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NAMA: ………………………………

SULIT TINGKATAN:……………………….
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KIMIA 2
April 2021
2 1/2 jam

SEKOLAH MENENGAH KEBANGSAAN SULTAN BADLISHAH.


09000 KULIM,KEDAH
___________________________________________________________________
PEPERIKSAAN PENGGAL 1
TAHUN 2021
KIMIA KERTAS 2
TINGKATAN 5
2 JAM 30 MINIT

JANGAN BUKA SOALAN INI SEHINGGA DIBERITAHU


Markah Markah
1. Kertas soalan ini adalah dalam dwibahasa. Bahagian Soalan
Penuh Diperoleh
2. Soalan dalam bahasa Inggeris mendahului 1 5
soalan yang sepadan dalam bahasa Melayu. 2 5
3 6
3. Calon perlu menjawab semua soalan pada
4 7
bahagian A, pilih dan jawab satu soalan A
daripada bahagian B dan jawab soalan pada 5 8
bahagian C. 6 9
7 10
4. Calon dikehendaki merujuk kepada Jadual
Berkala Unsur dan siri keupayaan electrod kimia 8 10
yang disediakan di bahagian belakang sekiranya 9 20
perlu. B
10 20

C 11 20

Jumlah
Disediakan Oleh: Disemak Oleh :

…………………………………….. ………………………………………
(PN JOANNA MAGDALIN ) (PN HUFAIDAH BT ABD HAMID

Kertas soalan ini mengandungi 20 halaman bercetak


2

Section A
[60 marks]
Answer all questions in this section.
Jawab semua soalan dalam bahagian ini.

1. Diagram 1 shows a part of the Periodic Table of Elements. W, X, Y and Z are not the actual symbols
of the elements.
Rajah 1 menunjukkan sebahagian daripada Jadual Berkala Unsur. W, X, Y dan Z bukan simbol
sebenar unsur tersebut.

X W Y
Z

Diagram 1
Rajah 1
Based on Diagram 1,
Berdasarkan Rajah 1,

(a) (i) Write an electron arrangement of atom W.


Tuliskan susunan electron bagi atom W.

[1 mark]

(ii) Which of the element is halogen?


Unsur manakah adalah halogen?

[1 mark]

(b) The information below shows the special characteristics of an element in Diagram 1.
Maklumat di bawah menunjukkan ciri istimewa bagi suatu unsur dalam Rajah 1.

 Form coloured compounds  Acts as catalyst


Membentuk sebatian berwarna Bertindak sebagai mangkin

Which element shows the above characteristics?


Unsur manakah menunjukkan ciri di atas?

[1 mark]
(c) The atomic size of Y is smaller than X. Explain why.
Saiz atom Ylebih kecil daripada atom X. Terangkan mengapa.

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[2 marks]

2. Diagram 2 shows the apparatus set-up to investigate the effect of heat on zinc carbonate.
Rajah 2 menunjukkan susunan radas untuk mengkaji kesan haba ke atas zink karbonat.

Zinc carbonate
Zink karbonat

Lime water
Heat
Air kapur
Panaskan
Diagram 2
Rajah 2

The chemical equation for the reaction is as follow:


Persamaan kimia bagi tindak balas adalah seperti berikut:

ZnCO3 (s) X (s) + Y (g)

(a) Name residue X and gas Y released.


Namakan baki X dan gas Y yang terbebas.

Residue X : Gas Y:
[2 marks]

(b) State the colour of residue X.


Nyatakan warna baki X.

[1 mark]

(c) Calculate the volume of gas Y produced if 5g of zinc carbonate is heated at room conditions.
[Relative atomic mass: Zn = 65 ; C = 12 ; O = 16, Molar volume: 24 dm3 mol-1 at room
condition]
Hitungkan isipadu gas Yyang dihasilkan apabila 5g zink karbonat dipanaskan pada keadaan
bilik.
[Jisim atom relatif : Zn = 65 ; C = 12 ; O = 16, Isipadu molar 24 dm3 mol-1 pada keadaan
bilik]

[2 marks]

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3. Table 1 shows the set-up of apparatus and observation for two experiments, I and II.
Jadual 1 menunjukkan susunan radas dan pemerhatian bagi dua eksperimen, I dan II.

