T2E84] solutions ye NET 8 Ain 23. If any solute ‘A’ dimerises in water at 1 atm Pressure and the boiling point of this solution is 100.52°C. If 2 moles of Ais added to 1 kg of water and k, for water is 0.52°C/molal, calculate the Percentage association of A (1) 50%. (2) 30% @) 25% of\100% 24. Substance A tetramerises in water to the extent of 80%. A solution of 2.5 g of A in 100 g of water lowers the freezing point by 0.3°C. The molar mass of Ais (K, for water = 1.86 K kg mol) () 12 @ 3 @) 24 Be 25. K;,IFe(CN)_] is supposed to be 40% dissociated when 1M solution prepared. Its boiling point is equal to another 20% mass by volume of non-electrolytic solution A. Considering molality = molarity. The molecular weight of ) 7 2) or @ 7 @) 47 SECTION - C scicvsienincd Previous Year Questions 1. Which of the following is dependent on temperature? INEET-2017] (1) Molality 48) Molarity (3) Mole fraction (4) Weight percentage 2. If molality of the dilute solution is doubled, the value of molal depression constant (K,) will be INEET-2017] (1) Doubled (2) Halved @) Tripled i Unchanged 3. The van't Hoff factor (i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is [NEET-Phase-2-2016] @o @1 @ 2 gr 4. Which one of the following is incorrect for ideal ‘solution? [NEET-Phase-2-2016) (1) AH py, = 0 (2) AU, 4 = 0 @) AP= Pang ~ Peace by Raut = O Wi AG, = 0 10. ‘At 100°C the vapour pressure of a solution of 655 ‘of a solute in 100 g water is 732 mm. If K, = 0.57 ‘the boiling point of this solution will be INEET2019, (1) 103° (2) 101°C (3) 100°C (4) 102°C Which of the following statements about the composition of the vapour over an ideal 1 : 1 mola. mixture of benzene and toluene is correct) ‘Assume that the temperature is constant at 25° (Given, Vapour Pressure Data at 25°C, benzene = 12.8 kPa, toluene = 3.85 kPa) INEET-2016) (1) Not enough information is given to make a prediction (2) The vapour will contain a higher percentage benzene (3) The vapour will contain a higher percentage of toluene (4) The vapour will contain equal amounts of benzene and toluene What is the mole fraction of the solute in a 1.00 m aqueous solution? [Re-AIPMT-2015] (1) 0.0354 (2) 0.0177 (3) 0.177 (4) 1.770 Which one Is not equal to zero for an ideal ‘solution? [AIPMT-2015] (1) AP = Pobserves — Praoutt (2) BH ya @) AS pie 4) AV The boiling point of 0.2 mol kg solution of X in water is greater than equimolal solution of Y in water. Which one of the following statements is tue in this case? [AIPMT-2015] (1) Y is undergoing dissociation in water while X undergoes no change (2) Xis undergoing dissociation in water (8) Molecular mass of X is greater than the molecular mass of Y (4) Molecular mass of X is less than the molecular mass of Y Which one of the following electrolytes has the ‘same value of van't Hoff's factor (/) as that AL{SO,), (if all are 100% ionised)? [AIPMT-20151 (1) K{Fe(CN),) (2) K,S0, (8) KFe(CN),) (4) AUNOs)y [Aakash Educational Services Limited “Regd, Office Aakash Tower, 8, Pusa Road, New aint 10005 Pr.o11-476234 hhea eo So 15 dew 15) yep gS stuns 88 2 1B “4 16. 16. 