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Cl OCH 3
NO 2
4. Write correct order of stability of carbocation
+
+ CH2
CH
+
C H
(1) (3) (4)
(2)
a) 2 >4 >3 >1 b) 4> 2> 3> 1 c) 2> 3> 1> 4 d)1>2>3>4
5. The covalent compound, which does not give positive test in Lassaigne’s test is
1) 1,3 – Dinitrobenzene 2) Glycine 3) Urea 4) Hydrazine
6. Glucose and fructose are
1) chain isomers 2) functional isomers
3) position isomers 4) metamers
7. Two substances when separated on the basis of partition coefficient between two liquid
phase, the technique is known as
1) Column chromatography 2) Paper chromatography
3) GLC 4) TLC
8. In which of the following compounds percentage of nitrogen cannot be estimated
accurately by Kjeldlhl’s method
1) Urea 2) Phenyl hydrazine 3) Nitrobenzene 4) Gaunidine
9. Which of the following has the most acidic hydrogen
a)3-hexanone b)2,4-hexanedione c)2,5-hexanedione d)2,3-hexanedione
12. In a reaction of C6H5Y, the major product (>60%) is m-isomer, so the group Y is -
(A) –COOH (B) –Cl
13. Which one of the following compounds will be most easily attacked by an electrophile ?
Cl
(A) (B)
CH3 OH
(C) (D)
15. Which one of the following chlorides gives white precipitate with AgNO 3 most readily -
(A) CH2=CH–CH2Cl
(B) CH2=CH–Cl
(C) CH3–CH2Cl
(D) (C6H5)2CH–Cl
16. In the anion HCOO–, the two carbon-oxygen bonds are found to be equal length. What is the reason for it -
(D) the anion of obtained by removal of proton from the acid molecule
17. If benzene ring has one OH, one NO2 and one CHO, IUPAC name can never be
[1] 2-hydroxy-3-nitrobenzene carbaldehyde [2] 2-hydroxy-4-nitrobenzene carbaldehyde
[3] 2-hydroxy-6-nitrobenzene carbaldehyde [4] 4-formyl-2-nitrophenol