1.

Answer: (c) Butane-2-ol

2. Answer: (c) 2 moles of ethyl alcohol
3. Answer: (b) KMnO4 in acidic medium
4. Answer: (c) methyl iodide and magnesium (Grignard reagent’s)
5. Answer: (b) 2-methyl-2-propanol
6. Answer: (c) CH3CH2CH2OH
7. Answer: (c) 1 ° > 2° > 3°
8. Answer: (b) 2-methylpropene is formed
9. Answer: (c)
10. Answer: (a) (CH3)2C = CHCH3
11. Answer: (d) 2-methylpropanal and isopropyl magnesium iodide
12. Answer: (b) Pentan-1-ol > 3-methylbutan-2-ol > 2-methylbutan-2-ol
13. Answer: (a) tertiary carbocation is more stable than primary carbocation
14. Answer: (c) Tertiary alcohol by SN1
15. Answer: (b) butan-2-ol
16. Answer: (c)
17. Answer: (c) tertiary alcohol
18. Answer: (c) tertiary alcohol
19. Answer: (a) 2, 4, 6-tribromophenol
20. Answer: (b) 2, 4, 6-trinitropheriol
21. Answer: (a) o-nitrophenol shows intramolecular H-bonding
22. Answer: (d) pyridiriium chlorochromate
23. Answer: (b) Acetophenone
24. Answer: (c) (i) < (ii) < (iii)
25. Answer: (c) electrophilic substitution reaction
26. Answer: (d) PCC
27. Answer: (c) 2-methylpropan-2-ol
28. Answer: (a) 1 -methylcyclohexene andbut-1-ene
29. Answer: (a) Conc HCl/anhydrous ZnCl3
30. Answer: (c) p-CH3OC6H4CH(OH)CH3
31. Answer: (d) Kolbe’s reaction and Reimer-Tiemann reaction
32. Answer: (d) All of these
33. Answer: (a) Na2Cr2O7, H2SO4
34. Answer: (b)
35. Answer: (c) salicylic acid
36. Answer: (d)
37. Answer: (d) Any one of Ni, Pt or Pd can be used in the reduction of aldehydes.
38. Answer: (b)
39. Answer: (a)
40. Answer: (b)
41. Answer: (c)
42. Answer: (c)
43. Answer: (b)
44. Answer: (b)
45. Answer: (d)
46. Answer: (b)
47. Answer: (c)
48. Answer: (b) Greater the stability of the intermediate carbocation, more reactive is the alcohol.
Since 2-methylpropan-2-ol generates 3° carbocation, therefore, it reacts fastest with HBr.
49. Answer: (c) Primary alcohol on oxidation give aldehyde which on further oxidation give
carboxylic acid whereas secondary alcohols give ketone.
50. Answer: (a)