=
Nerxptunaion = Paw (work clogs by DE = gow (work.done
TAS = 4H + Wnow “re ME = Fay “Maw
aay * [B= 745) Rettig Sec
= [6 | SA= Ypay- Wow - Yuu
Gibks Pree Bury Helmoltz fre Burgy,
4G aA
sent 2yclian, bo “Wjork Lunchion” > 2t pines fre
= 3 * ed mavnum work ecaaale:
met available
cae, she jrobiely Yoe “4
pserk
w= - PAV AA = 0E - TAS
46 = 4H- TAS work by
Physical Significance er Phageical Ligetbeewce
Ate b fret Law? AS = Yoo 7
SE =g-w (work dows. by a
3 qs bere he AF ) TAS = Vw
+
ME + Wenpmaion Mii | BR= DE- Grav |i)
BA = — Mw
lor y= OA
Ao. \) in free emugy 5 0 Bo, | dw work functiow
Aplin ia & meaaure Ff, us a meacure | maninaun
or work J now expavaien um Abali .
OF ow = 4G
low(ely A pAoeess,
FAG enw, pices HB spoons
conaitions or fans fi prosad vos focwssel, Me Tien
[AG = 44 - ras
a) bHe - 4 TAS= tw
on Cer + Ong) — Og)
OH= ~— 393-SKT
Pavawable
AG=(AH)
oe + TAS But nitude of =-10-4
6) AH= = -lo+4
4H> TOs =I
°F Nalg? + Sty g) 9 ANI (9) He — 92°36 kJ
famouratele,
c) dH = pee & TOS2 ew (Bot omg niliode 4) Gs OH
=tlo-
Ths 744 an
eg Call, (3) —> BOE) + sig) SH = 18-00 KT
Favourable
7 8G = 0, process does not occur & is
uihbian,.
BAe
> age Me, prac dacs nat proceed «iw form
inet it ty psc se
Back .
W)felition berwu fru Grurgy + emt
EMP The etuctromatine force J a cell or EME G a cll
aot . i
Lie naomi ral difference betwen Fwd
elitr ooles a cell
G2 - nFEow
Ie no. of electron dw a ow
Steolend Free Gurgry OG) * Pre
“elon dard ell potowtial(E°)
Ren, apolivstirs
ho, ages £70
ogee 9 E22 equi hare
won- en lanwous
bqeres e Ake
a > %) orl —%]
h
8G= Ge- 4 = fvdp
fh
Fox fdltak a0 Pu= “RT
v= URT
P
A
age Pum dp = net/ de » [mer bee
; P 8 P
A) 9 fui Bis
A.
elmerte | | few
% A &
face change inv bobasic: proces.
do, Mobasse process ofp=0
l= =r]
Toto Faun Evrgy tale 4 —7 Abe i oh
1 FR
S —— Szfrssgure ue Cormslird Constant Sy do, Temp
Infnthestmay
Ga dG, = ~ (5-81) AT
(ag) =~ Ss A7
4(6G)_ 4s
aT
248) --AS or.~4
aT
Meo, bG= 4H- Tas
4G = oH +7226)
eT /p
Alto, OG= -nFEwwy
=n FE
-nFbay = 077 (2nFeae))
faa > ~ 88. +735)
“nF
Si taal
Ge -NFEw
=)
26 . Temp. l|
ar congo |Numeiors
al Fie mel fom an vp ripened linterna aut’
at AFC prove fad nibial volume § dm* fo 0
ae b phat dt paduced. Calewlolo
apt “
4G + 4S for process (Re & 314 JK")
holy bS= R bw Va
Y
= 2-303 Rog Ma 2 & 403K (esta) x fop $2
!
= 9344 TK"
T= 2734aF
= 300k AG= MRT IWMI = 8-303 x5 XB 214 X00 xb 6
Va, SO
=~ R72 kine!
Tewap = Hon k
2 Clalak ~qem cout
NOW Qe QNOCq) + hig
SH°= 4 ote 20 TKO ) ;
oe cod” = 360
ohn. AAG = RTL Ke » agnk
YA bG = AH- TAs = $0000 - 298 x 120
v ° = 4YY240T
WYa4o = — ¢-34x Yoo X &203 bry ke
Ke = 68899
- outlay (6-8894)= 4-761 x104 NH, (4? + $09) —> UNOC4) +éHol)
_ Sponitamichey
4G (Nk) = -168 KI rat
G° (No) = +467 ”
AG" (1:0) = ~ 237-2”
toln 6 "> 8G, — 8G
AK
fresno) +629 C#e0)] —[4 x06'(n4)+s xogel]
= 4X84 + 6 ABT “R) — YX(-16-8)
= }009-a KT (Ren ut xprulororoes )
8 H2BK Qh4+R—>c AH] lov Kal
Age 0:S0 Keak ko!
At what Lbrp Rin will become cupovtaneous
8G = 4H- TAS Agee 70g 7 44
ve we
Gro “gem
AH= Ths % T= AH = foo - 200K
As 0:0
Above aovk , Axn ve Apertoesous
Leow AVR, LENSBS — Nilni*” |] Ag” Ag Caleuledé perm coustont
atasc , Hew mucky Ax. werk vould oe
obtainable, by gpasbon Ff ~ihia coll
Ena = — OAS
Reduced nit] NP : we Joo tecuton pd
Ble DE 47 |g v
Reduced Low
Aol, dG = — ne Econ ve
° ° ° ovidliaw
Eny = Ecatrods ~ EAnove my
Lay = (8°80)-(-0- 8s)
= 1asv
ig°= -nFEww
QG°= — 2-303 RT bog k
86 EME g cell
CA | dy .2-5H,0 (4abisalid) [f a
cdtsy + sagtonys CAGE, . 8S 10 (eat) +
a
us O° 0. ees ane 0: eis at ASC 86g ord 96 (1) Ags)
Caleults Hea. teak B “he Kanth), free Ca
(48) ab ase eps)Aoln Twp. coefficient”
9G) 2 0°67S3-0-6418
a ———~_ = +0: 00065 Vk
298 — a8
Ai
Fou <2 Gi) me den
o-61s3 = -4H Ot + an/- 0-eo06s
ot X 16800
AH = —I67-17 Toutes
So te. — nF Ett ace
= — (2) (46500 ) (0° 158) “eh .creg
= = 1303224 Touks
A
OG = Bu- Tas Fe 96800
Ase mF (26 )
at /Pe +
OQ. Ban + 2Cr—s 38m + QCr%
Eme = 0°89 AG= 7
Sole AG’s —nF Eau
ond boll Aan >
tr —> Or 4 ge- | XV
Red” hol} uns J os
Sn" "res —> Sn*
asnlt¢acr—s Zen) Ber
Ag°= — 6K Fb6son x 0°89
= -— $[s3(oT
= ~ SIS:310 “FT