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    8 views6 pages

    Alcohols, Phenols and Ethers Aakash - Removed

    Uploaded by

    Sriram .R

    Copyright:

    © All Rights Reserved
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    2747} Alcohols, Phenols and Ethers NeEy Ms cosstabsiubraiuiia SECTION,» Co a cmon, 2" ao oO oma, : 1. The compound A on treatment with Na gives B, HICH), on Cr CHW and with PCI, gives C. B and C react together to “ i give diethy! ether. A, B and C are in the order INEET-2018] 4, Which one is the most acidic compoun, (1) CH,OH, C2Hy, CHCl Nery (2) CH,OH, C,H,Cl, CH,ONa OH (8) C,H,OH, CH,ONa, C,H,C1 0 oO (4) CHCl, CH, CHJOH 2. Inthe reaction {NEET-2018} CH, ai OH ONa’ ge °9 + CHCl, + NaoH —> OH ‘The electrophile involved is. @ QO : @ (1) Dichloromethyt cation (Biciy) NO, OH ON No, (4) @) Dichlorocarbene (: CCl) ie @ 5. The heating of phenyl-methyl ethers wih (4) Dichloromethy! anion (Exc) produces. INEET=2 3. Kentify the major products P, Q and R in the (1) Ethyl chlorides (2), lodobenzene following sequence of reactions: [NEET-2018] @) Phenot (4) Benzene 6. The reaction sero ey +cH,cH.cH,c1 “S++ Do att Dron Mec! m0, P+ R ono P a R ST CHCH.CH, CHO can be classified as necr oy : + CH,CH,- OH (1) Williamson alcohol synthesis reaction Ce _— 2) Williamson ether synthesis reaction eae (8) Alcohol formation reaction 2 : : (4) Dehydration reaction Pusa Road, New Dethi:110005 Ph. 011-476" Aakash Educational Services Limited ; Regd. Office - Aakash Tower, 1 a the following reagents would distinguish 14 Wi Sent! 2-80 fom he anesaomer? INEET-2016] reaction of phenol with chloroform in presence of Gate sodium hydroxide finally introduces which Gre of the folowing functional group? [Re-AIPMT-2015] () oH, @) CHO 9 4G (4) COOH nich of the following is not the product of rooms OYE 1 pan 12. Which of the following reaction(s) can be used for ‘Pe preparation of alkyl halides? % CH,CH,OH+ HCI 22h, CH,CH,OH + Hot — (CH),COH + HCI — 9M (CH, ),CHOH+ HCI S25 [Re-AIPMT-2015] ©) ony OH) and (¥) onty ) 9.) and (tv) ony © and.) only 4. cH, ct, —bonia + cH.cH,c) ———» bu a cH, CHE 0-H 0, cH, is called (1) Gatterman - Koch reaction (2) Williamson synthesis (3) Williamson continuous etherification process (4) Etard reaction ‘Among the following sets of reactants which one produces anisole ? {AIPMT-2014) (1) CH,CHO;RMgx (2) C,H,OH; NaOH: CH, @) C,H,0H;netural ect, (4) C,H,-CH; CH,COCKAIC, [APMT-2015} 3. Identity Z in the sequence of reactions CH,CH,CH=CH, "8%, _,Y¥_cosone_, Z (APMT.2014) (1) CH{CH)-0-CHLCH, @) (CH),CH-0-cH,CH, @) CHYCH,-O-cH, (8) CH,CH-CHCH-0-CHCH, “Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated H? (NEET-2013) (1) CHy-CH,-cH-O-cH, cH, Hs @) cH, H, cH, (3) CH,-CH-CH,-O-CH, oy, (4) CH,-CH-CH,-CH,-O-CH, ‘The major product is [AIPMT (Prelims)-2012] 16. ih he folowing ractons. 17. 