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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

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ANSWERS, HINTS & SOLUTIONS
ALL INDIA INTEGRATED TEST SERIES

HALF COURSE TEST–VII


(Paper - 2)

Q. No. PHYSICS CHEMISTRY MATHEMATICS


1. C B B
B A A
4551 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.

2.

3. A, C D A

4. A C B

5. C B A

6. A B C

7. B C A

8. A B, C, D A, B, C, D

9. A, C, D B, C, D A, B

10. A, C, D A, D A, B, C

11. C B, C A, C

12. C D C

13. A D D

14. B A A

15. A C A

16. C D B

(A  s); (B  r); (C  (A  p, q, r, t); (B  (A  s); (B  q); (C 


1. q); (D  p) p, q, t); (C  p, q, s, r); (D  p)
t); (D  p, q)
(A  q); (B  r); (C  (A  p); (B  t); (C  (A  s); (B  r); (C 
2.
t); (D  r) q, r, t); (D  p) r); (D  s)
1. 1 4 3

2. 2 2 4

3. 1 5 1

4. 4 3 7

5. 5 1 1

6. 3 1 1

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

Physics PART – I
Hints & Solution
SECTION – A

1. VP cos  = u cos 
usin  – VP sin  ucos  sin 
t =  u sin  –
g cos 
u sin( –  )
=
gcos 

2. Just before the particle moves to inclined


ucos ucos
surface, we resolve its velocity along and
normal to the plane.  
Before impact After impact

usin 
For the trajectory of the particle to sharply change from the horizontal line to the inclined line, the
impact of the particle with inclined plane should reduce the u sin  component of velocity to zero.
Hence the particle moves up the incline with speed u cos .
Hence as  increases, the height to which the particle rises shall decrease.

3. By balancing force along horizontal and vertical direction


µ N1 sin  + µ N2 sin  = (N1 – N2) cos  … (1)
(N1 – N2 ) µ cos  + (N1 + N2 ) sin  = W + mg … (2)
Balancing torque about centre N2
(N1 + N2 ) µa = b mg … (3)
By solving (1), (2) and (3)
aW
M = 2
(b(1   )sin   a)g

m M
2R GM   dx x
R GMm dx m
4. F=  =
R x2 2R 2 R
R
5. aA = g sin 37°
Spring is at its natural length
Hence aB = g sin 37° = 6 m/s2

6. Total mass melted is 10 gm


Total heat in 100 sec 10 × 80
800
Heat given to ice/sec  = 8 Cal/sec.
100
T T
Rate of Rise of temp = (10)(1) = 8, = .8°C/sec.
sec . sec.

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

7. The KE of given section AP and PB will be equal if MI of each section AP and section PB about A is
same.
x
x2 L2 x2
IAP= (x) IPB= IAB – IAP = (x) – (x)
3 3 3 A P B
3 3 3 L
x L x
IAP= IPB  = 
3 3 3
3
L L
or x3 = or x = 1/ 3
2 2

8. If S is the distance between them at any time :


 S2 = (4 – 2sin t)2 + (3 – 2 cos t)2
= 29 – (16 sint + 12 cos t) .... (1)
S will be 3 cm only when
 16 sint + 12 cost = 20
 4 sint + 3 cost = 5
4 3
 sint + cost = 1  sin (t + 37°) = 1
5 5
Now the only solution is t=53° so only once in a time period, it will be 3 cm.
(B) By equation (1), S varies between 3 cm and 7 cm.
(C) Maximum magnitude of force is 2A.
(D) Kinetic energy is not conserved.

9. % Rise in area will be 0.4%


% Rise in vol will be 0.6%
 0.2 
1  100  D = [1 +  × 80] D
 
0.002 1
=   0.25  10 –4 C –1
80 400

10. Slope of displacement time graph is velocity and rate of change of velocity is acceleration.

11. That wire will break first whose stress reaches the breaking stress (for that material) first.
F F
Stress =  where F is the tension in the wire. F is same in both the wires.
A r 2
1
Thus stress  2 for the wire of smaller radius, the stress is more.
r
Thus the wire with smaller radius will break first.

