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ppp1 KSSM 2021 Form 5 Paper 2
ppp1 KSSM 2021 Form 5 Paper 2
SULIT TINGKATAN:……………………….
4541 / 2
KIMIA 2
April 2021
2 1/2 jam
C 11 20
Jumlah
Disediakan Oleh: Disemak Oleh :
…………………………………….. ………………………………………
(PN JOANNA MAGDALIN ) (PN HUFAIDAH BT ABD HAMID
Section A
[60 marks]
Answer all questions in this section.
Jawab semua soalan dalam bahagian ini.
1. Diagram 1 shows a part of the Periodic Table of Elements. W, X, Y and Z are not the actual symbols
of the elements.
Rajah 1 menunjukkan sebahagian daripada Jadual Berkala Unsur. W, X, Y dan Z bukan simbol
sebenar unsur tersebut.
X W Y
Z
Diagram 1
Rajah 1
Based on Diagram 1,
Berdasarkan Rajah 1,
[1 mark]
[1 mark]
(b) The information below shows the special characteristics of an element in Diagram 1.
Maklumat di bawah menunjukkan ciri istimewa bagi suatu unsur dalam Rajah 1.
[1 mark]
(c) The atomic size of Y is smaller than X. Explain why.
Saiz atom Ylebih kecil daripada atom X. Terangkan mengapa.
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[2 marks]
2. Diagram 2 shows the apparatus set-up to investigate the effect of heat on zinc carbonate.
Rajah 2 menunjukkan susunan radas untuk mengkaji kesan haba ke atas zink karbonat.
Zinc carbonate
Zink karbonat
Lime water
Heat
Air kapur
Panaskan
Diagram 2
Rajah 2
Residue X : Gas Y:
[2 marks]
[1 mark]
(c) Calculate the volume of gas Y produced if 5g of zinc carbonate is heated at room conditions.
[Relative atomic mass: Zn = 65 ; C = 12 ; O = 16, Molar volume: 24 dm3 mol-1 at room
condition]
Hitungkan isipadu gas Yyang dihasilkan apabila 5g zink karbonat dipanaskan pada keadaan
bilik.
[Jisim atom relatif : Zn = 65 ; C = 12 ; O = 16, Isipadu molar 24 dm3 mol-1 pada keadaan
bilik]
[2 marks]
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3. Table 1 shows the set-up of apparatus and observation for two experiments, I and II.
Jadual 1 menunjukkan susunan radas dan pemerhatian bagi dua eksperimen, I dan II.
Experiment
I II
Eksperimen
Test tube
Tabung uji Magnesium powder Copper powder
Serbuk magnesium Serbuk kuprum
[1 mark]
[1 mark]
(c) The reaction is a redox reaction. Explain in term of change in oxidation number.
Tindak balas itu ialah suatu tindak balas redoks. Terangkan dari segi perubahan nombor
pengoksidaan.
[2 marks]
(d) Explain the observation in Experiment II
Terangkan pemerhatian dalam Eksperimen II.
[2 marks]
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4. A student carried out two experiments to investigate the factor that affects the rate of reaction.
Table 2 shows the results of the experiments.
Seorang pelajar telah menjalankan dua eksperimen untuk menyiasat faktor-faktor yang
menpengaruhi kadar sesuatu tindak balas. Jadual 2 menunjukkan keputusan bagi eksperimen-
eksperimen tersebut.
I 50
5 minutes
5 minit
II 3 minutes 50
3 minit
…………………………………………………………………………………….............
…………………………………………………………………………………….............
[1 mark]
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(b) State the factor that affects the rate of reaction in this experiment.
Nyatakan faktor yang mempengaruhi kadar tindak balas dalam eksperimen ini :
…………………………………………………………………………………….............
[1 mark]
(c) (i) From the information in Table 2, calculate the average rate of reaction for
Experiment I and Experiment II.
Daripada maklumat dalam Jadual 2 hitungkan kadar tindak balas purata untuk
Eksperimen I dan Eksperiment II.