Experiment
I II
Eksperimen

Copper(II) sulphate solution Magnesium sulphate solution


Larutan kuprum(II) sulfat Larutan magnesium sulfat

Test tube
Tabung uji Magnesium powder Copper powder
Serbuk magnesium Serbuk kuprum

Observation Brown solid formed.


Pemerhatian Blue solution becomes paler. No change.
Pepejal perang terbentuk. Tiada perubahan.
Larutan biru menjadi pucat.
Table 1
Based on the table above,
Berdasarkan jadual diatas,

(a) State the name of the brown solid formed.


Nyatakan nama bagi pepejal perang yang terbentuk.

[1 mark]

(b) Give a reason for the observation on the solution in Experiment I.


Berikan satu sebab bagi pemerhatian ke atas larutan dalam Eksperimen I.

[1 mark]

(c) The reaction is a redox reaction. Explain in term of change in oxidation number.
Tindak balas itu ialah suatu tindak balas redoks. Terangkan dari segi perubahan nombor
pengoksidaan.

[2 marks]
(d) Explain the observation in Experiment II
Terangkan pemerhatian dalam Eksperimen II.

[2 marks]

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4. A student carried out two experiments to investigate the factor that affects the rate of reaction.
Table 2 shows the results of the experiments.
Seorang pelajar telah menjalankan dua eksperimen untuk menyiasat faktor-faktor yang
menpengaruhi kadar sesuatu tindak balas. Jadual 2 menunjukkan keputusan bagi eksperimen-
eksperimen tersebut.

Volume of gas collected


when magnesium reacted
completely /cm3
Experiment Diagram
Isipadu gas yang
Eksperimen Rajah
dikumpul apabila
magnesium lengkap
bertindak balas /cm3
m g of magnesium ribbon
m g pita magnesium

I 50
5 minutes

5 minit

0.5 mol dm-3 hydrochloric acid


in excess
asid hidroklorik 0.5 mol dm-3
m g of magnesium powder
m g serbuk magnesium

II 3 minutes 50

3 minit

0.5 mol dm-3 hydrochloric acid


in excess
asid hidroklorik 0.5 mol dm-3
berlebihan
Table 2

(a) From this experiment, state the meaning of rate of reaction.


Daripada ekperimen ini, nyatakan maksud kadar tindak balas.

…………………………………………………………………………………….............

…………………………………………………………………………………….............
[1 mark]

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(b) State the factor that affects the rate of reaction in this experiment.
Nyatakan faktor yang mempengaruhi kadar tindak balas dalam eksperimen ini :

…………………………………………………………………………………….............
[1 mark]

(c) (i) From the information in Table 2, calculate the average rate of reaction for
Experiment I and Experiment II.
Daripada maklumat dalam Jadual 2 hitungkan kadar tindak balas purata untuk
Eksperimen I dan Eksperiment II.

[1 mark]

(ii) Rate of reaction in Experiment II is higher than Experiment I.


By referring to the Collision Theory, explain why there are differences in the rate
of reaction in both experiments.
Kadar tindak balas dalam Eksperimen II lebih tinggi daripada Eksperimen I.
Dengan merujuk kepada Teori Perlanggaran, terangkan mengapa terdapat
perbezaan dalam kadar tindak balas bagi kedua-dua eksperimen itu.

……………………………………………………………………………………..............
Size of magnesium in exp II is smaller than exp I // Total surface area of
magnesium that exposed to the collision in Exp II is larger than Exp I.
……………………………………………………………………………………..............
Frequency of collision between Mg atom and H+ ion in Exp II is higher.
Frequency of effective collision between particles in Exp II is higher.
……………………………………………………………………………………...............

……………………………………………………………………………………...............
[3 marks]

(d) Give one reason why the final volume of gas obtained in all experiments are the same.
Beri satu sebab mengapa isipadu akhir gas yang diperolehi dalam semua eksperimen
adalah sama.

…………………………………………………………………………………….............
[1 mark]

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5. Diagram 3 shows the apparatus set-up to investigate the transfer of electrons at a distance in a redox
reaction.
Rajah 3 menunjukkan susunan radas untuk mengkaji pemindahan elektron pada suatu jarak dalam
tindak balas redoks.