If rA < rB, then wire A will break first.


If rA > rB, then wire B will break first.
If rA = rB, either of them could break.


12. dl  dx ˆi  dy ˆj
 
F  dl   xy 2 dy
 
on the path, x = y so F  dl   y 3 dy

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

 y2 
W    y 4 y1     y 42  y14 
4 4
y1 = 0; y2 = 3.00 m
1
So W  (2.50)(3)4  50.6 J
4
L
(14-16). Kx 0  A  g  Mg  2Mg  0
2
L 
K(x0  x)  A   x  g  Mg  2Mg  3Ma
2 
g
2 
amplitude
SECTION – C

2. Mg – T = Ma
T – mg = ma
2Mmg
T=
(M  m)
T 2Mmg 2mg
    2  109
A A(M  m)  m
A 1 
 M
 M=2

F/ A b a
3. Y= ,r  b   x
dy / dx  L 
r = b – tan x, A = (b – x tan )2
L L
F dx
0 dy 
Y 0 (b  x tan )2
L = 10–3m = 1mm
  
4. || = | v  (B  ) |
ˆi ˆj kˆ
ˆ
= (2i) 0 1 2  4
0 3/5 4/5
5. In fluid frame ball is moving with constant velocity (terminal) and resultant of all forces acting on it
zero.
(A) Buoyant force
(B) viscous force
(C) mg
2 (  0 )gr 2 2 900  10
vt     25  10 4 = 50 m/s
9  9 0.1

2
6. 2Av = 2F
F A
 2

3r 3
v 2
 v
3 v
v = 30 m/s

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

Chemistry PART – II

SECTION – A

2. Strength of H – bond: 2 – 10 kcal or (8 – 42 kJ)

3. It may be possible that few particles of gas A have higher velocities than that of few particles of gas
B.

4. 96 ppm of SO 24 = 100 ppm of CaCO3 so 384 ppm of SO 24 = 400 ppm of CaCO3

5.

6. LiF is insoluble in water but not because of its covalent character rather its high lattice energy which
is not easily compensated by its hydration energy.

7.
  O3
H /H2 O H /
  OH  
Zn

 O
O
H
(Major)

8. Total lines
6 6 6
for Balnmer series
for Lyman series

for all IR region

5 5 5
4 4 4
& UV region

3 3 3
2 2 2
1 1 1

w w
9. All are extension of PV = nRT, n  &d
M V

10. (B) and (C) are amphoteric.

12. The carbocation formed will be 3, hence will be more stable.

13. Compound (D) will form most stable carbocation on protonation.

14. All other molecules are symmetrical.

15. It contains only one lone pair so no chances of lp – lp repulsion.


In CO2 & CH 4 there are no lone pairs and in XeF2 two lone pair are there so lp – lp repulsion is also
present.

16. Shape of I3 is linear despite of the presence of 3 lone pairs.

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

SECTION – C
1.
CH 2 CH2 CH2 CH2

+
O O O O

2. In Cu2 S  2  , In FeS2  1 , In Na 2S2O3  2 


In Na 2S2O 4  3 

3. OH
OH OH
OH OH

CH3 CH3

A n 
 AO3
4.
x  n x  6  1  x  5
 number of electron releases in oxidation = (5 – n)
 equivalent of An+ = 2  (5 – n)
 equivalent of MnO4 = 0.8  5
2  (5 – n) = 0.8  5
n=3

5. A  2B  2C  D

2 4 0 0
at eq. 2  x 4  2x 2x x
2x = 2 so x = 1
2
 2x   x 4
K eq  2
 1
 2  x  4  2x  4

6. Either 7  1 or 6  1 or 5  1 or 4  1 or 3  1 or 2  1
Only one transition can be obtained at a time as only single atom is given.

