZ Shows elydLw'cal propertiv like metals - | * Lastie site Wn pus cuystat cannot be oceupitd oy s@lacbion . Graphib is a | + Total no- 6} resorahidsiarveldsimeconis® [on- 244-8] | * T Gabicwctoseiperkings ;tre unit Cl hoo SeTertaksebtalvoidls within | | | | | | | the unit Colle HB Charadderistics _propuditn Of various type bf Fonte coliels | Type Guysat Tons fonming Tons peut Cooraltnahon rot He ¢lbse pocud in Vol number. ebuctune ° ‘ - ting AG type Song anions Znay y } ine Ri i - | ea fomcir aon VOFds - [hal TV. AB. Nar = “ype CI" jons No? fons in Not=¢ 4 Hock salt oS acumen crreé Ap. Coe) bee uti, C+ ions ot Cet type Civ fons ot the tenbe i 4 Conners 0} 6| the cube cl=8 oe A CaF, ran " type . lone fre! ES tonsiin.s Catee 4 Sburtion =U tea pe ( Floonits) p hudral heb ao A.B No.0 02> ions form Not tons te 2 2 Ceca Ce eo 4. + tafleust) Tho. OO? -y 2 | fe 1i65~ 0°225 3 01998 O71" 4 geuly — 0132 6 9°132 ~ 40 8 pul! 1 Raq» InOdahsdral peuuR= %& b gna wid <0°925 - eee spree woangunt ae Planoxt ‘teicnpalors Bayon trioncle 8,5 tebro heelrtod @ pholenilt zg Odahrobtal Nace toch sat Prodly tenlattol abic- Cg CL os i) - pe (9-19 Mera SV VIME 7189 HF Chapter P=Block — C-P Cy The thmunts in whieh laste” enlixs into p- orbital known a, f- block, elemunts. Cyeneral EC ns*np3-6 Ve na ggst 9 For Ce bact 9 Ne na Fete © 9 Nan Chobry B ungan .g-) re C8ha 8 § Pau Gtkmi Alu Knee = Bye Be Se Se As Wanye Ge et Cpa jax Xew LI Teh She “Th Rno At Any po p? Br haw Pbite. Tht oy Me Gp is Gp Cpt ip p-H bp-3- | * Duck bor Propuitivs ° tnottaav [ENG chive Nucliar charge dleouare) Ae fs é $ Boi R Oo n . | pruaitiyh tury, a Nyda tgs | eeborgtvig a e gan Unthalpy chictases 5 AL mM aD inow | 2) YN. : 5 (nog nomic. "8 | ee dunsity ——gttin Ahus \ oin 9) WV gndiv talute te (wl Gantt me Character - Waal 4 eserbarton) ee ee , = Filled 4 p-on ' Stability Nis [les vudaeing ch) / nat ml orbite ganic Charo cle Pils Baofe characterd_]_ ; lubiby : Haduei , $0 Asis charad _ bond angle Sbilg » Soangth P4-H bond | Oils [sb fs rea : 2 an ff Heluetin charactov] 2 Pruparation py Nibiogin omni» var vy haaling Ammonis dlehseran. * Cerda A Niy)y C907(S) ———> Ny + Un, ON)+ 61,0 35) mmenunr clichxemall = aga oxide ro msec C = Nitrogen B0(N3)p jo os 2 high electrone: ivi. Corum aioe Fab Bacs) - wigh “Tonisation “9 Chum 'col Hoar. df ao ? 7 2can form pr-p? me) 2 alg) aa (8) pane nes (ithiiun nfbr fol. ee - "39 (8) + N: a sath are: Oe ee ae) Sere ium nibuols pes ‘tran the eile -P bond [high inten- Edemont (yesh ef nibwogun| lows il husporahion- Pungent gao * Catenation tenden } ‘le + Cal: whale, is weaker in nitrogen. 