Carbon electrode Y
Carbon electrode X
Elektrod karbonY
Elektrod karbonX

Iron(II) sulphate solution Acidified potassium dichromate (VI) solution


Larutan ferum(II)sulfat Larutan kalium dikromat(VI) berasid

Dilute sulphuric acid


Asid sulfurik cair
Diagram 3
Rajah 3

Based on Diagram 3,
Berdasarkan Rajah 3,
(a) State the function of dilute sulphuric acid.
Nyatakan fungsi asid sulfurik cair.

[1 mark]
(b) State the observation at electrode X and electrode Y.
Nyatakan pemerhatian pada elektrod X dan elektrod Y.

Electrode X:

Electrode Y:
[2 marks]
(c) The following equation shows the reaction that takes place at carbon electrode Y.
Persamaan berikut menunjukkan tindakbalas yang berlaku pada elektrod karbon Y.

Cr2O72-- + 14H+ + 6e-→ 2Cr3+ + 7H2O

(i) State the change of oxidation number for chromium.


Nyatakan perubahan nombor pengoksidaan bagi kromium.

[1 mark]
(ii) State the type of reaction that occurs.
Nyatakan jenis tindakbalas yang berlaku.

[1 mark]

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(d) Based on the reaction that takes place at carbon electrode X,


Berdasarkan tindak balas yang berlaku pada elektrod karbonX,

(i) write the half equation for the reaction


Tuliskan persamaan setengah bagi tindakbalas itu.

[1 mark]

(ii) describe briefly a chemical test to identify the cation formed in (d)(i)
Huraikan secara ringkas ujian kimia untuk mengena lpasti kation yang terbentuk di
c(i).

[2 marks]

6. Diagram 4 shows the apparatus set-up to determine the empirical formula of an oxide of copper.
Rajah 4 menunjukkan susunan radas untuk menentukan formula empirik kuprum oksida.

Diagram 4
Based on Diagram 4,
Berdasarkan Rajah 4,
(a) What is the purpose of putting zinc granules in the hydrochloric acid?
Apakah tujuan memasukkan ketulan zink ke dalam asid hidroklorik?

[1 mark]
(b) What is the the function of water in the boiling tube at the left-hand side?
Apakah fungsi air didalam tabung didih pada sebelah kiri?

[1 mark]

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(c) Why must the two-holes stopper be fitted to the boiling tube at the left-hand side?
Kenapa penyumbat dengan dua lubang digunakan pada tabung didh disebelah kiri?

[1 mark]

(d) The results obtained from the experiment is recorded in Table 5 below.
Keputusan eksperimen ini direkodkan dalam Jadual 5 dibawah.
Description Mass (g)
Diskripsi Jisim(g)
Glass tube 3.4168
Tiub kaca
Glass tube + oxide of copper 3.4918
Tiub kaca + oksida kuprum
Glass tube + copper 3.4768
Tiub kaca + kuprum

Calculate the empirical formula of the oxide of copper.


Hitungkan formula empirik oksida kuprum.
[Realative atomic mass/ Jisim atom relatif : O = 16, Cu = 64]

[3 marks]

(e) How do you ensure that all the oxide of copper is reduced to copper?
Bagaimanakah untuk memeastikan semua oksida kuprum telah diturunkan kepada kuprum?
Repeat process of heating, cooling, weighing until a constant mass is obtained
[1 mark]

(f) Why hydrogen gas is allowed to flow continuously while cooling the heated product to room
temperature?
Kenapa gas hidrogen dialirkan tanpa henti semasa penyejukkan bahan yang dipanaskan ke
suhu bilik?
To avoid copper from being oxidized to copper(II) oxide again // avoid copper from
change to copper(II) oxide
[ 1 mark]

(g) Explain why the empirical formula of magnesium oxide cannot be determine using this
method.
Terangkan mengapa formula empirik magnesium oksida tidak dapat ditentukan menggunakan
kaedah ini?

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Magnesium is more reactive than hydrogen

[1 mark]

7. Table 3 shows the information about four solutions; P, Q, R and S. P, Q, R and S may be acid
or alkali.
Jadual 3 menunjukkan maklumat tentang empat larutan P, Q, R dan S. Larutan P, Q, R dan S
mungkin asid atau alkali.