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

Mathematics PART – III

SECTION – A

1. It represent 3 different non concurrent lines hence can represent a triangle

2.  p < 0 let p = – q, q > 0, so p1/3 = – q1/3 (1)1/3


1/3
  = –q
1/3
=–q w
1/3
=–q w
x  yw  zw 2 1
so given expression is 2
 = w2
xw  yw  z w

3. Let a, 3 be two number the


A1 + A2 = a + b
2
G1G2   ab 
1 1 1 1 H1H2 G1G2
    
H1 H2 a b H1  H2 A1  A 2

4. Mid point of the chord intercepted by hyperbola is same as mid point of the chord intercepted
between asymptotes.
h  1 2  4 k  2 6  2
  , 
2 2 2 2
 (h, k)  (1, – 2).
 line intersect asymptote at one point only hence it is the centre of hyperbola.

5. Let y = sin3A + sin3B + sin3C for sin3A to be non positive


2
we have 2 < 3A < 3  <A<
3
since A + B + C =   all of sin3A, sin3B, sin3C can’t be negative.

Let us take sin3A = – 1  A =  sin3A = – 1, sin3B = – 1 and sin3C = 0 is possible
2
 the minimum value is – 2.

6. Sum of 7 digits = a multiple of 9


Sum of number 1, 2, 3, 4, 5, 6, 7, 8, 9 = 45 so two left should also have sum of 9.
The pair of left numbers is (1, 8), (2, 7), (3, 6), (4, 5).
with each pair left number of 7 digit number = 7!
So with all 4 pairs = 4  7! .

200
7. If p is a prime such that 100 > p > , then p and 2p but not 3p belong to [1, 2, …, 200].
3
While just p belongs to (1, 2, …, 100), so p does not divide 200C100 but consider 61 the largest prime <
200
3
61 3 divides 200! but only 61 divides 100!.
200
Hence 61 divides C100.

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

2 2 n
8. In the expansion of (a x + 2bx +c)
2 n
the sum of the coefficients = (a + 2b +c)
2
Let f() = a + 2b +c
2 2
Its discriminant = 4b – 4ac = 4(b –ac ) < 0
Hence, f() < 0 or f() > 0 for all   R
If a > 0 then f() > 0  (a2 + 2b + c)n > 0
2 n
If c > 0 i.e. f(0) > 0  f() > 0  (a + 2b + c) > 0
2 n
If a < 0 then f() < 0  (a + 2b + c) < 0 if n is odd
If c < 0 i.e. f(0) < 0  f() < 0  (a2 + 2b + c)n > 0 if n is even.
2
9. Roots of x +x +1 = 0 are complex cube roots of unity,
so h(w) = h(w2) =0
2 2
 w f(1) + w g(1) = 0 and w f(1) + wg(1) =0
 f(1) = g(1) = 0.

abc
10.  b H.M 
3
 a + c > 2b
a2  c 2 2 2 2
Also  a 2c 2  a + c > 2ac > 2 b ( G.M. > H.M)
2
 a2 + c 2 > 2b2 .

1
11. y  2 and |sinx + cosx|  2.
y
1
Hence y + = 2 and sinx + cosx = 2 , which is possible for y = 1, x = /4.
y

 3
12. Solving it, we get sin( + ) = sin   cos2   cos = 0   = ,
2 2
   5 
(i)  =  tan = 1,    , .
2 4 4 
3  3 7 
(ii)  =  tan = – 1,    , .
2 4 4

13. Let cosA + cosB + k cosC = y


C  A B C
 2k sin2  2cos   sin 2  y  k = 0. As D  0
2  2 
1  A B 1 1
 k(y – k)  cos2   2 y k.
2  2  2k

14–16. Let the roots of z 3 + az 2 + bz + c = 0 be , , , then


1 1 1
|c| = || = 1 and | +  + | =  
  
= | +  + | = |a|
 |a| = |b| and |c| = 1
also, |a| = | +  + |  3
1
put |a| = 2k + 1, where – k1
2
3 2 3 2
thus z + |a|z + |b|z + |c| = z + (2k + 1)z + (2k + 1)z + 1

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

2
= (z + 1)(z + 2kz + 1).
It has roots – 1 and k  k 2  1 since k2  1, we have k 2  1  i 1  k2 so
2
k  k 2  1  k 2  1  k 2  1.
so, all the roots have modulus 1.