9 i Zac) + E (ON)n —> QNM5 Cg) 10H 071) -4 cach CO Bl Nu ‘lium : Chlonicu nydoteniet ene Nt SH, fen se => INN, An? =~ 46. Pose (bel ky FP MIGH p Harsume Nny* (0g) +04” (04) (A9(nH3),7 C1 (04) [Coleus] Gu (.N5)y)”” (ag) 2 3 stip pac Nos) Pk |Rh gouge catalyst Slips LENE) +5059) a unbyg)-+ $4 0/9) nitiic 500k, Iban Oxidt- Shp 2 2Nog + (9) — No, nibae hibtoger one cliortets Step -3 3NDo(9) + Hy0(1) A HtNo3 (09) + Nola) &. Peta spsaneusin: Ow bol pours to make HNO in mnclecatae. * 7Gumical wax Sh ride actol bmp) |* 4 NBN mono cid | £ 2n + ati) uN03 ——» Zn (Nos), “+50 + m0) ough | ¢ » Gt + Corie. Ho; ——> Cu (N03), + M0 + NO», is XA + Cone: HNog, 2P(No3), + tho + NOp H Gynwpal O » +6 S st +6 Se up! Te 5p* fo op +Y || dete tavet pair efeer | A > Pre eup [seducing shag noe pend aa wn pyar stability down te 9p once 4 Huse t y feet oe fo pt ‘ 4 hie, (9, kahit oD wpyon (99) ———> 2,00) +0() hyoleogen porta fool WKN » Chem A 2aMa(s) +0 (p —— 2190 (9) y agnesium Oriel, ? $6) + 0.(9) pana 0,4) ant A , Stu phwt clionide. 7 LknScs) + Or: ) > fine Sulphi) J 2zn0(e) + 25024) + OZone o. oa frapaxotion , Me ~ = 30, (9) ebschang, 20, An's +iW27 O-4 % Chircal surat PbS (s) + 40: ee soa S00 > ia. 8D PT (aq) + ,0(1) +0. 3 ——? Ron (ag) + Blo) +9, mae _ Fooliole Sulphue AUoteope ¢ Souuctirws fone SOK A meno clinse < Cole ruppmer(%) Lay a) | Chemical Muackons 6 LU penn Ay %0()) > W40'(04) + H Soy (a9) [i sa H, Soy _Gu(s) , CurSoy/9) + S02 (9) + >, C1) Rpt [. ] , 1200s) + IM O(1) [ dngartany “GE Onoocisle of Suiphwt prey * Siphon acid. ( Hy S05) + Sulphweio ( 5 achat (% S04) 2 S05 ° ou So AX on a7] So on © foroxodiculphwiie ackol ; oe CHS, rie a Oleuum | hepa thee R ‘ R46 9 1 f Pr be (07 | e040 0% To4so om Ay ay L youp-IT ebemunts FA ome stabil — F296 ao WE méut dean Tre Cl 495 Bond lingth T Thuxmal stabivtyd Ry 4p H p sage! wu ee a i — 8 oe ens ateng rt Mt 6p? Po equ Chop ‘ " ae Mak ep Nact + YSY ~~? NaH Loy) +t He (9) v Cence Sooktium biculphau got SH qlantSoy (9) ++ Nace (s) S098 , Nay Soy(s) + Hol(g) Secltum qunical Mie sulphate ia Ws0"(ag) + c1- yep ZnCly, hy us acicl-+ oO P= a en Lf thionew ger een ON? OY, * Wg (ehiewe aca) B = _M Intex alogen Compounds ps Type Compound Shope. J XH CIP Bre barca 5 CIPy, But T-shopo *X5 cf, Bubs a ne xxy IF, Pentagonat : bipftamtda \* Qynoup-18 Element N He Ne 26 cally enya, Ax aps dur fo" fully filed cliebunic kx ups Conpiquration Xe gps ; D ; '£ He fiet nob gare Aftcomrud by» Neil boy | Rn ops J > cohfpuna wey 7 ltaot TE [xenon 48° Frnpon Umposttant Xenon Compounds. / “naent . 613K Pa ” See E 2/9) 13K Yoo “Tax flaine eh” x Renn ciflowiole & (9) + 813K 6 (its : (8) ah oat xety ——> squase planax atl (enon tubraflourtiols) Xe(g) + 3F2(9) SBE 350% fe (1 #20) 60-16 bar ——— ison Cxeroe hexaflowride) Octahidea! % Xenen _gr4gen Compounda . * Kee + ho = auf + Xeor . . (Xenen ony feloo ploride * Keg + 2H0 > Yh + Xeo, fy 2 eran etsy ea | rere + 90 > gue + Cree op lenitsy he Shusctivw Kenda! Compoxk, ee iioxide ) ¢ Xedos 9 P a LIN Yxamidal Xeo Fur ee =° 07 is af paras pyomiclat Keo, fp f am LD 2 Su Saw | ‘ LY \ Ov 6 