DE THI ONLINE: BAI KIEM TRA GIUA HQC Ki I- DE SO 1 MON HOA: LOP 11 Myc - Kiém tra kién thire 2 chong: + Chuong 1: Sy dign li + Chuong 2: Nito'- Photpho I. TRAC NGHIBND(S diém) CAu 1 (1D:206926)-[NB]: Cho day céc chit sau: HCI, H2SOs, H3PO1,NaOH, CHsOH, Ba(OH)2, Fe(NOs)s, NHACl, KAIO>. S6 chat dign li manh AL 6, B.7. C.8. D.9. Cu 2 (1D:206927)-[NB]: Cho cfc chit sau: KOH, Ca(OH)2, AI(OH)s, Zn(OH)2, Sn(OH): va Pb(OH)2. $6 chit 66 tinh chat lugng tinh 1a: A.2 B.3. C4, D.S. Cu 3 (1D:206932)-[NB]: Cho thi nghiém nh hinh vé, bén trong binh 6 chita khi NHs, trong chu thiy tinh chita nude c6 nhé vai giot phenolphthalein, Hign twong xiy ra trong thi nghigm A. Nude phun vao binh va chuyén thinh mau xanh. B. Nude phun vao binh va chuyén thanh mau hing. C. Nude phun vio binh va khéng ¢6 mau. D. Nude phun vao binh va chuyén-thanh'mau tim. hi NH pphenolphtalein Cau 4 (1D:206929)-[TH]: Day gém cac ion co thé ciing tdn tai trong mét dung dich la: A. NH4', NOx, HCOs,, OH" B. K’, H', SO.*, OH. C.Na‘, NH4*, H',COs*, D. Ca®*, Fe®*, NOs, Cl. Cfiu 5 (1D:206931)-[TH]: Cho phan img héa hoc NaOH + HCl — NaCl + H20. Phan mg héa hoc nao sau day €6 cing phurong trinh ion rat gon véi phan ting trén? A, 2KOH + FeCl —> Fe(OH): + 2KCL B. NaOH + NaHCO; — NaxCO; + H20. C. NaOH + NHsCl > NaCl + NH3 + H20. D. KOH + HNOs — KNO; + H20. Cu 6 (1D:206928)-[VD]: Khi trdn 100 ml dung dich Ba(OH)2 0,125M véi 400 ml dung dich HCI 0,05M thu duge dung dich ¢6 pH la: A.2 BL6 c.10 D.12 Cfiu 7 (ID:206930)-[VD]» The: ‘NaOH 0,1M_yacBa(OH)2 0,1M la A, 100 mk: B, 150m, ©. 200 ml D, 250 ml. Cau 8 (1D:206933)-[VD]: Hoa tan hoan toan 13 gam Zn trong dung dich HNOs loang, du thu duge dung dich X va 0,448 lit khi Nz (dktc). Khéi lrong mudi trong dung dich X a: A. 37,8 gam, B. 18,9 gam. C. 28,35 gam. D. 398 gam, Cu 9 (1D:206934)-[VD]: Dung dich X gdm a mol Na’; 0,15 mol K*; 0,1 mol HCOr; 0,15 mol COs* va 0,05 mol SO. Téng khéi Itong mudi trong dung dich X la: A, 33,8 gam, B. 28,5 gam. C.29,5 gam, D.31,3 gam. dung dich HNOs 0,3M vita dit dé trung hoa 100:mbdting-dich chia hén hop 1 | Truy ep trang Tuyensinh247.com dé hge Toan — Ly — Héa — Sinh — Van — Anh — Sir Dia - GDCD tot nhat!CA 10 (1D:206935)-[VD]: Cho 3,2 gam Cu tic dung véi 100 ml dung dich gm HINO 0,8M va H2SOs 0.2M. ‘Sau khi cae phan ‘ing xy ra hoan toan, sinh ra V lit khi NO (san phim khit duy nhdt, 6 dktc). Gid tri eiia V Lic A. 0,448, B.0,792 C.0,672, D.0,746, Tl. TU LUAN (5 diém) CAu 11 (1D:206936)-[TH]: (1 diém) Chi ding mét héa chat, hay trinh biy phurong phap héa hoc phn biét ba dung dich dung trong céc Ip mat nhan sau: NHsCl, (NH4)2SOs va KNOs. Viét cde phuong trinh hoa hoe xay ra. CAu 12 (1D:206937)-[VD]: (2 diém) Viét phuong trinh phan img thyc hién day bién héa sau (ghi r6 