Q1 At a certain temperature 2 moles of carbonmonoxide and 3 moles of chlorine were allowed to reach

equilibrium according to the reaction CO + Cl 2 —> COCl2 in a 5 lit vessel. At equilibrium if one mole of CO
is present then equilibrium constant for the reaction is:

                   (A) 2                                                         (B) 2.5

                   (C) 3.0                                                      (D) 4

Q2

Q3 The vapour density of undecomposed N 2O4 is 46. When heated, vapour density decreases to 24.5
due to its dissociation to NO2. The % dissociation of N2O4 at the final temperature is
                   (A) 80        (B)       60
                   (C) 40        (D)       70

Q4 If CuSO4.5H2O(s) CuSO4.3H2O(s) + 2H2O(l) Kp = 1.086 × 0 10–4 atm2 at 25°C. The efflorescent nature
of CuSO4.5H2O can be noticed when vapour pressure of H2O in atmosphere is

                   (A) > 7.29 mm     (B)       < 7.92 mm

                   (C) > 7.92 mm     (D)       None

Q5 At what molar concentration of HCI will its aqueous solution have an [H+] to which equal
contribution come from HCI and H2O at 900C.
[Kw of H2O = 10–12M2 at 900C]

(A) √50 × 10–8                                                                  (B) √40 × 10–7 M

(C) √50 × 10–7                                                                 (D) √30 × 10–7

Q6. STATEMENT-1 : A bowler bowling the last crucial over in an India – Pakistan 20-20 match
breathes heavily due to excitement and tension, leading to significant change in the pH of blood.
because
STATEMENT-2 : pH of blood = pKa + log [HCO3- ]/[H2 CO3 ]

(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-
1.
(B) Statement-1 is True, Statement-2 is True; statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

Q7 STATEMENT-1 : Le Chatliers principle is not applicable to Fe(s) + S(s) ⇌ FeS(s)

STATEMTN-2 : Le Chatliers principle aims to push the reaction into stress – free environment.
(A) Statement-1 is True, statement-2 is True; Statement-2 is a correct explanation for Statement-
1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, statement-2 is True.

Q Paragraph for Question Nos. 8 to 10

The pH value for pure water is 7.0 at 270C, where natural rain water is slightly acidic. This is mainly due
to presence of CO2 in atmosphere. In many cases, however rain water is more acidic due to presence of
SO3 and NO2 gas obtained by oxidation of SO2 & NO gas. In some cases acid rain due to SO 3 and NO2
consist of pH of 4.5 to a value as low as 1.7 at 27 0C the acidity constants are

8. The pH of 0.01 M aqueous solution of Na 2SO3 will be

(A) 8.5                                                                   (B) 9
(C) 9.25                                                                (D) 9.5

9. If rain water consists of 2.463 litre SO 3 gas dissolved in 1 litre water at partial pressure of 2 atm, then
pH of solution is
(R = 0.0821 litre atm/K mole) (log2 = 0.3)
(A) 0.7                                                                 (B) 1.4
(C) 0.6                                                                (D) 0.4

10. If acid rain in Assam it was found that 1 litre rain water consist of 2.463 litre equimolar mixture of
SO3 and NO2 gas dissolved at a partial pressure of 0.1 atm. Find out the pH of the solution if HNO 2
produced is 60% dissociated under given condition at 27 0C. (R = 0.0821 litre atm/mole K) (log 1.8 = 0.25)
(A) 2                                                                 (B) 2.75
(C) 2.25                                                           (D) 1.75
11.

12

13

14

QUESTION paragraph for questions 15to 17

Q18. 50 ml of solution of pH = 1 is mixed With 50 ml of solution PH =2 the pH of mixture is
A)2 B)1.74 C)1.28 D)0

Q19 Molarity of H+ in the solution formed by mixing a (1000 ml of 0.5 molar HCL) ,( 500 ml of 0.1 molar
NaOH) and 250 ml of 0.2 molar Ca(OH)2 is ?
A ) 0.2 M B) 0.8 M C) 0.5M D)0.3M

Q20) MATRIX TYPE

Q21 . The solubility product of MI is 10 -6( conc are expressed in moles\kg) what is solubility of MI in 0.1
M (KI solution)
A)10-5 B)10-4 C)10-6 D)10-3 units (mole\kg)

Q22. a system at 273 k absorbs 1200J heat as a result its volume as well as temperature become double
.the work done by system on surrounding is 800J then change in internal energy for the process is
A)+400 J B)-400 j C)+2000J D)-2000J