Woon a 0 Sulphux > shomanty stably of neem timp-7 (i t roger Pinembie Sulphive is Sfabu al wom ltmp:- ) C58) onge in ine Ovdax of acicl’c chotachx ' ot Mp0 , HyS,HpSey HyTe Se> NS >Hy0 Bona Lungtn ‘ « derple following sox? ZCUABINOs (Clif) —>feu fos), ##o4N0 103 9 ads as pow! exicuiry perc if Srtawily cissouialk +0 give, nascant oxy gen’ 03—9 0p 0) © yum Sypthiots of Xedg prem xeke oO KeP, +3H,0 —> GHP +(Ke0g) Sturn, 7 ee cae & of Fipromicta rely + [2H,0 —7 3xed3 + DYHP +30, +4Xe, y" ———— Pe ole prope of ie, ep ntting point NH > Sbi3 7 Asis 3 * Boiling pount Bin S bly > N37 Asn3? PH3 ' Amrnonig, fouscture - oe 4 wager aenmnine Sous - 2nSoy (24) + 9NHy on (09) —y zn(on), (8) Hnng) Soy whi ppt ) 7 (Ms actos Lewis bose - FeClalog) + WHyOM (09) —> Fea 05 x20, tn i . : "in WHg has one Lone pair ae which if, Guaiae iF nna PP Nie ouid_ structure Brown ning test CaGparason abibty @ Pe to ruduer nitvatin 5 0 wo Prribut onic , oe ea rane he 40 Sw ° four bxewn iia tinh} a ite-..””- = [Fert 0), ] 2% vo —> [Feomostint + ho “> Gprvop-t7 5 Manu focticu of chlorine Deacon's proces = ay oxi sf HCL i” Yer +0, Gite, lly +2Ng0 - 723k * Some | Imp: points for mey's- 7 UsPoy “Ahoy give thee Sutin of Sale * prroxoocids Of Sulphust > Hy S0¢ y H, 85 Og 2399 parornag netic eee: BIOMIOrECULES 7 ae Coodborgdratis 4 nucle acid JN # Zorg (Co(hody)] guna (oo! JG sor Sacchascicu “von i eo eeaaniaieaea J 5 M 0: CH," | ketone VF alachy dt 1 guoup . c=ol fF ! | pH — Cc —wo0 yo-C—on 4 ! ' } ou—c—Hn w-€ ou Polyh doy! on —d—ou y-c —On gpeuep mm aa he 1 CH, 01 cHon [Fevetose] - wi [oyweose ] “ye T memo S accortiolu-( 4 unity DUigo soc chawiclun sain ap units) | Sxample Succore (_tyLunoee + Prerelow) Pol Lolysiqechanides (> jo unit) Example» Gunylase'y Slovitchy glycogen ». cellulose ete oat clos t { : 7 ‘i itary Feilingtc & 201" ¢ foulten Sol” Ko ruduen - Kandle (ance on (caou) tsar x Silvorto [ey > Madttoses lacie | ethu ‘Pat hyaiuage song “Stalin oo (chert C5 a TD Ag hg Domino gacchawids NO Hedutein Segaxs Whien clonot Huduer Peiluhg 01" 4 foulen’s ‘ So” fuase 6.45 ( 1 45M1296) ~~ Risch _prrojtetions | Oy lucose. oe Son wy aL anos Maye ee ay Ce, -> Ov aight 9p Q “ “ 5 i . Nw ¢ c ! 1 A= GoM , ow 0M : ! on —C M . ye Em oy 4 on—c —H : \ y —€ —ou rad —u | ’ Cyyon Cu,on' rey D - Glucose ' L- Gyureose “Haworth Propctans Che eon onal cH on lL? co" BR a > OH upry 7 on (P) | a 5 cate on { ¢ " Ne at at Orde EL eames Mana = noch tet | 4 2 (Glowting > No fuser Gmonberd ies poration Hing 6150410 Hspaxations Hing Boiled with dilue HCL DF MySoy iMaleohol'e fol? * hab a pee ead ~Suewse “5 Gylucose. b Fyictose, Mu o ; CLGM12%6) Clg 06) © indusbriol _miéthod Staxon ne Cy tueose “BA3K 9 aan Ce N00 2-304 unit) Bhot Savi C 61105 )n Gertie hycviakon (7 anit) ot Sari ay _—_———4 [CX = NOH real i“ by a oy on Ch! Cn, OCOCHs pylLucese On : ues ta- autal