SECTION – B

1 (A). y2 = 4x P(at2, 2at)


2
Clearly, if P (at , 2at) then by symmetry,
2
Q (at ,  2at)
Equation of tangent is
O M R(x2, 0)
ty = x + at2 T
2 (x1, 0)
for t, y = 0, x1 =  at
and equation of normal is Q(at2, 2at)
3
y =  tx + 2at + at
2
for R, y = 0, x2 = (2a + at )
Here, a = 1  x1 =  t and x2 (2 + t2)
2
2 2
x2 = 3 = 2 + t  t = 1  t =  1
Take t = 1, then x1 =  1,  PM = 2at = 2  1  1 = 2
RT = x1 + x2 = (1 + 3) = 4
1 
 Area of quadrilateral PTQR = 2    4  2  = 8 sq. units.
2 

(B) Length of latus rectum + tangent PT = 4a + S1


=41+ 02  4( 1)  4  2  6 units.

(C) Clearly, RT will be the diameter of circle


 Circumference = (  diameter)
 4
=   RT =  1.
4

2
(D) Since in the part (1), we have found x2 (2a + at ) > 2a, (if t  0)
 For three real normals, x2 > 2a = 2  1 = 2
i.e. x2 > 2.

p
2. (A) sp =
2
2A  (p  1)d  a
2a
 2A  (p  1)d … (1)
p
2b
 2A  (q  1)d … (2)
q
2c
 2A  (r  1)d … (3)
r
Multiply (1), (2) and (3) by (q  r), (r  p) and (p  q) and add
a
  (q  r)  0 .
p

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AIITS-HCT-VII (Paper-2)-PCM (Sol)-JEE(Advanced)/16

(B) Let common ratio be taken as k and a be the first term


r1
R = Tr = ak
R = a k (r1)(st)
s–t st
tr tr (s1)(tr)
Similarly, s = a k
rx rs (t1)(rs)
T =a k .
Multiplying the above three and knowing that
AmAnAp = Am+n+p
st tr rs 0 0
R S T = a k = 1.
m1
(C) x = a + (m  1)d = AR
n1
y = a + (n  1)d = AR
z = a + (p + 1)d = AR p1
y  z = (n  p)d, z  x = (p  m)d, x  y = (m  n)d
(n p)d (p m)d (mn)d
x
yz
y
zx
z
xy

= ARm 1  
 ARn1  
 ARp1 
= A0R0 = 1.

(D) a = AR p1, b = ARq1, c = ARr1 for G.P.


1 1 1
a= , b , c for H.P.
A1  (p  1)D A1  (q  1)D A1  (r  1)D
1 1
  (q  r)D … (1)
b c
log a = log A + (p  1) log R
= (log A  log R) + (log R) … (2)
 1 1
  b  c  loga  D log A  logR    q  r   DlogR p  q  r   0
c b
  loga  0
bc
multiplying by  abc
 a b  c  loga  0 .
SECTION – C

1. Let a – d, d, a + d be roots then


a – d  d  a  d  12  a4
 solve
 a  b  
d a  d   28  d  3
 |d|=3
2 2
2. Let root of x –3x + c = 0 be ,  and that of x –cx + b = 0 is , 
2
–=     4  b2  4c r

     c 2  4b so  –  =  –  gives (b + c)(b – c) = 4(c – b)


 – (b + c) = 4.

c1 c c n  n  1
3. We know that  2 2  ...  n n  .
c0 c1 cm 2

6. For sum of coefficients put x = 1 and so we get ( – 1)35 = (1 – )35   = 1.

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