Solution Information pH value


Larutan Maklumat Nilai pH

Ionised completely in water


P 2
Mengion lengkap dalam air

Ionised partially in water


Q 6
Mengion separa lengkap dalam air

Ionised completely in water


R 13
Mengion lengkap dalam air

Ionised partially in water


S 8
Mengion separa lengkap dalam air
Table 3
(a) State the meaning of alkali.
Nyatakan maksud alkali.
Substance that ionises in water to produce hydroxide ion
……………………………………………………………………………………………...

……………………………………………………………………………………………...
[1 mark]
(b) Based on Table 3, state the
Berdasarkan Jadual 3, nyatakan

(i) strong alkali / alkali kuat : ……………………………………………………........

(ii) weak acid / asid lemah : ……………………………………………………….....


[2 marks]

(c) Diagram 5.1 shows a bottle of powder malic acid.


Rajah 5.1 menunjukkan sebotol serbuk asid malik.

Diagram 5.1

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Malic acid is a weak acid which is found naturally in green apples and in a wide variety
of unripe fruits.
Asid malik merupakan suatu asid lemah yang wujud secara semula jadi dalam epal hijau
dan juga dalam pelbagai jenis buah-buahan yang belum masak.

Describe a chemical test to prove that the malic acid is an acid.


Huraikan satu ujian kimia untuk membuktikan bahawa asid malik merupakan suatu asid.
Dissolve malic acid powder in distilled water. add 2 cm3 of malic acid
……………………………………………………………………………………………...
solution into a test tube. add half spatula of magnesium/zinc/calcium
carbonate powder into the test tube. Effervescene occur/ bubble gas
……………………………………………………………………………………………...
produced
……………………………………………………………………………………………...
[3 marks]

(d) Diagram 5.2 shows a volumetric flask containing 500 cm3 of 2.0 mol dm-3 sodium
hydroxide solution. This solution is known as a standard solution.
Rajah 5.2 menunjukkan sebuah kelalang volumetrik yang mengandungi 500 cm3 larutan
natrium hidroksida 2.0 mol dm-3. Larutan ini dikenali sebagai larutan piawai.

Graduation mark
Tanda senggatan

500 cm3 of 2.0 mol dm-3


sodium hydroxide solution

500 cm3 larutan natrium

Diagram 5.2

(i) To prepare the standard solution in Diagram 5.2, a student added x g of solid
sodium hydroxide into a 500 cm3 volumetric flask. Then, distilled water is added
until graduation mark is reached.
Untuk menyediakan larutan piawai seperti dalam Rajah 5.2, seorang pelajar telah
menambahkan x g pepejal natrium hidroksida ke dalam sebuah kelalang
volumetrik 500 cm3. Kemudian, air suling ditambahkan sehingga mencapai tanda
senggatan.

Calculate the value of x.


Hitungkan nilai x.
[Molar mass of sodium hydroxide, NaOH = 40]
[Jisim molar bagi natrium hidroksida, NaOH = 40]

[2 marks]

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(ii) The standard solution in Diagram 5.2 is used to determine the concentration of a
sample of sulphuric acid by titration method. Diagram 5.3 shows the apparatus set-
up used.
Larutan piawai dalam Rajah 5.2 digunakan untuk menentukan kepekatan satu
contoh asid sulfurik menggunakan kaedah pentitratan. Rajah 5.3 menunjukkan
susunan alat radas yang digunakan

Sulphuric acid

Asid sulfurik

50.0 cm3 of 2.0 mol dm-3 sodium hydroxide solution


+ phenolphthalein indicator

50.0 cm3 larutan natrium hidroksida 2.0 mol dm-3

Diagram 5.3

Complete neutralisation of 50.0 cm3 of 2.0 mol dm-3 sodium hydroxide solution
required 25.0 cm3 of the sulphuric acid.
Peneutralan lengkap 50.0 cm3 larutan natrium hidroksida 2.0 mol dm-3
memerlukan 25.0 cm3 asid sulfurik.

Calculate the concentration of the sulphuric acid in mol dm-3.


Hitungkan kepekatan asid sulfurik tersebut dalam mol dm-3.