diéu kign néu €6): NH,NO; — N; > NH; + NO — NO; — HNO; — Cu(NO;); > O; J Al(OH); Cfu 13 (1D:206938)-[VD]: (2 diém) Hoa tan hoan toan 23,6 gam hén hop X gém Cu va Fe vo dung dich HINO; 2M (dur), thu duge dung dich A va 7,84 lit khi NO (san phim khir duy nhat, & dkte) 1. Tinh thanh phan % khéi long mi kim loai trong hén hop dau. 2. Tinh khéi lwgng mudi khan thu durge khi c6 can dung dich A. 3. Tinh thé tich cuia dung dich HNOs ban dau (bi rang ding du 10% so vai Iugng can phan img). HET — 2 | Truy cap trang Tuyensinh247.com dé hoc Ton — Ly — Héa — Sinh — Vin — Anh — Sir— Dia— GDCD tét nhat!TuyenSinh247.com pAp AN VA HUONG DAN GIAI Thy hign: Ban chuyén mén Tuyensinh247.com [1B [2c | 3B | 4p [ sp | op | 7a | sp | 9a | 0c | Céu 1 (1D:206926) Phwong ph: - Khai nigm: Chat dign li manh i ede chat Khi tan trong nue, phin tan dign li hoan toan thanh,ion. = Chat dién li manh goms + Axitmanh, + Bazo manh + Hau hét cde mudi Huéng din “ae chat dign li manh gdm: HCI, H2SOs, NaOH, Ba(OH)2, Fe(NOs)s, NHsCl, KAIO2 Dap in B Cfu 2 (1D:206927) Phwong phap: Chat lung tinh 1a chat vita c6 thé cho va nhan proton (H’) Huéng din ‘dc chat c6 tinh ludng tinh 1a: Al(OH)s, Zn(OH)2, Sn(OH)2, Pb(OH)> Dap dn C Cfu 3 (1D:206932) Phwong php: Dua vio tinh tan cla amoniac. Hung dan gi ~ NH la khi tan tot trong nude do dé lam dp suat trong binh thiyy tinh giam — Nuse phun vao binh = NH; tan trong nudc tao thanh dung dich c6 tinh bazo lam phenolphtalein chuyén sang mau hing — Nuée trong, binh thiy tinh c6 mau héng Dap an B Cfu 4 (1D:206929) Phwong phap: Didu kign dé Huéng din gidi: A loai vi NH,’ + OH + NH + H20; HCOs + OH’ > CO;* + H20 B loai vi H’ + OH" > H20 C loai vi 2H* + CO3* > H20 + CO2 Dap an D Céu 5 (1D:206931) Phwong php: Dua vio each chuyén d6i tit phutong trinh phan tit sang phuong trinh ion rat gon. Huong di yidi: NaOH + HCl — NaCl + 120 cé phuong trinh ion rit gon li: OH + H > 20 Xét cde phuong an: A. 2KOH + FeCl: > Fe(OH)2 + 2KCI — PT ion rit gon: 20H” + Fe’ — Fe(OH)2 B. NaOH + NaHCO; — Na2COs + H20 — PT ion nit gon: OH’ + HCOx > CO?"+ H:0 C. NaOH + NHsCl — NaCl + NH + 120 fic chat cling tn tai trong mt dung dich la chang khéng duoc phan img voi nhau. 3 | Truy cp trang Tuvensinh247.com dé hge Toan — Ly — Héa — Sinh — Van — Anh — Sir— Dia — GDCD tot nhit!» PT ion rit gon: OH + NHa* > NH + D. KOH + HNOs — KNOs + Ha — PT ion rut gon: OH' + H’ + H20 Dap an D Cfiu 6 (1D:206928) Phwong php: Tinh toan theo phuong trinh ion rit gon: H! + OH’ H20 = 0,02 mol Huéng din gi HY + OHH: Bd: 0,02 0,025 Pu: 0,02 —+ 0,02 Sau") | \/ 0,005 = nou de = 0,005 mol Mat khic, V ai sap = 0,1 + 0,4 = => [OH] = 0,005 : 0,5 = 0,01M => pOH = -log[OH-] = 2 = pH = 14 - pOH = 12 Dap an D Cf 7 (1D:206930) Phuong phap: Phan img trung hda vira