1. ‘othe following 0.10m aqueous solutions, which one wil exhibit the largest freezing point depression 2 TAIPMT-2014) KCl (2) CH,,0, @ ASO, (4) K,S0, 8nd Pp are the vapour pressure of pure liquid components. Aand B, respectively of an ideal binary solution. If x, represents the mole fraction of component A, the total pressure of the solution will be. [AIPMT (Prelims)-2012] (1) Pa*%(Pa-Pa) (2) Py +Xq (Py— Pp) @) Pa*%a(Pa- Pa) (A) Px +4 (P,P) ‘The van't Hoff factor i for a compound which undergoes dissociation in one solvent and association in other solvent is respectively [AIPMT (Pretims)-2011] (1) Greater than one and greater than one @ Less than one and greater than one @ Less than one and less than one (4) Greater than one and less than one ‘The freezing point depression constant for water is -1.86° Cm ~'. If §.00 g Na,SO, is dissolved in 45.0 9H,0, the freezing point is changed by -3.82°C. Calculate the van't Hoff factor for Na,SO, TAIPMT (Pretims)-2011] () 0381 @) 205 @) 263 @ 31 A0.1 molal aqueous solution of a weak acid is 30% ‘ionized, fK, for water is 1.86°C/m, the freezing point of the solution will be [AIPMT (Mains)-2011] (1) 036° 2) 024°C @) ~0.18°C (4) 054°C 200 ml of an aqueous solution of a protein contains its 1.269. The osmotic pressure of this solution at 300 Kis found to be 2.57 * 10~* bar. The molar mass 0f protein will be (R = 0.083 L bar mol-* K-") TAPMT (Mains)-2011] () 31014 gmort (2) 61038 g mot" @) 510229 mor (4) 122044 g mot ‘A Solution of sucrose (molar mass = 342 g mol) has been prepared by dissolving 68.5 g of sucrose | 1000 g of water. The freezing point of the solution obiained will be (K, for water = 1.86 K kg mol") [AIPMT (Prelims)-2010] (2) -0s20°C (4) -0570°C 1) 3720 ®) +0.372°¢ 18, 19, 21. ‘An aqueous solution is 1.00 molal in KI. Which change will cause the vapour pressure of the solution to increase? —_[AIPMT (Prelims)-2010] (1) Addition of NaCl (2) Additon of Na,SO, (8) Addition of 1.00 motal KI (4) Addition of water ‘A.0.0020 m aqueous solution of an ionic compound ‘Co(NH,), (NO,)CI freezes at ~0.00732°C. Number ‘of moles of ions which 1 mol of ionic compound Produces on being dissolved in water will be (Ky = 1.88°C /m) [AIPMT (Prelims)-2009] Ms @4 @ 1 @) 2 0.5 molal aqueous solution of a weak acid (HX) is 20% ionized. If K, for water is 1.86 K kg mol"*, the lowering in freezing point of the solution is [AIPMT (Prelims)-2007] (1) 0.56 K (2) -1.12K @ 056K (412K A solution containing 109 per dm? of ure: (molecular mass = 60 g mol) is isotonic with a 5% solution of a non-volatile solute. The molecular mass of this non-volatile solute is IAIPMT (Prelims)-2006] (1) 250 g mor* (2) 300g mot () 350 g mor (4) 200 g mot* 1.00 g of a non-electrolyte solute (molar mass 250g mot") was dissolved in 51.2 9 of benzene. If the freezing point depression constant, K, of benzene is 5.12 K kg mot", the freezing point of benzene will be lowered by [AIPMT (Pretims)-2006] () 04K @) 03k @ 05k @) 02K A solution of acetone in ethanol [AIPMT (Pretims)-2006] (1) Shows a negative deviation from Raout's law (2) Shows a positive deviation from Raoult law (3) Behaves like a near ideal solution (4) Obeys Raoutt's jaw ‘Mhash Educational Services Limited” Regd. Office Aakash Tower, 8, Pusa Road) New Delift10005 Ph.011-47623456) * 2 ot a [Sie eeae "86)) Solutions 24. During osmosis. flow of water through a semi- permeable membrane is. [AIPMT (Prelims)-2006] (1), From solution having higher concentration only (2) From both sides of semi-permeable membrane with equal flow rates (8) From both sides of