ANos [oy tN { —on ‘ MOM soup (cHony Cn. on te (qlutauic acid 4 Gy (come Cyanohydsiin bin Sotchauic oud yf 4b Peor A Sylycanio ocr. (anno Avid to long chan) Bspuctin 4 Copicatly active) © Zwitls con» ° Conte! i 4,0 . se R—cu-c—ow —*—— > R-on—l-o- i F tiie i, my = * Pe Gybyetne:fophcainy Sollee machve = pecty * Petite Bend 4 vere ty Same, molreule. ao oe ) Gn COBH - Hhan —(M-loon > fino Connie, g 4,9 A ppl e+ fre Ni ° I, L : 7 tes J] peption Bend. Bond ON | Sy pute : Labulow Ol, Fibyous Protas : : Hobe * have spheroidal bh Slater thruad teee . ; “t Shue. ' Soluble Ip walix t + Trfolubl. uv water : re AP) san Page eclenet change with rtp : modtral ch&ngen * TABramdliculass H~ Bog ume gt pa Example? Albumin, | * Trtemolecular H-bonding Fxampli* Cattagen, Keutin maser may , 7 Moayecir . | 7 eo AL fe fp pleated | _Pasasrianiny preotaen * Qeronelawy nat Tet Meu o-aminoauidn in whe a Lot 46) pee | Oe ee polyp Hole tue! ery anothur bond's arnumad eee oo a Keault : 4 V-bonding - atic Be Plinted Saag ile doar eae amino side. m 21q-7a¢ Moe’ pero in-@ forma chain PSPS bw COFNKaP. so thtn HB. ~~ _ Clanifieation €f amino acts tal. Cimino C Essential § vohien owe ooly can't pscooua. « es art ia Sappled vin fem od Non -enenties snc eur bocty produce . tal amino . anol newsary to ken in Lit . | ei : guar plane : fs Essential ane ° Wistelint et =a © Tooleucine rt « leucine fesamte acid Bret ser © Methionuy or + Phanylalanine yen ; oe ee > Tyee 7“ Ribose ej se : re, <, i own 7d 5! WP Poe ‘i Bape rang , p" Ls 2,9 nacre | 7 Ni * nibiopnews Bao 40N A Ral T Of 1 o__(at at go Colle sayin. SS > Guanine Psi ” 4RVA + Uf A nw o C cytesing eh yuonine A Ave ‘ a ( U et gee oy) ci y DIVA vs | © cloubl hel * Single hub Adiueturce Sbudelwu | © Cloubk strand ° Single Abianol Ht Voy ump at 10S [ pre aud on reLax: of O- gluco > (ylucertic acid 2% what is glycosiole linkage: SIS NG &monoeatcaridls Ko oan swith Ba, Waty, * Teaportart_fon micas - poe, shpat 7 Gyucose* Idohe memboued xing — P Gucose* Mdopyriose Aldohexose .ed “> _ one > Froctases ketohexoce * Ribose? Aldopentose ? Erythnose> Aldotetrose - . | 44 Anomers > Two cyclie. hemiacelal form of jieose whieh only differ OF | hydroxy) Gp (0H) af Cy position. % Nuckoside > Sugor+ Base © Nucleotide » + Rone + phosphoric avid goer: * DNA > Cgtoat e t Thyrnine & RNA > Cotosine + Uracil: + m-P of amino acios once highw than cowotee pond haloaciols because, amino acids exist os zwitter ions reoalting on Sheng ctpole-dipole athrachin x proteins axe Condensation pelyenae ¢ 4 amino aid. 4 Acidic: amino acid? Crlutomic acid. ¥ nucleoside on hylrelis VS > Gldopentse ¢ nitragenous bace . ¥ Lysine > Basie Amino avid. 4 Aepontic acid 2 Acidic amino aud - & Yoline 2 Nedbrally optically active amino acid K (qlycine 2 Neutral ically — in acti in Acial . v, yATen = NEIORIN ANTS AND _HMLOARENES. ( Imp 