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= Nerxptunaion = Paw (work clogs by DE = gow (work.done TAS = 4H + Wnow “re ME = Fay “Maw aay * [B= 745) Rettig Sec = [6 | SA= Ypay- Wow - Yuu Gibks Pree Bury Helmoltz fre Burgy, 4G aA sent 2yclian, bo “Wjork Lunchion” > 2t pines fre = 3 * ed mavnum work ecaaale: met available cae, she jrobiely Yoe “4 pserk w= - PAV AA = 0E - TAS 46 = 4H- TAS work by Physical Significance er Phageical Ligetbeewce Ate b fret Law? AS = Yoo 7 SE =g-w (work dows. by a 3 qs bere he AF ) TAS = Vw + ME + Wenpmaion Mii | BR= DE- Grav |i) BA = — Mw lor y= OA Ao. \) in free emugy 5 0 Bo, | dw work functiow Aplin ia & meaaure Ff, us a meacure | maninaun or work J now expavaien um Abali . OF ow = 4G low (ely A pAoeess, FAG enw, pices HB spoons conaitions or fans fi prosad vos focwssel, Me Tien [AG = 44 - ras a) bHe - 4 TAS= tw on Cer + Ong) — Og) OH= ~— 393-SKT Pavawable AG=(AH) oe + TAS But nitude of =-10-4 6) AH= = -lo+4 4H> TOs =I °F Nalg? + Sty g) 9 ANI (9) He — 92°36 kJ famouratele, c) dH = pee & TOS2 ew (Bot omg niliode 4) Gs OH =tlo- Ths 744 an eg Call, (3) —> BOE) + sig) SH = 18-00 KT Favourable 7 8G = 0, process does not occur & is uihbian,. BAe > age Me, prac dacs nat proceed «iw form inet it ty psc se Back . W) felition berwu fru Grurgy + emt EMP The etuctromatine force J a cell or EME G a cll aot . i Lie naomi ral difference betwen Fwd elitr ooles a cell G2 - nFEow Ie no. of electron dw a ow Steolend Free Gurgry OG) * Pre “elon dard ell potowtial(E°) Ren, apolivstirs ho, ages £70 ogee 9 E22 equi hare won- en lanwous bqeres e Ake a > %) orl —%] h 8G= Ge- 4 = fvdp fh Fox fdltak a0 Pu= “RT v= URT P A age Pum dp = net/ de » [mer bee ; P 8 P A) 9 fui Bis A. elmerte | | few % A & face change inv bobasic: proces. do, Mobasse process ofp=0 l= =r] Toto Faun Evrgy tale 4 —7 Abe i oh 1 FR S —— Sz frssgure ue Cormslird Constant Sy do, Temp Infnthestmay Ga dG, = ~ (5-81) AT (ag) =~ Ss A7 4(6G)_ 4s aT 248) --AS or.~4 aT Meo, bG= 4H- Tas 4G = oH +7226) eT /p Alto, OG= -nFEwwy =n FE -nFbay = 077 (2nFeae)) faa > ~ 88. +735) “nF Si taal Ge -NFEw =) 26 . Temp. l| ar congo | Numeiors al Fie mel fom an vp ripened linterna aut’ at AFC prove fad nibial volume § dm* fo 0 ae b phat dt paduced. Calewlolo apt “ 4G + 4S for process (Re & 314 JK") holy bS= R bw Va Y = 2-303 Rog Ma 2 & 403K (esta) x fop $2 ! = 9344 TK" T= 2734aF = 300k AG= MRT IWMI = 8-303 x5 XB 214 X00 xb 6 Va, SO =~ R72 kine! Tewap = Hon k 2 Clalak ~qem cout NOW Qe QNOCq) + hig SH°= 4 ote 20 TKO ) ; oe cod” = 360 ohn. AAG = RTL Ke » agnk YA bG = AH- TAs = $0000 - 298 x 120 v ° = 4YY240T WYa4o = — ¢-34x Yoo X &203 bry ke Ke = 68899 - outlay (6-8894)= 4-761 x10 4 NH, (4? + $09) —> UNOC4) +éHol) _ Sponitamichey 4G (Nk) = -168 KI rat G° (No) = +467 ” AG" (1:0) = ~ 237-2” toln 6 "> 8G, — 8G AK fresno) +629 C#e0)] —[4 x06'(n4)+s xogel] = 4X84 + 6 ABT “R) — YX(-16-8) = }009-a KT (Ren ut xprulororoes ) 8 H2BK Qh4+R—>c AH] lov Kal Age 0:S0 Keak ko! At what Lbrp Rin will become cupovtaneous 8G = 4H- TAS Agee 70g 7 44 ve we Gro “gem AH= Ths % T= AH = foo - 200K As 0:0 Above aovk , Axn ve Apertoesous Leow AVR, LENS BS — Nilni*” |] Ag” Ag Caleuledé perm coustont atasc , Hew mucky Ax. werk vould oe obtainable, by gpasbon Ff ~ihia coll Ena = — OAS Reduced nit] NP : we Joo tecuton pd Ble DE 47 |g v Reduced Low Aol, dG = — ne Econ ve ° ° ° ovidliaw Eny = Ecatrods ~ EAnove my Lay = (8°80)-(-0- 8s) = 1asv ig°= -nFEww QG°= — 2-303 RT bog k 86 EME g cell CA | dy .2-5H,0 (4abisalid) [f a cdtsy + sagtonys CAGE, . 8S 10 (eat) + a us O° 0. ees ane 0: eis at ASC 86g ord 96 (1) Ags) Caleults Hea. teak B “he Kanth), free Ca (48) ab ase eps) Aoln Twp. coefficient” 9G) 2 0°67S3-0-6418 a ———~_ = +0: 00065 Vk 298 — a8 Ai Fou <2 Gi) me den o-61s3 = -4H Ot + an/- 0-eo06s ot X 16800 AH = —I67-17 Toutes So te. — nF Ett ace = — (2) (46500 ) (0° 158) “eh .creg = = 1303224 Touks A OG = Bu- Tas Fe 96800 Ase mF (26 ) at /P e + OQ. Ban + 2Cr—s 38m + QCr% Eme = 0°89 AG= 7 Sole AG’s —nF Eau ond boll Aan > tr —> Or 4 ge- | XV Red” hol} uns J os Sn" "res —> Sn* asnlt¢acr—s Zen) Ber Ag°= — 6K Fb6son x 0°89 = -— $[s3(oT = ~ SIS:310 “FT

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