[2 marks]

8. Electrolysis of 0.5 mol dm-3 and 0.0001 mol dm-3 of hydrochloric acid is conducted in an
electrolytic cell as shown in the diagram 6 below. The experiment is left for a few minutes and the
observations obtained are recorded.
Elektrolisis asid hidroklorik 0.5 mol dm-3 dan 0.0001 mol dm-3 di jalankan di dalam sel ektrolitik
seperti yang ditunjukkan dalam rajah 6 dibawah. Eksperimen di biarkan selama beberapa minit
dan pemerhatian yang di perolehi di rekodkan.

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X Y Test Tubes

Electrolytic Cell 0.5 mol dm-3 of


Hydrochloric Acid
Carbon electrode

Cell 1

P Q
Test Tubes

Electrolytic Cell 0.0001 mol dm-3 of


Hydrochloric Acid
Carbon electrode

Cell II

Diagram 6
(a) Write all ions that exist in hydrochloric acid.
Tuliskan semua ion yang wujud di dalam asid hidroklorik.

……………………………………………………………………………………………...
[ 1 mark]

(b) What is meant by electrolyte?


Apakah yang yang di maksudkan dengan elektrolit?
Substance that can conduct electricity either in molten state or aqueous
……………………………………………………………………………………………...
solution
………………………………………………………………………………………… …..
[ 1 mark]

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(c) State the gas produced at anode in the cells.


Nyatakan gas yang dihasilkan di anod di sel berikut.

Cell I :
……………………………………………………………………………………………..
Cell II
: ……………………………………………………………………………………
………..
[ 2 marks]
(d) Write the half equations at anode in
Tuliskan setengah persamaan di anod dalam

Cell I
: ……………………………………………………………………………………
………..
Cell II
: ……………………………………………………………………………………
……….. [2
marks]

(e) State the factor that affects the selection of ion to be discharged at anode during
electrolysis in Cell I.
Nyatakan faktor yang terlibat di dalam pemilihan ion yang di discas di anod semasa
elektrolisis di dalam sel I.

……………………………………………………………………………………………..
[1 mark]

(f) Cathode Y in Cell I produced bubbles of hydrogen gas during the electrolysis. State how
to identify the hydrogen gas produced.
Katod Y dalam Sel I menghasilkan gelembung gas hydrogen semasa elektrolisis.
Nyatakan bagaimana untuk mengenal pasto gas hydrogen yang di hasilkan.

……………………………………………………………………………………………..

……………………………………………………………………………………………..

………………………………………………………………………………………… …..
[2 marks]
(g) State one usage of electrolysis in our daily life.
Nyatakan satu kegunaan elektrolisis di dalam kehidupan seharian.

……………………………………………………………………………………………...
[ 1 mark]

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Section B
[20 marks]
Answer any one question.
Jawab mana-mana satu soalan daripada bahagian ini.

9. (a) Diagram 7 shows a methane cycle.


Rajah 7 menunjukkan kitaran metana.

CH4 CO2

Diagram 7

Methane, CH4 is formed as an end product of an anaerobic decay of cow dung.


Describe how methane, CH4 is formed in terms of chemical bonding.
Metana, CH4 terbentuk sebagai hasil akhir bagi pereputan anaerobik tinja
lembu. Huraikan bagaimana sebatian CH4 terbentuk dari segi ikatan kimia.
[7 marks]

(b) Calcium chloride is used as an additive to fire extinguishers. Describe how


compound calcium chloride is formed in terms of chemical bonding.
Kalsium klorida digunakan sebagai bahan tambah dalam alat pemadam api .
Huraikan bagaimana sebatian kalsium klorida terbentuk dari segi ikatan kimia.
[7 marks]

(c) Compare two physical properties of methane and calcium chloride. Explain your
answer.
Bandingkan dua sifat fizikal metana dan kalsium klorida. Jelaskan jawapan anda.
[6 marks]

10. (a) Table 4.1 show the chemical equation of two reactions.
Jadual 4.1 menunjukkan persamaan kimia bagi dua tindak balas.

Reaction Chemical equation


Tindak balas Persamaan kimia

X NaOH + HCl → NaCl + H2O

Y Zn + Cu(NO3)2 → Zn(NO3)2 + Cu
Table 4.1

Determine whether each of the reactions is a redox reaction or not a redox reaction. Explain your

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answer in term of oxidation number.