[1 mark]
……………………………………………………………………………………..............
Size of magnesium in exp II is smaller than exp I // Total surface area of
magnesium that exposed to the collision in Exp II is larger than Exp I.
……………………………………………………………………………………..............
Frequency of collision between Mg atom and H+ ion in Exp II is higher.
Frequency of effective collision between particles in Exp II is higher.
……………………………………………………………………………………...............
……………………………………………………………………………………...............
[3 marks]
(d) Give one reason why the final volume of gas obtained in all experiments are the same.
Beri satu sebab mengapa isipadu akhir gas yang diperolehi dalam semua eksperimen
adalah sama.
…………………………………………………………………………………….............
[1 mark]
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5. Diagram 3 shows the apparatus set-up to investigate the transfer of electrons at a distance in a redox
reaction.
Rajah 3 menunjukkan susunan radas untuk mengkaji pemindahan elektron pada suatu jarak dalam
tindak balas redoks.
Carbon electrode Y
Carbon electrode X
Elektrod karbonY
Elektrod karbonX
Based on Diagram 3,
Berdasarkan Rajah 3,
(a) State the function of dilute sulphuric acid.
Nyatakan fungsi asid sulfurik cair.
[1 mark]
(b) State the observation at electrode X and electrode Y.
Nyatakan pemerhatian pada elektrod X dan elektrod Y.
Electrode X:
Electrode Y:
[2 marks]
(c) The following equation shows the reaction that takes place at carbon electrode Y.
Persamaan berikut menunjukkan tindakbalas yang berlaku pada elektrod karbon Y.
[1 mark]
(ii) State the type of reaction that occurs.
Nyatakan jenis tindakbalas yang berlaku.
[1 mark]
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[1 mark]
(ii) describe briefly a chemical test to identify the cation formed in (d)(i)
Huraikan secara ringkas ujian kimia untuk mengena lpasti kation yang terbentuk di
c(i).
[2 marks]
6. Diagram 4 shows the apparatus set-up to determine the empirical formula of an oxide of copper.
Rajah 4 menunjukkan susunan radas untuk menentukan formula empirik kuprum oksida.
Diagram 4
Based on Diagram 4,
Berdasarkan Rajah 4,
(a) What is the purpose of putting zinc granules in the hydrochloric acid?
Apakah tujuan memasukkan ketulan zink ke dalam asid hidroklorik?
[1 mark]
(b) What is the the function of water in the boiling tube at the left-hand side?
Apakah fungsi air didalam tabung didih pada sebelah kiri?
[1 mark]
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(c) Why must the two-holes stopper be fitted to the boiling tube at the left-hand side?
Kenapa penyumbat dengan dua lubang digunakan pada tabung didh disebelah kiri?
[1 mark]
(d) The results obtained from the experiment is recorded in Table 5 below.
Keputusan eksperimen ini direkodkan dalam Jadual 5 dibawah.
Description Mass (g)
Diskripsi Jisim(g)
Glass tube 3.4168
Tiub kaca
Glass tube + oxide of copper 3.4918
Tiub kaca + oksida kuprum
Glass tube + copper 3.4768
Tiub kaca + kuprum
[3 marks]
(e) How do you ensure that all the oxide of copper is reduced to copper?
Bagaimanakah untuk memeastikan semua oksida kuprum telah diturunkan kepada kuprum?
Repeat process of heating, cooling, weighing until a constant mass is obtained
[1 mark]
(f) Why hydrogen gas is allowed to flow continuously while cooling the heated product to room
temperature?
Kenapa gas hidrogen dialirkan tanpa henti semasa penyejukkan bahan yang dipanaskan ke
suhu bilik?
To avoid copper from being oxidized to copper(II) oxide again // avoid copper from
change to copper(II) oxide
[ 1 mark]
(g) Explain why the empirical formula of magnesium oxide cannot be determine using this
method.
Terangkan mengapa formula empirik magnesium oksida tidak dapat ditentukan menggunakan
kaedah ini?
