Course outline Wook Wook Ponoten Trew ute: Assignment Assignment Sotton Text Taner rmvewusoratimacin Assignment 4 ‘Thode date or ubomting tis assignment Nas pasos Due on 2021-02-17, 23:59 IST. the frst order perturbation formula BD = (6 | Hf | 6) inapplicable to the Ts round state alone a Tue b. Fale scr Aone ? the second order correction Eto the ground state energy ie alvaye negative tod a. Tue b. alee oe powers cost ‘ecw rowers one-dimensional partice-in-a-box potentials perturbed such that the potential is pont raised by a constant (ve) inthe left half of the box and lowered by w in the right half, What s the first order correction tothe lowest energy state? m and Fare the mass of the particle and lenath ofthe box, respectively a0 b. w/e © tw 4. ww/me ‘eco nawers: * pate and E(° are the zeroth order energy and fist order energy correction ofthe round state ofa given system whose true ground state energy is W. Which ofthe following relations is/are necessarily comrect? a BO +6 = Ww b BO 4 oO ow 6 6+ BO cw 4. Nosuch relation exists crt Aone An electron moves in a harmonic potential ¥ = kx? and an extemal etd 7? = ‘211s applied, What isthe first order energy correction to the 1 excited state? a /2 boke 3872 40 oe powers cost sce owe © The symmetry of the ground electronic state of water is Ax. An electric field (H” {paint £3) is applied. Excited states of which symmetry species may be mixed with the ‘round state by this perturbation? aA ba eB 4b cco Answers ? the polarizability volume (a’ = a/(4n€,)) of tetrachloromethane Is 1.05 x 10 m?. pont \What would be the change inthe dipole moment (in Debye) of this molecule when it fs subjected to an external electric field of strength 10 &V/m. (ey = 885 x 10-2? (Cow; A Debye = 3.336 107°C mi a. 35x10° b ase10" & 75x20° 4. 75x10" ‘econ posers: © The oscillator strength of a transition at 160 nm is 0.3. What isthe mean ae polarizability volume ofthis molecule? a. 5x10 mF b. 5x10" a? 6 5x10 m? 4. 5x10" m? ‘evap ewan 9 A hydrogen atom in ground state is perturbed by a uniform electric field along == = diection (H" = ~€r2080). Which ofthe following statements is/are correct? 2. I order encray correction tothe ground state is negative b. 2"order energy correction to the ground state is zero Contribution of the 2: orbital othe 1 order wavefunction corestion iO 4. Contribution of the 2p- orbital to the 1" order wavefunction correction is 0 ecw rowers: sisi ierietitiniiierterieennieasd 7 = use the Hellmann-Feynman theorem and obtain (1/r), Which of the following i the correct expression for (1/1)? PrP ecoptd Annes