3m Packing efficiency of Simple Cube, BCC, FCC Problems on density, calculation of number of particles per unit cell, 2m Binding force Differences between n-type and p–type, crystalline and amorphous, 2m Frenkel and Schottky defect, magnetic properties & Example, electron Arrow mark indication. 3m Problems to calculate molar mass using colligative properties Differences between ideal and non-ideal or graph of ideal and non-ideal 2 m or give reason of non-ideal.
Henry’s law, Raoult’s law, Mathematical form, example of solutions,
1m Van’t Hoff factor. Reverse osmosis Azeotropic mixture and types.
1m Definitions, units and uses of Reverse osmosis
3m Calculate EMF or Go
Faraday’s I and II law, Kohlrausch’s law statement and its application 2m and problems Conductivity, molar conductance, problems, its unit variation with 2m dilution, SHE diagram, cell reaction and representation
Products of Electrolysis, Battery, cell reactions of 1o, 2o battery, fuel
2m cell rusting of iron Marks d and f – Block elements, Co-ordination compounds
3m Manufacture of K2Cr2O7 and KMnO4
Give reason – transition (d – block) elements exhibits variable OS,
2m catalytic property, formation of complex, colour, alloy, interstitial compounds and its properties, calculation of magnetic moment
Lanthanoid contraction and its consequences difference between
2m Lanthanoid and actinoid, causes /reasons of lanthanoid and actionoid contraction, Reaction of Lanthanum, common OS
Postulates of werner’s theory, Isomers with eg, crystal field splitting
2m diagram of octahedral and tetrahedral, IUPAC, ligand structure of Metal carbonyls,
Formation of hydbrization, mention geometry and magnetic property.
electrophilic substitution of aniline, diazotisation reaction, basicity. 2m aliphatic amine with HNO2 conversion of aniline to p-bromoaniline, p- nitroaniline. Basicity of amines in aqueous solution.