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[1 mark]
7. Table 3 shows the information about four solutions; P, Q, R and S. P, Q, R and S may be acid
or alkali.
Jadual 3 menunjukkan maklumat tentang empat larutan P, Q, R dan S. Larutan P, Q, R dan S
mungkin asid atau alkali.
……………………………………………………………………………………………...
[1 mark]
(b) Based on Table 3, state the
Berdasarkan Jadual 3, nyatakan
Diagram 5.1
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Malic acid is a weak acid which is found naturally in green apples and in a wide variety
of unripe fruits.
Asid malik merupakan suatu asid lemah yang wujud secara semula jadi dalam epal hijau
dan juga dalam pelbagai jenis buah-buahan yang belum masak.
(d) Diagram 5.2 shows a volumetric flask containing 500 cm3 of 2.0 mol dm-3 sodium
hydroxide solution. This solution is known as a standard solution.
Rajah 5.2 menunjukkan sebuah kelalang volumetrik yang mengandungi 500 cm3 larutan
natrium hidroksida 2.0 mol dm-3. Larutan ini dikenali sebagai larutan piawai.
Graduation mark
Tanda senggatan
Diagram 5.2
(i) To prepare the standard solution in Diagram 5.2, a student added x g of solid
sodium hydroxide into a 500 cm3 volumetric flask. Then, distilled water is added
until graduation mark is reached.
Untuk menyediakan larutan piawai seperti dalam Rajah 5.2, seorang pelajar telah
menambahkan x g pepejal natrium hidroksida ke dalam sebuah kelalang
volumetrik 500 cm3. Kemudian, air suling ditambahkan sehingga mencapai tanda
senggatan.
[2 marks]
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(ii) The standard solution in Diagram 5.2 is used to determine the concentration of a
sample of sulphuric acid by titration method. Diagram 5.3 shows the apparatus set-
up used.
Larutan piawai dalam Rajah 5.2 digunakan untuk menentukan kepekatan satu
contoh asid sulfurik menggunakan kaedah pentitratan. Rajah 5.3 menunjukkan
susunan alat radas yang digunakan
Sulphuric acid
Asid sulfurik
Diagram 5.3
Complete neutralisation of 50.0 cm3 of 2.0 mol dm-3 sodium hydroxide solution
required 25.0 cm3 of the sulphuric acid.
Peneutralan lengkap 50.0 cm3 larutan natrium hidroksida 2.0 mol dm-3
memerlukan 25.0 cm3 asid sulfurik.
[2 marks]
8. Electrolysis of 0.5 mol dm-3 and 0.0001 mol dm-3 of hydrochloric acid is conducted in an
electrolytic cell as shown in the diagram 6 below. The experiment is left for a few minutes and the
observations obtained are recorded.
Elektrolisis asid hidroklorik 0.5 mol dm-3 dan 0.0001 mol dm-3 di jalankan di dalam sel ektrolitik
seperti yang ditunjukkan dalam rajah 6 dibawah. Eksperimen di biarkan selama beberapa minit
dan pemerhatian yang di perolehi di rekodkan.
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X Y Test Tubes
Cell 1
P Q
Test Tubes
Cell II
Diagram 6
(a) Write all ions that exist in hydrochloric acid.
Tuliskan semua ion yang wujud di dalam asid hidroklorik.
……………………………………………………………………………………………...
[ 1 mark]
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Cell I :
……………………………………………………………………………………………..
Cell II
: ……………………………………………………………………………………
………..
[ 2 marks]
(d) Write the half equations at anode in
Tuliskan setengah persamaan di anod dalam
Cell I
: ……………………………………………………………………………………
………..
Cell II
: ……………………………………………………………………………………
……….. [2
marks]
(e) State the factor that affects the selection of ion to be discharged at anode during
electrolysis in Cell I.
Nyatakan faktor yang terlibat di dalam pemilihan ion yang di discas di anod semasa
elektrolisis di dalam sel I.
……………………………………………………………………………………………..