2 Nemsetalis 5 7 = ON ony @ SNa) fac. Nomencloture cl ‘ EE tron (ew (a weinen Orde in numbeung er white nod name s} hologen poet Write name of hnydnocasben chain RCL + Ho R-Bu + NaHSoy + Hy0 R-Cr + Poclg + HCL Chlorination: Noes Chy LY csc CB Omer, Coph oye), Ce LB cery “ie Cig — CH = Ch + H6x Peon Potonicls prervaent ) MoxtRenikov's vanti= 1) (1202) sale cu ‘ahaxansh) sar Cs C3 — CH, — CH, BX I~ BHomopHopant) . cy [2-Gromoprqpan] 7 ; aie a is foamsd oe + Bn, —Cly 5 Buc ~ CH, Bx i 7 ‘ VIc = Ditporniols oe = — = ——_a_ ally'c Canbon 9 Finkelstun sua: F holegen wtehanges yuax) RXtwAT HS er + way + CH3X +N : 8 AI dato fone Cy 2 +NAx = Swoonty M10. ¢ 5, purines ef aioe louse) Hs x Ag c Bue X ECL Bn — SE + Ag : flowered My! flowried eo Wurednceanie ee —tasalitekux sua CH3cu. 1 Coon, ° d+ Bh, Sy sflee CH3cy -Bx + Con + oe Siler pro pander = Chemical Suox: G alo atkanss. 0D nucleophilic Aubstitution tuax, Bsemo ethane: Lf d Spy L- rronr(2 stp) (ype Lausing group Syd feat, F Sp BMS as p> eAubstittion — stp) © Substitution t flee Nucleophiltio biomole Nuclrophiiic ~ tunimokoul at. * Cig ny0°s 3° Braga l"> Cry * Snvesion op tonpipe™ Intermediate Cosihocotion fokes pla. is formed: © Give Hadmic milion ( Heicemisation taku P| ) + Stootic hindotanee Ewe one fen Na 7 3 { } u nt yee Travin lus slow Polar ‘net pep neta apm Slt ws oe 7 ch ve macthyl> 9°93" Aatoney yee? = Dmgo. poet stax} SN KCN CHiy-cnl +f 182 math! unit CH3- NC “PA Bre, CHg-O- CH; + NABH (william con abhor © aynthens CHy-O-N=0 + KBx Parte Methyl nibule +07 ‘| K CH3-N. + Ag Bre Silver nit 3 \ 9 No preumethans fqwtabl condition fon SNj Ci T ik nackophile eed ary group: Hable avteation er nae Myo Row Foopurcireh BP>2°7 1>CH3 Vo, methanol, + - Py i . $= timenalign. suo can Seno! We~ay-cn—cuecu, Ale Kou. WC = CHy “CH =CH-CHy 1 more grab Hw Pen t-2-ene.( Major) a Bremepentete . oa Wg C-CHy~ CH CHE Cha Pet ~ Tene (minor) WAT MOL (pails q olty! Malia | PI AME) i x Droy ether CHsBK + ONA + Cigar PIES Cog +2.Noay eed Pru pore: jon_af_halensarrt? + Prem yebe Cambor CH, C3 lo a x Saree . Toluene O- halotoluene - filo tune (minor) Page) © Prem Artie : x wee © we © X=C1y Be Nao, + Her, tHe, ah” Is oO at ae z Chloride © Nugleophilic substitution Hox ° on a “ol Noon + om A nor Bers No ere Zid ut poe el ee “10 8k NO; Nog No. (iy yt Ney * oY cl cl SS ae , Noy map miner SogH > xeon _wilh meals * wate - Pting Hear Ca -fon dana ord ory SU ED-01y + 2a raul lengow , hig saat duy thy Or camara) SES oy! chloidt « Biphuny! (OL PHENOL PIO FT a ‘lech eb nomepCclalioee f pup Achum tar . Boye ces Chan Ww b: io ye “opto Oi lent pet (he wih yor itt § Pxepaxaction 1 alecho fuem Aster ea haloatkone « Cr a-CHy-Ont KCL From ALKENES CH=CH, + 29 avid + Woke — CH — CH, i ! on M 7 marikonikovis rule - QO Th Ni €tg—OY “yr Conboy Cua-Cy,-on Pompous 3° (aeoon) aAln Na‘ba —_———" Ch=N-CH34+ HO | + | Ciig-CH — CH wd | S OH > 2° Meche! | tus cy "HIPS ons cit-cwgS 3 | fem 29g * Bashy ¢ oan —_—, Ee Ea owt é. “Ey tg -cl in” aleohol by earl with ippayPe: erly, tomy nye: in prustner of ‘i an ae se MWe" CON er? CHg—CHy- OW + Hy © Comet) eat ] fin s 2 3 ate uaM ler cng C-0- cng WAM 5 Ciig—Ci,04 + OM-CHy £ Chemical stax 6, alcohol. 