semi-permeable membrane with unequal flor rates. (4) From solution having lower concentration only 25. The vapour pressure of two liquids P and Q are 80 and 60 torr, respectively. The total vapour pressure of solution obtained by mixing 3 moles of P and 2 moles of Qwouldbe _[AIPMT (Prelims)-2005] (1) 140tor 2) 20tor @) 68tor (4) 72tor 26. A solution of urea (mol. mass 60g mol) boils at 100.18°C at the atmospheric pressure. If k, and ky for water are 1.86 and 0.512K kg mot respectively, the above solution will freeze at [AIPMT (Prelims)-2005] (1) 654°C @) 654°C @) 654°C (4) -0.654°C 27. Asolutionhasa 1:4 mole ratioof pentane to hexane. ‘The vapour pressure of the pure hydrocarbons at 20°C, are 440 mm of Hg for pentane and 120 mm of Hg for hexane. The mole fraction of pentane in the vapour phase would be IAIPMT (Prelims)-2005] (1) 0549 2) 0.200 @) 0786 (4) 0478 28. The mole fraction of the solute in one molal aqueous, solution is [AIPMT (Pretims)-2005] (1) 0.027 2) 0.036 @) 0.018 (4) 0.009 Questions asked Prior to Medical Ent. Exams. 2005 29. Which of the following compounds can be used as, antifreeze in automobile radiators? (1) Methyl alcohol (2) Glycol (3) Ntrophenot (4) Ethyl alcoho! 30. Mole fraction of the solute in a 1.00 motal aqueous solution is (1) 1.7700 (2) 0.4770 @) 0.0177 (4) 0.0344 34 35. 37, NEET & Aye 1 « 10-9 m solution of PHINH,).Cl I9 H,0 shay depression in freezing point by 0.0054%c, yy structure of the compound will be (Give , = 1.860 km) (1) [PUINH,),JCl, (2) [PUNH,),ClICI, (@) [PUNH,),CLICL (4) PRINH, )C1,Jc1 Which of the following salt has the same vaiug van't Hoft’s factor j as that of K,[Fe(CN),}? (1) Na,SO, (2) A(NO,), @) AL{SO,)s (4) NaCl At 25°C, the highest osmotic pressure is exhibity by 0.1 M solution of (1) Glucose (2) Urea @ cect, @) Kel According to Raoult's law, the relative lowering g vapour pressure for a solution is equal to (1) Mole fraction of solute (2) Mole fraction of solvent Q) Moles of solute (4) Moles of solvent The concentration units, independent of ‘temperature, would be (1) Normality (2) Weight volume percent @) Motatity (4) Motarity In liquid-gas equilibrium, the pressure of vapout above the liquid is constant at (1) Constant temperature (2) Low temperature (@) High temperature (4) None of these ‘The vapour pressure of CCI, at 25°C is 143 mm HE 1f0.5 gm of a non-volatile solute (mol. weight = 65)6 dissolved in 100 g CCI,, the vapour pressure of t¥ solution will be (1) 199.34 mm Hg @) 143.99 mm Hg @) 141.43 mm Hg (4) 94.39 mm Hg ‘Aakash Educational Services Limited - Regd! Office !Aakash Tower, 8, Pusa Road, New Delhi-110006 Ph.01 147620465neeT 8 AIMS. What is the molarity of H,SO, solution, that has a censity 1.84 g/cc at 35°C and contains 98% by ‘weight of solute? (1) 184M @) 18M @ 418M 4) 814m 'A5% (w/v) solution of cane sugar (mol. wt. = 342) ‘sisotonic with 1% (w/v) solution of a substance X. The molecular weight of X's (684 2 1712 @ H2 (4) 1368 ‘The vapour pressure of a solvent decreased by 410mm of mercury when a non-volatile solute was added to the solvent. The mole fraction of the solute in the solution is 0.2. What should be the mole fraction of the solvent if the decrease in the vapour pressure is to be 20 mm of mercury? () 04 @ 06 @) 08 (4) 02 10.15 g of a solute, dissolved in 15 g of solvent, is botled at a temperature