Tentukan sama ada setiap tindak balas tersebut merupakan tindak balas redoks atau bukan tindak
balas redoks. Terangkan jawapan anda dari segi nombor pengoksidaan.
[5 marks]
(b) Table 4.2 shows the formulae for two chlorides of iron compounds.
Jadual 4.2 menunjukkan formula dua sebatian klorida bagi ferum.

Compound
Formula
Sebatian
R FeCl2

S FeCl3

Table 4.2
(i) Determine the oxidation number of iron in both compounds and name the compounds
based on IUPAC nomenclature.
Tentukan nombor pengoksidaan bagi ferum dalam kedua-dua sebatian dan namakan
sebatian-sebatian tersebut berdasarkan penamaan IUPAC.
[4 marks]
(ii) Compound R can be converted to compound S in the presence of an oxidising agent.
Suggest the oxidising agent and state one observation for the reaction.
Sebatian R boleh ditukarkan kepada sebatian S dengan kehadiran satu agen
pengoksidaan. Cadangkan agen pengoksidaan tersebut dan nyatakan satu pemerhatian
bagi tindak balas yang berlaku.
[2 marks]

(c) A chemical cell can be constructed by combining two half cells with different E0 values. Diagram 7
below shows a chemical cell where silver metal and iron metal are used as electrodes, which are
dipped into their respective ionic salt solutions. Both salt solutions are connected by a salt bridge.
Sel kimia boleh dibina dengan mennggabungkan dua setengah cell dengan nilai E0 yang berbeza.
Rajah 7 dibawah menunjukkan sel kimia dimana logam argentum dan logam ferum digunakan
sebagai elektrod dan dicelup kedalam larutan garam masing-masing. Larutan garam tersebut
dihubungkan dengan jambatan garam.

Diagram 7
You are provided with the following standard electrode potential:
Anda diberikan nilai electrod piawai berikut:
Ag + (aq) + e-  Ag (s) E0 = + 0.80V

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Fe2+ + 2e-  Fe (s) E0 = -0.44V


(i) What is the function of salt bridge?
Apakah fungsi titian garam?

(ii) State the products formed at the negative terminal and positive terminal. Explain
your answer. In your answer, include half equations.
Nyatakan hasil yang terbentuk di terminal negatif dan terminal positif. Terangkan
jawapan anda. Sertakan persamaan setengah.

(iv) write the cell notation for the cell and calculate the voltage of the cell.
Tuliskan notasi sel dan kirakan nilai voltan cell.
[9 marks]

Section C
[20 marks]
Answer all the questions from this section.
11 A house wife`s discovered that the cake she bake did not rise.
Seorang suri rumah mendapati kek yang dibakarnya tidak naik.

A farmer discovered that plants in his farm not growth well.


Seorang petani mendapati tanaman dalam kebunnya tidak membesar dengan
baik.
(a) Suggest how they can overcome these problems. Give a reason.
Cadangkan bagaimana mereka boleh mengatasi masalah-masalah tersebut. Beri satu
sebab.
[4 marks]

(b) Diagram 8 shows a series of reaction starting from Salt P.


Rajah 9 menunjukkan satu siri tindak balas bermula daripada garam P.

Salt P Heated Residue X Gas Y


+
Garam P Dipanaskan Baki X
Gas Y

+ Acid M

+ Asid M

Lead(II) nitrate
Plumbum(II) nitrat

Diagram 8
(i) Based on Diagram 8 :

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 Identify salt P, residue X, gas Y and acid M.


 Write the chemical equation for the reaction between residue X and acid M.
Berdasarkan Rajah 8 :
 Kenal pasti garam P, baki X, gas Y dan asid M.
 Tulis persamaan kimia bagi tindak balas antara baki X dan asid M.
[6 marks]
(c) Barium sulphate can be prepared by double decomposition reaction using salt A and salt
B solution. Both salts are soluble. Suggest salt A and B.
Describe preparation of barium sulphate salt by using salts that you have stated and then
write chemical equation involved.
Barium sulfat boleh disediakan melalui tindak balas penguraian ganda dua
menggunakan larutan garam A dan larutan garam B. Kedua-dua larutan garam ini
merupakan garam terlarutkan. Cadangkan garam A dan garam B.
Huraikan penyediaan garam Barium sulfat dengan menggunakan garam-garam yang
anda nyatakan seterusnya tuliskan persamaan kimia yang terlibat.
[10 marks]

END OF QUESTION PAPER


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