2R-ONa+ |p Ho R-COOR J Este Ron) px + 4,0 bor up 9 ¥ praioriion. a RV-c) tHe + Po cis] phosphony! chlovicls R-C1 +HAT+ Soy 7 Reon YSe9 RHE \ tule R-c0.04 8, C=0 Onn dation - 1°ale > aldah ole Dale katone 3°ole> alkens- “tits R-CHo on RC =0 | x Torus ka ‘ C aD) Oxiclatien + Aleshole can be convertit inte mill ori ces By 7 ote C1035 Peee Fpsciniane chlovochtomak ) é Qu at 573% > CHs—CHy— on Ge on CH3- CHO Pee On Cu at 513k “ade ae et pe ia can kt tonvertd into Coxbouylic actd by suax- with PoYarsivn J " feeeeeneb hg doontuem fen (Spent i C3 CH -0n —() te 004 — Koy 11) W300 CH3 - Coon. CD iv) yee? at PREPARATHONS OF PHENOL © Dow PRockss ( Fremn aleaxne) 0 ee O-Na Naor? Hoe . _— “gee + Nail (° 3ocatm — roeen + ¥S.% — 0 deem oil ) “ane, +H UyojAt + Ng tHe _ wan ar a eed a ysthnd) oa Cay e003 + > See — Quen : ve Ba na Ee) # Rox: of Phenol oo a : Mw ' N ae Og 6x i oy4n6 -Gulxomophenal ° {I _— | Benzo quinone } | i | on | dh o-Na 84 {Kamae ace Naon +%ey "40. 7? oon [setue't pris ye somes o-Ne + Naor, gine i CN, > ono ae coe — at Ethux formation (forrest ec rerum) . Olesmaacttsith “conemsSoysoit 143% Cone” Woy Cy CHy— GA THO — Cy Chg FF Oyig CH, 0 — Cy Ole ae Bagi? OO but at |To%G temp AlReru i formed. & William Son synthwit : cmamseiarinemerimper + Nox chy CH. a 4 3 ~o-¢- ) Ci-Gycty + Na-o CaCl) a? Cig =O — ¢— eng taNats Za] Ns SAB GHsOH + HO Gs EEE Hs Coe + Ho e 2GusCl + Ago ge Be as Gis ~O-COUE + Agee © cngCl +Ag,o +69 . ye ‘ ea Ol + 2Agcr Mu w@sOn+ cHon, —SFa_, Calg6 dha nt a Be i Fg s Preparations > Prom phunel oO } o-Nw i Ou oe cynical mao i Anigole ee qe cae x anh As ; 4 ts Mba Ot allylation ° f Cus minor P-rmuthony fouls) CH o “" (3, 0 AP Owe-¢ é-ct onhy- AIC 0-3 0-H; — [Paced capt dey © - ? { 0 5 Cc HOns brigole he [minox] wwe - re Toop wei) ZA 3 (one) MaSoufeons) 9 cuy 9 Oy Nitration + J i ° 2 + M,0 0 Now Ing manos [p-Nibsoanisua] i id HS O-¢hy efbtinore acid + ‘ 7 BX 9 h ' pay) Lminox) ~ Solub Alle ¢ phenil ip ce 4h aS haven ots A dla Fbonaing ° iy. Branching bf Ale dic 8°P. RO > Ale > Ethos ews? ey | | PS at CHO micAL TEST 4 (LUCAS TEST (ted to dish) nguiehs Me), 3° AIG + HCL ——— tewrbiolity v immudiate- 2 ale + HL ——— ome 5-lomin. Ale + UCL ———? — denot show fustbidely - h hon, heated - Q- (Arcomina “at ( ustinguon endl) ow WwW J iniprmene of Britto fnatog) she] white ppt 3° Silvee nidrott “Usl (Agios + KOH) hon-Chlovine. Singte bond (Ualoatrans) — Agee (whi ppt) 2 Agen ( geltow ppt.)

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