[1 mark]
(f) Cathode Y in Cell I produced bubbles of hydrogen gas during the electrolysis. State how
to identify the hydrogen gas produced.
Katod Y dalam Sel I menghasilkan gelembung gas hydrogen semasa elektrolisis.
Nyatakan bagaimana untuk mengenal pasto gas hydrogen yang di hasilkan.
……………………………………………………………………………………………..
……………………………………………………………………………………………..
………………………………………………………………………………………… …..
[2 marks]
(g) State one usage of electrolysis in our daily life.
Nyatakan satu kegunaan elektrolisis di dalam kehidupan seharian.
……………………………………………………………………………………………...
[ 1 mark]
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Section B
[20 marks]
Answer any one question.
Jawab mana-mana satu soalan daripada bahagian ini.
CH4 CO2
Diagram 7
(c) Compare two physical properties of methane and calcium chloride. Explain your
answer.
Bandingkan dua sifat fizikal metana dan kalsium klorida. Jelaskan jawapan anda.
[6 marks]
10. (a) Table 4.1 show the chemical equation of two reactions.
Jadual 4.1 menunjukkan persamaan kimia bagi dua tindak balas.
Y Zn + Cu(NO3)2 → Zn(NO3)2 + Cu
Table 4.1
Determine whether each of the reactions is a redox reaction or not a redox reaction. Explain your
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Tentukan sama ada setiap tindak balas tersebut merupakan tindak balas redoks atau bukan tindak
balas redoks. Terangkan jawapan anda dari segi nombor pengoksidaan.
[5 marks]
(b) Table 4.2 shows the formulae for two chlorides of iron compounds.
Jadual 4.2 menunjukkan formula dua sebatian klorida bagi ferum.
Compound
Formula
Sebatian
R FeCl2
S FeCl3
Table 4.2
(i) Determine the oxidation number of iron in both compounds and name the compounds
based on IUPAC nomenclature.
Tentukan nombor pengoksidaan bagi ferum dalam kedua-dua sebatian dan namakan
sebatian-sebatian tersebut berdasarkan penamaan IUPAC.
[4 marks]
(ii) Compound R can be converted to compound S in the presence of an oxidising agent.
Suggest the oxidising agent and state one observation for the reaction.
Sebatian R boleh ditukarkan kepada sebatian S dengan kehadiran satu agen
pengoksidaan. Cadangkan agen pengoksidaan tersebut dan nyatakan satu pemerhatian
bagi tindak balas yang berlaku.
[2 marks]
(c) A chemical cell can be constructed by combining two half cells with different E0 values. Diagram 7
below shows a chemical cell where silver metal and iron metal are used as electrodes, which are
dipped into their respective ionic salt solutions. Both salt solutions are connected by a salt bridge.
Sel kimia boleh dibina dengan mennggabungkan dua setengah cell dengan nilai E0 yang berbeza.
Rajah 7 dibawah menunjukkan sel kimia dimana logam argentum dan logam ferum digunakan
sebagai elektrod dan dicelup kedalam larutan garam masing-masing. Larutan garam tersebut
dihubungkan dengan jambatan garam.
Diagram 7
You are provided with the following standard electrode potential:
Anda diberikan nilai electrod piawai berikut:
Ag + (aq) + e- Ag (s) E0 = + 0.80V
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(ii) State the products formed at the negative terminal and positive terminal. Explain
your answer. In your answer, include half equations.
Nyatakan hasil yang terbentuk di terminal negatif dan terminal positif. Terangkan
jawapan anda. Sertakan persamaan setengah.
(iv) write the cell notation for the cell and calculate the voltage of the cell.
Tuliskan notasi sel dan kirakan nilai voltan cell.
[9 marks]
Section C
[20 marks]
Answer all the questions from this section.
11 A house wife`s discovered that the cake she bake did not rise.
Seorang suri rumah mendapati kek yang dibakarnya tidak naik.
+ Acid M
+ Asid M
Lead(II) nitrate
Plumbum(II) nitrat
Diagram 8
(i) Based on Diagram 8 :
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