higher by 0.216°C, than, that of the pure solvent. The molecular weight of the substance, (Molal elevation constant for the sotvent is 2.16°C) is () 104 @ 101 a (2) 100 (4) 1000 The vapour pressure of benzene at a certain temperature is 640 mm of Hg. A non-volatile and on-electrotyte solid, weighing 2.175 g is added to 39.08 of benzene. The vapour pressure of the solubon is 600 mm of Hg. What is the molecular weight of solid substance? a 2) 596 ®) 4950 (@) 798 From the cofigative properties of solution which one ' the best method for the determination of olecutar weight of proteins and polymers? (1) Osmote pressure 2) Lowering in vapour pressure ) Lowering in freezing point (4) Elevation in boiling point Molarity of fiquid HCI. if density of solution is "17 grec is 65 ® 205 (2) 1825 (4) 42.10 EE ‘“akach Educational Services Limited - Regd. Ofice Aakash Tower, 8, Pues Road, New Dein-110005 Ph.011-47623456) Solutions 45. Asolution contains non volatile solute of molecular mass M,. Which of the following can be used to calculate the molecular mass of solute in terms of ‘osmotic pressure? (m, - mass of solute, V - volume of solution, x -osmotic pressure) “ mM, =( 2] ver 2 m, -(%) er r Tig) .8 @ M,=(%2) aR (4) m4, = (2) 46. A solution containing components A and B follows Raoult’s law (1) A-Batraction force is greater than A-Aand B-B. (2) A-Battraction force is less than A-Aand B - 8 (3) A-B attraction force remains same as A - A and B- B (4) Volume of solution is different from sum of volume of solute and solvent 47. Formation of a solution from two components can be considered as (Pure solvent — separated solvent molecules, AH, (i) Pure solute + separated solute molecules, AH, (ii) Separated solvent and solute molecules —> solution, aH, Solution so formed will be ideal i (1) dHyge= AH, + aH, + aH, 2) AH a= OH, + AH, = aH, (8) Hye, AH, — AH, — AH, (4) OH AHy— AH, ~ aH, Camphor is often used in molecular mass determination because (1) tis readily available (2) Ithas very high cryoscopic constant @) Itis volatile (4) Itis solvent for organic substances 48, 49. Which condition is not satisfied by an ideal solution? j (1) Spee H = 2) Agee V = 0 ~P) by, S = 0 (4) Obeyance to Raoult's Law i i at onee ee 220 Answers NET & Aimee EXERCISE oe a A oe) 10. @) "4 2 @ 13, 2) 14 12) NS 2) 18) 7. @ 18 3) 19. (2) 20, 4) tity 2 2B 24. (1) 25. @) 26. (1) a7. (1) 2B 3) 2. 4) 30. @) ASSIGNMENT Section A : Objective Type Questions 1 8) 2 8 3 @) 4° 2 5. @) a an) & @ % 8) 10. 3) 1. Q) 12. (2) 13. (2) 14. (3) : 15. @) 16. (2) 17. (4) 18. (4) 19. (2) 20. (1) 2. 22. 4) 23. (3) 24. (2) 25. (1) 2. (1) zm 28. (2) Oo 8 tO eo a i em 7 8M MH OO i oe oe Oe et) 48. (1) 49. (1) 50. () | ‘Section B : Objective Type Questions | oe 2 3 4) 4) 5. @) 6 @) nw eee eh ee kh &8 62 7H 8 4 22. (1) 23.) 24. (4) 25. (1) Section C : Previous Year Questions Oe 2 6) 2. @ ee ae) 6 te) ey 12, 13. 4) 4. 8) 18% @) 62 7) 8 12 w 20. (4) 21. @) an SG ae ee aw oo ) 27. a) 28. 6) 29. @) @ @ 32, (2) 33. @) 34. (1) 36. 3) 36. (1) 37. @) 3% 1) 39. (1) 40. 1 Q) (1 43. (1) 44. 3) 6 46. (3) 47. (ty 48, . : : 49. Section O : Assertion-Reason Type Questions 1 2 1) 3 a) 4 a 5. 8 2 () 10. (1) 1 ay 2 o oe) el 45. (2) 16. (3) 17. @) 1% ® B @ 14, 2) ‘Aakash Eaicational Servicoe Liiid Road On Aakash touees oa = oad NeW Doi Yo008 print tia7en3es® cea ca