dit: nr = non. 10 = 2npaor2 = 0,025 mol; ny = nyc lit Hwéng din gi Trong phan img trung hda: nis= nou. => nuyos = nNson + 2npacon2 = 0,1.0,1 + 2.0,1.0,1 = 0,03 mol => Varnisos = 0,03 : 0,3 = 0,1 lit = 100 ml Dap an A Céu 8 (1D:206933) Phwong php: Bio toin electron. Huéng din nz» = 0,2 mol; ny2 = 0,02 mol Bao toan e: 2nz, = 2.0,2 = 10,0,02 + Snxrenos => nxsanos = 0,025 mol = Mudi gém: 0,2 mol Zn(NOs)2 va 0,025 mol NHsNOx 0,2.189 + 0,025.80 10nn2 + Smxnsnos = mM obi Dp an D Céu 9 (ID:206934) Phuong phép: Bio toin dign'tich. Hw6ng din giai: 39,8 gam Bao toain dign tich: nas + mk+ = Micox. + 2nso42. + 2ncos2- =) a+0,15 = 0,1 +2.0,15 +2.0,05 => a= 0,35 mol => Mansi = Yimin = 0,35.23 + 0,15.39 + 0,1.61 + 0,15.60 + 0,05.96 = 33,8 gam Dap in A Cfiu 10 (1D:206935) Phuong phap: 4] Truy cp trang Tuyensinh247.com dé hge Toan— Ly — Héa— Sink — Van — Anh — Sir— = GDCD tot nhat!Tinh theo PT ion: 3Cu + SH” + 2N Huéng din » 3Cu? +2NO +4120 ney = PT ion: 3Cu + 8H* +2NOx — 3Cu** + 2NO + 4H20. Bd: 0,05 0,12 0,08 (Ta thay: 0,12/8 < 0,05/3 < 0,08/2 = H’ hét; Cu va NOx dur) Pu: 0,045 — 0,12 + 0,03 ,05 mol; nit: = niNos + 2nras04 = 0,12 mol; nxo3. = ni1No3 = 0,08 mol = No = 0,03 mol = V = 0,672 lit Dap an C Cfiu 11 (1D:206936) Hwéng din gi Cho’dung dich Ba(OH)2 vao ting éng nghiém dung c + Xuat hién két tia tring va c6 khi mii khai bay ra => (NH4)2SO4 Ba(OH)2 + (NH:):S0s > BaSOs | + 2NHs t +2H20 + C6 khi mii khai bay ra => NHC1 Ba(OH): + 2NH4Cl —* BaCls + 2NH; 1 + 2H20 + Khdng hign trong => KNOs Cfiu 12 (1D:206937) Phwong phap: Dya vao tinh chat héa hoc cia cdc chat dé hoan thanh day chuyén hoa. Huéng din gi (1) NHiNO2 — Nz + 2H20. (2)No+3H2 A 2NH3 (3) 3NHb + AICh + 3F20 + AIH); +3NH,CI (4) 4NHa + 502 > 4NO + 6120 (5) 2NO + O2 > 2NO2 (6) ANO2 + O2 + 2H20 — 4HINO3 (7) 2HNOs+ CuO —> Cu(NOs)2 + H: (8) 2Cu(NOs)2 5 2cwo +4N0: +0: Cfu 13 (1D:206938) Phwong phap: Bio toin electron. Huéng di 1. Dit ncu= x mol; npe= + Khdéiduong/hén hop: m: + Cac qua trinh cho va nhin e: Cu Cu? +2e N‘S+3e—4N? 23,6 (1) Fe— Fe +3e Ap dung dinh luat bao toan e: 1 entuing = N'enhin => 2ncy + 3nre= Sno => 2x + 3y = 3.(7,84/22,4) (2) Giai hé (1) va (2) thu duge: x = 0,15 va y= 0,25 5 | Truy cp trang Tuyensinh247.com dé hgc Ton — Ly — Hoa - Sinh— Van — Anh — Sir— = GDCD tot nhat!mo, = 24294 100% = 40,68% > 23,6 %m,, = 100% —40,68% =59,32% 2. Khi c6 can dung dich A thu duge khéi lrong mudi khan 1a: ™M mudi = Meugnosy2 + MFeGNO3)3 = 0,15.188 + 0,25.242 = 88,7 gam 3. BINT "N": nyno3 pe = 2ncwvo3)2 + 3nFeqvo3ys + HNO = 2.0,15 + 3.0,25 + 0,35 = 1,4 mol => MANOS da ding = NANOS pu + 10%.ntNO3 pu 1,4 + 10%.1,4 = 1,54 mol ).77 lit = 770 ml = Vaannos asaing ‘Truy cp trang Tuyensinh247.com dé hge Toan — Ly — Héa— Sink — Van — Anh — Sir— = GDCD tot nhat!