0 -* CHO ke = ieee (Ze) Ooze) om Area nS tee Pel BS) ‘The manor products (A) and (C) are respectively {AIPMT (Pretims)-2011) 16. rt OF Oye 0-0, 0H, ord NE : ere, cH, I (2) CH, = C- CH, —CHy ang ch, I cH, - CH, Cry Br Cty { @) CH, - C= CH=CH, and CH, | CH B= Gr Br cH, i “ (6) CHy- C= CH=CH, and Ch, CH, GH er Which one of the following compounds has! most acidic nature 7 a) Grenier acm @ Crow ee ooo Which one is most reactive towards enc reagent? [AIPMT (Prelims)-2 TAIPMT (Pretims) — "Among the following four compounds 24 2 Prono b Metry pheno! ce, mbtrophenot 4. Peitophenel tre acdty overis —_[AIPMT (Mains}-2010] ( drererd : gerdrard pperdrerb uw brererd cero is treated with excess of HI, it ae IAIPMT (Mains)-2010] (1) Bocopropane (2) Aliytiodide @) Propene 4) Glycerol trioaide 21, Wich one ofthe following compounds will be most readily dehydrated? [AIPMT (Mains)-2010] Aw * 0 yw @ ne ; 1 ® oY @ wy ‘2 Which of the following conformers for ethylene Shea most stable? [AIPM (Mains)-2010] HopeH n JA Ho oH Wa on H : A : "ae 4 Me I 4 ® Corser tne folowing reaction, Eraroi Ph, x ve ony . Hohe Z; (AIPMT (Prelims)-2009) : CHCH OCH cH, a a 27. ———— OS LG, ‘Consider the following reaction Phenol ara Xa vy Hamano, > The product Z is [AIPMT (Pretims)-2009) (1) Benzaldehyde @) Benzoic acid (8) Benzene (4) Toluene H,COH.CH,OH on heating with periodic acid gives IAIPMT (Pretims)-2009) (1) 2HCOOH @ gHO CHO @) 2tlsc=0 (4) 2Co, The major: ‘organic product in the ‘reaction, CH, ~O-CH(CH,), + HI > Product is [AIPMT (Prelims)-2006) (1) CH,OH+(CH),cH @) ICHOCHCH), ®) CHO FICH), 1 (4) CH,I+(CH,),CHOH Ethylene oxide when treated with Grignard reagent yields IAIPMT (Prelima).2006) (1) Secondary alcoho! (2) Tertiary alcoho (8) Cyclopropy| alcoho! (4) Primary alcohol Which one ofthe folowing compounds fe Most acidic? [AIPMT (Prelims)-2005) (1) CLCH,-CH,-OH a Or © eon New Deini-410008; Ph.011-47623466¢ = » cS [Aenath tavemonsi Services Limned } Regd, Oe =) when &, 3 HE> HF @ > HGr > HCI > HF @ nF Hc> HBr > HI 4) ME > HBr > HI > HOI More acktic than ethanol is (1) CCH,CH,CH,CHH, @ O4,CO,CH.CH, @) CH,COCH,COCH, fh) CH,COM, neh reagent converts propene to t-propanol? ty 4,0. 4,80, @ BH, HO, OF () HQ@Ac),. NaBH H,O- 14) Aa KOH mproey! aicono! and isopropyl alcohol can be chemically distinguished by which reagent? m POY @ Reactor {@_ Ouetaton wah potassium dichromate 26) Oronoiysis Writ one of the following will not form a yellow precentate on heating with an sikaline solution of one? ) OOOH, B_CRACHOMIH, O4OH @) OACH0H CH.CHy 35. 37. 39. at ne ee ine homologous series of alkanols is a. (1) GHan + 29 2) CHO, 8) CyHaO (4) CyHan «0 On heating glycerol with cone. H2SO, a fe abtained which has bad odour. The compo, (1) Acrolein (2) Formic acig 3) Ally! alcoho! (4) Glycerol suphay ‘The correct acidic order of the following is é.O- CH, No, (ay b> nea (2) m>t>m a) w>mat (4) >> When phenol is treated with CHC!, and Nao; product formed (2) Salicylaldehyde (1) Benzaldehyde (4) Benzoie acid @) Salicylic acid The compound which does not react with sodiun (1) CH,COOH (@) CH, - CHOH - CH, (8) GH,OH (4) CH, -O-CH, Reaction of CH, — CH, with RMaX leads toforret RS a (1) RCH,CH,OH (2) RCHOHCH, (3) RCHOHR: R 4) @ p. Which of the following will not be solubh hydrogen carbonate? (1) 2.4,6-trinitropheno! @) Benzoie acid (3) ONitrophenot (4) Benzenesulphonic acid SeHcH,on 19 in sod ict 288. Answers NEET & Alms 2 @ wemener : ® ist

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